scholarly journals Pyro-expanded black slate in sculptural art

Cerâmica ◽  
2013 ◽  
Vol 59 (349) ◽  
pp. 134-140
Author(s):  
J. C. e Costa ◽  
T. Almeida ◽  
C. S. F. Gomes
Keyword(s):  
Organic Matter ◽  
Firing Rate ◽  
Black Shale ◽  
Functional Relationship ◽  
Regional Metamorphism ◽  
Science Research ◽  
Low Grade ◽  
New Techniques ◽  
Fine Grained ◽  
Black Slate

Black slate transformed through a pyroplastic process named pyro-expansion or exfoliation has been explored in the present work in order to be used as sculptural material. Black slate is a highly fissile, fine grained and organic matter rich rock that is the product of the action of low-grade regional metamorphism on black shale (a sedimentary clay and organic matter rich, also fissile and fine grained rock). Black slate if fired at an adequate firing rate up to the temperature range 1000 ºC-1240 ºC shows great potential for the manufacture of sculptural pieces. The technical possibilities of the shaping or conformation of pyro-expanded black slate have also been studied, including the reactions that take place when two different black slate pieces are closely associated with each other, or when black slate pieces are closely associated to other materials, such as metals and ceramics. These interactions, while associating different materials that react with each other, emphasize the unique characteristics of new sculptural compositions increasing the plastic capacities of the pyro-expanded black slate. Some examples of the associations referred to will be shown, which highlight the close functional relationship between art and science; research involves the approach to new techniques and materials, looking at the development of unique plastic configurations.

scholarly journals Regional geochemical variations in a metamorphosed black shale: a reconnaissance study of the Silurian Smalls Falls Formation, Maine, USA

2020 ◽  
Vol 56 ◽  
pp. 231-255
Author(s):  
John F. Slack ◽  
M.R. Van Baalen ◽  
Douglas N. Reusch
Keyword(s):  
Organic Matter ◽  
Black Shale ◽  
Nutrient Loading ◽  
Regional Metamorphism ◽  
Enrichment Factors ◽  
Geochemical Data ◽  
The Black Sea ◽  
Three Samples ◽  
Geochemical Study ◽  
Geochemical Variations

A reconnaissance geochemical study of 21 samples of sulphidic black phyllite and schist from the Silurian Smalls Falls Formation in Maine was undertaken in order to evaluate compositional changes during regional metamorphism. These samples represent variably metamorphosed black shale. Analyzed samples come from the chlorite zone in northern Maine and the biotite, garnet, and staurolite-andalusite zones in west-central Maine. Strata of the Smalls Falls Formation are distinctive in containing abundant pyrite and/or pyrrhotite (total S = 1.2–9.7 wt%), but only minor organic matter or graphite (TOC = 0.43–1.85 wt%); TOC/S ratios are uniformly low (average = 0.37 ± 0.22). Median enrichment factors were calculated for each element by normalizing the concentration to Ti in each sample to the Ti-normalized median composition of global black shale. In the chlorite zone, moderate to large decreases in enrichment factors (-23.1 to -49.8%) are evident for V, Cr, Cu, Ni, Zn, Pb, Sb, and U, attributed here to various factors during sedimentation plus variable element mobility during diagenesis. With increasing metamorphic grade (biotite through staurolite-andalusite zones), systematic small to extreme decreases (-14.5 to -99.0%) were found for Ba, Sb, Au, and U, together with less-systematic moderate to large decreases (-35.4 to -61.1%) for V and As. Molybdenum shows an extreme decrease (-94.7%) from the garnet to staurolite-andalusite zones. Excluding Ba, these results are interpreted to mainly reflect mobility of trace elements during pyrite recrystallization, and during the metamorphic transformations of organic matter to graphite and of pyrite to pyrrhotite. Moderate to large increases for Rb (+28.1 to +61.5%) and Th (+39.1 to +47.3%) from the biotite to staurolite-andalusite zones likely record the introduction of alkalis and mass loss, respectively, during metamorphism. Three samples from one site in the garnet zone differ in having anomalously high Fe/Al and low La/Yb ratios, attributed here to epigenetic formation of pyrite and related leaching of light rare earth elements during syn-metamorphic, channelized fluid flow.Geologic and geochemical data indicate that strata of the Smalls Falls Formation were deposited during an interval of anoxia on the northwestern flank of the Central Maine Basin, for which detrital sources included an evolved continental arc. Onset of anoxia coincided with deposition of the Mayflower Hill Formation of the Vassalboro Group, on the basin’s southeastern flank, related to emergence of the Brunswick subduction complex. We suggest that this emergence played a role in promoting both lateral and vertical circulation changes, nutrient loading, and deoxygenation through subsequent basin closure that culminated with Acadian deformation and metamorphism. Based on the relatively high contents of total sulphur present in our Smalls Falls samples, sediments in the Black Sea represent the only known plausible candidate among those in modern suboxic to euxinic basins.

TEM/AEM characterization of fine-grained clay minerals in very-low-grade rocks: Evaluation of contamination by empa involving celadonite family minerals

1996 ◽  
Vol 54 ◽  
pp. 694-695
Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi
Keyword(s):  
Electron Microscopy ◽  
Volcanic Rocks ◽  
Analytical Electron Microscopy ◽  
Metamorphic Rocks ◽  
New Mineral ◽  
Chemical Compositions ◽  
Low Grade ◽  
Fine Grained ◽  
Depth Analysis ◽  
Mineral Aggregates

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.

scholarly journals The influences of sedimentary environments on organic matter enrichment in fine-grained rocks of the Paleogene Shahejie formation in Nanpu Sag, Huanghua Depression, Bohai Bay Basin

2021 ◽  
pp. 014459872110310
Author(s):  
Min Li ◽  
Xiongqi Pang ◽  
Guoyong Liu ◽  
Di Chen ◽  
Lingjian Meng ◽  
...  
Keyword(s):  
Organic Matter ◽  
Source Rocks ◽  
Bohai Bay ◽  
Bohai Bay Basin ◽  
Humid Climate ◽  
High Productivity ◽  
Fine Grained ◽  
Huanghua Depression ◽  
Shahejie Formation ◽  
Nanpu Sag

The fine-grained rocks in the Paleogene Shahejie Formation in Nanpu Sag, Huanghua Depression, Bohai Bay Basin, are extremely important source rocks. These Paleogene rocks are mainly subdivided into organic-rich black shale and gray mudstone. The average total organic carbon contents of the shale and mudstone are 11.5 wt.% and 8.4 wt.%, respectively. The average hydrocarbon (HC)-generating potentials (which is equal to the sum of free hydrocarbons (S1) and potential hydrocarbons (S2)) of the shale and mudstone are 39.3 mg HC/g rock and 28.5 mg HC/g rock, respectively, with mean vitrinite reflectance values of 0.82% and 0.81%, respectively. The higher abundance of organic matter in the shale than in the mudstone is due mainly to paleoenvironmental differences. The chemical index of alteration values and Na/Al ratios reveal a warm and humid climate during shale deposition and a cold and dry climate during mudstone deposition. The biologically derived Ba and Ba/Al ratios indicate high productivity in both the shale and mudstone, with relatively low productivity in the shale. The shale formed in fresh to brackish water, whereas the mudstone was deposited in fresh water, with the former having a higher salinity. Compared with the shale, the mudstone underwent higher detrital input, exhibiting higher Si/Al and Ti/Al ratios. Shale deposition was more dysoxic than mudstone deposition. The organic matter enrichment of the shale sediments was controlled mainly by reducing conditions followed by moderate-to-high productivity, which was promoted by a warm and humid climate and salinity stratification. The organic matter enrichment of the mudstone was less than that of the shale and was controlled by relatively oxic conditions.

Soil stripping and replacement for the rehabilitation of bauxite-mined land at Weipa. I. Initial changes to soil organic matter and related parameters

Soil Research ◽  
2000 ◽  
Vol 38 (2) ◽  
pp. 345 ◽  
Author(s):  
G. D. Schwenke ◽  
D. R. Mulligan ◽  
L. C. Bell
Keyword(s):  
Organic Matter ◽  
Soil Organic Matter ◽  
Field Experiments ◽  
Surface Soil ◽  
Soil Disturbance ◽  
Microbial Biomass C ◽  
Low Grade ◽  
Double Pass ◽  
Organic C ◽  
The Difference

At Weipa, in Queensland, Australia, sown tree and shrub species sometimes fail to establish on bauxite-mined land, possibly because surface-soil organic matter declines during soil stripping and replacement. We devised 2 field experiments to investigate the links between soil rehabilitation operations, organic matter decline, and revegetation failure. Experiment 1 compared two routinely practiced operations, dual-strip (DS) and stockpile soil, with double-pass (DP), an alternative method, and subsoil only, an occasional result of the DS operation. Other treatments included variations in stripping-time, ripping-time, fertiliser rate, and cultivation. Dilution of topsoil with subsoil, low-grade bauxite, and ironstone accounted for the 46% decline of surface-soil (0–10 cm) organic C in DS compared with pre-strip soil. In contrast, organic C in the surface-soil (0–10 cm) of DP plots (25.0 t/ha) closely resembled the pre-strip area (28.6 t/ha). However, profile (0–60 cm) organic C did not differ between DS (91.5 t/ha), DP (107 t/ha), and pre-strip soil (89.9 t/ha). Eighteen months after plots were sown with native vegetation, surface-soil (0–10 cm) organic C had declined by an average of 9% across all plots. In Experiment 2, we measured the potential for post-rehabilitation decline of organic matter in hand-stripped and replaced soil columns that simulated the DS operation. Soils were incubated in situ without organic inputs. After 1 year’s incubation, organic C had declined by up to 26% and microbial biomass C by up to 61%. The difference in organic C decline between vegetated replaced soils (Expt 1) and bare replaced soils (Expt 2) showed that organic inputs affect levels of organic matter more than soil disturbance. Where topsoil was replaced at the top of the profile (DP) and not ploughed, inputs from volunteer native grasses balanced oxidation losses and organic C levels did not decline.

Progressive Regional Metamorphism in Southern New Zealand

1938 ◽  
Vol 75 (4) ◽  
pp. 160-174 ◽  
Author(s):  
F. J. Turner
Keyword(s):  
New Zealand ◽  
Regional Metamorphism ◽  
Parent Rock ◽  
Chemical Compositions ◽  
Low Grade ◽  
Scottish Highlands ◽  
The Past ◽  
Structural Peculiarities ◽  
Chemical Conditions ◽  
Pelitic Rocks

During the past ten years a number of papers dealing with progressive regional metamorphism in the southern portion of New Zealand have been published. In the following pages a brief summary of the assemblages of minerals typical of the various metamorphic zones is given, but the writer's main object is to draw attention to certain mineralogical and structural peculiarities that appear to differ in some degree from what are usually regarded as the normal features of regional metamorphism in such classic areas as the Scottish Highlands and the Caledonian chain of Norway. The possibility that such departures from the normal may in some instances be connected with chemical peculiarities in the parent rock is suggested by such phenomena as the well-known general limitation of chloritoid, staurolite, and low-grade garnets to pelitic rocks of special chemical compositions. Other unusual features, especially when found to recur in widely separated regions, may well be governed by some particular combination of physical rather than chemical conditions.

Estimates of the energy required for maintenance by adult sheep 2. Grazing sheep

1963 ◽  
Vol 5 (1) ◽  
pp. 11-16 ◽  
Author(s):  
J. P. Langlands ◽  
J. L. Corbett ◽  
I. McDonald ◽  
G. W. Reid
Keyword(s):  
Organic Matter ◽  
Energy Cost ◽  
Functional Relationship ◽  
Adult Sheep ◽  
Maintenance Requirement ◽  
Digestible Organic Matter ◽  
Faecal Nitrogen ◽  
Grazing Period ◽  
The Mean ◽  
Maintenance Requirements

SUMMARYThe mean daily digestible organic matter intake (D) of each of 47 adult sheep during a grazing period of mean length 48 days was estimated by the chromium sesquioxide/faecal nitrogen technique. Mean live-weights (W) and mean daily weight gains (G) were also measured.The regression of D on W and G, and the underlying or functional relationship between D, W and G were both estimated. From the underlying relationship, the preferred equation, the maintenance requirement of a 100 lb. sheep at pasture is estimated to be 1·02 lb. digestible organic matter daily. This value is 24% higher than the corresponding value for housed sheep obtained previously by us.This result is compared with other estimates of the energy cost of grazing and it is concluded that further work is needed in order to define those circumstances which elevate the maintenance requirements of grazing animals.

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