Initial Stages of Lamellae Formation in High Nb Containing γ-TiAl Based Alloys

2008 ◽  
Vol 1128 ◽  
Author(s):  
Limei Cha ◽  
Christina Scheu ◽  
Gerhard Dehm ◽  
Ronald Schnitzer ◽  
Helmut Clemens
Keyword(s):  
Heat Treatment ◽  
Phase Field ◽  
Volume Fraction ◽  
Transmission Electron ◽  
Initial Stage ◽  
The Matrix ◽  
Small Volume Fraction ◽  
Step Heat Treatment ◽  
Treatment Step ◽  
Heat Treatment Step

AbstractIn this study a two-step heat treatment was applied to high Nb containing γ-TiAl based alloys in order to investigate the initial stage of the lamellae formation in ordered α2-grains as well as in massively transformed γm-grains. The first heat treatment step, conducted in the single α-phase field followed by oil quenching, leads to a microstructure consisting of supersaturated α2-grains and a small volume fraction of γm-grains. The second step of the heat treatment was performed below the eutectoid temperature, i.e. within the (α2+γ)-phase field region and was again followed by oil quenching. There, the formation of ultra-fine γ-lamellae takes place in the α2-grains and (some) fine α2-lamellae are formed in the γm-grains. In both cases the lamellae show a Blackburn orientation relationship with the matrix grain. It was found that the precipitation of γ-laths in the supersaturated α2-grains is faster than the formation of α2-laths in γm-grains. The characteristics of the initial stage of formation were investigated by transmission electron microscopy.

Microstructure and Tensile Ductility of a Ti-43Al-4Nb-1Mo-0.1B Alloy

2008 ◽  
Vol 1128 ◽  
Author(s):  
Laura M. Droessler ◽  
Thomas Schmoelzer ◽  
Wilfried Wallgram ◽  
Limei Cha ◽  
Gopal Das ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Thermodynamic Equilibrium ◽  
Room Temperature ◽  
Volume Fraction ◽  
Tensile Ductility ◽  
Heat Treatments ◽  
Air Cooling ◽  
B2 Phase ◽  
Treatment Step ◽  
Heat Treatment Step

AbstractThe microstructural development of a forged Ti-43Al-4Nb-1Mo-0.1B (in at%) alloy during two-step heat-treatments was investigated and its impact on the tensile ductility at room temperature was analyzed. The investigated material, a so-called TNM™ gamma alloy, solidifies via the β-route, exhibits an adjustable β/B2-phase volume fraction and can be forged under near conventional conditions. Post-forging heat-treatments can be applied to achieve moderate to near zero volume fractions of β/B2-phase allowing for a controlled adjustment of the mechanical properties. The first step of the heat-treatment minimizes the β/B2-phase and adjusts the size of the α-grains, which are a precursor to the lamellar γ/α2-colonies. However, due to air cooling after the first annealing step, the resulting microstructure is far from thermodynamic equilibrium. Therefore, a second heat-treatment step is conducted below the eutectoid temperature which brings the microstructural constituents closer to thermodynamic equilibrium. It was found that temperature and duration of the second heat-treatment step critically affect the solid-state phase transformations and, thus, control the plastic fracture strain at room temperature. Scanning and transmission electron microscopy studies as well as hardness tests have been conducted to characterize the multi-phase microstructure and to study its correlation to the observed room temperature ductility.

Atomic-scale structural and compositional analyses of Ruddlesden-Popper planar faults in AO-excess SrTiO3 (A = Sr2+, Ca2+, Ba2+) ceramics

2009 ◽  
Vol 24 (8) ◽  
pp. 2596-2604 ◽  
Author(s):  
Sašo Šturm ◽  
Makoto Shiojiri ◽  
Miran Čeh
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Dark Field ◽  
Atomic Scale ◽  
Transmission Electron ◽  
Initial Stage ◽  
Final Microstructure ◽  
Scanning Transmission ◽  
The Matrix ◽  
Annular Dark Field

The microstructure in AO-excess SrTiO3 (A = Sr2+, Ca2+, Ba2+) ceramics is strongly affected by the formation of Ruddlesden-Popper fault–rich (RP fault) lamellae, which are coherently intergrown with the matrix of the perovskite grains. We studied the structure and chemistry of RP faults by applying quantitative high-resolution transmission electron microscopy and high-angle annular dark-field scanning transmission electron microscopy analyses. We showed that the Sr2+ and Ca2+ dopant ions form RP faults during the initial stage of sintering. The final microstructure showed preferentially grown RP fault lamellae embedded in the central part of the anisotropic perovskite grains. In contrast, the dopant Ba2+ ions preferably substituted for Sr2+ in the SrTiO3 matrix by forming a BaxSr1−xTiO3 solid solution. The surplus of Sr2+ ions was compensated structurally in the later stages of sintering by the formation of SrO-rich RP faults. The resulting microstructure showed RP fault lamellae located at the surface of equiaxed BaxSr1-xTiO3 perovskite grains.

Loading Rate Effect on Translaminar Fracture Toughness of Hybrid Composite Laminate

2000 ◽  
Author(s):  
Paul Moy ◽  
Jerome Tzeng
Keyword(s):  
Fracture Toughness ◽  
Composite Laminates ◽  
Glass Matrix ◽  
Small Volume ◽  
Loading Rate ◽  
Volume Fraction ◽  
Rate Effect ◽  
The Matrix ◽  
Small Volume Fraction ◽  
Matrix Property

Abstract Fracture toughness properties of composite laminates were evaluated at a loading rate commonly observed in ordinance applications. The laminates are composed of IM7 graphite and a small volume fraction of S2 glass plies to form a cross-ply laminate. Fracture toughness appears to be very rate sensitive if the crack growth perpendicular to the plane dominated by glass/matrix property. Experimental data shows a 30–40% increase of fracture toughness for various layup as the loading rate was increase by 1000 times. The specimens examined under microscopic indicates the strengthening might due to different failure mechanism in the matrix. In addition, there is no visible rate effect if the crack propagation is perpendicular to the graphite dominant plane.

Effect of Heat Treatment on Fracture during Bending in AA6016 Aluminium Alloy Sheets

2011 ◽  
Vol 488-489 ◽  
pp. 521-524
Author(s):  
Aleksandar Davidkov ◽  
Roumen H. Petrov ◽  
Peter De Smet ◽  
Leo Kestens
Keyword(s):  
Heat Treatment ◽  
Grain Boundary ◽  
Volume Fraction ◽  
Boundary Structure ◽  
Homogeneous Distribution ◽  
Fracture Mechanisms ◽  
Al Alloy ◽  
Technological Parameters ◽  
The Matrix ◽  
Strengthening Phases

The bending properties of high strength precipitation-hardening AA6016-type Al alloy thin sheets in pre-aged T4P temper state were studied in this work. Microstructural features like grain boundary particles distribution and volume fraction of the matrix strengthening phases were considered as factors controlling the mechanical properties and the fracture of this grade. Remarkable decrease in ductility, accompanied by severe deterioration of bendability occurred when coarse precipitates were found into the grain boundaries. The in-situ fracture sequence investigations as well as the post-failure surfaces observations indicated that grain boundary ductile fracture mechanisms were involved in the propagation of the cracks during bending. Heat treatment simulations were carried out and the results showed that the precise control of the technological parameters during production of these sheets is the key factor responsible for obtaining an appropriate combination of strength and bendability. Only by providing both, homogeneous distribution of the matrix strengthening phases and a favourable grain boundary structure, the severe and often contradictory requirements for the functional properties of these alloys can be successfully satisfied.

Laves Phase Formation in the Fe20Co18W Alloy Annealed at 800°C

2011 ◽  
Vol 172-174 ◽  
pp. 517-522 ◽  
Author(s):  
Paolo Galimberti ◽  
Sabine Lay ◽  
Annie Antoni-Zdziobek
Keyword(s):  
Electron Microscopy ◽  
Heat Treatment ◽  
Transmission Electron Microscopy ◽  
Orientation Relationship ◽  
Phase Formation ◽  
Laves Phase ◽  
Transmission Electron ◽  
Precipitation Behaviour ◽  
The Matrix

The precipitation behaviour of the Fe20Co18W (wt%) alloy was studied by transmission electron microscopy during aging treatments at 800°C. The decomposition of the matrix produces the C14 phase. At the beginning of the heat treatment, the observation at the atom scale indicates that the structure of the precipitates does not coincide exactly with the Laves phase. Using the orientation relationship between the Fe based matrix and the precipitates it is shown that simple atomic shifts can lead to the transformation from the bcc matrix to the C14 Laves phase.

Finite Element Simulation and Optimisation of Ageing Precipitation in Nickel Base Superalloys with a Low Gamma-Prime (g’) Volume Fraction

2011 ◽  
Vol 172-174 ◽  
pp. 881-886 ◽  
Author(s):  
Franck Tancret ◽  
Philippe Guillemet ◽  
Florent Fournier Dit Chabert ◽  
René Le Gall ◽  
Jean François Castagné
Keyword(s):  
Heat Treatment ◽  
Finite Element ◽  
Volume Fraction ◽  
Nucleation And Growth ◽  
Thermodynamic Quantities ◽  
Gamma Prime ◽  
The Matrix ◽  
Element Approach ◽  
Automatic Heat ◽  
Nickel Base

A finite element approach is used to simulate the precipitation of Ni3(Al,Ti) intermetallics in nickel-based superalloys containing a low volume fraction of spherical g’ precipitates, in which precipitation occurs following nucleation and growth mechanisms. Classical differential equations of nucleation and growth are implemented in the software Comsol (formerly Femlab), to compute the number of precipitates per unit volume and their mean size. Another originality of the model is the use of thermodynamic quantities coming from phase diagram computations (Thermo-Calc), like the temperature variation of the equilibrium g’ volume fraction, and the evolution of the concentration of g’ forming elements (Al, Ti) in the matrix with the volume fraction of precipitates. Once adjusted to experiment in the case of isothermal ageings, the model can be used to simulate precipitation during complex thermal histories. Finally, automatic heat treatment optimisation procedures are proposed and tested, which can reduce heat treatment times by a factor of more than five.

scholarly journals PHASE-TRANSFORMATION DYNAMICS AND CHARACTERIZATION OF PRECIPITATES IN THE Cu-3Ti-3Ni-0.5Si ALLOY

2021 ◽  
Vol 55 (4) ◽  
Author(s):  
Jia Liu ◽  
Jituo Liu ◽  
Xianhui Wang ◽  
Chong Fu ◽  
Yanlong Wang ◽  
...  
Keyword(s):  
Electron Microscopy ◽  
Electrical Conductivity ◽  
Phase Transformation ◽  
Volume Fraction ◽  
Formation Enthalpy ◽  
Selected Area Electron Diffraction ◽  
Transmission Electron ◽  
The Matrix ◽  
Diffraction Patterns ◽  
Precipitated Phases

In this paper we investigated the phase-transformation dynamics of the Cu-3Ti-3Ni-0.5Si alloy by applying the Avrami method to phase-transformation dynamics and electrical conductivity based on the relationship between the electrical conductivity and the volume fraction of precipitates in the Cu-3Ti-3Ni-0.5Si alloy. The results corroborated well with the experimental data. The microstructure and precipitated phases were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The analysis of the selected-area electron-diffraction patterns indicated that the precipitates formed in the matrix of the Cu-3Ti-3Ni-0.5Si alloy during aging, correspond to the Ni3Ti, Ni3Si, and Ni2Si phases. According to the values of formation enthalpy and cohesive energy determined by first-principle calculations, the formation of the Ni2Si phase is more favorable compared to the Ni3Si and Ni3Ti phases, and the Ni3Ti exhibits improved structural stability compared to the Ni2Si and Ni3Si phases.

scholarly journals Rheological and Mechanical Properties of Silica/Nitrile Butadiene Rubber Vulcanizates with Eco-Friendly Ionic Liquid

Polymers ◽  
2020 ◽  
Vol 12 (11) ◽  
pp. 2763
Author(s):  
Munir Hussain ◽  
Sohail Yasin ◽  
Hafeezullah Memon ◽  
Zhiyun Li ◽  
Xinpeng Fan ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Volume Fraction ◽  
High Strength ◽  
Crosslinking Density ◽  
Mechanical And Thermal Properties ◽  
Butadiene Rubber ◽  
Transmission Electron ◽  
The Matrix ◽  
Silica Dispersion ◽  
The Impact

In this paper we designed greener rubber nanocomposites exhibiting high crosslinking density, and excellent mechanical and thermal properties, with a potential application in technical fields including high-strength and heat-resistance products. Herein 1-ethyl-3-methylimidazolium acetate ([EMIM]OAc) ionic liquid was combined with silane coupling agent to formulate the nanocomposites. The impact of [EMIM]OAc on silica dispersion in a nitrile rubber (NBR) matrix was investigated by a transmission electron microscope and scanning electron microscopy. The combined use of the ionic liquid and silane in an NBR/silica system facilitates the homogeneous dispersion of the silica volume fraction (φ) from 0.041 to 0.177 and enhances crosslinking density of the matrix up to three-fold in comparison with neat NBR, and also it is beneficial for solving the risks of alcohol emission and ignition during the rubber manufacturing. The introduction of ionic liquid greatly improves the mechanical strength (9.7 MPa) with respect to neat NBR vulcanizate, especially at high temperatures e.g., 100 °C. Furthermore, it impacts on rheological behaviors of the nanocomposites and tends to reduce energy dissipation for the vulcanizates under large amplitude dynamic shear deformation.

Heat Treatment of Friction Surfaced Steel-Aluminum Couple

2015 ◽  
Vol 830-831 ◽  
pp. 135-138 ◽  
Author(s):  
K. Udaya Bhat ◽  
Nithin ◽  
Suma Bhat ◽  
Sudeendran
Keyword(s):  
Heat Treatment ◽  
Solid State ◽  
Mild Steel ◽  
Steel Surface ◽  
Aluminum Layer ◽  
Friction Surfacing ◽  
State Process ◽  
Aluminide Layer ◽  
Treatment Step ◽  
Heat Treatment Step

Friction surfacing is a solid state process and it is amenable for deposition of aluminum on steel. In this investigation, the mild steel surface was coated with a layer of aluminum using friction surfacing route. The aluminum thickness was in the range of 40-50 μm. It was followed by a heat treatment step to convert aluminum layer in to an aluminide layer. Heat treatment was done in open atmosphere at 700 °C for 2 hours. Microstuctural analysis showed that the aluminide layer is mainly made of Fe2Al5 and Fe4Al13, FeAl and Fe3Al are minor in fraction. Formation of Fe2Al5 is discussed. The aluminide layer also has some amount of porosities.

scholarly journals Effect of heat treatment residual stress on stress behavior of constant stress beam

2017 ◽  
Vol 5 (1) ◽  
pp. 137-143 ◽  
Author(s):  
Si Young Kwak ◽  
Ho Young Hwang
Keyword(s):  
Heat Treatment ◽  
Residual Stress ◽  
External Load ◽  
Treatment Process ◽  
Constant Stress ◽  
Design Stage ◽  
Treatment Processes ◽  
Stress Behavior ◽  
Treatment Step ◽  
Heat Treatment Step

Abstract Although most casting and heat treatment processes generate significantly high residual stress in the products, this factor is generally not taken into account in the design stage of the product. In this study, experimental study and numerical analysis were conducted on a constant stress beam to examine effects of the residual stress generated during the heat treatment process on yielding behavior of the product in use. A constant stress beam of SUS 304 was designed in order to test the stress behavior related to residual stress. The residual stresses generated during quenching heat treatment of the beam were measured in advance by ESPI (Electronic Speckle-Pattern Interferometry) equipment, and then the external stresses generated while applying a simple external load on the beam were measured. Also, the residual stress distribution generated during the heat treatment process was computed using a numerical analysis program designed for analyzing heat treatment processes. Then, the stress distribution by a simple external load to the beam was combined with the calculated residual stress results of the previous heat treatment step. Finally, the results were compared with experimental ones. Simulation results were in good agreement with the experimental results. Consistency between experimental results and computational results prove that residual stress has significant effects on the stress behavior of mechanical parts. Therefore, the residual stress generated in the previous heat treatment step of casting must be taken into account in the stage of mechanical product design. Highlights The bigger compressive residual stress occurs, the closer surface. When the residual stress is close to plastic deformation, the stress by external load did not significantly change. The residual stress generated during the manufacturing process should be considered in the design stage.

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