The Role of Boron in the Mechanical Milling of Titanium-6 %Aluminium-4% Vanadium Powders

1999 ◽  
Vol 581 ◽  
Author(s):  
A.P. Brown ◽  
R. Brydson ◽  
C. Hammond ◽  
T.M.T. Godfrey ◽  
A. Wisbey

ABSTRACTThe reduction in grain size of a metal can lead to significant improvement in mechanical properties. Mechanical alloying (MA) with a second phase is a possible route to producing fine-grained, particulate reinforced material. This study describes the microstructural development of Ti-6%Al-4%V milled with increasing concentrations of boron. Mechanical milling of Ti-6%Al-4%V powder produces a nanocrystalline material. MA of Ti-6%Al-4%V with boron results in the alloying of the two to form either a boride or an amorphous phase when the local concentration of boron is ∼ 50 at.%. During milling, the boron tends to remain near to its original particle form and in these boron-rich regions TiB is formed. Beyond these regions small amounts of boron (a few at.%) mix with the titanium matrix and reduce further the grain size of the titanium. An increase in the global concentration of boron increases the volume fraction of boride produced.

Metals ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 1019 ◽  
Author(s):  
Angella ◽  
Donnini ◽  
Ripamonti ◽  
Górny ◽  
Zanardi

Tensile testing on ductile iron GJS 400 with different microstructures produced through four different cooling rates was performed in order to investigate the relevance of the microstructure’s parameters on its plastic behaviour. Tensile flow curve modelling was carried out with the Follansbee and Estrin-Kocks-Mecking approach that allowed for an explicit correlation between plastic behaviour and some microstructure parameters. In the model, the ferritic grain size and volume fraction of pearlite and ferrite gathered in the first part of this investigation were used as inputs, while other parameters, like nodule count and interlamellar spacing in pearlite, were neglected. The model matched very well with the experimental flow curves at high strains, while some mismatch was found only at small strains, which was ascribed to the decohesion between the graphite nodules and the ferritic matrix that occurred just after yielding. It can be concluded that the plastic behaviour of GJS 400 depends mainly on the ferritic grain size and pearlitic volume fraction, and other microstructure parameters can be neglected, primarily because of their high nodularity and few defects.


1992 ◽  
Vol 273 ◽  
Author(s):  
A. K. Ghosh ◽  
A. Basu ◽  
H. Kung

ABSTRACTIn an effort to enhance the toughness and creep strength of MoSi2, the role of various metallic and ceramic reinforcements is being examined. In this work, the effects of an oxide, a carbide and a nitride reinforcement on the compression creep behavior of MoSi2 are explored. Variations in the deformability of reinforcements and their relative strength and flaw population appear to influence the creep strength of the composites. Refinements in grain size also improve crack tolerance of the composite during deformation at 1200°C.


2014 ◽  
Vol 1004-1005 ◽  
pp. 123-126 ◽  
Author(s):  
Jian Yin ◽  
Xiu Jun Ma ◽  
Jun Ping Yao ◽  
Zhi Jian Zhou

Effect of pulsed magnetic field treatment on the microstructure and mechanical properties of Mg97Y2Zn1 alloy has been investigated. When the pulsed magnetic field is applied on the alloy in semi-solid state, the α-Mg was modified from developed dendrite to fine rosette, resulting in a refined solidification microstructure with the grain size decreased from 4 mm to 0.5 mm. The volume fraction of the second phase ( X phase) increased by about 10 %. The yield strength, fracture strength and plasticity were improved by 21 MPa, 38 MPa and 2.4 %, respectively. The improvement of mechanical properties was attributed to the refined grain size and increased volume fraction of X phase.


2007 ◽  
Vol 558-559 ◽  
pp. 557-562 ◽  
Author(s):  
Behrang Poorganji ◽  
Takuto Yamaguchi ◽  
Tadashi Maki ◽  
G. Miyamoto ◽  
Tadashi Furuhara

Microstructure change during warm deformation of tempered lath martensite in Fe-2mass%Mn-C alloys with different carbon contents in the range between 0.1 and 0.8mass%C was investigated. Specimens of the alloys after being quenched and tempered at 923K for 0.3ks were compressed by 50% with a strain rate varying from 10-3 to 10-4s-1 at 923K. EBSD analysis of the deformed microstructures has revealed that fine equiaxed ferrite (α) grains surrounded by high-angle boundaries are formed by dynamic recrystallization (DRX). As carbon content increases, the DRX α grain size decreases. This could be attributed to the change in volume fraction of the cementite (θ) phase as boundary dragging particles. The sub-micron θ particles can suppress the coarsening of the DRX α grains by exerting a pinning effect on grain boundary migration. Furthermore, the fraction of recrystallized region increases by increasing carbon content, presumably due to a decrease in the martensite block width as an initial α grain size and a larger volume fraction of hard second phase (θ) particles. Both of these should increase inhomogeneous plastic deformation which promotes the recrystallization. It seems that continuous DRX is responsible for the formation of ultrafine α grains in the tempered lath martensite.


2011 ◽  
Vol 702-703 ◽  
pp. 320-323 ◽  
Author(s):  
Sivaswamy Giribaskar ◽  
Gouthama ◽  
Rajesh Prasad

In present study microstructural evolution during swaging on aluminium alloy based metal matrix composite (MMC) reinforced with 15% volume fraction silicon carbide (SiC) particles is presented. Samples were swaged at room temperature in steps with reducing die dimensions using rotary swaging technique. SEM and TEM are used to study the microstructural characteristics of swaged samples. SEM observations were made to understand the flow and deformation characteristics of deforming aluminium matrix in the presence of second phase and reinforced SiC particles during swaging. TEM observations on swaged samples confirmed the formation of ultra-fine grains in Al-15%SiC MMC. It is shown that the dynamic recrystallisation occurring in the proximities of second phase particles during the deformation at room temperature, leads to very fine grained microstructure.


2014 ◽  
Vol 1061-1062 ◽  
pp. 17-22
Author(s):  
Hao Zhang ◽  
Quan Zhou ◽  
Sen Zhang

The influences of different pulse voltage, pulse frequency, pouring temperature and mold temperature on solidified structure of Mg97Y2Cu1alloy reinforced by long-period ordered structure with compound treatment of pulsed magnetic field and mechanical vibration were studied. The results show that grains of the alloy can be refined greatly with compound treatment. Primary phase degrades from developed dendrites into rosette-shaped crystal. Distribution of second phase is more uniform and continuous, and its volume fraction increases. When the pulse voltage is at 0-280V or the pulse frequency is at 1-10Hz, grain size of the alloy decreases dramatically as pulse voltage or pulse frequency increases. When the pouring temperature is at 660-750°C or the mold temperature is at 20-600oC, grain size of the alloy with compound treatment decreases grossly with the increase of the pouring temperature or the mold temperature.


2007 ◽  
Vol 534-536 ◽  
pp. 505-508 ◽  
Author(s):  
Yun Sung Kang ◽  
B.H. Cha ◽  
H.G. Kang ◽  
Jai Sung Lee

Densification behavior of nano-agglomerate powder during pressureless sintering of Fe-Ni nanopowder was investigated in terms of diffusion kinetics and microstructural development. To understand the role of agglomerate boundary for sintering process, densification kinetics of Fe-Ni nano-agglomerate powder with different agglomerate size was investigated. It was found that activation energy for densification process was lower in the small-sized agglomerate powder. The increase in the volume fraction of inter-agglomerate boundary acting as high diffusion path might be responsible for the enhanced diffusion process.


Solid Earth ◽  
2019 ◽  
Vol 10 (4) ◽  
pp. 1099-1121 ◽  
Author(s):  
Károly Hidas ◽  
Carlos J. Garrido ◽  
Guillermo Booth-Rea ◽  
Claudio Marchesi ◽  
Jean-Louis Bodinier ◽  
...  

Abstract. Subduction-transform edge propagator (STEP) faults are the locus of continual lithospheric tearing at slab edges, resulting in sharp changes in the lithospheric and crustal thickness and triggering lateral and/or near-vertical mantle flow. However, the mechanisms at the lithospheric mantle scale are still poorly understood. Here, we present the microstructural study of olivine-rich lherzolite, harzburgite and wehrlite mantle xenoliths from the Oran volcanic field (Tell Atlas, northwest Algeria). This alkali volcanic field occurs along a major STEP fault responsible for the Miocene westward slab retreat in the westernmost Mediterranean. Mantle xenoliths provide a unique opportunity to investigate the microstructures in the mantle section of a STEP fault system. The microstructures of mantle xenoliths show a variable grain size ranging from coarse granular to fine-grained equigranular textures uncorrelated with lithology. The major element composition of the mantle peridotites provides temperature estimates in a wide range (790–1165 ∘C) but in general, the coarse-grained and fine-grained peridotites suggest deeper and shallower provenance depth, respectively. Olivine grain size in the fine-grained peridotites depends on the size and volume fraction of the pyroxene grains, which is consistent with pinning of olivine grain growth by pyroxenes as second-phase particles. In the coarse-grained peridotites, well-developed olivine crystal-preferred orientation (CPO) is characterized by orthorhombic and [100]-fiber symmetries, and orthopyroxene has a coherent CPO with that of olivine, suggesting their coeval deformation by dislocation creep at high temperature. In the fine-grained microstructures, along with the weakening of the fabric strength, olivine CPO symmetry exhibits a shift towards [010] fiber and the [010] and [001] axes of orthopyroxene are generally distributed subparallel to those of olivine. These data are consistent with deformation of olivine in the presence of low amounts of melts and the precipitation of orthopyroxenes from a melt phase. The bulk CPO of clinopyroxene mimics that of orthopyroxene via a topotaxial relationship of the two pyroxenes. This observation points to a melt-related origin of most clinopyroxenes in the Oran mantle xenoliths. The textural and geochemical record of the peridotites are consistent with interaction of a refractory harzburgite protolith with a high-Mg no. melt at depth (resulting in the formation of coarse-grained clinopyroxene-rich lherzolite and wehrlite) and with a low-Mg no. evolved melt in the shallow subcontinental lithospheric mantle (forming fine-grained harzburgite). We propose that pervasive melt–peridotite reaction – promoted by lateral and/or near-vertical mantle flow associated with lithospheric tearing – resulted in the synkinematic crystallization of secondary lherzolite and wehrlite and had a key effect on grain size reduction during the operation of the Tell–Rif STEP fault. Melt–rock reaction and secondary formation of lherzolite and wehrlite may be widespread in other STEP fault systems worldwide.


2021 ◽  
Author(s):  
Luca Pellegrino ◽  
Luca Menegon ◽  
Stefano Zanchetta ◽  
Falko Langenhorst ◽  
Kilian Pollok ◽  
...  

<p>Pyroxenites are common compositional heterogeneities in the upper mantle and represent key lithologies in mantle deformation processes, as the local presence of pyroxene-rich compositions can weaken the mantle strength. Pyroxenites occur ubiquitously as variably deformed layers in most of oceanic and orogenic peridotite massifs, and thus can be used as a proxy to investigate the rheological behavior of the mantle in different geodynamic settings, including subduction zones.  <br>In the Ulten Zone (Tonale nappe, Eastern Alps, N Italy), numerous peridotite bodies occur within high-grade crustal rocks. Peridotites show a transition from coarse protogranular spinel lherzolites to finer-grained amphibole + garnet peridotites (Obata and Morten, 1987). Pyroxenites veins and dikes, transposed along the peridotite foliation, show a similar evolution from coarse garnet-free websterites to finer-grained garnet clinopyroxenites (Morten and Obata, 1983). This evolution has been interpreted to reflect cooling and pressure increase of pyroxenites and host peridotites from spinel- (1200 °C, 1.3-1.6 GPa) to garnet-facies conditions (850 °C and 2.7 GPa) within the mantle corner flow (Nimis and Morten, 2000). This results in the consequent formation of garnet at the expense of spinel. In particular, garnet initially formed as coronas around spinel and as exsolution lamellae in high-T pyroxenes, and later as neoblasts along the foliation of pyroxenites and host peridotites. <br>Microstructures and crystallographic orientation data indicate that the transition from spinel- to garnet-facies conditions occurred in a deformation regime. Pyroxene porphyroclasts in garnet clinopyroxenites show well-developed crystallographic preferred orientation, high frequency of low-angle misorientations, and non-random distribution of the low-angle misorientation axes. These features indicate that pyroxene porphyroclasts primarily deformed by grain size insensitive (GSI) creep. Core-and-mantle microstructures in pyroxene porphyroclasts also suggest that GSI creep was aided by subgrain rotation (SGR) during recrystallization, leading the formation of smaller, neoblastic, and strain-free pyroxene grains around porphyroclasts. These recrystallized grains have been interpreted to deform by grain boundary sliding, i.e. a grain size sensitive (GSS) creep mechanism, as indicated by the occurrence of quadruple junctions between straight grain boundaries. Our rheological models also suggest that GSS creep of neoblastic pyroxenes occurred at differential stress of 40 MPa and strain rates of 10<sup>-18</sup>-10<sup>-15</sup> s<sup>-1</sup>. <br>The transition from GSI creep in the porphyroclasts to GSS creep in the neoblasts was accompanied not only by a reduction of the grain size of pyroxenes, but also by the crystallization of garnet along the pyroxenite foliation which facilitated pinning by second phase in the recrystallized matrix. This stabilized the fine-grained microtexture produced by the GSS creep process, and finally contributed to the rheological weakening of pyroxenites. <br>Pyroxenites of Ulten Zone thus offer a unique opportunity to investigate the effects of mantle weakening on the processes that control the material exchange between crust and mantle at subduction zones.</p><p>Morten, L., & Obata, M. (1983). Bulletin de Minéralogie, 106(6), 775-780.<br>Nimis, P. & Morten, L. (2000). Journal of Geodynamics, 30(1-2), 93-115<br>Obata, M., & Morten, L. (1987). Journal of Petrology, 28(3), 599-623.</p>


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