Comparison of RZWQM2 and DNDC Models to Simulate Greenhouse Gas Emissions under Combined Inorganic/Organic Fertilization in a Subsurface-Drained Field

2020 ◽  
Vol 63 (4) ◽  
pp. 771-787
Author(s):  
Qianjing Jiang ◽  
Zhiming Qi ◽  
Chandra A. Madramootoo ◽  
Ward Smith ◽  
Naeem A. Abbasi ◽  
...  

HighlightsRZWQM2 was compared with DNDC to predict greenhouse gas emissions.RZWQM2 was applied to simulate the greenhouse gas emissions under manure application.RZWQM2 performed better than DNDC in simulating soil water content and CO2 emissions.Abstract. N management has the potential to mitigate greenhouse gas (GHG) emissions. Process-based models are promising tools for evaluating and developing management practices that may optimize sustainability goals as well as promote crop productivity. In this study, the GHG emission component of the Root Zone Water Quality Model (RZWQM2) was tested under two different types of N management and subsequently compared with the Denitrification-Decomposition (DNDC) model using measured data from a subsurface-drained field with a corn-soybean rotation in southern Ontario, Canada. Field-measured data included N2O and CO2 fluxes, soil temperature, and soil moisture content from a four-year field experiment (2012 to 2015). The experiment was composed of two N treatments: inorganic fertilizer (IF), and inorganic fertilizer combined with solid cattle manure (SCM). Both models were calibrated using the data from IF and validated with SCM. Statistical results indicated that both models predicted well the soil temperature, but RZWQM2 performed better than DNDC in simulating soil water content (SWC) because DNDC lacked a heterogeneous soil profile, had shallow simulation depth, and lacked crop root density functions. Both RZWQM2 and DNDC predicted the cumulative N2O and CO2 emissions within 15% error under all treatments, while the timing of daily CO2 emissions was more accurately predicted by RZWQM2 (RMSE = 0.43 to 0.54) than by DNDC (RMSE = 0.60 to 0.67). Modeling results for N management effects on GHG emissions showed consistency with the field measurements, indicating higher CO2 emissions under SCM than IF, higher N2O emissions under IF in corn years, but lower N2O emissions in soybean years. Overall, RZWQM2 required more experienced and intensive calibration and validation, but it provided more accurate predictions of soil hydrology and better timing of CO2 emissions than DNDC. Keywords: CO2 emission, Corn-soybean rotation, Inorganic fertilization, Manure application, N2O emission, Process-based modeling.

2021 ◽  
Author(s):  
Ain Kull ◽  
Iuliia Burdun ◽  
Gert Veber ◽  
Oleksandr Karasov ◽  
Martin Maddison ◽  
...  

<p>Besides water table depth, soil temperature is one of the main drivers of greenhouse gas (GHG) emissions in intact and managed peatlands. In this work, we evaluate the performance of remotely sensed land surface temperature (LST) as a proxy of greenhouse gas emissions in intact, drained and extracted peatlands. For this, we used chamber-measured carbon dioxide (CO<sub>2</sub>) and methane (CH<sub>4</sub>) data from seven peatlands in Estonia collected during vegetation season in 2017–2020. Additionally, we used temperature and water table depth data measured in situ. We studied relationships between CO<sub>2</sub>, CH<sub>4</sub>, in-situ parameters and remotely sensed LST from Landsat 7 and 8, and MODIS Terra. Results of our study suggest that LST has stronger relationships with surface and soil temperature as well as with ecosystem respiration (R<sub>eco</sub>) over drained and extracted sites than over intact ones. Over the extracted cites the correlation between R<sub>eco</sub> CO<sub>2</sub> and LST is 0.7, and over the drained sites correlation is 0.5. In natural sites, we revealed a moderate positive relationship between LST and CO<sub>2</sub> emitted in hollows (correlation is 0.6) while it is weak in hummocks (correlation is 0.3). Our study contributes to the better understanding of relationships between greenhouse gas emissions and their remotely sensed proxies over peatlands with different management status and enables better spatial assessment of GHG emissions in drainage affected northern temperate peatlands.</p>


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Xue Hao ◽  
Yu Ruihong ◽  
Zhang Zhuangzhuang ◽  
Qi Zhen ◽  
Lu Xixi ◽  
...  

AbstractGreenhouse gas (GHG) emissions from rivers and lakes have been shown to significantly contribute to global carbon and nitrogen cycling. In spatiotemporal-variable and human-impacted rivers in the grassland region, simultaneous carbon dioxide, methane and nitrous oxide emissions and their relationships under the different land use types are poorly documented. This research estimated greenhouse gas (CO2, CH4, N2O) emissions in the Xilin River of Inner Mongolia of China using direct measurements from 18 field campaigns under seven land use type (such as swamp, sand land, grassland, pond, reservoir, lake, waste water) conducted in 2018. The results showed that CO2 emissions were higher in June and August, mainly affected by pH and DO. Emissions of CH4 and N2O were higher in October, which were influenced by TN and TP. According to global warming potential, CO2 emissions accounted for 63.35% of the three GHG emissions, and CH4 and N2O emissions accounted for 35.98% and 0.66% in the Xilin river, respectively. Under the influence of different degrees of human-impact, the amount of CO2 emissions in the sand land type was very high, however, CH4 emissions and N2O emissions were very high in the artificial pond and the wastewater, respectively. For natural river, the greenhouse gas emissions from the reservoir and sand land were both low. The Xilin river was observed to be a source of carbon dioxide and methane, and the lake was a sink for nitrous oxide.


Energies ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 5664
Author(s):  
Wenjing Wei ◽  
Peter B. Samuelsson ◽  
Anders Tilliander ◽  
Rutger Gyllenram ◽  
Pär G. Jönsson

The primary energy consumption and greenhouse gas emissions from nickel smelting products have been assessed through case studies using a process model based on mass and energy balance. The required primary energy for producing nickel metal, nickel oxide, ferronickel, and nickel pig iron is 174 GJ/t alloy (174 GJ/t contained Ni), 369 GJ/t alloy (485 GJ/t contained Ni), 110 GJ/t alloy (309 GJ/t contained Ni), and 60 GJ/t alloy (598 GJ/t contained Ni), respectively. Furthermore, the associated GHG emissions are 14 tCO2-eq/t alloy (14 tCO2-eq/t contained Ni), 30 t CO2-eq/t alloy (40 t CO2-eq/t contained Ni), 6 t CO2-eq/t alloy (18 t CO2-eq/t contained Ni), and 7 t CO2-eq/t alloy (69 t CO2-eq/t contained Ni). A possible carbon emission reduction can be observed by comparing ore type, ore grade, and electricity source, as well as allocation strategy. The suggested process model overcomes the limitation of a conventional life cycle assessment study which considers the process as a ‘black box’ and allows for an identification of further possibilities to implement sustainable nickel production.


2020 ◽  
Author(s):  
Theresa Klausner ◽  
Mariano Mertens ◽  
Heidi Huntrieser ◽  
Michal Galkowski ◽  
Gerrit Kuhlmann ◽  
...  

<p>Urban areas are recognised as a significant source of greenhouse gas emissions (GHG), such as carbon dioxide (CO<sub>2</sub>) and methane (CH<sub>4</sub>). The total amount of urban GHG emissions, especially for CH<sub>4</sub>, however, is not well quantified. Here we report on airborne in situ measurements using a Picarro G1301-m analyser aboard the DLR Cessna Grand Caravan to study GHG emissions downwind of the German capital city Berlin. In total, five aircraft-based mass balance experiments were conducted in July 2018 within the Urban Climate Under Change [UC]<sup>2</sup> project. The detection and isolation of the Berlin plume was often challenging because of comparatively small GHG signals above variable atmospheric background concentrations. However, on July 20<sup>th</sup> enhancements of up to 4 ppm CO<sub>2</sub> and 21 ppb CH<sub>4</sub> were observed over a horizontal extent of roughly 45 to 65 km downwind of Berlin. These enhanced mixing ratios are clearly distinguishable from the background and can partly be assigned to city emissions. The estimated CO<sub>2</sub> emission flux of 1.39 ± 0.75 t s<sup>-1 </sup>is in agreement with current inventories, while the CH<sub>4</sub> emission flux of 5.20 ± 1.61 kg s<sup>-1</sup> is almost two times larger than the highest reported value in the inventories. We localized the source area with HYSPLIT trajectory calculations and the high resolution numerical model MECO(n) (down to ~1 km), and investigated the contribution from sewage-treatment plants and waste deposition to CH<sub>4</sub>, which are treated differently by the emission inventories. Our work highlights the importance of a) strong CH<sub>4</sub> sources in the surroundings of Berlin and b) a detailed knowledge of GHG inflow mixing ratios to suitably estimate emission rates.</p>


2020 ◽  
Vol 10 (15) ◽  
pp. 5056
Author(s):  
Cevat Yaman

This study investigated the biomedical waste collection, transportation, and treatment activities in the city of Kocaeli, Turkey. As an alternative to incineration technology, a steam autoclave was used to sterilize the biomedical waste. Information regarding the collection, transportation, treatment and associated greenhouse gas emissions (GHG) were also investigated. Prior to sterilization, biological indicator vials containing Bacillus stearothermophilus were placed in the center of the load to ensure that the pathogens were destroyed. GHG emissions were calculated based on the fuel consumed by the biomedical waste collection vehicles and the electricity/natural gas used at the sterilization plant. Results of this work revealed that the total biomedical waste generated per year increased from 1362 tons in 2009 to 2375 tons in 2019. The amount of biomedical waste generated per hospital bed was determined as 1.19 kg.bed−1.day−1. Results show that for efficient sterilization of biomedical wastes, the steam treatment system process should be operated at a contact time of 45 min, a temperature of 150 °C, and at a steam pressure of 5 bar. Biological indicator tests showed that the number of living Bacillus stearothermophilus decreased significantly, with removal rates greater than 6log10. Finally, it was determined that the biomedical waste management activities generated a total of GHG emissions of 5573 ton CO2 equivalency (tCO2-e) from 2009 to 2019. Furthermore, the average global warming factor (GWF) was calculated to be 0.269 tCO2-e per ton of biomedical waste generated. This study showed that the sterilization process is very effective in destroying the pathogens and the management of biomedical waste generates considerable amounts of GHG emissions.


2020 ◽  
Vol 12 (8) ◽  
pp. 3436 ◽  
Author(s):  
Qi Zhang ◽  
Jing Xiao ◽  
Jianhui Xue ◽  
Lang Zhang

Agricultural disturbance has significantly boosted soil greenhouse gas (GHG) emissions such as methane (CH4), carbon dioxide (CO2), and nitrous oxide (N2O). Biochar application is a potential option for regulating soil GHG emissions. However, the effects of biochar application on soil GHG emissions are variable among different environmental conditions. In this study, a dataset based on 129 published papers was used to quantify the effect sizes of biochar application on soil GHG emissions. Overall, biochar application significantly increased soil CH4 and CO2 emissions by an average of 15% and 16% but decreased soil N2O emissions by an average of 38%. The response ratio of biochar applications on soil GHG emissions was significantly different under various management strategies, biochar characteristics, and soil properties. The relative influence of biochar characteristics differed among soil GHG emissions, with the overall contribution of biochar characteristics to soil GHG emissions ranging from 29% (N2O) to 71% (CO2). Soil pH, the biochar C:N ratio, and the biochar application rate were the most influential variables on soil CH4, CO2, and N2O emissions, respectively. With biochar application, global warming potential (impact of the emission of different greenhouse gases on their radiative forcing by agricultural practices) and the intensity of greenhouse gas emissions (emission rate of a given pollutant relative to the intensity of a specific activity) significantly decreased, and crop yield greatly increased, with an average response ratio of 23%, 41%, and 21%, respectively. Our findings provide a scientific basis for reducing soil GHG emissions and increasing crop yield through biochar application.


2009 ◽  
Vol 55 (No. 8) ◽  
pp. 311-319 ◽  
Author(s):  
Z. Exnerová ◽  
E. Cienciala

As a part of its obligations under the Climate Convention, the Czech Republic must annually estimate and report its anthropogenic emissions of greenhouse gases. This also applies for the sector of agriculture, which is one of the greatest producers of methane and nitrous oxide emissions. This paper presents the approaches applied to estimate emissions in agricultural sector during the period 1990–2006. It describes the origin and sources of emissions, applied methodology, parameters and emission estimates for the sector of agriculture in the country. The total greenhouse gas emissions reached 7644 Gg CO<sub>2</sub> eq. in 2006. About 59% (4479 Gg CO<sub>2</sub> eq.) of these emissions has originated from agricultural soils. This quantity ranks agriculture as the third largest sector in the Czech Republic representing 5.3% of the total greenhouse gas emissions (GHG). The emissions under the Czech conditions consist mainly of emissions from enteric fermentation, manure management and agricultural soils. During the period 1990–2006, GHG emissions from agriculture decreased by 50%, which was linked to reduced cattle population and amount of applied fertilizers. The study concludes that the GHG emissions in the sector of agriculture remain significant and their proper assessment is required for sound climate change adaptation and mitigation policies.


2009 ◽  
Vol 20 (4) ◽  
pp. 533-551 ◽  
Author(s):  
R Saidur ◽  
MA Sattar ◽  
H.H. Masjuki ◽  
M.Y. Jamaluddin

This paper presents an analysis of the greenhouse gas (GHG) emissions from refrigeration equipment. The refrigeration equipments use refrigerants such as chlorofluorocarbons (CFCs) and hydrofluorocarbons HFCs, which are believed to contribute the ozone depletion and global warming. Refrigeration equipment thus contributes indirectly through emission due to electricity consumption and directly due to the emission of refrigerants. Greenhouse gas emissions resulting from the burning of fossil fuels are quantified and presented in this paper. The calculation was carried out based on emissions per unit electricity generated and the type of fuel used. The direct emission of refrigerant was calculated based on emission factor and according to the procedure of Environmental Protection Agency (EPA), USA. A study was conducted to evaluate the refrigerant losses to the atmosphere and the CO2 emission from fossil fuels to generate power to run the refrigeration and air-conditioning systems. In this paper, total appliance annual energy consumption by refrigerator-freezer and air conditioner as well as emission has been estimated for a period of 19 years (1997–2015) using the survey data. Energy savings and emission reductions achievable by raising thermostat set point temperature have been calculated for a period of 10 (i.e. 2005–2015) years.


2020 ◽  
Author(s):  
Matthias Kuhnert ◽  
Viktoria Oliver ◽  
Andrea Volante ◽  
Stefano Monaco ◽  
Yit Arn Teh ◽  
...  

&lt;p&gt;Rice cultivation has high water consumption and emits large quantities of greenhouse gases. Therefore, rice fields provide great potential to mitigate GHG emissions by modifications to cultivation practices or external inputs. Previous studies showed differences for impacts of alternated wetting and drying (AWD) practices for above-ground and below-ground biomass, which might have long term impacts on soil organic carbon stocks. The objective of this study is to parameterise and evaluate the model ECOSSE for rice simulations based on data from an Italian rice test site where the effects of different water management practices and 12 common European cultivars, on yield and GHG emissions, were investigated. Special focus is on the differences of the impacts on the greenhouse gas emissions for AWD and continuous flooding (CF). The model is calibrated and tested for field measurements and is used for model experiments to explore climate change impacts and long-term effects. Long term carbon storage is of particular interest since it is a suitable mitigation strategy. As experiments showed different impacts of management practices on the below ground biomass, long term model experiments are used to estimate impacts on SOC of the different practices. The measurements also allow an analysis of the impacts of different cultivars and the uncertainty of model approaches using a single data set for calibration.&lt;/p&gt;


2012 ◽  
Vol 616-618 ◽  
pp. 1148-1153
Author(s):  
Dong Sun ◽  
Chu Xia Tong

This paper attempts to discuss the embodied energy consumption and embodied greenhouse gas emissions in manufacturing industry. Based the on input-output theory, this paper establishes the calculation model, which gives the calculation of embodied energy consumption and embodied greenhouse gas emissions of 2002 and 2007 respectively. By comparison, it draws the conclusion that the total direct energy consumption of 2007 is much more than the year of 2002, while the total embodied energy consumption is less than the year of 2002. However, Non-metallic mineral products, Metal smelting and pressing and Electric equipment and machinery perform otherwise. The reason accounting for the calculation results is that the embodied energy intensity is greatly decreased.


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