scholarly journals EFFECT OF TIO2 NANOPARTICLES IN NI MATRIX ON MECHANICAL AND CORROSION RESISTANCE PROPERTIES

2017 ◽  
Vol 23 (1) ◽  
pp. 37 ◽  
Author(s):  
Amer Mekkaoui ◽  
Shahnez Saied ◽  
Okba Belahssen ◽  
Abdelouahed Chala

<p class="AMSmaintext">Nickel (Ni) is one of the most important hard coatings. Improvement in its tribological and mechanical properties would greatly enhance its use in industry. Nanocomposite coatings of metals with various reinforced nanoparticles have been developed in last few decades. Titania (TiO<sub>2</sub>) exhibit excellent mechanical properties. It is believed that TiO<sub>2</sub> incorporation in Ni matrix will improve the properties of Ni coatings significantly. The main purpose of the current work is to investigate the mechanical and anti-corrosion properties of the electroplated Nickel nanocomposite with a different percentage of TiO<sub>2</sub>. The results showed that the content of TiO<sub>2</sub> and the microhardness in the Ni-TiO<sub>2</sub> coatings first increased and reached the maximum at the loading of 20 g/L, then decreased, due to agglomeration of dioxide of Titania for high concentration of TiO<sub>2</sub>. The [200] preferred orientation for Ni pure gradually evolved to [111] orientation with increasing TiO<sub>2</sub> nanoparticle loading. At 20 g/L of TiO<sub>2</sub> we obtained the minimum crystallite size (27 nm). The anti-corrosion property of nanocomposite coating was carried out in 3.5 % NaCl solution and the result also showed that the nanocomposite coatings improve the corrosion resistance significantly. This present work reveals that incorporation of TiO<sub>2</sub> in nickel nanocomposite coating can improved corrosion resistance and mechanical properties of both hardness and corrosion resistance performances, and the improvement becomes at it maximum for 20 g/L of TiO<sub>2</sub>.</p>

Metals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 167 ◽  
Author(s):  
Omid Khalaj ◽  
Ehsan Saebnoori ◽  
Hana Jirková ◽  
Ondřej Chocholatý ◽  
Jiří Svoboda

Fe–Al–O-based materials are currently undergoing a great deal of development because of their many special properties. However, lack of strength at high temperatures, limited ductility at ambient temperatures and corrosion resistance have hindered a wider application of these materials. Recently, a new Fe–Al-based oxide precipitation hardened (OPH) steel was developed by the authors to improve the mechanical properties and oxidation resistance. The new OPH alloys are produced by dissolving a specific amount of oxygen in the matrix during mechanical alloying followed by precipitation of fine dispersion of aluminum or yttrium oxides during hot consolidation. A series of tests was performed to evaluate the thermomechanical properties and corrosion resistance in a 3.5% NaCl solution. The results show improved corrosion resistance, as well as mechanical properties, while the production costs of this material are lower than for traditional materials.


2006 ◽  
Vol 13 (04) ◽  
pp. 489-494 ◽  
Author(s):  
YINGWU YAO ◽  
SUWEI YAO ◽  
LU ZHANG

Ni–W/SiC nanocomposite coatings were prepared by electrodeposition in Ni–W plating bath containing SiC nanoparticulates. The effect of incorporation of SiC particulates into the Ni–W matrix on the morphology of the coating surface and corrosion properties was investigated. Scanning electron microscopy (SEM) showed that the SiC nanoparticulates are uniformly distributed in the Ni–W matrix. Corrosion tests were performed in 0.5 M NaCl solution using electrochemical measurements for Ni–W alloy coating and Ni–W/SiC nanocomposite coating. The results showed that the co-deposition of SiC nanoparticulates in the composite coatings increased the corrosion resistance. At last, the anti-corrosion mechanism of the nanocomposite coatings is also discussed.


2021 ◽  
Vol 104 (2) ◽  
pp. 003685042110294
Author(s):  
Khaled Abd El-Aziz ◽  
Emad M Ahmed ◽  
Abdulaziz H Alghtani ◽  
Bassem F Felemban ◽  
Hafiz T Ali ◽  
...  

Aluminum alloys are the most essential part of all shaped castings manufactured, mainly in the automotive, food industry, and structural applications. There is little consensus as to the precise relationship between grain size after grain refinement and corrosion resistance; conflicting conclusions have been published showing that reduced grain size can decrease or increase corrosion resistance. The effect of Al–5Ti–1B grain refiner (GR alloy) with different percentages on the mechanical properties and corrosion behavior of Aluminum-magnesium-silicon alloy (Al–Mg–Si) was studied. The average grain size is determined according to the E112ASTM standard. The compressive test specimens were made as per ASTM: E8/E8M-16 standard to get their compressive properties. The bulk hardness using Vickers hardness testing machine at a load of 50 g. Electrochemical corrosion tests were carried out in 3.5 % NaCl solution using Autolab Potentiostat/Galvanostat (PGSTAT 30).The grain size of the Al–Mg–Si alloy was reduced from 82 to 46 µm by the addition of GR alloy. The morphology of α-Al dendrites changes from coarse dendritic structure to fine equiaxed grains due to the addition of GR alloy and segregation of Ti, which controls the growth of primary α-Al. In addition, the mechanical properties of the Al–Mg–Si alloy were improved by GR alloy addition. GR alloy addition to Al–Mg–Si alloy produced fine-grained structure and better hardness and compressive strength. The addition of GR alloy did not reveal any marked improvements in the corrosion properties of Al–Mg–Si alloy.


2012 ◽  
Vol 548 ◽  
pp. 101-104 ◽  
Author(s):  
W. Shao ◽  
D. Nabb ◽  
N. Renevier ◽  
I. Sherrington ◽  
J.K. Luo

Ni-carbon nanotubes nanocomposite coatings were obtained from a Watts bath containing uniformly dispersed carbon nanotubes (CNTs). The surface morphology was investigated by the SEM images of coatings. The mechanical property and corrosion resistance of the nanocomposite coatings were investigated. This study revealed these CNTs reinforced Ni nanocoatings have improved mechanical and corrosion property.


2020 ◽  
Vol 62 (4) ◽  
pp. 395-399
Author(s):  
Jiehui Liu ◽  
Hongjun Hu ◽  
Yang Liu ◽  
Dingfei Zhang ◽  
Zhongwen Ou ◽  
...  

Abstract Compound extrusion (CE) is a newly developed plastic deformation technique which combines direct extrusion (DE) with a two-pass equal channel angular extrusion (ECAE). This paper focuses on the strength, ductility and anti-corrosion properties of an NaCl solution at certain concentrations and the wear-resistance of dry sliding AZ61 magnesium alloy prepared by CE and DE. It is found that the strength and elongation of the AZ61 alloy prepared by CE are enhanced because of grain refinement. Furthermore, AZ61 magnesium alloy made by CE displays higher corrosion and wear resistance than that prepared by DE. Experimental results prove that CE is a prospective manufacturing method for improving the mechanical properties, anti-corrosion and anti-wear of AZ61 magnesium alloy.


2017 ◽  
Vol 11 (2) ◽  
pp. 91-95 ◽  
Author(s):  
Eliza Romańczuk ◽  
Zbigniew Oksiuta

AbstractIn this work two austenitic stainless steels, REX734 and 316LV were tested in terms of their microstructure and corrosion properties. The REX734 is a newer generation stainless steel, with modified chemical composition, in comparison to the 316LV grade. Potentiodynamic study of corrosion resistance was conducted in physiological saline solution (0.9% NaCl solution). In spite of the similarities of microstructure, grain size and phase structure in both materials, the corrosion tests revealed that the REX734, with lower nickel and higher nitrogen content, had better corrosion resistance than 316LV. Repassivation potential in the REX734 was almost six times higher than for the 316LV steel. Superior corrosion resistance of the REX734 steel was also confirmed by surface observations of both materials, since bigger and more densely distributed pits were detected in 316LV alloy.


2019 ◽  
Vol 33 (01n03) ◽  
pp. 1940019 ◽  
Author(s):  
Weihui Zhang ◽  
Di Cao ◽  
Yanxin Qiao ◽  
Yuxin Wang ◽  
Xiang Li ◽  
...  

Duplex Ni-P-TiO2/Ni coatings were deposited on the brass substrate by using two baths. Ni-P-TiO2 nanocomposite coatings were electroplated as the outer layer on the Ni-plated brass substrate by adding transparent TiO2 sol (0–50 mL/L) into the Ni-P plating solution. The microstructure, mechanical property and corrosion resistance of the duplex Ni-P-TiO2/Ni nanocomposite coatings were systemically investigated. The results show that the interface of duplex coating was uniform and the adhesion between two layers was extremely good. The microhardness of duplex Ni-P-12.5 mL/L TiO2 /Ni coating was [Formula: see text]616 HV[Formula: see text] compared to [Formula: see text]539 HV[Formula: see text] of Ni-P /Ni coating and [Formula: see text]307 HV[Formula: see text] of single Ni coating. Meanwhile, the wear resistance and the corrosion resistance of the duplex nanocomposite coating have also been improved remarkably compared with single Ni coating. However, adding excessive TiO2 sol (more than 12.5 mL/L) caused the agglomeration of TiO2 nanoparticles and led to a porous structure in the outer layer, resulting in the deterioration of coating properties.


RSC Advances ◽  
2017 ◽  
Vol 7 (13) ◽  
pp. 7531-7539 ◽  
Author(s):  
Cong-cong Jiang ◽  
Yan-ke Cao ◽  
Gui-yong Xiao ◽  
Rui-fu Zhu ◽  
Yu-peng Lu

Nanocomposite coatings obtained by the controlled addition of inorganic nanoparticles into the treatment baths not only improve the corrosion resistance and mechanical properties, but also enhance the functional properties.


2008 ◽  
Vol 591-593 ◽  
pp. 860-864 ◽  
Author(s):  
Leszek Adam Dobrzański ◽  
Krzysztof Lukaszkowicz

The properties of thin hard coatings and consequently their functionality are influenced by microstructural characteristics such as mechanical properties. A variety of interlayers has been used in hybrid coatings for various purposes. The paper presents investigation results of the structure, erosion and corrosion resistance, and mechanical properties of the galvanic Ni/Cr, hybrid Ni/Cr + Zr/ZrN (galvanic + PVD) and monolithic nitride coatings deposited by PVD technique (dc magnetron sputtering) onto brass (CuZn40Pb2) substrates. The ceramic PVD coatings or layers are the Cr-, Ti-, TiAl-, Zr-nitrides. The investigation covered the metallographic analysis on the scanning electron microscope, mechanical properties and erosion test. The corrosion tests were made in a 1 M NaOH solution. It was found out that PVD coatings display high corrosion resistance.


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