scholarly journals On the effects of flow pulsation upon the performance of flow deflector for catalytic converter

2017 ◽  
Vol 4 (6) ◽  
pp. 16-00665-16-00665
Author(s):  
Katsuya HIRATA ◽  
Shinya TANAKA ◽  
Masaya OTA ◽  
Taishi INOUE ◽  
Tomohiro OZAKI ◽  
...  
Author(s):  
K Hirata ◽  
R Oda ◽  
S Tanaka ◽  
H Tanigawa ◽  
J Funaki

In automobile exhaust systems, catalytic converters have become essential in reducing environmental pollution. However, the main components of catalytic converters produce large pressure drops in exhaust systems, which decrease engine power and increase fuel consumption. In addition to the need to reduce pressure loss, the flow passing through the catalytic substrate strate should be as uniform as possible, which provides a uniform thermal distribution and high catalytic conversion efficiency. The goal of the present study is simultaneously to reduce the pressure loss and to improve the flow distribution under spatial constraints. The authors herein propose new types of device and investigate their performances experimentally. Specifically, the possibilities of two types of flow deflector with a shell structure, which are placed inside the diffuser part of the catalytic converter in order to reduce flow separation, were investigated. In addition, using the particle image velocimetry technique and Pitot tube velocimetry, flow features such as the velocity profiles were elucidated. The tested converter has a standard cylindrical ceramic monolith substrate with channels of square cross-section. As a result, the two flow deflectors can reduce the pressure loss by 17 per cent and 22 per cent, compared with a no-deflector converter and can effectively improve the velocity profile.


Author(s):  
L.D. Schmidt ◽  
K. R. Krause ◽  
J. M. Schwartz ◽  
X. Chu

The evolution of microstructures of 10- to 100-Å diameter particles of Rh and Pt on SiO2 and Al2O3 following treatment in reducing, oxidizing, and reacting conditions have been characterized by TEM. We are able to transfer particles repeatedly between microscope and a reactor furnace so that the structural evolution of single particles can be examined following treatments in gases at atmospheric pressure. We are especially interested in the role of Ce additives on noble metals such as Pt and Rh. These systems are crucial in the automotive catalytic converter, and rare earths can significantly modify catalytic properties in many reactions. In particular, we are concerned with the oxidation state of Ce and its role in formation of mixed oxides with metals or with the support. For this we employ EELS in TEM, a technique uniquely suited to detect chemical shifts with ∼30Å resolution.


Author(s):  
Jan-Olle Malm ◽  
Jan-Olov Bovin

Understanding of catalytic processes requires detailed knowledge of the catalyst. As heterogeneous catalysis is a surface phenomena the understanding of the atomic surface structure of both the active material and the support material is of utmost importance. This work is a high resolution electron microscopy (HREM) study of different phases found in a used automobile catalytic converter.The high resolution micrographs were obtained with a JEM-4000EX working with a structural resolution better than 0.17 nm and equipped with a Gatan 622 TV-camera with an image intensifier. Some work (e.g. EDS-analysis and diffraction) was done with a JEM-2000FX equipped with a Link AN10000 EDX spectrometer. The catalytic converter in this study has been used under normal driving conditions for several years and has also been poisoned by using leaded fuel. To prepare the sample, parts of the monolith were crushed, dispersed in methanol and a drop of the dispersion was placed on the holey carbon grid.


Author(s):  
M. Assad ◽  
V. V. Grushevski ◽  
O. G. Penyazkov ◽  
I. N. Tarasenko

The concentration of 16 polycyclic aromatic hydrocarbons (PAHs) in the gasoline combustion products emitted into the atmosphere by internal combustion engines (ICE) has been measured using the gas chromatography method. The concentrations of PAHs in the exhaust gases sampled behind a catalytic converter has been determined when the ICE operates in five modes: idle mode, high speed mode, load mode, ICE cold start mode (engine warm-up) and transient mode. Using 92 RON, 95 RON and 98 RON gasoline the effect of the octane number of gasoline on the PAHs content in the exhaust gases has been revealed. The concentration of the most carcinogenic component (benzo(α)pyrene) in the exhaust gases behind a catalytic converter significantly exceeds a reference value of benzo(α)pyrene in the atmospheric air established by the WHO and the EU for ICE in the load mode.


2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Sreeharsh Nair ◽  
Mayank Mittal

AbstractThe advent of stricter emission standards has increased the importance of aftertreatment devices and the role of numerical simulations in the evolution of better catalytic converters in order to satisfy these emission regulations. In this paper, a 2-D numerical simulation of a single channel of the monolith catalytic converter is presented by using detailed surface reaction kinetics aiming to investigate the chemical behaviour inside the converter. The model has been developed to study the conversion of carbon monoxide (CO) in the presence of propene (C3H6) for low-temperature combustion (LTC) engine application. The inhibition effect of C3H6 over a wide range of CO inlet concentrations is investigated. Considering both low and high levels of CO concentration at the inlet, the 2-D model predicted better results than their corresponding 1-D counterparts when compared with the experimental data from literature. It was also observed that C3H6 inhibition at high temperatures was significant, particularly for high concentrations of CO compared to low concentrations of CO at the inlet.


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