scholarly journals Identification of Iron Oxides and Effects of Magnetic Materials Washing for Sand Iron Jomblom Beach Using Sonochemical Methods

2019 ◽  
Vol 16 (3) ◽  
pp. 140-151
Author(s):  
Ricka Prasdiantika ◽  
Niyar Candra Agustin ◽  
Abdul Rohman
Keyword(s):  
Magnetic Material ◽  
Iron Oxide ◽  
Material Characterization ◽  
Crystal Size ◽  
Sonochemical Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Magnetite Fe3o4 ◽  
Ft Ir

This study aims to prepare iron sand, determine the type of iron oxide, and determine the effect of washing iron sand with sonochemical methods. Iron sand samples were obtained from Jomblom Beach, Kendal Regency. Iron sand was separated using an external magnet to obtain magnetic material. The magnetic material obtained was washed using distilled water manually stirred and using the sonochemical method. The material was dried at 80 °C. Material characterization was carried out using X-Ray Fluorescence (XRF) to determine the elements contained in iron sand, Fourier Transform Infrared (FT-IR) Spectrophotometer to identify functional groups in iron sand, X-Ray Diffraction (XRD) to find out the crystal size and crystallinity of iron sand, and the Transmission Electron microscope (TEM) to determine the morphology of iron sand. The characterization results showed that the iron sand of Jomblom Beach contained Fe (72.28%), Ti (7.89%), Al (7.00%), and Si (7.60%). The iron oxide contained in the Jomblom Beach iron sand was dominated by magnetite (Fe3O4). Washing iron sand magnetic material using the sonochemical method increased the composition of the element Fe, increased the crystallinity of the magnetic material, prevented aggregation, and reduced the crystal size of the magnetic material. Magnetic material which was washed using the sonochemical method produced 79.47% Fe element, crystallinity 74.94%, and crystal size 52.78 nm.

Synthesis and Characterization of HgSe Nanostructure Using a Novel Precursor

2013 ◽  
Vol 32 (2) ◽  
pp. 157-162 ◽  
Author(s):  
Mahdiyeh Esmaeili-Zare ◽  
Masoud Salavati-Niasari ◽  
Davood Ghanbari
Keyword(s):  
Electron Microscopy ◽  
Synthesis And Characterization ◽  
Sonochemical Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Mercury Selenide ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

AbstractMercury selenide nanostructures were synthesized from the reaction of N, N′-bis(salicylidene)propane-1,3-diamine mercury complex, (Hg(Salpn)) as a novel precursor, via sonochemical method. The effect of different surfactant on the morphology and particle size of the products was investigated. Products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared (FT-IR) spectroscopy and X-ray energy dispersive spectroscopy (EDS).

scholarly journals PENCUCIAN MATERIAL MAGNETIK PASIR BESI LANSILOWO MENGGUNAKAN LARUTAN ASAM KLORIDA

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Ricka Prasdiantika ◽  
Susanto Susanto
Keyword(s):  
Magnetic Material ◽  
Fourier Transform ◽  
Iron Oxide ◽  
Material Characterization ◽  
Acidic Solution ◽  
Fourier Transform Infrared ◽  
Drying Process ◽  
X Ray ◽  
Ft Ir ◽  
Hcl Solution

Iron sand was widely used in various fields such as in the manufacturing of magnets, cement, and steel. Iron sand has the main composition of iron oxide and several impurities of oxides. To remove these impurities, iron sand needs to be washed with acidic solution such as HCl solution. This study aims to minimize impurities in the magnetic material of Lansilowo iron sand. Iron sand was prepared using an external magnet to obtain magnetic material. The magnetic material was washed using distilled water and 0.5 M HCl solution. The drying process was carried out at 80oC for 24 hours. Magnetic material was crushed, weighed, and characterized. Material characterization was carried out using X-Ray Fluorescence (XRF), Fourier Transform Infrared (FT-IR) Spectrophotometer, and X-Ray Diffractometer (XRD). The Characterization results showed that washing of magnetic material using H2O-HCl 0.5 M was able to increase the percentage of Fe element composition in Lansilowo iron sand. The iron oxide contained in Lansilowo Iron Sand remains magnetite. The washing the iron sand magnetic material using 0.5 M HCl solution succeeded in removing impurities such as Mg, Pr, K, Cl, P, S, Co, Ce, and Sn as well as reducing the percentage of the Si and Al elements.The washing magnetic material using 0.5 M H2O-HCl produced higher XRD intensities than those washed with H2O. The washing magnetic material with 0.5 M H2O-HCl was result particle size of 37,70 ± 4,62 nm  and crystallinity of 53.12%.Pasir besi banyak dimanfaatkan dalam berbagai bidang seperti pada industri pembuatan magnet, semen, dan baja. Pasir besi memiliki kandungan oksida besi dan beberapa oksida pengotor. Untuk menghilangkan oksida-oksida pengotor tersebut, pasir besi perlu dicuci dengan larutan asam seperti larutan HCl. Penelitian ini bertujuan untuk meminimalisir oksida-oksida pengotor pada material magnetik pasir besi Lansilowo. Pasir besi dipreparasi menggunakan magnet eksternal untuk mendapatkan material magnetik. Material magnetik dicuci menggunakan akuades dan larutan HCl 0,5 M. Proses pengeringan dilakukan pada suhu 80oC selama 24 jam. Material magnetik digerus, ditimbang, dan dikarakterisasi. Karakterisasi material dilakukan menggunakan X-Ray Fluorescence (XRF), Fourier Transform Infrared (FT-IR) Spectrophotometer dan X-Ray Difraktometer (XRD). Hasil karakterisasi menunjukkan bahwa pencucian material magnetik dengan menggunakan H2O-HCl 0,5 M mampu meningkatkan persentase komposisi unsur Fe material magnetik pasir besi Lansilowo. Oksida besi yang terkandung dalam Pasir Besi Lansilowo tetap magnetit. Pencucian material magnetik pasir besi menggunakan larutan HCl 0,5 M berhasil menghilangkan unsur-unsur pengotor seperti Mg, Pr, K, Cl, P, S, Co, Ce, dan Sn serta menurukan persentase komposisi dari unsur Si dan Al. Pencucian material magnetik menggunakan H2O-HCl 0,5 M menghasilkan intensitas XRD yang lebih tinggi dibandingkan yang dicuci dengan H2O. Pencucian material magnetik dengan H2O-HCl 0,5 M menghasilkan ukuran partikel 37,70 ± 4,62 nm dan kristalinitas sebesar 53,12%.

scholarly journals Sonochemical Synthesis of Cadmium(II) Coordination Polymer Nanospheres as Precursor for Cadmium Oxide Nanoparticles

Crystals ◽  
2019 ◽  
Vol 9 (4) ◽  
pp. 199 ◽  
Author(s):  
Farhad Afkhami ◽  
Ali Khandar ◽  
Ghodrat Mahmoudi ◽  
Reza Abdollahi ◽  
Atash Gurbanov ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Cadmium Oxide ◽  
Average Diameter ◽  
Synthetic Methods ◽  
Sonochemical Method ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Ft Ir ◽  
Ft Ir Spectroscopy

Nanospheres of a new coordination polymer {[Cd2(µ-HL)(µ-L)(NO3)3(H2O)]·H2O}n (1) were easily prepared by a sonochemical method from cadmium(II) nitrate and HL (HL, pyridine-2-carboxaldehyde isonicotinoyl hydrazone) in ethanol. Single crystals of 1 were also obtained using a branched tube method. The crystal structure of 1 indicates that the µ-HL/µ-L− blocks act as linkers between the Cd(II) centers, assembling them into 1D tooth-shaped interdigitated chains, which are further interlinked into a complex 3D H-bonded network with a rare hms (3,5-conn) topology. Nanoparticles of 1 were characterized by elemental analysis, FT-IR spectroscopy, and powder X-ray diffraction (XPRD), while their spherical morphology was confirmed by transmission electron microscopy (TEM). Furthermore, in the presence of a surfactant, the thermolysis of sonochemically generated nanoparticles of 1 led to the formation of cadmium oxide nanospheres (cubic CdO) with an average diameter of 10 nm. This study extends the application of sonochemical synthetic methods for the generation of phase pure nanoparticles of coordination polymers and their thermolysis products.

scholarly journals Hydrothermal Synthesis, Characterization and Exploration of Photocatalytic Activities of Polyoxometalate: Ni-CoWO4 Nanoparticles

Crystals ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 456
Author(s):  
Fahad A. Alharthi ◽  
Hamdah S. Alanazi ◽  
Amjad Abdullah Alsyahi ◽  
Naushad Ahmad
Keyword(s):  
Electron Microscopy ◽  
Hydrothermal Synthesis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Structure Morphology ◽  
Photocatalytic Activities ◽  
Ft Ir ◽  
Photocatalytic Reactions ◽  
Cobalt Tungstate

This study demonstrated the hydrothermal synthesis of bimetallic nickel-cobalt tungstate nanostructures, Ni-CoWO4 (NCW-NPs), and their phase structure, morphology, porosity, and optical properties were examined using X-ray Diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), Scanning electron microscopy- energy dispersive X-ray spectroscopy (SEM-EDS), high resolution Transmission electron microscopy (HR-TEM), Brunauer-Emmett-Teller (BET) and Raman instruments. It was found that as-calcined NCW-NPs have a monoclinic phase with crystal size ~50–60 nm and is mesoporous. It possessed smooth, spherical, and cubic shape microstructures with defined fringe distance (~0.342 nm). The photocatalytic degradation of methylene blue (MB) and rose bengal (RB) dye in the presence of NCW-NPs was evaluated, and about 49.85% of MB in 150 min and 92.28% of RB in 90 min degraded under visible light. In addition, based on the scavenger’s study, the mechanism for photocatalytic reactions is proposed.

One Step Synthesis and Characterization of Zirconia-Graphene Composites

2012 ◽  
Vol 600 ◽  
pp. 174-177 ◽  
Author(s):  
Jian Fei Xia ◽  
Zong Hua Wang ◽  
Yan Zhi Xia ◽  
Fei Fei Zhang ◽  
Fu Qiang Zhu ◽  
...  
Keyword(s):  
Synthesis And Characterization ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
X Ray ◽  
Graphene Composite ◽  
Transmission Electron ◽  
One Step ◽  
Ft Ir ◽  
Xrd Techniques

Zirconia-graphene composite (ZrO2-G) has been successfully synthesized via decomposition of ZrOCl2•6H2O in a water-isopropanol system with dispersed graphene oxide (GO) utilizing Na2S as a precursor could enable the occurrence of the deposition of Zr4+ and the deoxygenation of GO at the same time. Transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) techniques were used to characterize the samples. It was found that graphene were fully coated with ZrO2, and the ZrO2 existing in tetragonal phase, which resulted in the formation of two-dimensional composite.

Structural changes in titanium dioxide nanocrystals during plastic deformation

2005 ◽  
Vol 38 (5) ◽  
pp. 749-756 ◽  
Author(s):  
Ulrich Gesenhues
Keyword(s):  
Structural Changes ◽  
Crystal Size ◽  
Lower Layer ◽  
High Energy ◽  
Primary Crystal ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Hall Method ◽  
Means Of Transmission

The polygonization of 200 nm rutile crystals during dry ball-milling at 10gwas monitored in detail by means of transmission electron microscopy (TEM) and X-ray diffraction (XRD). The TEM results showed how to modify the Williamson–Hall method for a successful evaluation of crystal size and microstrain from XRD profiles. Macrostrain development was determined from the minute shift of the most intense reflection. In addition, changes in pycnometrical density were monitored. Accordingly, the primary crystal is disintegrated during milling into a mosaic of 12–35 nm pieces where the grain boundaries induce up to 1.2% microstrain in a lower layer of 6 nm thickness. Macrostrain in the interior of the crystals rises to 0.03%. The pycnometrical density, reflecting the packing density of atoms in the grain boundary, decreases steadily by 1.1%. The results bear relevance to our understanding of plastic flow and the mechanism of phase transitions of metal oxides during high-energy milling.

Effect of Synthesis Temperature on Particles Size and Morphology of Zirconium Oxide Nanoparticle

2017 ◽  
Vol 50 ◽  
pp. 18-31 ◽  
Author(s):  
Rudzani Sigwadi ◽  
Simon Dhlamini ◽  
Touhami Mokrani ◽  
Patrick Nonjola
Keyword(s):  
Electron Microscopy ◽  
Particle Size ◽  
Zirconium Oxide ◽  
Thermo Gravimetric Analysis ◽  
Gravimetric Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Transmission Electron ◽  
Crystallite Sizes ◽  
Ft Ir

The paper presents the synthesis and investigation of zirconium oxide (ZrO2) nanoparticles that were synthesised by precipitation method with the effects of the temperatures of reaction on the particles size, morphology, crystallite sizes and stability at high temperature. The reaction temperature effect on the particle size, morphology, crystallite sizes and stabilized a higher temperature (tetragonal and cubic) phases was studied. Thermal decomposition, band structure and functional groups were analyzed by Brunauer-Emmett-Teller (BET), Scanning Electron Microscopy (SEM), Transmission electron microscopy (TEM), X-ray diffraction (XRD), Thermo-gravimetric analysis (TGA) and Fourier transform infrared (FT-IR). The crystal structure was determined using X-ray diffraction. The morphology and the particle size were studied using (SEM) and (TEM). The shaped particles were confirmed through the SEM analysis. The transmission electron microscopic analysis confirmed the formation of the nanoparticles with the particle size. The FT-IR spectra showed the strong presence of ZrO2 nanoparticles.

scholarly journals Dual Light- and pH-Responsive Composite of Polyazo-Derivative Grafted Cellulose Nanocrystals

Materials ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 1725 ◽  
Author(s):  
Xiaohong Liu ◽  
Ming Li ◽  
Xuemei Zheng ◽  
Elias Retulainen ◽  
Shiyu Fu
Keyword(s):  
Cellulose Nanocrystals ◽  
Photoelectron Spectroscopy ◽  
Surface Composition ◽  
X Ray Diffraction ◽  
Responsive Materials ◽  
X Ray ◽  
Ph Response ◽  
Transmission Electron ◽  
Ft Ir ◽  
Hexyl Methacrylate

As a type of functional group, azo-derivatives are commonly used to synthesize responsive materials. Cellulose nanocrystals (CNCs), prepared by acid hydrolysis of cotton, were dewatered and reacted with 2-bromoisobuturyl bromide to form a macro-initiator, which grafted 6-[4-(4-methoxyphenyl-azo) phenoxy] hexyl methacrylate (MMAZO) via atom transfer radical polymerization. The successful grafting was supported by Fourier transform infrared spectroscopy (FT-IR) and Solid magnetic resonance carbon spectrum (MAS 13C-NMR). The morphology and surface composition of the poly{6-[4-(4-methoxyphenylazo) phenoxy] hexyl methacrylate} (PMMAZO)-grafted CNCs were confirmed with Transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The grafting rate on the macro-initiator of CNCs was over 870%, and the polydispersities of branched polymers were narrow. The crystal structure of CNCs did not change after grafting, as determined by X-ray diffraction (XRD). The polymer PMMAZO improved the thermal stability of cellulose nanocrystals, as shown by thermogravimetry analysis (TGA). Then the PMMAZO-grafted CNCs were mixed with polyurethane and casted to form a composite film. The film showed a significant light and pH response, which may be suitable for visual acid-alkali measurement and reversible optical storage.

Synthesis of Indole Derivatives Using Biosynthesized ZnO-CaO Nanoparticles as an Efficient Catalyst

2021 ◽  
Vol 66 ◽  
pp. 61-71
Author(s):  
Tahereh Heidarzadeh ◽  
Navabeh Nami ◽  
Daryoush Zareyee
Keyword(s):  
Electron Microscopy ◽  
Indole Derivatives ◽  
X Ray Diffraction ◽  
Efficient Catalyst ◽  
X Ray ◽  
Transmission Electron ◽  
Solvent Free Conditions ◽  
Ft Ir ◽  
Eggshell Waste ◽  
Aromatic And Aliphatic Amines

The principal aim of this research is using biosynthesized ZnO-CaO nanoparticles (NPs) for preparation of indole derivatives. ZnO-CaO NPs have been prepared using Zn(CH3COO)2 and eggshell waste powder in solvent-free conditions. Morphology and structure of NPs were determined by FT-IR, X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and energy dispersive spectra (EDS). It was used as a highly efficient catalyst for the synthesis of indole derivatives. Some indole derivatives were synthesized by the reaction of indole, formaldehyde, aromatic and aliphatic amines in the presence of ZnO-CaO NPs (5 mol%) in ethanol under reflux conditions. The assigned structure was further established by CHN analyses, NMR, and FT-IR spectra. Because of excellent capacity, the exceedingly simple workup and good yield, eco-friendly catalyst ZnO-CaO NPs were proved to be a good catalyst for this reaction.

scholarly journals Enhanced Photocatalytic Activity of Vanadium-Doped SnO2 Nanoparticles in Rhodamine B Degradation

2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
H. Letifi ◽  
Y. Litaiem ◽  
D. Dridi ◽  
S. Ammar ◽  
R. Chtourou
Keyword(s):  
Photocatalytic Activity ◽  
Rhodamine B ◽  
Crystal Size ◽  
Sno2 Nanoparticles ◽  
X Ray Diffraction ◽  
Optical Studies ◽  
Vanadium Concentration ◽  
X Ray ◽  
Transmission Electron ◽  
20 Nm

In this paper, we have reported a novel photocatalytic study of vanadium-doped SnO2 nanoparticles (SnO2: V NPs) in rhodamine B degradation. These NPs have been prepared with vanadium concentrations varying from 0% to 4% via the coprecipitation method. Structural, morphological, and optical properties of the prepared nanoparticles have been investigated by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, transmission electron microscope (TEM), and UV-Vis and photoluminescence (PL) spectroscopy. Structural properties showed that both undoped and SnO2: V NPs exhibited the tetragonal structure, and the average crystal size has been decreased from 20 nm to 10 nm with the increasing doping level of vanadium. Optical studies showed that the absorption edge of SnO2: V NPs showed a redshift with the increasing vanadium concentration. This redshift leads to the decrease in the optical band gap from 3.25 eV to 2.55 eV. A quenching in luminescence intensity has been observed in SnO2: V NPs, as compared to the undoped sample. Rhodamine B dye (RhB) has been used to study the photocatalytic degradation of all synthesized NPs. As compared to undoped SnO2 NPs, the photocatalytic activity of SnO2: V NPs has been improved. RhB dye was considerably degraded by 95% within 150 min over on the SnO2: V NPs.

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