scholarly journals Length Scale Plasticity: A Review from the Perspective of Dislocation Nucleation

2018 ◽  
Vol 56 (1) ◽  
pp. 21-61 ◽  
Author(s):  
Mahdi Bagheripoor ◽  
Robert Klassen

Abstract Sub-micron and nano-size material systems and components are now regularly being fabricated for use in a wide variety of new applications. These systems exhibit mechanical properties that can be drastically different from their macroscopic counterparts and recently much work has focused on the size effects on the mechanical behaviour of materials. Although the size dependent behaviour has been observed in all of the crystal structures, the governing mechanisms have been found to be different. Different theories have been proposed to describe the size dependent behaviour of metallic samples and the governing mechanisms and it is well known that the surface plays an important role in the plasticity of small scales. Some of the theories indicate the importance of surface in nucleating dislocation and some other ones consider the surface importance as its effect on truncating dislocation loops and activation of internal sources. Moreover, recent studies have revealed that while dislocation based deformation in fcc metals is not very sensitive to temperature, deformation is strongly temperature dependent in bcc metals. The effect of orientation is more clear in the size scale behavior of hcp metals. This review covers recent literature that has focused on uniaxial compression of single crystals at the sub-micron and nanometer scale. The fundamental mechanisms governing the size dependent mechanical behaviour of different crystal structures are described. The effect of fabrication process and current experimental techniques for micro and nano-compression are studied as well.

2016 ◽  
Vol 18 (31) ◽  
pp. 21508-21517 ◽  
Author(s):  
Xiao-Ye Zhou ◽  
Bao-Ling Huang ◽  
Tong-Yi Zhang

Surfaces of nanomaterials play an essential role in size-dependent material properties.


2017 ◽  
Vol 229 ◽  
pp. 31-44 ◽  
Author(s):  
W.G.P. Kumari ◽  
P.G. Ranjith ◽  
M.S.A. Perera ◽  
B.K. Chen ◽  
I.M. Abdulagatov

Metals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 2000
Author(s):  
Marcelo Roldán ◽  
Fernando José Sánchez ◽  
Pilar Fernández ◽  
Christophe J. Ortiz ◽  
Adrián Gómez-Herrero ◽  
...  

In the present investigation, high-energy self-ion irradiation experiments (20 MeV Fe+4) were performed on two types of pure Fe samples to evaluate the formation of dislocation loops as a function of material volume. The choice of model material, namely EFDA pure Fe, was made to emulate experiments simulated with computational models that study defect evolution. The experimental conditions were an ion fluence of 4.25 and 8.5 × 1015 ions/cm2 and an irradiation temperature of 350 and 450 °C, respectively. First, the ions pass through the samples, which are thin films of less than 100 nm. With this procedure, the formation of the accumulated damage zone, which is the peak where the ions stop, and the injection of interstitials are prevented. As a result, the effect of two free surfaces on defect formation can be studied. In the second type of experiments, the same irradiations were performed on bulk samples to compare the creation of defects in the first 100 nm depth with the microstructure found in the whole thickness of the thin films. Apparent differences were found between the thin foil irradiation and the first 100 nm in bulk specimens in terms of dislocation loops, even with a similar primary knock-on atom (PKA) spectrum. In thin films, the most loops identified in all four experimental conditions were b ±a0<100>{200} type with sizes of hundreds of nm depending on the experimental conditions, similarly to bulk samples where practically no defects were detected. These important results would help validate computational simulations about the evolution of defects in alpha iron thin films irradiated with energetic ions at large doses, which would predict the dislocation nucleation and growth.


2014 ◽  
Vol 92 (10) ◽  
pp. 958-965 ◽  
Author(s):  
Stéphanie Poirier ◽  
Philippe Guionneau ◽  
Dominique Luneau ◽  
Christian Reber

Temperature-dependent luminescence spectra for a series of palladium(II) and platinum(II) complexes with thiocyanate, halide, and dithiocarbamate ligands are presented. All complexes show broad d−d luminescence. Crystal structures are reported for (n-Bu4N)2[Pt(SCN)4] and (n-Bu4N)2[Pd(SCN)4] at 150 and 250 K, for the palladium(II) dimethyldithiocarbamate (MeDTC) complex [Pd(MeDTC)2] at 150 and 300 K, and for its platinum(II) analog at 100 and 300 K. The structures of (n-Bu4N)2[Pt(SCN)4], (n-Bu4N)2[Pd(SCN)4], and [Pt(MeDTC)2] show similar volume increases with temperature. In contrast, the luminescence band maxima of palladium(II) and platinum(II) complexes have opposite shifts with increasing temperature. (n-Bu4N)2[Pd(SCN)4] shows a shift of −2.0 cm−1/K and [Pd(MeDTC)2] a shift of −1.1 cm−1/K, while both platinum(II) complexes have a positive shift of +1.6 cm−1/K. Calculated luminescence spectra with adjustable parameters reproduce the experimental spectra. The variation of their parameters with temperature shows the origin of different trends. Temperature-dependent luminescence spectra of [Pd(SCN)4]2− and [Pt(SCN)4]2− in polymer films of polyvinyl alcohol were measured. No clearcut shifts of maxima were observed for either compound, and their spectra are broader due to the disordered environment.


2003 ◽  
Vol 58 (12) ◽  
pp. 722-726 ◽  
Author(s):  
A. Waśkowska ◽  
S. Dacko ◽  
Z. Czapla

Crystals of [(CH2OH)3CNH3]H2AsO4 have been grown, and X-ray diffraction analysis has shown them to be monoclinic, with space group P21. A three-dimensional network of hydrogen bonds of the type O-H. . . O and N-H. . . O forms strong cation-cation and cation-anion linkages. Stabilizing the structure, they create favourable conditions in the crystal to be polar. The temperature dependent behaviour of the dielectric permittivity, measured along three crystal axes in the range 100 - 300 K, did not show any evidence for a phase transition, while the pyroelectric properties of the crystal confirmed the lack of a centre of symmetry. These polar features locate [(CH2OH)3CNH3]H2AsO4 among the materials applicable to electrooptics and for the second harmonic generation.


Sign in / Sign up

Export Citation Format

Share Document