Apparent Inversion of the Effect of Alloyed Molybdenum for Corrosion of Ordinary and Enhanced 316L Stainless Steel in Sulfuric Acid

2008 ◽  
Vol 1107 ◽  
Author(s):  
Gloria Kwong ◽  
Anatolie Carcea ◽  
Roger C. Newman

AbstractAn aging assessment of the OPG waste resin storage system predicted the potential for premature failure of the carbon steel resin liners. Consequently, resin liners made of 316L stainless steel with a minimum content of 2.5% molybdenum were selected to replace the carbon steel liners. The 2.5% Mo 316L stainless steel was specified to enhance pitting resistance in the spent resin environment. With the additional Mo, one would expect that a brief electrochemical corrosion test will reveal the superiority of such alloy over conventional 316L steel. This study reports a contrary experience

Coatings ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1567
Author(s):  
Hany S. Abdo ◽  
Asiful H. Seikh ◽  
Hamad F. Alharbi ◽  
Jabair Ali Mohammed ◽  
Mahmoud S. Soliman ◽  
...  

The present study investigates the electrochemical corrosion response and tribo-behavior of 304L and 316L stainless steel welded by gas metal arc welding (GMAW), which offered a high deposition rate. During this research, the metallurgically prepared welded samples were subjected to a tribological test and a corrosion test. The wear results were favorable for 316L steel, and it showed a lower coefficient of friction than the 304L specimen. These samples also underwent characterization studies, such as X-ray diffractometry (XRD) and scanning electron microscopy (SEM), to identify the different phases obtained on the cooling of the weld pool. Finally, both specimens were compared against their mechanical properties. Owing to the above properties, the 316L sample showed lasting durability, as compared to the 304L steel. The primary compositional difference is the higher presence of molybdenum and chromium in the 316L steel, compared to the 304L stainless steel.


2022 ◽  
Vol 60 (1) ◽  
pp. 46-52
Author(s):  
Young Woo Seo ◽  
Chan Yang Kim ◽  
Bo Kyung Seo ◽  
Won Sub Chung

This study evaluated changes in delta-ferrite content depending on the preheating of AISI 316L stainless steel. We also determined the reasons for the variation in delta-ferrite content, which affects corrosion resistance. Changes in delta-ferrite content after preheating was confirmed using a Feritscope, and the microstructure was analyzed using optical microscopy (OM). We found that the delta-ferrite microstructure size decreased when preheating time was increased at 1295 oC, and that the delta-ferrite content could be controlled through preheating. Potentiodynamic polarization test were carried out in NaCl (0.5 M) + H2SO4 (0.5 M) solution, and it was found that higher delta-ferrite content resulted in less corrosion potential and passive potential. To determine the cause, an analysis was conducted using energy-dispersive spectroscopy (EDS), which confirmed that higher delta-ferrite content led to weaker corrosion resistance, due to Cr degradation at the delta-ferrite and austenite boundaries. The degradation of Cr on the boundaries between austenite and delta-ferrite can be explained by the difference in the diffusion coefficient of Cr in the ferrite and austenite. A scanning electron microscopy (SEM) analysis of material used for actual semiconductor piping confirmed that corrosion begins at the delta-ferrite and austenite boundaries. These results confirm the need to control delta-ferrite content in AISI 316L stainless steel used for semiconductor piping.


Materials ◽  
2020 ◽  
Vol 13 (2) ◽  
pp. 388 ◽  
Author(s):  
Waseem Akram ◽  
Amer Farhan Rafique ◽  
Nabeel Maqsood ◽  
Afzal Khan ◽  
Saeed Badshah ◽  
...  

Polytetrafluoroethylene (PTFE) was coated on 316L stainless steel (SS) substrate through a spin coating technique to enhance its corrosion resistance properties in hydrochloric acid (HCl) and nitric acid (HNO3) medium. Scanning electron microscopy (SEM) revealed the morphology of the coated and uncoated substrates and showed a uniform and crack-free PTFE coating on 316L SS substrate, while a damaged surface with thick corrosive layers was observed after the electrochemical test on the uncoated sample. However, an increased concentration of HCl and HNO3 slightly affected the surface morphology by covering the corrosive pits. An atomic force microscope (AFM) showed that the average surface roughness on 316L SS and PTFE coating was 26.3 nm and 24.1 nm, respectively. Energy dispersive X-ray spectroscopy (EDS) was used for the compositional analysis, which confirmed the presence of PTFE coating. The micro Vickers hardness test was used to estimate the hardness of 316L SS and PTFE-coated substrate, while the scratch test was used to study the adhesion properties of PTFE coating on 316L SS. The anticorrosion measurements of 316L SS and PTFE-coated substrates were made in various HCl and HNO3 solutions by using the electrochemical corrosion test. A comparison of the corrosion performance of PTFE-coated substrate with that of bare 316L SS substrate in HCl medium showed a protection efficiency (PE) of 96.7%, and in the case of HNO3 medium, the PE was 99.02%, by slightly shifting the corrosion potential of the coated sample towards the anodic direction.


2011 ◽  
Vol 347-353 ◽  
pp. 3135-3138
Author(s):  
Hong Hua Ge ◽  
Jie Ting Tao ◽  
Xiao Ming Gong ◽  
Cheng Jun Wei ◽  
Xue Min Xu

Abstract: The effect of electromagnetic treatment on corrosion behavior of carbon steel and stainless steel in simulated cooling water was investigated by electrochemical impedance spectroscopy, potentiodynamic polarization techniques and water analysis. It was found that the charge transfer resistance decreased and the corrosion current density increased after electromagnetic treatment for carbon steel electrode, which shows that such treatment promotes corrosion of carbon steel in simulated cooling water. In contrast, the pitting potential of 316L stainless steel electrode rose which revealed that electromagnetic treatment of the experimental water exhibited corrosion inhibition to 316L stainless steel. Reasons for different corrosion behavior of the two metals were discussed.


2015 ◽  
Vol 819 ◽  
pp. 57-62 ◽  
Author(s):  
M.F. Mamat ◽  
E. Hamzah ◽  
Z. Ibrahim ◽  
A.M. Rohah ◽  
A. Bahador

In this paper, dissimilar joining of 316L stainless steel to low carbon steel was carried out using gas metal arc welding (GMAW) and gas tungsten arc welding (GTAW). Samples were welded using AWS: ER309L welding electrode for GMAW and AWS: ER316L welding electrode for GTAW process. Determination of mechanical properties and material characterization on the welded joints were carried out using the Instron tensile test machine and an optical microscope respectively. The cross section area of the welded joint consists of three main areas namely the base metal (BM), heat affected zone (HAZ), and weld metal (WM). It was found that, the yield and tensile strengths of welded samples using ER316L filler metal were slightly higher than the welded sample using ER309L welding electrode. All welded samples fractured at low carbon steel base metal indicating that the regions of ER316L stainless steel base metal, ER316L filler metal and heat affected zone (HAZ) have a higher strength than low carbon steel base metal. It was also found that ER316L welding electrode was the best filler to be used for welding two dissimilar metals between carbon and stainless steel.


Author(s):  
Chunyang Pan ◽  
Changfeng Xu ◽  
Jun Zhou

Abstract Due to the good biocompatibility, 316L stainless steel is widely used in the manufacture of medical instru-ments and human implants. The super hydrophilic 316L steel surface is used for reducing friction and adhe-sion. By choosing appropriate laser process parameters 316L steel surfaces with super-hydrophilic were ob-tained. The effects of laser process parameters including repeat frequency, pulse width, scanning speed, and the number of scanning were investigated to find the relationship between surface microstructure and wet-ting ability. To investigate the super-hydrophilic maintenance time on the textured surface, the textured sur-faces were preserved in ambident air, distilled water, and absolute ethanol. The results showed that by choosing appropriate laser process parameters surface with super-hydrophilicity can be maintained for 30 days.


2021 ◽  
Author(s):  
Paulo Moreira-Filho ◽  
Paloma de Paula da Silva Figueiredo ◽  
Artur Capão ◽  
Luciano Procópio

Abstract The present study evaluated the influence of the marine bacteria Bacillus cereus Mc-1 on the corrosion of 1020 carbon steel, 316L stainless steel, and copper alloy. The Mc-1 strain was grown in a modified ammoniacal citrate culture medium (CFA.ico-), CFA.ico- with sodium nitrate supplementation (NO3-), and CFA.ico- with sodium chloride supplementation (NaCl). The and mass loss and corrosion rate were evaluated after the periods of seven, 15, and 30 days. The results showed that in CFA.ico- and CFA.ico- medium added NO3- the corrosion rates of carbon steel and copper alloy were high when compared to the control. Whereas the medium was supplemented with NaCl, despite the rates being above the averages of the control system, they were considerably below the previous results. In general, the corrosion rates induced by Mc-1 on 316L coupons were below the results compared to carbon steel and copper alloy. When analyzing the corrosion rate measurements, regardless of the culture medium, the corrosion levels decreased consistently after 15 days, being below the levels evaluated after seven days of the experiment. Our analyzes suggest that B. cereus Mc-1 has different influences on corrosion in different metals and environmental conditions, such as the presence of NO3- and NaCl. These results can help to better understand the influence of this bacteria genus on the corrosion of metals in marine environments.


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