Development of a Laboratory Bioassay and Effect of Soil Properties on Sulfentrazone Phytotoxicity in Soil

2009 ◽  
Vol 23 (3) ◽  
pp. 486-491 ◽  
Author(s):  
Anna M. Szmigielski ◽  
Jeff J. Schoenau ◽  
Eric N. Johnson ◽  
Frederick A. Holm ◽  
Ken L. Sapsford ◽  
...  

Sulfentrazone is a phenyl triazolinone herbicide used for control of certain broadleaf and grass weed species. Sulfentrazone persists in soil and has residual activity beyond the season of application. A laboratory bioassay was developed for the detection of sulfentrazone in soil using root and shoot response of several crops. Shoot length inhibition of sugar beet was found to be the most sensitive and reproducible parameter for measurement of soil-incorporated sulfentrazone. The sugar beet bioassay was then used to examine the effect of soil properties on sulfentrazone phytotoxicity using 10 different Canadian prairie soils. Concentrations corresponding to 50% inhibition (I50values) were obtained from the dose–response curves constructed for the soils. Sulfentrazone phytotoxicity was strongly correlated to the percentage organic carbon (P = 0.01) and also to percentage clay content (P = 0.05), whereas correlation with soil pH was nonsignificant (P = 0.21). Because sulfentrazone phytotoxicity was found to be soil dependent, the efficacy of sulfentrazone for weed control and sulfentrazone potential carryover injury will vary with soil type in the Canadian prairies.

Land ◽  
2021 ◽  
Vol 10 (5) ◽  
pp. 544
Author(s):  
Jetse J. Stoorvogel ◽  
Vera L. Mulder

Despite the increased usage of global soil property maps, a proper review of the maps rarely takes place. This study aims to explore the options for such a review with an application for the S-World global soil property database. Global soil organic carbon (SOC) and clay content maps from S-World were studied at two spatial resolutions in three steps. First, a comparative analysis with an ensemble of seven datasets derived from five other global soil databases was done. Second, a validation of S-World was done with independent soil observations from the WoSIS soil profile database. Third, a methodological evaluation of S-world took place by looking at the variation of soil properties per soil type and short distance variability. In the comparative analysis, S-World and the ensemble of other maps show similar spatial patterns. However, the ensemble locally shows large discrepancies (e.g., in boreal regions where typically SOC contents are high and the sampling density is low). Overall, the results show that S-World is not deviating strongly from the model ensemble (91% of the area falls within a 1.5% SOC range in the topsoil). The validation with the WoSIS database showed that S-World was able to capture a large part of the variation (with, e.g., a root mean square difference of 1.7% for SOC in the topsoil and a mean difference of 1.2%). Finally, the methodological evaluation revealed that estimates of the ranges of soil properties for the different soil types can be improved by using the larger WoSIS database. It is concluded that the review through the comparison, validation, and evaluation provides a good overview of the strengths and the weaknesses of S-World. The three approaches to review the database each provide specific insights regarding the quality of the database. Specific evaluation criteria for an application will determine whether S-World is a suitable soil database for use in global environmental studies.


Pedosphere ◽  
2021 ◽  
Vol 31 (4) ◽  
pp. 572-582
Author(s):  
Barbara Samartini Queiroz ALVES ◽  
Katherin Prissila Sevilla ZELAYA ◽  
Fernando COLEN ◽  
Ledivan Almeida FRAZÃO ◽  
Alfredo NAPOLI ◽  
...  

2004 ◽  
Vol 39 (3) ◽  
pp. 241-246 ◽  
Author(s):  
Marcelo Eduardo Alves ◽  
Arquimedes Lavorenti

The remaining phosphorus (Prem) has been used for estimating the phosphorus buffer capacity (PBC) of soils of some Brazilian regions. Furthermore, the remaining phosphorus can also be used for estimating P, S and Zn soil critical levels determined with PBC-sensible extractants and for defining P and S levels to be used not only in P and S adsorption studies but also for the establishment of P and S response curves. The objective of this work was to evaluate the effects of soil clay content and clay mineralogy on Prem and its relationship with pH values measured in saturated NaF solution (pH NaF). Ammonium-oxalate-extractable aluminum exerts the major impacts on both Prem and pH NaF, which, in turn, are less dependent on soil clay content. Although Prem and pH NaF have consistent correlation, the former has a soil-PBC discriminatory capacity much greater than pH NaF.


2014 ◽  
Vol 2014 ◽  
pp. 1-11 ◽  
Author(s):  
Glécio Machado Siqueira ◽  
Jorge Dafonte Dafonte ◽  
Montserrat Valcárcel Armesto ◽  
Ênio Farias França e Silva

The apparent soil electrical conductivity (ECa) was continuously recorded in three successive dates using electromagnetic induction in horizontal (ECa-H) and vertical (ECa-V) dipole modes at a 6 ha plot located in Northwestern Spain. One of the ECadata sets was used to devise an optimized sampling scheme consisting of 40 points. Soil was sampled at the 0.0–0.3 m depth, in these 40 points, and analyzed for sand, silt, and clay content; gravimetric water content; and electrical conductivity of saturated soil paste. Coefficients of correlation between ECaand gravimetric soil water content (0.685 for ECa-V and 0.649 for ECa-H) were higher than those between ECaand clay content (ranging from 0.197 to 0.495, when different ECarecording dates were taken into account). Ordinary and universal kriging have been used to assess the patterns of spatial variability of the ECadata sets recorded at successive dates and the analyzed soil properties. Ordinary and universal cokriging methods have improved the estimation of gravimetric soil water content using the data of ECaas secondary variable with respect to the use of ordinary kriging.


2014 ◽  
Vol 11 (6) ◽  
pp. 9667-9695 ◽  
Author(s):  
C. M. White ◽  
A. R. Kemanian ◽  
J. P. Kaye

Abstract. Carbon (C) saturation theory suggests that soils have a~limited capacity to stabilize organic C and that this capacity may be regulated by intrinsic soil properties such as clay content and mineralogy. While C saturation theory has advanced our ability to predict soil C stabilization, we only have a weak understanding of how C saturation affects N cycling. In biogeochemical models, C and N cycling are tightly coupled, with C decomposition and respiration driving N mineralization. Thus, changing model structures from non-saturation to C saturation dynamics can change simulated N dynamics. Carbon saturation models proposed in the literature calculate a theoretical maximum C storage capacity of saturating pools based on intrinsic soil properties, such as clay content. The extent to which current C stocks fill the storage capacity of the pool is termed the C saturation ratio, and this ratio is used to regulate either the efficiency or the rate of C transfer from donor to receiving pools. In this study, we evaluated how the method of implementing C saturation and the number of pools in a model affected net N mineralization from decomposing plant residues. In models that use the C saturation ratio to regulate transfer efficiency, C saturation affected N mineralization, while in those in which the C saturation ratio regulates transfer rates, N mineralization was independent of C saturation. When C saturation ratio regulates transfer efficiency, as the saturation ratio increases, the threshold C : N ratio at which positive net N mineralization occurs also increases because more of the C in the residue is respired. In a single-pool model where C saturation ratio regulated the transfer efficiency, predictions of N mineralization from residue inputs were unrealistically high, missing the cycle of N immobilization and mineralization typically seen after the addition of high C : N inputs to soils. A more realistic simulation of N mineralization was achieved simply by adding a second pool to the model to represent short-term storage and turnover of C and N in microbial biomass. These findings increase our understanding of how to couple C saturation and N mineralization models, while offering new hypotheses about the relationship between C saturation and N mineralization that can be tested empirically.


2002 ◽  
Vol 11 (4) ◽  
pp. 381-390
Author(s):  
A. TALKKARI ◽  
L. JAUHIAINEN ◽  
M. YLI-HALLA

In precision farming fields may be divided into management zones according to the spatial variation in soil properties. Clay content is an important soil characteristic, because it is associated with other soil properties that are important in management. Soil survey data from 150 sampling sites taken from an area of 218 ha were used to predict the spatial variation of clay percentage geostatistically in an agricultural soil in Jokioinen, Finland. The exponential and spherical models with a nugget component were fitted to the experimental variogram. This indicated that the medium-range pattern could be modelled, but the short-range variation could not, due to sparsity of sample points at short distances. The effect of sampling density on the kriging error was evaluated using the random simulation method. Kriging with a spherical model produced a map with smooth variation in clay percentage. The standard error of kriging estimates decreased only slightly when the density of samples was increased. The predictions were divided into three classes based on the clay percentage. Areas with clay content below 30%, between 30% and 60% and over 60% belong to non-clay, clay and heavy clay zones, respectively. With additional information from the soil samples on the contents of nutrients and organic matter these areas can serve as agricultural management zones.;


2021 ◽  
Vol 2021 ◽  
pp. 1-14
Author(s):  
Hai-Bang Ly ◽  
Thuy-Anh Nguyen ◽  
Binh Thai Pham

Soil cohesion (C) is one of the critical soil properties and is closely related to basic soil properties such as particle size distribution, pore size, and shear strength. Hence, it is mainly determined by experimental methods. However, the experimental methods are often time-consuming and costly. Therefore, developing an alternative approach based on machine learning (ML) techniques to solve this problem is highly recommended. In this study, machine learning models, namely, support vector machine (SVM), Gaussian regression process (GPR), and random forest (RF), were built based on a data set of 145 soil samples collected from the Da Nang-Quang Ngai expressway project, Vietnam. The database also includes six input parameters, that is, clay content, moisture content, liquid limit, plastic limit, specific gravity, and void ratio. The performance of the model was assessed by three statistical criteria, namely, the correlation coefficient (R), mean absolute error (MAE), and root mean square error (RMSE). The results demonstrated that the proposed RF model could accurately predict soil cohesion with high accuracy (R = 0.891) and low error (RMSE = 3.323 and MAE = 2.511), and its predictive capability is better than SVM and GPR. Therefore, the RF model can be used as a cost-effective approach in predicting soil cohesion forces used in the design and inspection of constructions.


Soil Research ◽  
1992 ◽  
Vol 30 (2) ◽  
pp. 119 ◽  
Author(s):  
RL Aitken

The objectives of this study were to examine (1) interrelationships between various forms of extractable A1 and selected soil properties, (2) the contribution of extractable A1 to pH buffer capacity, and (3) investigate the use of extractable A1 to predict lime requirement. Aluminium was extracted from each of 60 Queensland soils with a range of chloride salts: 1 M KCl (AlK), 0.5 M CuCl2 (AlCu), 0.33 M LaCl3 (AlLa) and 0.01 M CaCl2 (AlCa). The amounts of A1 extracted were in the order AlCu > AlLa > Alk > AlCa. Little or no A1 was extracted by KC1 or Lac13 in soils with pHw values greater than 5.5 , whereas CuCl2 extracted some A1 irrespective of soil pH. The greater amounts of A1 extracted by CuCl2 were attributed mainly to A1 from organic matter, even though all of the soils were mineral soils (organic carbon 54.7%). Both AlCu and AlLa, were significantly (P < 0.001) correlated with organic carbon, whereas none of the extractable A1 measures was correlated with clay content. AlK and A~L, were poorly correlated to pH buffer capacity. The linear relationship between AlCu and pH buffer capacity (r2 = 0.49) obtained in this study supports the view of previous researchers that the hydrolysis of A1 adsorbed by organic matter is a source of pH buffering in soils. However, the change in CEC with pH accounted for 76% of the variation in pH buffer capacity, indicating that other mechanisms such as deprotonation of organic groups and variable charge minerals are also involved in pH buffering. The ability of CuCl2 and LaCl3extractable Al to estimate lime requirement depended on the target pH. The results suggest that lime requirements based on neutralization of AlLa would be sufficient to raise pHw to around 5.5, whereas requirements based on neutralization of AlCu substantially overestimated the actual lime requirement to pHw 5.5, but gave a reasonable estimation of the lime requirement to pHw 6 5.


Circulation ◽  
2015 ◽  
Vol 132 (suppl_3) ◽  
Author(s):  
David Rhainds ◽  
Renaud Julien ◽  
Boulé Marie ◽  
Denis Maxime ◽  
Rhéaume Eric ◽  
...  

Recent clinical studies suggest that raising HDL-cholesterol (HDL-C) concentration is insufficient to lower cardiovascular risk and that protection derives from other characteristics of HDL particles. One such characteristic that can be measured in vitro is the cholesterol efflux capacity of plasma, an assay where HDL accepts labelled cholesterol from macrophages. Recently, a method for the measurement of cholesterol efflux with a fluorescent tracer, BODIPY-cholesterol-2 (BC2), has been proposed as an alternative to the radioactive method. We undertook a systematic comparison of BC2 and 3H-cholesterol methods with J774 macrophages in basal and cAMP-stimulated conditions with purified acceptors, plasma from healthy volunteers and patients with myocardial infarction of the Montreal Heart Institute Biobank. Dose-response curves show higher affinity of BC2 vs. 3H cholesterol with apoA-I, HDL and apoB-depleted plasma (all p<0.01) and a higher maximal efflux for HDL and depleted plasma (both p<0.001) in stimulated conditions. This was reflected in a faster kinetics of BC2 efflux compared to 3H-cholesterol efflux (time for half-maximal efflux 4.1h vs. 10.2 h) and resulted in a 2.5-fold increase of BC2 maximal efflux (p<0.01). With 50 normolipidemic plasmas (2.8%, 4h efflux), the two methods were not correlated in basal conditions (r2=0.079) and strongly correlated in stimulated conditions (r2=0.830). BC2 values did not correlate with HDL-C in all conditions, contrary to 3H cholesterol values (p<0.01). Using more complex samples from patients with MI (n=115), the correlations were modest in basal (r2=0.219) and stimulated (r2=0.400) conditions. Differences between controls and MI cases showed reduced significance with BC-2 compared to 3H cholesterol. Lastly, in macrophages examined under the confocal microscope, BC2 labels vesicular structures colocalized with filipin, a free cholesterol marker, suggesting endosomal loading of BC2. Thus, the BC2 method is not equivalent to the classic 3H cholesterol method for cholesterol efflux measurement.


2004 ◽  
Vol 3 (2) ◽  
pp. 56-60 ◽  
Author(s):  
Nazli Dide Kutlu ◽  
Yusuf Yanar . ◽  
Hikmet Gunal . ◽  
Semih Erkan .

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