Abstract
Antimony (Sb) and tin (Sn) in soils along railway lines pose a serious environmental risk. The study, conducted at 60 sites along the 160 km railway line connecting the Croatian capital Zagreb with surrounding smaller settlements and towns, showed pronounced soil Sb and Sn enrichment up to 87 and 33 times the median for European soils, respectively. The total mass fractions of Sb ranged from 0.98 to 52.0 mg/kg and of Sn from 3.04 mg/kg to 97.6 mg/kg. The origin of the enrichment is railway traffic, but precise sources are difficult to define, however available literature points to abrasion from brakes, rails, wheels and overhead wires, exhaust fumes from locomotive engines and cargo waste as predominant sources. The comprehensive data analysis suggested that the Sb and Sn distribution in soils near railway lines was not only conditioned by natural factors such as soil texture, humus content and soil pH, but also by the distance to the tracks, which is not necessarily linear, the site functionality, the topography and the age of the railway line. Observed soil contamination with antimony and tin requires further research to increase knowledge of the impact of railways on Sb and Sn soil content, and to establish safety distances that will ensure the least possible impact of rail traffic on nearby crops and prevent their excessive entry into the food chain.