Milestones in microwave-assisted organophosphorus chemistry

2016 ◽  
Vol 88 (10-11) ◽  
pp. 931-939 ◽  
Author(s):  
György Keglevich ◽  
Nóra Zs. Kiss ◽  
Zoltán Mucsi
Keyword(s):  
Arrhenius Equation ◽  
Conventional Heating ◽  
Organic Chemical ◽  
Order Kinetic ◽  
First Order ◽  
Microwave Assisted ◽  
Pseudo First Order ◽  
Catalyst Systems ◽  
Organophosphorus Chemistry ◽  
Order Kinetic Equation

AbstractOur recent results in the field of microwave (MW)-assisted organophosphorus syntheses, especially regarding esterifications, condensations, substitutions and additions are surveyed. Beside making organic chemical reactions more efficient, it was possible to perform transformations that are reluctant on conventional heating. Another option is to substitute catalysts, or to simplify catalyst systems under MW conditions. It is also the purpose of this paper to elucidate the scope and limitations of the MW tool, to interpret the MW effects, and to model the distribution of the local overheatings and their beneficial effect. All these considerations are possible on the basis of the enthalpy of activations determined by us utilizing the Arrhenius equation and the pseudo first order kinetic equation.

Degradation of 4-nitrophenol using the Fenton process

2000 ◽  
Vol 42 (3-4) ◽  
pp. 155-160 ◽  
Author(s):  
Y.-S. Ma ◽  
S.-T. Huang ◽  
J.-G. Lin
Keyword(s):  
Kinetic Equation ◽  
Nitrogen Concentration ◽  
Order Kinetic ◽  
Fenton Process ◽  
Nitrogenous Compounds ◽  
First Order ◽  
Degradation Rate Constant ◽  
Before And After ◽  
Pseudo First Order ◽  
Order Kinetic Equation

In this study, The Fenton process was applied as a pretreatment method to treat industrial wastewater containing 4-nitrophenol (4-NP). The effect of oxidant dosages on the decomposition of 4-NP and the reaction kinetics were investigated. More than 99% of 4-NP was readily decomposed when the reaction was carried out at oxidant concentrations of 5 mM H2O2 and 5 mg/L Fe2+ for 2 hours. The total nitrogenous compounds and the nitrogen gas evolved, accounted for 88% of the initial nitrogen concentration. However, the maximum DOC removal efficiency was 30.6%; and only 1/3 of 4-NP was mineralized to carbon dioxide by the Fenton process. 4-NP degradation profiles fitted well into a pseudo first-order kinetic equation; degradation rate constant (min-1) of 4-NP increased from 4.3×10-3 to 66.1×10-3 with increasing dosages of H2O2 and Fe2+. In addition, the t value was calculated for studying the significance of simulation by the t-test. It was found that the t value was greater than the value for 99% confidence. This result suggested that the 4-NP decomposition profile could be described by the pseudo first-order kinetic equation. Biodegradability of 4-NP before and after the reaction was 0.018 and 0.594, respectively.

scholarly journals Ganglioside incorporation and release by the isolated perfused rat liver

1991 ◽  
Vol 274 (2) ◽  
pp. 581-585 ◽  
Author(s):  
S C Kivatinitz ◽  
A Miglio ◽  
R Ghidoni
Keyword(s):  
Rat Liver ◽  
The Other ◽  
Regulatory Role ◽  
Isolated Perfused Rat Liver ◽  
Order Kinetic ◽  
Perfused Rat Liver ◽  
Ganglioside Gm1 ◽  
First Order ◽  
Pseudo First Order

The fate of exogenous ganglioside GM1 labelled in the sphingosine moiety, [Sph-3H]GM1, administered as a pulse, in the isolated perfused rat liver was investigated. When a non-recirculating protocol was employed, the amount of radioactivity in the liver and perfusates was found to be dependent on the presence of BSA in the perfusion liquid and on the time elapsed after the administration of the ganglioside. When BSA was added to the perfusion liquid, less radioactivity was found in the liver and more in the perfusate at each time tested, for up to 1 h. The recovery of radioactivity in the perfusates followed a complex course which can be described by three pseudo-first-order kinetic constants. The constants, in order of decreasing velocity, are interpreted as: (a) the dilution of the labelled GM1 by the constant influx of perfusion liquid; (b) the washing off of GM1 loosely bound to the surface of liver cells; (c) the release of gangliosides from the liver. Process (b) was found to be faster in the presence of BSA, probably owing to the ability of BSA to bind gangliosides. The [Sph-3H]GM1 in the liver underwent metabolism, leading to the appearance of products of anabolic (GD1a, GD1b) and catabolic (GM2, GM3) origin; GD1a appeared before GM2 and GM3 but, at times longer than 10 min, GM2 and GM3 showed more radioactivity than GD1a. At a given time the distribution of the radioactivity in the perfusates was quite different from that of the liver. In fact, after 60 min GD1a was the only metabolite present in any amount, the other being GM3, the quantity of which was small. This indicates that the liver is able to release newly synthesized gangliosides quite specifically. When a recirculating protocol was used, there were more catabolites and less GD1a than with the non-recirculating protocol. A possible regulatory role of ganglioside re-internalization on their own metabolism in the liver is postulated.

scholarly journals Enhanced photocatalytic activity of wool-ball-like TiO2 microspheres on carbon fabric and FTO substrates

2018 ◽  
Vol 38 ◽  
pp. 02014
Author(s):  
Yu Zhang ◽  
Jian Gu ◽  
Mengqi Zhang
Keyword(s):  
Hydrothermal Method ◽  
Order Kinetic ◽  
Carbon Fabric ◽  
Facile Hydrothermal Method ◽  
Sem Images ◽  
First Order ◽  
Good Crystallinity ◽  
Degradation Rate Constant ◽  
Order Kinetic Model ◽  
Pseudo First Order

The wool-ball-like TiO2 microspheres on carbon fabric (TiO2-CF) and FTO substrates (TiO2-FTO) have been synthesized by a facile hydrothermal method in alkali environment, using commercial TiO2 (P25) as precursors. The XRD results indicate that the as-prepared TiO2 have good crystallinity. And the SEM images show that the wool-ball-like TiO2 microspheres with a diameter of 2-3 μm are composed of TiO2 nanowires, which have a diameter of ~50 nm. The photocatalytic behavior of the wool-ball-like TiO2 microspheres, TiO2-CF and TiO2-FTO under ultraviolet light was investigated by a pseudo first-order kinetic model, using methyl orange (MO) as pollutant. The wool-ball-like TiO2 microspheres obtained a degradation rate constant (Kap) of 6.91×10-3 min-1 . The Kap values of TiO2-FTO and TiO2-CF reach 13.97×10-3 min-1 and 11.80×10-3 min-1, which are 2.0 and 1.7 times higher than that of pristine wool-ball-like TiO2 microspheres due to the “sum effect” between TiO2 and substrates. This study offers a facile hydrothermal method to prepare wool-ball-like TiO2 microspheres on CF and FTO substrates, which will improve the recyclability of phtocatalysts and can be extended to other fields.

scholarly journals Photocatalytic degradation of indigo carmine by ZnO photocatalyst under visible light irradiation

2017 ◽  
Vol 14 (3) ◽  
pp. 582-587
Author(s):  
Baghdad Science Journal
Keyword(s):  
Zinc Oxide ◽  
Photocatalytic Degradation ◽  
Indigo Carmine ◽  
Catalyst Loading ◽  
Order Kinetic ◽  
Kinetic Reaction ◽  
First Order ◽  
Pseudo First Order ◽  
The Relationship ◽  
Influential Parameters

In this work, the photocatalytic degradation of indigo carmine (IC) using zinc oxide suspension was studied. The effect of influential parameters such as initial indigo carmine concentration and catalyst loading were studied with the effect of Vis irradiation in the presence of reused ZnO was also investigated. The increased in initial dye concentration decreased the photodegradation and the increased catalyst loading increased the degradation percentage and the reused-ZnO exhibits lower photocatalytic activity than the ZnO catalyst. It has been found that the photocatalytic degradation of indigo carmine obeyed the pseudo-first-order kinetic reaction in presence of zinc oxide. This was found from plotting the relationship between ln (C0/Ct) and irradiation the rate constant of the process.UV- spectrophotometer was used to study the indigo carmine photodegradation.

scholarly journals Effect of inoculum to substrate ratio on biogas production of sheep paunch manure

2016 ◽  
Vol 62 (No. 1) ◽  
pp. 8-14 ◽  
Author(s):  
A.A. Lawal ◽  
A.U. Dzivama ◽  
M.K. Wasinda
Keyword(s):  
Biogas Production ◽  
Coefficient Of Determination ◽  
Order Kinetic ◽  
Production Rates ◽  
Exponential Equation ◽  
First Order ◽  
Gompertz Equation ◽  
Volatile Solids ◽  
Substrate Ratio ◽  
Order Kinetic Equation

Sheep paunch manure was anaerobically digested to study the effect of inoculum to substrate ratio on biogas production rates and accumulation. Inoculum to substrate ratios of 1.37, 2.05 and 4.1 were digested in biodigesters labelled R1, R2 and <br /> R3 respectively. Results showed that inoculum to substrate ratio had a significant effect on biogas production rates and accumulation. Biogas production rates increased to peak in the order of R3 (0.30526 Nm<sup>3</sup>/kg volatile solids (VS) days), R2 (0.15308 Nm<sup>3</sup>/kg VS d) and R1 (0.11009 Nm<sup>3</sup>/kg VS d) on the 5<sup>th</sup> day. The biogas production accumulation increased from 0.57195 to 1.46784 Nm<sup>3</sup>/kg VS as the inoculum to substrate ratio increased. The result of regression showed that coefficient of determination values for the linear equation ranged from 0.707 to 0.797, while the exponential equation had higher values that ranged from 0.7718 to 0.9929 showing better simulation. The modified Gompertz equation showed better simulation of the biogas production accumulation than the first order kinetic equation due to its higher coefficient of determination values.

Associations of ajmaline and homatropine with bromocresol green and bromophenol blue in dichloromethane: thermodynamic and kinetic parameters

1987 ◽  
Vol 65 (6) ◽  
pp. 1279-1291 ◽  
Author(s):  
Alberto Hernández Gaínza
Keyword(s):  
Thermodynamic Parameters ◽  
Arrhenius Equation ◽  
Charge Transfer Complex ◽  
Ion Pairs ◽  
Bromocresol Green ◽  
Bromophenol Blue ◽  
Order Kinetic ◽  
Large Excess ◽  
First Order ◽  
Hoff Equation

Ajmaline (AJ) and homatropine (HM) react with bromocresol green (BCG) and bromophenol blue (BPB) in dichloromethane forming 1:1 and 1:2 ion pairs clearly in a chemical equilibrium. Thermodynamic parameters ΔG0, ΔH0, and ΔS0 are calculated using the Van't Hoff equation. In a large excess of HM a product P is formed from the 1:2 ion pair in a pseudo-first order kinetic process which fits Arrhenius' equation. The P product has been identified as a type of charge transfer complex. The thermodynamic parameters corresponding to the formation of the ion pairs BPB—(AJ)2, BCG—(AJ)2, BPB—(HM)2, and BCG—(HM)2 are, respectively: ΔG0 at 294 K, −26, −21, −26, and −19 kJ/mol; ΔH0, −63, −39, −63, and −61 kJ/mol; ΔS0, −125, −62, −125, and −138 J/K mol (ΔH0 and ΔS0 determined in a 288 to 313 K range). The values of the activation energy, Ea, for the reaction of HM (in large excess) with BCG and BPB are 58 and 91 kJ/mol.

Evidence for the formation of lignin-hexenuronic acid-xylan complexes during modified kraft pulping processes

Holzforschung ◽  
2006 ◽  
Vol 60 (2) ◽  
pp. 137-142 ◽  
Author(s):  
Zhi-Hua Jiang ◽  
Jean Bouchard ◽  
Richard Berry
Keyword(s):  
Acid Hydrolysis ◽  
Kraft Pulp ◽  
Kraft Pulping ◽  
Order Kinetic ◽  
Kraft Pulps ◽  
First Order ◽  
Pseudo First Order ◽  
Hexenuronic Acid ◽  
Kinetics Of ◽  
Hydrolysis Of

Abstract The finding that hexenuronic acid (HexA) groups can be selectively removed from kraft pulps by acid hydrolysis has provided an opportunity to reduce bleaching chemicals. However, there is evidence that the acid hydrolysis is not uniform. In this report, we evaluate the kinetics of acid hydrolysis of HexA in a xylan sample enriched with HexA, a conventional kraft pulp, and three modified kraft pulps: anthraquinone pulp (Kraft-AQ), polysulfide pulp (PS), and polysulfide-anthraquinone pulp (PS-AQ). We found that HexA present in the xylan and conventional kraft pulp behaved similarly toward the acid hydrolysis throughout. On the other hand, HexA present in the Kraft-AQ, PS-AQ and PS pulps was heterogeneous toward acid hydrolysis and the reaction can be separated into two pseudo-first-order kinetic phases, each of which has a different rate constant. The kinetic data provide evidence for the formation of lignin-HexA-xylan complexes during modified kraft pulping processes.

scholarly journals Adsorption of Cu (II) and Ni (II) Ions from Solution onto Calcium Alginate Beads

2020 ◽  
Vol 24 (2) ◽  
pp. 329-333
Author(s):  
D.O. Jalija ◽  
A . Uzairu
Keyword(s):  
Contact Time ◽  
Calcium Alginate ◽  
Alginate Beads ◽  
Second Order ◽  
Ion Concentration ◽  
Order Kinetic ◽  
Calcium Alginate Beads ◽  
First Order ◽  
Pseudo Second Order ◽  
Pseudo First Order

The objective of this study was to investigate the biosorption of Cu (II) and Ni (II) ions from aqueous solution by calcium alginate beads. The effects of solution pH, contact time and initial metal ion concentration were evaluated. The results showed that maximum Cu (II) removal (93.10%) occurred at pH of 9.0, contact time of 120 minutes and initial ion concentration of 10 mg/L while that of Ni (II) was 94.6%, which was achieved at pH of 8.0, contact time of 120 minutes and initial ion concentration of 10 mg/L. The equilibrium data fitted well to the Langmuir Isotherm indicating that the process is a monolayer adsorption. The coefficients of determination, R2, values for the Langmuir Isotherm were 0.9799 and 0.9822 respectively for Cu (II) and Ni (II) ions. The values of the maximum biosorption capacity, Qo, were 10.79 and 6.25 mgg-1 respectively. The kinetic data also revealed that the sorption process could best be described by the pseudo – second order kinetic model. The R2 values for the pseudo – second order kinetic plots for Cu (II) and Ni (II) were 0.9988 and 0.9969 respectively. These values were higher than those for the pseudo – first order plots. The values of the biosorption capacity qe obtained from the pseudo – second order plots were very close to the experimental values of qe indicating that the biosorption process follows the second order kinetics. This study has therefore shown that calcium alginate beads can be used for the removal of Cu (II) and Ni (II) ions from wastewaters. Keywords: Keywords: Adsorption, Calcium alginate, Isotherm, Langmuir, Pseudo- first order, Pseudo-second order

scholarly journals Oxidative Degradation of Amoxicillin in Aqueous Solution by Thermally Activated Persulfate

2019 ◽  
Vol 2019 ◽  
pp. 1-10 ◽  
Author(s):  
Juanjuan Zhao ◽  
Yujiao Sun ◽  
Fachao Wu ◽  
Minjian Shi ◽  
Xurui Liu
Keyword(s):  
Aqueous Solution ◽  
Reaction Temperature ◽  
Oxidative Degradation ◽  
Water Remediation ◽  
Order Kinetic ◽  
Production Chain ◽  
First Order ◽  
Thermally Activated ◽  
Pseudo First Order ◽  
Activated Persulfate

Antibiotic residues and antibiotic resistance genes (ARGs) pose a great threat to public health and food security via the horizontal transfer in the food production chain. Oxidative degradation of amoxicillin (AMO) in aqueous solution by thermally activated persulfate (TAP) was investigated. The AMO degradation followed a pseudo-first-order kinetic model at all tested conditions. The pseudo-first-order rate constants of AMO degradation well-fitted the Arrhenius equation when the reaction temperature ranged from 35°C to 60°C, with the apparent activate energy of 126.9 kJ·mol−1. High reaction temperature, high initial persulfate concentration, low pH, high Cl− concentration, and humic acid (HA) concentration increased the AMO degradation efficiency. The EPR test demonstrated that both ·OH and SO4·− were generated in the TAP system, and the radical scavenging test identified that the predominant reactive radical species were SO4·− in aqueous solution without adjusting the solution pH. In groundwater and drinking water, AMO degradation suggested that TAP could be a reliable technology for water remediation contaminated by AMO in practice.

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