scholarly journals Physico-chemical properties of β-diketone phosphorus-containing dendrimers

2017 ◽  
Vol 5 (2) ◽  
pp. 128-135 ◽  
Author(s):  
Viktoriia Starova ◽  
Mykhailo Ianchuk ◽  
Olga Zaporozhets ◽  
Anne-Marie Caminade

Protolytic, absorbance and fluorescence properties of β-diketone phosphorus-containing dendrimers based on cyclotriphosphazene core were studied. Dendrimer solutions in acetone are characterized by intense absorbance band at ≈ 340 nm (ε340≈ 8.5·104L/mol·сm) and fluorescence band with maximum at 440 nm. Position of these maxima does not change in various solvents, unlike the bands of monomer β-diketone. It was found that dendrimer aggregation is accompanied by appearance of a second absorbance band ε400≈ 4.5·103L/mol·сm, by red shift of emission spectra ∆λ ≈ 10 nm and also by decrease in surface tension of acetone solution. Ability of dendrimer aggregates to solubilize organic substrates was observed with the fluorescent indicator acridine.

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1883
Author(s):  
Martin Pisárčik ◽  
Miloš Lukáč ◽  
Josef Jampílek ◽  
František Bilka ◽  
Andrea Bilková ◽  
...  

Phosphorus-containing heterocyclic cationic surfactants alkyldimethylphenylphospholium bromides with the alkyl chain length 14 to 18 carbon atoms were used for the stabilization of silver nanodispersions. Zeta potential of silver nanodispersions ranges from +35 to +70 mV, which indicates the formation of stable silver nanoparticles (AgNPs). Long-chain heptadecyl and octadecyl homologs of the surfactants series provided the most intensive stabilizing effect to AgNPs, resulting in high positive zeta potential values and smaller diameter of AgNPs in the range 50–60 nm. A comparison with non-heterocyclic alkyltrimethylphosphonium surfactants of the same alkyl chain length showed better stability and more positive zeta potential values for silver nanodispersions stabilized with heterocyclic phospholium surfactants. Investigations of biological activity of phospholium-capped AgNPs are represented by the studies of antimicrobial activity and cytotoxicity. While cytotoxicity results revealed an increased level of HepG2 cell growth inhibition as compared with the cytotoxicity level of silver-free surfactant solutions, no enhanced antimicrobial action of phospholium-capped AgNPs against microbial pathogens was observed. The comparison of cytotoxicity of AgNPs stabilized with various non-heterocyclic ammonium and phosphonium surfactants shows that AgNPs capped with heterocyclic alkyldimethylphenylphospholium and non-heterocyclic triphenyl-substituted phosphonium surfactants have the highest cytotoxicity among silver nanodispersions stabilized by the series of ammonium and phosphonium surfactants.


Energies ◽  
2020 ◽  
Vol 13 (24) ◽  
pp. 6564
Author(s):  
Krzysztof Górski ◽  
Ruslans Smigins ◽  
Rafał Longwic

Physico-chemical properties of diethyl ether/linseed oil (DEE/LO) fuel blends were empirically tested in this article for the first time. In particular, kinematic viscosity (ν), density (ρ), lower heating value (LHV), cold filter plugging point (CFPP) and surface tension (σ) were examined. For this research diethyl ether (DEE) was blended with linseed oil (LO) in volumetric ratios of 10%, 20% and 30%. Obtained results were compared with literature data of diethyl ether/rapeseed oil (DEE/RO) fuel blends get in previous research in such a way looking on differences also between oil types. It was found that DEE impacts significantly on the reduction of plant oil viscosity, density and surface tension and improve low temperature properties of tested oils. In particular, the addition of 10% DEE to LO effectively reduces its kinematic viscosity by 53% and even by 82% for the blend containing 30% DEE. Tested ether reduces density and surface tension of LO up to 6% and 25% respectively for the blends containing 30% DEE. The measurements of the CFPP showed that DEE significantly improves the low temperature properties of LO. In the case of the blend containing 30% DEE the CFPP can be lowered up to −24 °C. For this reason DEE/LO blends seem to be valuable as a fuel for diesel engines in the coldest season of the year. Moreover, DEE/LO blends have been tested in the engine research. Based on results it can be stated that the engine operated with LO results in worse performance compared with regular diesel fuel (DF). However, it was found that these disadvantages could be reduced with DEE as a component of the fuel mixture. Addition of this ether to LO improves the quality of obtained fuel blends. For this reason, the efficiency of DEE/LO blend combustion process is similar for the engine fuelled with regular diesel fuel. In this research it was confirmed that the smoke opacity reaches the highest value for the engine fuelled with plant oils. However, addition of 20% DEE reduces this emission to the value comparable for the engine operated with diesel fuel.


2010 ◽  
pp. 607-613 ◽  
Author(s):  
Pavel Kadlec ◽  
Svatopluk Henke ◽  
Zdenek Bubník

This paper deals with the physico-chemical properties of ethanol and ethanol-water solutions. The data of ethanol properties and its water solutions, which were obtained from literature, are presented in the form of Equations and Tables.Extended properties include data for pure ethanol (density, vapor pressure, surface tension, viscosity, molar and specific heat capacity, enthalpy of evaporation, thermal conductivity and static relative permittivity) and tabled data for ethanol-water solutions (0–100% ethanol) as well: concentrative properties, surface tension and thermal conductivity at20 °C, density, viscosity, boiling point and equilibrium liquid-vapor at normal pressure.


2017 ◽  
Vol 53 (3) ◽  
pp. 309-318 ◽  
Author(s):  
J. Pstruś

The measurements of surface tension, density and viscosity of liquid Sn-Zn eutectic alloys containing 0, 5, 10, 15 and 25 mole fraction of In were carried out using the sessile drop method, dilatometric technique and capillary method. The measurements were performed at temperature range between 493 and 843 K. The technique of sessile drop was applied in the measurements of wetting angles and spreading test in the SnZnIn/ Cu system. Surface tension, density and viscosity measurements were carried out in a protective argon-hydrogen atmosphere. Wettability tests were performed in air in the presence of flux Alu33, at 250?C for 2 minutes. Subsequently, the microstructure of solder and the resulting joints was studied. The addition of In to eutectic Sn-Zn alloy improved the wetting properties and causes a reduction of thickness of the intermetallic compounds layer created at the interface between the liquid solder and the Cu substrate.


1985 ◽  
Vol 50 (8) ◽  
pp. 1629-1635 ◽  
Author(s):  
Marie Šišková ◽  
Jiřina Hejtmánková ◽  
Lidmila Bartovská

Surface tension of two binary systems ammonium nitrate-water and urea-water and of the ternary system ammonium nitrate-urea-water was measured as a function of concentration at 20 and 40 °C. The experimental values were compared with those calculated from the relations which were proposed for calculating surface tensions of ternary systems from measured surface tensions of both binary systems.


2012 ◽  
Vol 433-440 ◽  
pp. 94-99 ◽  
Author(s):  
Yue Ling Gu ◽  
Qian Qian Yin ◽  
Shu Rong Wang ◽  
Xin Bao Li ◽  
Zuo Gang Guo ◽  
...  

Experimental study on the physico-chemical properties of bio-oil and diesel emulsification has been carried out in this paper, which was based on the preliminary experiment. The effect of surface tension and viscosity on the stability of emulsions were particular concerned. It was found that the longest stable time, the lowest viscosity and lowest surface tension can be obtained simultaneously when the hydrophile and lipophile balance (HLB) value was of the optimal value, i.e. 6.5. Experimental results indicated that the stable time of emulsion decreased rapidly with the increase of bio-oil content, while the value of surface tension and viscosity increased. Meantime, it was shown that the most stable emulsions had the lowest value of viscosity and surface tension.


HortScience ◽  
2000 ◽  
Vol 35 (3) ◽  
pp. 435D-435
Author(s):  
Md. Shahidul Islam ◽  
Tadashi Ito

Characterization of physico-chemical properties of ecologically sound unprocessed coconut (Cocos nucifera L.) coir and carbonated rice husk in relation to rockwool were investigated to examine the crop performance along with productivity of tomatoes (Lycopersicon esculentum Mill.). In all substrates, the water-filled pore space and water-holding capacity were larger and air-filled pore space was smaller. Bulk densities, water-holding capacity, and water-filled, air-filled, and total pore spaces were lower in carbonated rice husk than coconut coir and rockwool. These values in coconut coir and carbonated rice husk were increased by use. Most of the physical properties, EC, pH, and inorganic elements, of these natural organic substrates were within appropriate levels as growing media. There were little differences in plant height, stem diameter, percent fruit set, harvest index, ascorbic acid, total soluble solid, fruit pH, and leaf chlorophyll ratio. But, number of nodes, internode length, leaf number and area, days to first anthesis, flower number, and fruit number and weight differed significantly among treatments. There was smaller fluctuation in absolute growth rate, relative growth rate, net assimilate rate, and leaf area ratio among the treatments. It appeared that carbonated rice husk and the coconut coir gave better crop performance than rockwool under moderate high temperatures (30 and 35 °C compared to 25 °C). Furthermore, crop productivity from the organic substrate coconut coir and carbonated rice husk gave more profit than that of rockwool. Thus, carbonated rice husk and coconut coir substrates can be used successfully as a bag culture media amendment for producing vegetables, especially in tropical and subtropical areas.


2012 ◽  
Vol 58 (No. 12) ◽  
pp. 568-572 ◽  
Author(s):  
J. Janků ◽  
L. Bartovská ◽  
J. Soukup ◽  
M. Jursík ◽  
K. Hamouzová

Adjuvants are surface active agents that are added to pesticide formulations or tank-mix to facilitate the mixing, application, or efficacy of these products. Addition of adjuvants changes the physico-chemical properties of spray liquid. In this work, we have focused in particular on surface tension and density of aqueous solutions of different adjuvants registered for mixing with herbicides. Eleven different adjuvants were subject of this study under laboratory conditions. An equation which enables determination of density of aqueous solutions in concentration range of 0–15 g/kg was designed. Average difference between the experimental and calculated density values amounts to ± 0.006%. The concentration dependence of surface tension was utilized to determine the critical micelle concentration (cmc). Evidently, the cmc of most tested adjuvants was lower than the amount recommended by manufacturer, especially in case of adjuvants Dedal 90 EC and Mero 33528. For adjuvant Trend 90 EC the recommended rate is even lower than that obtained for the cmc. Maximum reduction of the surface tension of water was achieved with adjuvants Silwet L-77 and Break Superb.    


2018 ◽  
Vol 268 ◽  
pp. 754-761 ◽  
Author(s):  
Blanka Kubíková ◽  
Jarmila Mlynáriková ◽  
Ondřej Beneš ◽  
Eva Mikšíková ◽  
Jozef Priščák ◽  
...  

2021 ◽  
Vol 36 (1) ◽  
pp. 35-43
Author(s):  
Antonije Zunic ◽  
Slavica Vukovic ◽  
Dragana Sunjka ◽  
Sanja Lazic ◽  
Dragana Boskovic

Mixtures of two or more pesticides are very common in contemporary agriculture. However, changes in their efficacy or biological activity, such as synergism and antagonism, phytotoxicity, persistence, toxicity to non-target organisms, may occur as a consequence. This study was conducted in order to evaluate the compatibility of insecticides (cyantraniliprole - Exirel, chlorantraniliprole - Coragen 20 SC), a fungicide (captan - Merpan 50 WP) and a foliar fertilizer (Folia Stim Mix TE), as well their mixtures, in spray liquids, depending on water quality (well water from two locations in Serbia - Mala Remeta and Cerevic). These products are used to control the most significant peach pests, and as an additional source of nutrients. Water analysis (pH, hardness, electroconductivity, chloride, nitrate, nitrite, ammonia, calcium and iron content) and tests of physico-chemical properties of the spray liquids (pH, suspensibility, dispersibility, surface tension, and electroconductivity) were performed in a laboratory experiment according to standard methods. The physico-chemical properties of the liquids changed depending on water quality and components incorporated in the mixture. However, all tested spray liquids showed consistency and compatibility over a period of 24 hours.


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