scholarly journals Tin Doped Barium Titanate (BaTiO3) Synthesized through Molten Salt Method as Promising Dielectric Material

2021 ◽  
Vol 33 (9) ◽  
pp. 2212-2218
Author(s):  
Richa Tomar ◽  
Karan Surana ◽  
Pankaj Gupta ◽  
N.B. Singh
Keyword(s):  
Dielectric Constant ◽  
Barium Titanate ◽  
Dielectric Material ◽  
Transference Number ◽  
Molten Salt Method ◽  
Pxrd Pattern ◽  
X Ray ◽  
Ionic Transference Number ◽  
Doped Barium Titanate ◽  
High Dielectric

Tin doped barium titanate (BaTiO3) was prepared through NaCl-KCl eutectic melt at 800 ºC. The synthesized materials were well characterized using powder-X-ray diffraction (PXRD) and FESEM-EDX spectroscopy. Cubic structure was observed in the PXRD pattern of tin doped sample. The crystallite size of tin doped barium titanate nanoparticles was found to be around 17 nm. Nanorods and aggregated nanocubes like structure were observed in the FESEM images and elemental ratio of doped ions was confirmed by energy dispersive X-ray spectrum (EDX). Electrical properties observed for the synthesized material were found better than those reported in the literature prepared by other methods. The dielectric constant and dielectric loss were measured in the temperature range of 100-400 K and the frequencies varying from 10 kHz to 10,000 kHz. The tin doped barium titanate showed rod type morphology with an unprecedented high dielectric constant of ~17,500 at 10 Hz. Dielectric constant values decreased with increasing frequency. The change in dielectric constant with frequency was well explained by Maxwell-Wanger polarization effect. The impedance and ionic transference number (tion) were also measured.

scholarly journals Microstructure and Electrical Properties of Fluorene Polyester Based Nanocomposite Dielectrics

Polymers ◽  
2021 ◽  
Vol 13 (18) ◽  
pp. 3053
Author(s):  
Wenchao Zhang ◽  
Kuo Zhao ◽  
Feng Guan ◽  
Jinghua Yin ◽  
Yu Feng ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Breakdown Strength ◽  
Dielectric Material ◽  
Composite Films ◽  
High Strength ◽  
Sio2 Nanoparticles ◽  
X Ray ◽  
Low Dielectric ◽  
High Dielectric ◽  
Corona Resistance

As a new type of dielectric material, the low dielectric constant and corona resistance life of fluorene polyester (FPE) restricts the range of its applications. In order to simultaneously achieve a high dielectric constant and the long corona aging lifetime of FPE, SiO2 nanoparticles were chosen as additive to prepare FPE-based composite films. The microstructure of the composite film was characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD), infrared spectroscopy (IR) and small-angle X-ray scattering (SAXS). The dielectric performances of the composites, including the dielectric constant, breakdown strength and corona resistance lifetime, were investigated. The results show that the introduced SiO2 does not destroy the structure of the FPE molecular chain and that it increases the thickness of the filler-matrix interface. The dielectric constant of SiO2/FPE composites increased from 3.54 to 7.30 at 1 Hz. Importantly, the corona resistance lifetime increased by about 12 times compared with the pure FPE matrix. In brief, this work shows what possibilities there might be when considering the potential applications of high-strength insulating materials.

Review on Preparation and Properties of High-K Dielectric Material Based on Lanthanum Doped Barium Titanate

2015 ◽  
Vol 819 ◽  
pp. 173-178 ◽  
Author(s):  
Nur Farahin Abdul Hamid ◽  
Rozana A.M. Osman ◽  
Mohd Sobri Idris ◽  
Mohd Rosydi Zakaria
Keyword(s):  
Barium Titanate ◽  
Dielectric Material ◽  
Ferroelectric Properties ◽  
Dielectric Behavior ◽  
Relaxor Ferroelectric ◽  
Preparation Methods ◽  
High K ◽  
Doped Barium Titanate ◽  
High K Dielectric ◽  
High Dielectric

Lanthanum doped barium titanate (BaTiO3) were studied for high-K dielectric and exhibit a relaxor ferroelectric properties and it can be prepared by using various method. Relaxor ferroelectric offers a wide temperature and frequency range of application for materials with high dielectric constant for microelectronic application. This paper reviews the preparation methods, the important features, advantages and limitation for the lanthanum doped barium titanate. Thus, the phase purity and mixture selected also been review on the second part of the article. The article concludes with a brief discussion of the methods with good dielectric behavior. The objectives of this paper are to determine the selection of suitable preparation methods and the properties of the high-K dielectric based on pure barium titanate and lanthanum doped barium titanate.

Skin–core structured fluorinated MWCNTs: a nanofiller towards a broadband dielectric material with a high dielectric constant and low dielectric loss

2018 ◽  
Vol 6 (9) ◽  
pp. 2370-2378 ◽  
Author(s):  
Yang Liu ◽  
Cheng Zhang ◽  
Benyuan Huang ◽  
Xu Wang ◽  
Yulong Li ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Dielectric Loss ◽  
High Dielectric Constant ◽  
Dielectric Material ◽  
Epoxy Composite ◽  
Low Dielectric ◽  
High Dielectric

A novel skin–core structured fluorinated MWCNT nanofiller was prepared to fabricate epoxy composite with broadband high dielectric constant and low dielectric loss.

scholarly journals Improved electromechanical properties of brominated butyl rubber filled with modified barium titanate

RSC Advances ◽  
2017 ◽  
Vol 7 (59) ◽  
pp. 37148-37157 ◽  
Author(s):  
Mengnan Ruan ◽  
Dan Yang ◽  
Wenli Guo ◽  
Shuo Huang ◽  
Yibo Wu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Dielectric Constant ◽  
Barium Titanate ◽  
High Dielectric Constant ◽  
Dielectric Elastomer ◽  
Butyl Rubber ◽  
Electromechanical Properties ◽  
Brominated Butyl Rubber ◽  
High Dielectric

Barium titanate (BT) particles, BT-KH570 particles, and polar plasticizer tri-n-butyl phosphate (TBP) were added into BIIR matrix to form a dielectric elastomer composite, which had a high dielectric constant, good mechanical properties, and large actuated strain.

scholarly journals Polyarylene Ether Nitrile and Barium Titanate Nanocomposite Plasticized by Carboxylated Zinc Phthalocyanine Buffer

Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 418 ◽  
Author(s):  
Shuning Liu ◽  
Chenchen Liu ◽  
Changyu Liu ◽  
Ling Tu ◽  
Yong You ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Barium Titanate ◽  
Photoelectron Spectroscopy ◽  
Energy Dispersive Spectrometer ◽  
Composite Films ◽  
Zinc Phthalocyanine ◽  
Hydroxyl Groups ◽  
X Ray ◽  
Polyarylene Ether Nitrile ◽  
High Dielectric

Barium titanate (BT) and polyarylene ether nitrile (PEN) nanocomposites with enhanced dielectric properties were obtained by using carboxylatedzinc phthalocyanine (ZnPc-COOH) buffer as the plasticizer. Carboxylated zinc phthalocyanine, prepared through hydrolyzing ZnPc in NaOH solution, reacted with the hydroxyl groups on the peripheral of hydrogen peroxide treated BT (BT-OH) yielding core-shell structured BT@ZnPc. Thermogravimetric analysis (TGA), transmission electron microscopy (TEM), TEM energy dispersive spectrometer mapping, scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and Fourier transform infrared (FTIR) demonstrated successful preparation of BT@ZnPc. The fabricated BT@ZnPc was incorporated into the PEN matrix through the solution casting method. Rheological measurements demonstrated that the ZnPc-COOH buffer can improve the compatibility between BT and PEN effectively. With the existence of the ZnPc-COOH buffer, the prepared BT@ZnPc/PEN nanocomposites exhibit a high dielectric constant of 5.94 and low dielectric loss (0.016 at 1000 Hz). BT@ZnPc/PEN dielectric composite films can be easily prepared, presenting great application prospects in the field of organic film capacitors.

scholarly journals High-K dielectric sulfur-selenium alloys

2019 ◽  
Vol 5 (5) ◽  
pp. eaau9785 ◽  
Author(s):  
Sandhya Susarla ◽  
Thierry Tsafack ◽  
Peter Samora Owuor ◽  
Anand B. Puthirath ◽  
Jordan A. Hachtel ◽  
...  
Keyword(s):  
Dielectric Constant ◽  
Metal Oxides ◽  
High Dielectric Constant ◽  
Dielectric Material ◽  
Dielectric Strength ◽  
Dielectric Materials ◽  
High K ◽  
Device Applications ◽  
High K Dielectric ◽  
High Dielectric

Upcoming advancements in flexible technology require mechanically compliant dielectric materials. Current dielectrics have either high dielectric constant, K (e.g., metal oxides) or good flexibility (e.g., polymers). Here, we achieve a golden mean of these properties and obtain a lightweight, viscoelastic, high-K dielectric material by combining two nonpolar, brittle constituents, namely, sulfur (S) and selenium (Se). This S-Se alloy retains polymer-like mechanical flexibility along with a dielectric strength (40 kV/mm) and a high dielectric constant (K = 74 at 1 MHz) similar to those of established metal oxides. Our theoretical model suggests that the principal reason is the strong dipole moment generated due to the unique structural orientation between S and Se atoms. The S-Se alloys can bridge the chasm between mechanically soft and high-K dielectric materials toward several flexible device applications.

Development of Poly(dimethylsiloxane)/BaTiO3 Nanocomposites as Dielectric Material

2012 ◽  
Vol 622-623 ◽  
pp. 897-900 ◽  
Author(s):  
Suryakanta Nayak ◽  
Tapan Kumar Chaki ◽  
Dipak Khastgir
Keyword(s):  
Mechanical Properties ◽  
Dielectric Constant ◽  
Electron Microscope ◽  
Barium Titanate ◽  
Dielectric Material ◽  
Volume Resistivity ◽  
Filler Concentration ◽  
Base Matrix ◽  
Batio3 Nanoparticles ◽  
Scanning Electron

Polymer-ceramic nanocomposites with controlled dielectric properties are prepared using poly(dimethylsiloxane) elastomer as base matrix and barium titanate as filler. Barium titanate (BaTiO3) used in this study is prepared by solid state reaction at high temperature. The effect of BaTiO3 nanoparticles on electrical and mechanical properties are extensively studied and found that dielectric constant of nanocomposites increases significantly with the increase in BaTiO3 concentration where as volume resistivity decreases continuously. Different mechanical properties are also studied for all the composites in order to find the effect of filler concentration. Morphology of the prepared BaTiO3 was studied by field emission scanning electron microscope (FESEM).

Sign in / Sign up

Export Citation Format

Share Document