Molecular Mechanics of Organic Composite Materials: A Case Study of Cellulose-Adhesive System

2014 ◽  
Vol 1662 ◽  
Author(s):  
Lik-ho Tam ◽  
Denvid Lau
Keyword(s):  
Composite Material ◽  
Composite Materials ◽  
Interfacial Adhesion ◽  
Phenol Formaldehyde ◽  
Cellulose Fiber ◽  
Cellulose Fibers ◽  
Adhesive System ◽  
Dynamics Simulation ◽  
Load Bearing ◽  
Material Systems

ABSTRACTOrganic composite materials can be readily found in our daily life, such as plywood used in construction industry and bamboo composites as indoor and outdoor flooring materials. These organic composite material systems consist of cellulose fibers bonded with each other through adhesives, leading to a bonded system with a gradient structure that possesses a unique structural behavior which has a great potential to be used as load-bearing building materials. In view of the manufacturing process of such composite material systems and the structure in-between the cellulose fibers and the adhesives, the interfacial adhesion of such systems at multiscale would play a major role in determining their capability in load-bearing structural applications. In this research work, the interface between cellulose fiber and phenol-formaldehyde adhesive is chosen as a representative of the organic composite material system and molecular dynamics simulation is used for quantifying their mechanical properties and the corresponding interfacial adhesion. Here we demonstrate that cellulose fiber has a strong affinity to a phenol-formaldehyde adhesive with an adhesion energy of 151.3 mJ/m2. To the best of our knowledge, this is the first study that reports this material property for cellulose-adhesive system, which is three times larger than that between the gecko foot’s hair and the mineral surface. The mechanism of such strong adhesion is due to the possible hydrogen bonding between the cellulose and the adhesive.

Mechanical and dynamic mechanical properties of polystyrene composites reinforced with cellulose fibers

2015 ◽  
Vol 30 (9) ◽  
pp. 1242-1254 ◽  
Author(s):  
Matheus Poletto ◽  
Ademir J Zattera
Keyword(s):  
Mechanical Properties ◽  
Coupling Agent ◽  
Interfacial Adhesion ◽  
Cellulose Fiber ◽  
Cellulose Fibers ◽  
Dynamic Mechanical Properties ◽  
Filler Loading ◽  
Fixed Amount ◽  
Dynamic Mechanical ◽  
Damping Peak

The mechanical and dynamic mechanical properties of cellulose fibers-reinforced polystyrene composites were investigated as a function of cellulose fiber content and coupling agent effect. The composites were prepared using a corotating twin-screw extruder and after injection molding. Three levels of filler loading (10, 20, and 30 wt%) and a fixed amount of coupling agent (2 wt%) were used. The results showed that a cellulose fiber loading of more than 20 wt% caused decrease in the mechanical properties. The addition of coupling agent substantially improves the mechanical and dynamic mechanical properties. The use of coupling agent improved the storage modulus and reduced the damping peak values of the composites due to the improved interfacial adhesion. The height of the damping peak was found to be dependent on the content of cellulose fiber and the interfacial adhesion between fiber and matrix. The adhesion factor values confirm that the better adhesion occurs when coupling agent is used.

scholarly journals Comparative Analysis of the Selection of Lay-Up Stacking of Polymer Composite Load-Bearing Elements for the Tail Section of Fuselage Structure of the Light Aircraft

2021 ◽  
Vol 346 ◽  
pp. 03111
Author(s):  
Tun Lin Htet ◽  
P.V. Prosuntsov
Keyword(s):  
Composite Material ◽  
Comparative Analysis ◽  
Composite Materials ◽  
Design Optimization ◽  
Polymer Composite ◽  
Optimization Method ◽  
Load Bearing ◽  
Rear Part ◽  
Continuous Range ◽  
Selection Of

The problem of the selecting the optimal lay-up stacking of polymer composite materials for the load-bearing elements of the rear part of fuselage structure is considered. The comparison of two approaches to the design of the load-bearing elements is carried out. The first of them is the use of multilayered composite material for the load-bearing elements, the stacking angles of which is selected from a given discrete set, and the second is the use of composite material with a continuous range of variables in fabric lay-up angles. As a result design optimization, it is shown that using an optimization method with a continuous range of lay-angles allows reducing the weight of the load-bearing elements by 12.79%

scholarly journals Processing of polymer wood composite material from pine cone and the binder of phenol formaldehyde/PVAc/molasses and improvement of its properties

2022 ◽  
Author(s):  
Melih Şahinöz ◽  
Hüseyin Yılmaz ARUNTAŞ ◽  
Metin GÜRÜ
Keyword(s):  
Composite Material ◽  
Composite Materials ◽  
Flexural Strength ◽  
Water Resistance ◽  
Phenol Formaldehyde ◽  
Molding Pressure ◽  
Wood Composite ◽  
Hemp Fiber ◽  
Pine Cone ◽  
Pressure Time

Abstract This paper deals with the processing of polymer wood composite material from pine cone and the binder of phenol formaldehyde/PVAc/molasses and improvement of its properties. The production of pine cone based polymer binding and molasses added composite material, and the development of the non-flammability, insect attack and water resistance properties of this material has been studied in the research. To this end, pine cone, polyvinyl acetate (PVAc), phenol-formaldehyde, molasses, hemp fiber and waste colemanite have been used in the production of composite materials. It is aimed to produce a cheaper composite material less harmful to human health using plant based waste materials. According to the results of the flexural strength test conducted in the laboratory, the most suitable composite material producing parameters were detected as 0.25 filler/binder (f/b) ratio, 35% molasses ratio, 100°C molding pressure temperature, 49 kg/cm2 molding pressure, 240 µm mean particle size, 20 minutes for molding pressure time, 20% PF ratio and 0.5% hemp fiber ratio. It was determined that molasses could be used at a ratio of 35% for producing composite materials and, PF resin and hemp fiber samples provide the necessary water resistance. It was observed that the colemanite waste used in the mixture adds the nonflammability property to the composite material and decreases flexural strength and screw withdrawal strength.

Study of the Composite Materials Optimal Structure Containing a Hollow Aluminum and Silica Microsphere Dependence on Humidity

2020 ◽  
Vol 12 ◽  
Author(s):  
Alexandra Atyaksheva ◽  
Yermek Sarsikeyev ◽  
Anastasia Atyaksheva ◽  
Olga Galtseva ◽  
Alexander Rogachev
Keyword(s):  
Composite Material ◽  
Composite Materials ◽  
Strength Function ◽  
Theory And Practice ◽  
Optimal Structure ◽  
Optimal Size ◽  
Structure And Properties ◽  
Power Functions ◽  
Silica Microsphere ◽  
Heat Engineering

Aims:: The main goals of this research are exploration of energy-efficient building materials when replacing natural materials with industrial waste and development of the theory and practice of obtaining light and ultra-light gravel materials based on mineral binders and waste dump ash and slag mixtures of hydraulic removal. Background.: Experimental data on the conditions of formation of gravel materials containing hollow aluminum and silica microsphere with opportunity of receipt of optimum structure and properties depending on humidity with the using of various binders are presented in this article. This article dwells on the scientific study of opportunity physical-mechanical properties of composite materials optimization are considered. Objective.: Composite material contains hollow aluminum and silica microsphere. Method.: The study is based on the application of the method of separation of power and heat engineering functions. The method is based on the use of the factor structure optimality, which takes into account the primary and secondary stress fields of the structural gravel material. This indicates the possibility of obtaining gravel material with the most uniform distribution of nano - and microparticles in the gravel material and the formation of stable matrices with minimization of stress concentrations. Experiments show that the thickness of the cement shell, which performs power functions, is directly related to the size of the raw granules. At the same time, the thickness of the cement crust, regardless of the type of binder, with increasing moisture content has a higher rate of formation for granules of larger diameter. Results.: The conditions for the formation of gravel composite materials containing a hollow aluminosilicate microsphere are studied. The optimal structure and properties of the gravel composite material were obtained. The dependence of the strength function on humidity and the type of binder has been investigated. The optimal size and shape of binary form of gravel material containing a hollow aluminosilicate microsphere with a minimum thickness of a cement shell and a maximum strength function was obtained. Conclusion.: Received structure allows to separate power and heat engineering functions in material and to minimize the content of the excited environment centers.

scholarly journals Influence of Alkali Treatment on the Microstructure and Mechanical Properties of Coir and Abaca Fibers

Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2636
Author(s):  
Petr Valášek ◽  
Miroslav Müller ◽  
Vladimír Šleger ◽  
Viktor Kolář ◽  
Monika Hromasová ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Composite Materials ◽  
Alkali Treatment ◽  
Fiber Surface ◽  
Cellulose Fibers ◽  
Sem Analysis ◽  
Experimental Program ◽  
Time Interval ◽  
The European Union ◽  
Vegetable Fibers

Composite materials with natural fillers have been increasingly used as an alternative to synthetically produced materials. This trend is visible from a representation of polymeric composites with natural cellulose fibers in the automotive industry of the European Union. This trend is entirely logical, owing to a preference for renewable resources. The experimental program itself follows pronounced hypotheses and focuses on a description of the mechanical properties of untreated and alkali-treated natural vegetable fibers, coconut and abaca fibers. These fibers have great potential for use in composite materials. The results and discussion sections contribute to an introduction of an individual methodology for mechanical property assessment of cellulose fibers, and allows for a clear definition of an optimal process of alkalization dependent on the content of hemicellulose and lignin in vegetable fibers. The aim of this research was to investigate the influence of alkali treatment on the surface microstructure and tensile properties of coir and abaca fibers. These fibers were immersed into a 5% solution of NaOH at laboratory temperature for a time interval of 30 min, 1 h, 2 h, 3 h, 6 h, 12 h, 24 h, and 48 h, rinsed and dried. The fiber surface microstructures before and after the alkali treatment were evaluated by SEM (scanning electron microscopy). SEM analysis showed that the alkali treatment in the NaOH solution led to a gradual connective material removal from the fiber surface. The effect of the alkali is evident from the visible changes on the surface of the fibers.

scholarly journals Clinching of Thermoplastic Composites and Metals—A Comparison of Three Novel Joining Technologies

Materials ◽  
2021 ◽  
Vol 14 (9) ◽  
pp. 2286
Author(s):  
Benjamin Gröger ◽  
Juliane Troschitz ◽  
Julian Vorderbrüggen ◽  
Christian Vogel ◽  
Robert Kupfer ◽  
...  
Keyword(s):  
Computed Tomography ◽  
Composite Material ◽  
Process Design ◽  
Failure Mechanisms ◽  
Thermoplastic Composites ◽  
Material Structure ◽  
Shear Tests ◽  
Load Bearing ◽  
Lap Shear ◽  
Resultant Material

Clinching continuous fibre reinforced thermoplastic composites and metals is challenging due to the low ductility of the composite material. Therefore, a number of novel clinching technologies has been developed specifically for these material combinations. A systematic overview of these advanced clinching methods is given in the present paper. With a focus on process design, three selected clinching methods suitable for different joining tasks are described in detail. The clinching processes including equipment and tools, observed process phenomena and the resultant material structure are compared. Process phenomena during joining are explained in general and compared using computed tomography and micrograph images for each process. In addition the load bearing behaviour and the corresponding failure mechanisms are investigated by means of single-lap shear tests. Finally, the new joining technologies are discussed regarding application relevant criteria.

Hierarchical ZSM-22/PHTS composite material and its hydro-isomerization performance in hydro-upgrading of gasoline

2021 ◽  
Author(s):  
Jiyuan Fan ◽  
Chengkun Xiao ◽  
Jinlin Mei ◽  
Cong Liu ◽  
Aijun Duan ◽  
...  
Keyword(s):  
Composite Material ◽  
Composite Materials ◽  
Impregnation Method ◽  
Molar Ratios

CoMo series catalysts based on ZSM-22/PHTS (ZP) composite materials with different SiO2/Al2O3 molar ratios were prepared via the impregnation method. The properties of the ZP material and the corresponding catalysts...

scholarly journals Acoustic Emission and K-S Metric Entropy as Methods for Determining Mechanical Properties of Composite Materials

Sensors ◽  
2020 ◽  
Vol 21 (1) ◽  
pp. 145
Author(s):  
Lesław Kyzioł ◽  
Katarzyna Panasiuk ◽  
Grzegorz Hajdukiewicz ◽  
Krzysztof Dudzik
Keyword(s):  
Mechanical Properties ◽  
Acoustic Emission ◽  
Composite Material ◽  
Composite Materials ◽  
Testing Machine ◽  
Measurement Data ◽  
Entropy Method ◽  
Displacement Sensor ◽  
Metric Entropy ◽  
Plastic Phase

Due to the unique properties of polymer composites, these materials are used in many industries, including shipbuilding (hulls of boats, yachts, motorboats, cutters, ship and cooling doors, pontoons and floats, torpedo tubes and missiles, protective shields, antenna masts, radar shields, and antennas, etc.). Modern measurement methods and tools allow to determine the properties of the composite material, already during its design. The article presents the use of the method of acoustic emission and Kolmogorov-Sinai (K-S) metric entropy to determine the mechanical properties of composites. The tested materials were polyester-glass laminate without additives and with a 10% content of polyester-glass waste. The changes taking place in the composite material during loading were visualized using a piezoelectric sensor used in the acoustic emission method. Thanks to the analysis of the RMS parameter (root mean square of the acoustic emission signal), it is possible to determine the range of stresses at which significant changes occur in the material in terms of its use as a construction material. In the K-S entropy method, an important measuring tool is the extensometer, namely the displacement sensor built into it. The results obtained during the static tensile test with the use of an extensometer allow them to be used to calculate the K-S metric entropy. Many materials, including composite materials, do not have a yield point. In principle, there are no methods for determining the transition of a material from elastic to plastic phase. The authors showed that, with the use of a modern testing machine and very high-quality instrumentation to record measurement data using the Kolmogorov-Sinai (K-S) metric entropy method and the acoustic emission (AE) method, it is possible to determine the material transition from elastic to plastic phase. Determining the yield strength of composite materials is extremely important information when designing a structure.

scholarly journals Fabrication and Application of SERS-Active Cellulose Fibers Regenerated from Waste Resource

Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2142
Author(s):  
Shengjun Wang ◽  
Jiaqi Guo ◽  
Yibo Ma ◽  
Alan X. Wang ◽  
Xianming Kong ◽  
...  
Keyword(s):  
Au Nanoparticles ◽  
Cellulose Fiber ◽  
Cellulose Fibers ◽  
Regenerated Cellulose ◽  
Sers Substrate ◽  
Au Nps ◽  
Convenient Approach ◽  
Theoretical Simulations ◽  
Difference Time ◽  
Raman Probe

The flexible SERS substrate were prepared base on regenerated cellulose fibers, in which the Au nanoparticles were controllably assembled on fiber through electrostatic interaction. The cellulose fiber was regenerated from waste paper through the dry-jet wet spinning method, an eco-friendly and convenient approach by using ionic liquid. The Au NPs could be controllably distributed on the surface of fiber by adjusting the conditions during the process of assembling. Finite-difference time-domain theoretical simulations verified the intense local electromagnetic fields of plasmonic composites. The flexible SERS fibers show excellent SERS sensitivity and adsorption capability. A typical Raman probe molecule, 4-Mercaptobenzoicacid (4-MBA), was used to verify the SERS cellulose fibers, the sensitivity could achieve to 10−9 M. The flexible SERS fibers were successfully used for identifying dimetridazole (DMZ) from aqueous solution. Furthermore, the flexible SERS fibers were used for detecting DMZ from the surface of fish by simply swabbing process. It is clear that the fabricated plasmonic composite can be applied for the identifying toxins and chemicals.

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