Substrate and film structure impacts on adhesion properties between lignocellulosic polymers

2012 ◽  
Vol 1422 ◽  
Author(s):  
Elias Estephan ◽  
Véronique Aguié-Béghin ◽  
Loïc Muraille ◽  
Michael Molinari

ABSTRACTUsing AFM, ellipsometric and profilometric measurements, we have investigated the topography and the thickness of the cellulose nanocristal (NCC) films prepared by two different methods: the first one is obtained by evaporation of concentrated suspension of NCC in petri-dish to produce a self-supported film; the second one is produced by dipping thin NCC layer on silicon substrate by Langmuir-Blodgett (LB) technique. Glucomanan (GM) functionalized AFM tip was brought into contact with these two kinds of NCC films in order to measure the adhesion between GM and NCC. The impact of the substrate and the thickness of NCC films on the measured adhesion forces were also studied: the mean measured adhesion force between the two polysaccharides was 17 nN regardless of the way the films were prepared. Adhesion properties can help us understand biochemical processes in the plant cell wall.


Geofluids ◽  
2021 ◽  
Vol 2021 ◽  
pp. 1-11
Author(s):  
Tao Qiu ◽  
Yonggang Zhang

Mud cakes are very likely to occur at the shield cutter when the shield machine passes through a clay stratum, which adhere to the cutter and reduce the excavation efficiency. Due to the thrust of the cutter, the mud cakes are compacted and cause friction at the soil-structure interface, which results in high temperature and aggravates the adhesion, and the effect tends to become stronger as the heating process lasts. In this paper, the effects of the interface temperature and the contacting time between the soil and the hot surface on the adhesion properties of the soil were studied by a self-made adhesion test device. According to the findings, at low interfacial temperature (≤40°C), both the adhesion force and the amount of adhered soil were insignificant in a short term, and the effects were found to be strengthened as the contacting time went on; at the high interfacial temperature (≥50°C), very significant soil adhesion occurred at the structure surface within a short time, and as the contacting time increased, the amount of the adhered soil decreased rapidly while the adhesion force kept increasing, and both tended to remain a constant and become independent with the temperature after a long-term contact. This study is of guiding significance for understanding the formation and development of the shield mud cakes during shield construction.



2022 ◽  
Vol 10 (1) ◽  
pp. 81
Author(s):  
Kaoru Uesugi ◽  
Kazuaki Nagayama ◽  
Euichi Hirose

While nanoscale nipple arrays are expected to reduce light reflection and/or dust contamination in some insects, similar structures have been reported in various marine invertebrates. To evaluate the anti-contamination property of the structure in aquatic regimes, we measured the adsorption and adhesion forces on the flat surface and MOSMITE™ (Mitsubishi Chemical Corporation, Tokyo, Japan), a synthetic material mimicking the nipple array, under water. A small force toward the surface occurred when the probe approached the substrate surface. This adsorption force was significantly smaller on MOSMITE™ than on the flat surface. The adhesion force toward the surface occurred when the probe was detached from the surface, and it was also significantly smaller on MOSMITE™ than on the flat surface. The adhesion force in the air was much greater than the force under water, and the force was also significantly smaller on MOSMITE™ than on the flat surface. In the aquatic regime, the nipple array provides less adsorption/adhesion properties for the surface and thus, the organisms would have less contamination of microparticles on their body surface. As the adsorption and adhesion forces are also involved in the attachment of cells, tissue, and larvae, less adhesive body surfaces should be beneficial for survival in aquatic environments, as well as land environments.



2020 ◽  
Vol 29 ◽  
pp. 2633366X2091244
Author(s):  
Yishu Zhang ◽  
Long Chen ◽  
Hui Liu

An anti-/deicing component of composite materials for wind turbine blades is usually carried out under heating conditions. In order to study the ice adhesion properties of composite anti-/deicing component under heating conditions, an experimental platform for measuring ice adhesion force on composites was set up. Based on the heating parameters such as the heating temperature, heating voltage, and heating time, the experiments of ice adhesion of composite anti-/deicing component under deicing conditions were designed by orthogonal analysis. In this article, ice adhesion forces on composite anti-/deicing component were measured at −9.74°C, −11.58°C, −14.1°C, and −16.84°C by the proposed experiment platform, and the real ice adhesion forces under various heating parameters were measured. Through the analysis of experimental data and fitting method, the relationship between various factors and ice adhesion on composite anti-/deicing component was expounded. The influence weight of each heating parameter on the ice adhesion was analyzed. In addition, the mathematical model of ice adhesion on composite anti-/deicing component under deicing condition was established to describe the influence of deicing variables on ice adhesion in the experiments. According to the fitting function of the experimental data, the relationship between the heat consumption of composite anti-/deicing component and ice adhesion force in the process of heating is in accordance with the inverse power exponential expression, which reveals the internal relationship between ice adhesion force and energy consumption.



2021 ◽  
Vol 4 (1) ◽  
Author(s):  
Andoni Garitano-Trojaola ◽  
Ana Sancho ◽  
Ralph Götz ◽  
Patrick Eiring ◽  
Susanne Walz ◽  
...  

AbstractThe presence of FMS-like tyrosine kinase 3-internal tandem duplication (FLT3-ITD) is one of the most frequent mutations in acute myeloid leukemia (AML) and is associated with an unfavorable prognosis. FLT3 inhibitors, such as midostaurin, are used clinically but fail to entirely eradicate FLT3-ITD + AML. This study introduces a new perspective and highlights the impact of RAC1-dependent actin cytoskeleton remodeling on resistance to midostaurin in AML. RAC1 hyperactivation leads resistance via hyperphosphorylation of the positive regulator of actin polymerization N-WASP and antiapoptotic BCL-2. RAC1/N-WASP, through ARP2/3 complex activation, increases the number of actin filaments, cell stiffness and adhesion forces to mesenchymal stromal cells (MSCs) being identified as a biomarker of resistance. Midostaurin resistance can be overcome by a combination of midostaruin, the BCL-2 inhibitor venetoclax and the RAC1 inhibitor Eht1864 in midostaurin-resistant AML cell lines and primary samples, providing the first evidence of a potential new treatment approach to eradicate FLT3-ITD + AML.



2016 ◽  
Vol 51 (11) ◽  
pp. 1573-1581 ◽  
Author(s):  
Somayeh Safi ◽  
Ali Zadhoush ◽  
Mahmood Masoomi

The performance of a composite material system depends critically on the interfacial characteristics of the reinforcement and the matrix material. In this study, the interfacial adhesion was tailored by the creation of textures on the glass fiber surface using inorganic-organic silane blends. A single-fiber microdroplet test was conducted to assess the interfacial properties between the textured glass surface and an epoxy matrix. The load–displacement curves from microdroplet tests were analyzed. The stress-based and energy-based micromechanic models of interfacial debonding and corresponding adhesional parameters (apparent and ultimate interfacial shear strength, friction stress, critical energy release rate, work of adhesion, and adhesional pressure) were applied for theoretical calculations. The results showed a clear trend for the impact of different silane blends on the interfacial properties. The specimens containing 75:25 and 50:50 of inorganic–organic silane blends show the most effective improvement in the interfacial adhesion properties between glass fiber and epoxy resin. Scanning electron microscopy was used to visualize the failure surface of the specimen after the microdroplet test. The scanning electron microscopic images indicated that the failure in the blend sized treated glass fiber–epoxy matrix specimen runs predominantly along the interphase and combines both cohesive failure in resin (the presence of some resin fragments) and adhesive failure (some bare fiber surfaces can be seen).



1992 ◽  
Vol 81 (3) ◽  
pp. 231-234
Author(s):  
V.I. Antonenko ◽  
P.A. Todua ◽  
D.A. Znamensky ◽  
Yu.N. Moiseev ◽  
V.I. Panov


2016 ◽  
Vol 43 (4) ◽  
pp. 324 ◽  
Author(s):  
Supriya Tiwari ◽  
Rüdiger Grote ◽  
Galina Churkina ◽  
Tim Butler

High concentrations of ozone (O3) can have significant impacts on the health and productivity of agricultural and forest ecosystems, leading to significant economic losses. In order to estimate this impact under a wide range of environmental conditions, the mechanisms of O3 impacts on physiological and biochemical processes have been intensively investigated. This includes the impact on stomatal conductance, the formation of reactive oxygen species and their effects on enzymes and membranes, as well as several induced and constitutive defence responses. This review summarises these processes, discusses their importance for O3 damage scenarios and assesses to which degree this knowledge is currently used in ecosystem models which are applied for impact analyses. We found that even in highly sophisticated models, feedbacks affecting regulation, detoxification capacity and vulnerability are generally not considered. This implies that O3 inflicted alterations in carbon and water balances cannot be sufficiently well described to cover immediate plant responses under changing environmental conditions. Therefore, we suggest conceptual models that link the depicted feedbacks to available process-based descriptions of stomatal conductance, photosynthesis and isoprenoid formation, particularly the linkage to isoprenoid models opens up new options for describing biosphere-atmosphere interactions.



2021 ◽  
Vol 8 (4) ◽  
pp. 783-796
Author(s):  
H. W. Salih ◽  
◽  
A. Nachaoui ◽  

In this work, we study an impulsive mathematical model proposed by Chavez et al. [1] to describe the dynamics of cancer growth and HIV infection, when chemotherapy and HIV treatment are combined. To better understand these complex biological phenomena, we study the stability of equilibrium points. To do this, we construct an appropriate Lyapunov function for the first equilibrium point while the indirect Lyapunov method is used for the second one. None of the equilibrium points obtained allow us to study the stability of the chemotherapeutic dynamics, we then propose a bifurcation of the model and make a study of the bifurcated system which contributes to a better understanding of the underlying biochemical processes which govern this highly active antiretroviral therapy. This shows that this mathematical model is sufficiently realistic to formulate the impact of this treatment.



Author(s):  
Kuahai Yu ◽  
Danesh Tafti

Sand ingestion and deposition in gas turbine engine components can lead to several operational hazards. This paper discusses a physics based model for modeling the impact and deposition of sand particles. The collision model divides the impact process into three stages, the elastic stage, the elastic-plastic stage, and full plastic stage. The recovery stage is assumed to be fully elastic. The contact force, contact radius and work of contact force are conformed to the Hertzian theory, using “Young’s modulus similarity” rule to predict the recovery displacement. The adhesion loss in the recovery stage is considered using Dunn’s model, which describes the adhesion force as an idealized line force with the contact radius. The validation case of steel spherical particle impact on a glass surface with the maximum Stokes number of 10000, shows that the adhesion model with elastoplastic impact model describes the experimental result well. When the Stokes number is less than 12, the particle deposits on the surface. Sand properties are characterized by size and temperature dependencies. Model predictions for particle sizes ranging from 0.5 to 50 micron, impact velocities up to 80 m/s, and temperatures above 1300 K are given and discussed. It is shown that both size and temperature have an effect on the deposition characteristics.



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