Geochemical characterization of the source rock intervals, Beni-Suef Basin, West Nile Valley, Egypt

2021 ◽  
Vol 13 (1) ◽  
pp. 1536-1551
Author(s):  
Nader A. A. Edress ◽  
Saudy Darwish ◽  
Amir Ismail
Keyword(s):  
Heat Flow ◽  
Source Rock ◽  
High Heat ◽  
Source Rocks ◽  
Nile Valley ◽  
Peak Oil ◽  
Burial History ◽  
Depth Limit ◽  
Oil Generation ◽  
Rock Depth

Abstract Geochemical and lithological investigations in the WON C-3X well record five organic-matter-rich intervals (OMRIs) of effective source rocks. These OMRIs correspond to moderate and good potentials. Two of these intervals occurred within the L-Kharita member of the Albian age represent 60.97% of the entire Albian thickness. The rest of OMRIs belongs to the Abu-Roash G and F members of the Late Cenomanian–Santonian age comprising 17.52 and 78.66% of their total thickness, respectively. The calculated heat flow of the studied basin is high within the range of 90.1–95.55 mW/m2 from shallower Abu-Roash F to deeper L-Kharita members. This high-heat flow is efficient for shallowing in the maximum threshold expulsion depth in the studied well to 2,000 m and active source rock depth limit to 2,750 m. Thermal maturity and burial history show that the source rock of L-Kharita entered the oil generation from 97 Ma till the late oil stage of 7.5 Ma, whereas the younger Abu-Roash G and F members have entered oil generation since 56 Ma and not reached peak oil yet. Hence, the source rock intervals from Abu-Roash F and G are promising for adequate oil generation.

scholarly journals Heat Flow in the Campos Sedimentary Basin and Thermal History of the Continental Margin of Southeast Brazil

2014 ◽  
Vol 2014 ◽  
pp. 1-19 ◽  
Author(s):  
Roberta A. Cardoso ◽  
Valiya M. Hamza
Keyword(s):  
Heat Flow ◽  
Continental Margin ◽  
High Heat ◽  
Geothermal Field ◽  
Peak Oil ◽  
Southeast Brazil ◽  
Campos Basin ◽  
Oil Generation ◽  
High Gradients ◽  
History Of

Bottom-hole temperatures and physical properties derived from geophysical logs of deep oil wells have been employed in assessment of the geothermal field of the Campos basin, situated in the continental margin of southeast Brazil. The results indicate geothermal gradients in the range of 24 to 41°C/km and crustal heat flow in the range of 30 to 100 mW/m2 within the study area. Maps of the regional distributions of these parameters point to arc-shaped northeast-southwest trending belts of relatively high gradients and heat flow in the central part of the Campos basin. This anomalous geothermal belt is coincident with the areas of occurrences of oil deposits. The present study also reports progress obtained in reconstructing the subsidence history of sedimentary strata at six localities within the Campos basin. The results point to episodes of crustal extension with magnitudes of 1.3 to 2, while extensions of subcrustal layers are in the range of 2 to 3. Thermal models indicate high heat flow during the initial stages of basin evolution. Maturation indices point to depths of oil generation greater than 3 km. The age of peak oil generation, allowing for variable time scales for cooling of the extended lithosphere, is found to be less than 40 Ma.

scholarly journals Oil And Gas Generation History Based On Burial History Reconstruction And Thermal Maturity Modeling Of Petroleum Systems In Northern Iraq

2020 ◽  
Vol 10 (4) ◽  
pp. 95-120
Author(s):  
Rzger Abdulkarim Abdula
Keyword(s):  
Source Rock ◽  
Late Cretaceous ◽  
Oil And Gas ◽  
Source Rocks ◽  
Hydrocarbon Generation ◽  
Thermal Maturity ◽  
Burial History ◽  
Gas Generation ◽  
Northern Iraq ◽  
Oil Generation

Burial history, thermal maturity, and timing of hydrocarbon generation were modeled for five key source-rock horizons at five locations in Northern Iraq. Constructed burial-history locations from east to west in the region are: Taq Taq-1; Qara Chugh-2; Zab-1; Guwair-2; and Shaikhan-2 wells. Generally, the thermal maturity status of the burial history sites based on increasing thermal maturity is Shaikhan-2 < Zab-1 < Guwair-2 < Qara Chugh-2 < Taq Taq-1. In well Qara Chugh-2, oil generation from Type-IIS kerogen in Geli Khana Formation started in the Late Cretaceous. Gas generation occurred at Qara Chugh-2 from Geli Khana Formation in the Late Miocene. The Kurra Chine Formation entered oil generation window at Guwair-2 and Shaikhan-2 at 64 Ma and 46 Ma, respectively. At Zab-1, the Baluti Formation started to generate gas at 120 Ma. The Butmah /Sarki reached peak oil generation at 45 Ma at Taq Taq-1. The main source rock in the area, Sargelu Formation started to generate oil at 47, 51, 33, 28, and 28 Ma at Taq Taq-1, Guwair-2, Shaikhan-2, Qara Chugh-2, and Zab-1, respectively. The results of the models demonstrated that peak petroleum generation from the Jurassic oil- and gas-prone source rocks in the most profound parts of the studied area occurred from Late Cretaceous to Middle Oligocene. At all localities, the Sargelu Formation is still within the oil window apart from Taq Taq-1 and Qara Chugh-2 where it is in the oil cracking and gas generation phase.

GEOLOGY AND HYDROCARBON POTENTIAL OF THE SOUTHERN GEORGINA BASIN, AUSTRALIA

2001 ◽  
Vol 41 (1) ◽  
pp. 139 ◽  
Author(s):  
G.J. Ambrose ◽  
P.D. Kruse ◽  
P.E. Putnam
Keyword(s):  
Early Carboniferous ◽  
Source Rocks ◽  
Peak Oil ◽  
Middle Cambrian ◽  
Late Cambrian ◽  
Oil Generation ◽  
World Class ◽  
Lower Palaeozoic ◽  
Southwestern Margin ◽  
Intracratonic Basin

The Georgina Basin is an intracratonic basin on the central-northern Australian craton. Its southern portion includes a highly prospective Middle Cambrian petroleum system which remains largely unexplored. A plethora of stratigraphic names plagued previous exploration but the lithostratigraphy has now been rationalised using previously unpublished electric-log correlations and seismic and core data.Neoproterozoic and Lower Palaeozoic sedimentary rocks of the southern portion of the basin cover an area of 100,000 km2 and thicken into two main depocentres, the Toko and Dulcie Synclines. In and between these depocentres, a Middle Cambrian carbonate succession comprising Thorntonia Limestone and Arthur Creek Formation provides a prospective reservoir-source/seal couplet extending over 80,000 km2. The lower Arthur Creek Formation includes world class microbial source rocks recording total organic carbon (TOC) values of up to 16% and hydrocarbon yields up to 50 kg/tonne. This blanket source/seal unconformably overlies sheetlike, platform dolostone of the Thorntonia Limestone which provides the prime target reservoir. Intra- Arthur Creek high-permeability grainstone shoals are important secondary targets.In the Toko Syncline, Middle Cambrian source rocks entered the oil window during the Ordovician, corresponding to major sediment loading at this time. The gas window was reached prior to structuring associated with the Middle Devonian-Early Carboniferous Alice Springs Orogeny, and source rocks today lie in the dry gas window. In contrast, high-temperature basement granites have resulted in overmaturity of the Arthur Creek Formation in the Dulcie Syncline area. On platform areas adjacent to both these depocentres source rocks reached peak oil generation shortly after the Alice Springs Orogeny; numerous structural leads have been identified in these areas. In addition, an important stratigraphic play occurs in the Late Cambrian Arrinthrunga Formation (Hagen Member) on the southwestern margin of the basin. Key elements of the play are the pinchout of porous oil-stained, vuggy dolostone onto basement where top seal is provided by massive anhydrite while underlying Arthur Creek Formation shale provides a potential source.

scholarly journals Organic geochemical and petrographical characteristics of the major lower cretaceous petroleum source rock (Makhul Formation) in Kuwait - Arabian Gulf

2021 ◽  
Vol 49 (1) ◽  
Author(s):  
Fatma K. Bahman ◽  
◽  
Fowzia H. Abdullah ◽  
Abbas Saleh ◽  
Hossein Alimi ◽  
...  
Keyword(s):  
Organic Matter ◽  
Sea Level ◽  
Source Rock ◽  
Lower Cretaceous ◽  
Arabian Gulf ◽  
Carbon Isotope Ratio ◽  
Middle Part ◽  
Source Rocks ◽  
Peak Oil ◽  
Rock Composition

The Lower Cretaceous Makhul Formation is one of the major petroleum source rocks in Kuwait. This study aims to evaluate the Makhul source rock for its organic matter richness and its relation to the rock composition and depositional environment. A total of 117 core samples were collected from five wells in Raudhatain, Ritqa, Mutriba, Burgan, and Minagish oil fields north and south Kuwait. The rock petrographical studies were carried out using a transmitted and polarized microscope, as well as SEM and XRD analyses on selected samples. Total organic matter TOC and elemental analyses were done for kerogen type optically. The GC and GC-MS were done as well as the carbon isotope ratio. The results of this study show that at its earliest time the Makhul Formation was deposited in an anoxic shallow marine shelf environment. During deposition of the middle part, the water oxicity level was fluctuating from oxic to anoxic condition due to changes in sea level. At the end of Makhul and the start of the upper Minagish Formation, the sea level raised forming an oxic open marine ramp depositional condition. Organic geochemical results show that the average TOC of the Makhul Formation is 2.39% wt. High TOC values of 6.7% wt. were usually associated with the laminated mudstone intervals of the formation. The kerogen is of type II and is dominated by marine amorphous sapropelic organic matter with a mixture of zoo- and phytoplankton and rare terrestrial particles. Solvent extract results indicate non-waxy oils of Mesozoic origin that are associated with marine carbonate rocks. The formation is mature and at its peak oil generation in its deepest part in north Kuwait.

scholarly journals A Novel Redox Indicator based on Relative Abundances of C31 And C32 Homohopanes in the Eocene Lacustrine Dongying Depression, East China

2021 ◽  
Author(s):  
Chong Jiang ◽  
Haiping Huang ◽  
Zheng Li ◽  
Hong Zhang ◽  
Zheng Zhai
Keyword(s):  
Vitrinite Reflectance ◽  
Source Rocks ◽  
East China ◽  
Peak Oil ◽  
Dongying Depression ◽  
Anoxic Environments ◽  
Oil Generation ◽  
Shahejie Formation ◽  
The Impact ◽  
Fourth Member

Abstract A suite of oils and bitumens from the Eocene Shahejie Formation (Es) in the Dongying Depression, East China was geochemically characterized to illustrate the impact of source input and redox conditions on the distributions of pentacyclic terpanes. The fourth member (Es4) developed under highly reducing, sulfidic hypersaline conditions, while the third member (Es3) formed under dysoxic, brackish to freshwater conditions. Oils derived from Es4 are enriched in C32 homohopanes (C32H), while those from Es3 are prominently enriched in C31 homohopanes (C31H). The C32H/C31H ratio shows positive correlation with homohopane index (HHI), gammacerane index (G/C30H), and negative correlation with pristane/phytane (Pr/Ph) ratio, and can be used to evaluate oxic/anoxic conditions during deposition and diagenesis. High C32H/C31H ratio (> 0.8) is an important characteristic of oils derived from sulfidic, hypersaline anoxic environments, while low values (< 0.8) indicate non-sulfidic, dysoxic conditions. Extremely low C32H/C31H ratios (< 0.4) indicate strong oxic conditions of coal depsoition. Advantages to use C32H/C31H ratio as redox condition proxy compared to the HHI and gammacerane indexes are wider valid maturity range, less sensitive to biodegradation influence and better differentiation of reducing from oxic environments. Preferential cracking of C35-homohopanes leads HHI to be valid in a narrow maturity range before peak oil generation. No C35 homohopane can be reliably detected in the Es4 bitumens when vitrinite reflectance is > 0.75%, which explains the rare occurrence of high HHI values in Es4 source rocks. Gammacerane is thermally more stable and biologically more refractory than C30 hopane, leading G/C30H ratio more sensitive to maturation and biodegradation than C32H/C31H ratio. Meanwhile, both HHI and gammacerane index cannot differentiate level of oxidation. The C32H/C31H ratio can be applied globally as a novel redox proxy in addition to the Dongying Depression.

scholarly journals Geochemical Characteristics of Expelled and Residual Oil from Artificial Thermal Maturation of an Early Permian Tasmanite Shale, Australia

Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 7218
Author(s):  
Xiaomin Xie ◽  
Ye Wang ◽  
Jingwen Lin ◽  
Fenting Wu ◽  
Lei Zhang ◽  
...  
Keyword(s):  
Source Rock ◽  
Oil Shale ◽  
Pyrolysis Temperature ◽  
Geochemical Characteristics ◽  
Peak Oil ◽  
Residual Oil ◽  
Oil Generation ◽  
Organic Matter Type ◽  
Oil Source ◽  
Group Compositions

Lipid biomarkers play an important role in defining oil-source rock correlations. A fundamental assumption is that composition (or ratios) of biomarkers in oil is not significantly different from that in bitumen in the source rock. In order to compare the geochemical characteristics of expelled oil and residual oil, a Permian Tasmanite oil shale was used for an artificial maturation experiment to simulate the oil generation period. The results show that the Tasmanite oil shale generated high amounts of hydrocarbons (731 mg HC/g TOC) at low maturation temperatures (340 °C). The hydrocarbon (HC) group compositions are different between the expelled oil (with more aromatic HC and saturated HC) and the residual oil (with more resin fraction and asphaltene). The Pr/Ph ratio (up to 4.01) of the expelled hydrocarbons was much higher than that in residual oil (<1.0). Maturity-related biomarkers Ts/(Ts + Tm), and αααC29-20S/(20S + 20R) and C29-αββ/(ααα + αββ), also showed complicated variations with pyrolysis temperature, especially at post peak oil generation. C27-, C28-, and C29- sterane distributions showed variations with pyrolysis temperature. Therefore, without considering the influence of maturity on the abundance of compounds, either source, maturity and/or organic matter type from the chemical characteristics may not be correct.

scholarly journals The Depth Limit for the Formation and Occurrence of Fossil Fuel Resources

2019 ◽  
Author(s):  
Xiongqi Pang ◽  
Chengzao Jia ◽  
Kun Zhang ◽  
Maowen Li ◽  
Youwei Wang ◽  
...  
Keyword(s):  
Source Rock ◽  
Fossil Fuel ◽  
Maximum Depth ◽  
Source Rocks ◽  
Distribution Area ◽  
Geochemical Data ◽  
Burial Depth ◽  
Human Beings ◽  
Depth Limit ◽  
Active Source

Abstract. Fossil resources are valuable wealth given to human beings by nature. Many mysteries related to them have been revealed such as the origin time and distribution area, but their vertical distribution depth has not been confirmed for people’s different understanding of their origin and the big depth variations from basin to basin. Geological and geochemical data of 13,634 source rock samples from 1,286 exploration wells in six representative petroliferous basins are examined to study their Active Source Rock Depth Limits (ASDL), defined in this study as the maximum burial depth of active source rocks beyond which the source rocks no longer generate or expel hydrocarbons and become inactive, to identify the maximum depth for fossil fuel resources distribution. Theoretically, the maximum depth for the ASDLs of fossil fuel resources ranges from 3,000 m to 16,000 m, while their thermal maturities (Ro) are almost the same with Ro≈3.5±0.5 %. A higher heat flow and more oil-prone kerogen are associated with a shallower ASDL. Active source rocks and the discovered 21.6 billion tons of reserves in six representative basins in China and 52,926 oil and gas reservoirs in the 1,186 basins over the world are found to be distributed above the ASDL, illustrating the universality of such kind of depth limit. The data are deposited in the repository of the PANGAEA database: https://doi.org/10.1594/PANGAEA.900865 (Pang et al., 2019).

scholarly journals Petroleum generation modeling of the organic-rich shales of Late Jurassic – Early Cretaceous succession from Mintaq-01 well in the Wadi Hajar sub-basin, Yemen

2016 ◽  
Vol 53 (10) ◽  
pp. 1053-1072 ◽  
Author(s):  
Mohammed Hail Hakimi ◽  
Abdulghani F. Ahmed
Keyword(s):  
Source Rock ◽  
Early Cretaceous ◽  
Late Jurassic ◽  
Oil And Gas ◽  
Late Eocene ◽  
Peak Oil ◽  
Oil Generation ◽  
Petroleum Generation ◽  
Rock Characterization ◽  
Excellent Source

Late Jurassic – Early Cretaceous shales of the Naifa, Safer, and Madbi formations were studied to evaluate source rock characterization. The results of the source rock were then incorporated into basin modeling to understand the timing of hydrocarbon (HC) generation and expulsion. The Late Jurassic – Early Cretaceous shales have low to high organic matter, with total organic carbon (TOC) values in the range of 0.50%–28.01%, indicating fair to excellent source rock potential. Main oil and gas are anticipated to be generated from the Naifa, Safer, and Lam shale samples with types I and (or) II and types II–III kerogens. In contrast, the Meem samples are dominated by type III kerogen (hydrogen index, HI < 200 mg HC / g TOC), and are thus considered to be gas prone. The Late Jurassic – Early Cretaceous shale samples have temperatures of maximum pyrolysis yield (Tmax) in the range of 337–515 °C, consistent with immature to post-mature stages. The Tmax data also indicate that the Safer and Madbi shale samples have sufficient thermal maturity, i.e., peak–mature oil and gas window. The basin models indicate that the Naifa Formation is early–mature, and the onset oil generation began during the Early Miocene. The models also indicate that the main phase of oil generation in the Safer source rock began during the Late Eocene. In contrast, the Madbi source rock units had passed the peak oil generation window, and the oil was converted to gas during the Late Cretaceous to Late Eocene. The modeled HC expulsion history reveals that most oils are contributed by both Madbi units, with significant amounts of gas originating from the Meem unit.

PETROLEUM SOURCE ROCKS IN THE ROPER GROUP OF THE MCARTHUR BASIN: SOURCE CHARACTERISATION AND MATURITY DETERMINATIONS USING PHYSICAL AND CHEMICAL METHODS

1994 ◽  
Vol 34 (1) ◽  
pp. 279 ◽  
Author(s):  
Dennis Taylor ◽  
Aleksai E. Kontorovich ◽  
Andrei I. Larichev ◽  
Miryam Glikson
Keyword(s):  
Organic Matter ◽  
Chemical Evolution ◽  
Oil And Gas ◽  
Source Rocks ◽  
Type I ◽  
Peak Oil ◽  
Gas Generation ◽  
Oil Generation ◽  
Physical And Chemical ◽  
Extractable Organic Matter

Organic rich shale units ranging up to 350 m in thickness with total organic carbon (TOC) values generally between one and ten per cent are present at several stratigraphic levels in the upper part of the Carpentarian Roper Group. Considerable variation in depositional environment is suggested by large differences in carbon:sulphur ratios and trace metal contents at different stratigraphic levels, but all of the preserved organic matter appears to be algal-sourced and hydrogen-rich. Conventional Rock-Eval pyrolysis indicates that a type I-II kerogen is present throughout.The elemental chemistry of this kerogen, shows a unique chemical evolution pathway on the ternary C:H:ONS diagram which differs from standard pathways followed by younger kerogens, suggesting that the maturation histories of Proterozoic basins may differ significantly from those of younger oil and gas producing basins. Extractable organic matter (EOM) from Roper Group source rocks shows a chemical evolution from polar rich to saturate rich with increasing maturity. Alginite reflectance increases in stepwise fashion through the zone of oil and gas generation, and then increases rapidly at higher levels of maturation. The increase in alginite reflectance with depth or proximity to sill contacts is lognormal.The area explored by Pacific Oil and Gas includes a northern area where the Velkerri Formation is within the zone of peak oil generation and the Kyalla Member is immature, and a southern area, the Beetaloo sub-basin, where the zone of peak oil generation is within the Kyalla Member. Most oil generation within the basin followed significant folding and faulting of the Roper Group.

THE PETROLEUM PROSPECTIVITY OF THE CLARENCE-MORETON BASIN IN NEW SOUTH WALES

1985 ◽  
Vol 25 (1) ◽  
pp. 15
Author(s):  
P. Ties ◽  
R.D. Shaw ◽  
G.C. Geary
Keyword(s):  
Source Rock ◽  
Seismic Data ◽  
New South ◽  
New South Wales ◽  
Source Rocks ◽  
Petroleum Exploration ◽  
South Wales ◽  
Oil Generation ◽  
Single Fold ◽  
Coal Measures

The Clarence-Moreton Basin covers an area of some 28 000 km2 in north-eastern New South Wales and south-eastern Queensland. The basin is relatively unexplored, with a well density in New South Wales of one per 1600 km2. Since 1980, Endeavour Resources and its co-venturers have pursued an active exploration programme which has resulted in the recognition of significant petroleum potential in the New South Wales portion of the basin.Previous studies indicated that the Upper Triassic to Lower Cretaceous Clarence-Moreton Basin sequence in general, lacked suitable reservoirs and had poor source- rock potential. While exinite rich, oil-prone source rocks were recognised in the Middle Jurassic Walloon Coal Measures, they were considered immature for oil generation. Moreover, during the 1960's the basin acquired a reputation as an area where seismic records were of poor quality.These ideas are now challenged following the results of a new round of exploration which commenced in the New South Wales portion of the basin in 1980. This exploration has involved the acquisition of over 1000 km of multifold seismic data, the reprocessing of some 200 km of existing single fold data, and the drilling of one wildcat well. Over twenty large structural leads have been identified, involving trapping mechanisms ranging from simple drape to antithetic and synthetic fault blocks associated with normal and reverse fault dependent and independent closures.The primary exploration targets in the Clarence- Moreton Basin sequence are Lower Jurassic sediments comprising a thick, porous and permeable sandstone unit in the Bundamba Group, and channel and point-bar sands in the Marburg Formation. Source rocks in these and the underlying Triassic coal measures are gas-prone and lie at maturity levels compatible with gas generation. In contrast, it was established from the results of Shannon 1 that the Walloon Coal Measures are mature for oil generation and this maturity regime is now considered to be applicable to most of the basin in New South Wales.A consideration of reservoir and source rock distribution, together with structural trends across the basin in Petroleum Exploration Licences 258 and 259, has led to the identification of three prospective fairways, two of which involve shallow oil plays. Exploration of these fairways is currently the focus of an ongoing programme of further seismic data acquisition and drilling.

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