scholarly journals Experimental Investigation on the Wind-driven Runback Motion of Water Droplets over Solid Surfaces with Different Wettabilities

2021 ◽  
Vol 1 (1) ◽  
Author(s):  
Liqun Ma ◽  
Zichen Zhang ◽  
Hui Hu
Keyword(s):  
Solid Surface ◽  
Contact Angles ◽  
Aircraft Icing ◽  
Water Droplets ◽  
Elastic Materials ◽  
Lotus Leaf ◽  
Liquid Lubricant ◽  
Measurement Results ◽  
Porous Surfaces ◽  
Ice Adhesion

Aircraft icing is widely recognized as one of the most serious weather hazards to flight safety. Specially designed hydro-/ice-phobic coatings are currently undergoing development for aircraft icing mitigation. It was found that hydro-/icephobic coatings would delay the ice accretion iover airframe surfaces so that the impacted supercooled water droplets could be blown away by the airflow from the airframe surface before being frozen into ice. It is of fundamental importance to understand the wind-driven runback behavior of water droplets over surfaces treated with different coatings, since the corresponding knowledge would be very helpful and essential to develop more efficient anti-/de-icing systems for aircraft icing protection. With the rapid development of surface engineering, a series of specially designed surface coatings succeed in icing mitigation using airflow to remove the remained water. While various hydro-/ice-phobic coatings/surfaces have been developed in recent years, the “state-of-the-art” icephobic coatings/surfaces can be generally divided into three categories, i.e., 1). Lotus-leaf-inspired superhydrophobic surfaces (SHS) with micro-/nano-scale surface textures to achieve very high contact angles (typically > 150°); 2). Pitcherplant-inspired slippery liquid infused porous surfaces (SLIPS) with a layer of liquid lubricant (which is immiscible with water) being sandwiched between ice and solid substrate materials; and 3). Icephobic elastic materials/surfaces with deformable structures/surfaces. SHS has a water droplet contact angle (CA) larger than 150° and a sliding angle (SA) less than 10° . SHS always has a hierarchical structure which is similar to the lotus leaf, and water droplets on SHS appear as water beads which can easily roll off the surface by wind or gravity before frozen. Another strategy to reduce ice adhesion strength to a solid surface is to use a layer of liquid lubricant, which is immiscible with water, between ice and the solid surface. The use of such lubricated surfaces was investigated as early as 1960s, and has gained increasing attentions again recently with the introduction of a concept called Slippery Liquid-Infused Porous Surfaces (SLIPS). SLIPS concept is inspired by the Nepenthes pitcher plants, which have evolved highly slippery, liquidinfused micro-textured rim to capture insects. SLIPS surfaces were not only found to be able to suppress ice/frost accretion by effectively removing condensed moisture even in high humidity conditions, but also exhibit at least an order of magnitude lower ice adhesion than most SHS coatings. More recently, elastic materials/surfaces, such as Polydimethylsiloxane or PDMS in short, which would be structurally deformed/altered dynamically upon applying extra mechanical stress, have also been suggested for icing mitigation. Elastic materials display ultra-low adhesion to ice due to their low work of adhesion and liquidlike deformability, while maintaining good mechanical durability due to their solid-like rigidity. It is found that water droplets would not only be more readily rebounding away from the surface after impingement, but also be able to roll away before frozen due to the hydrophobicity of PDMS. Considering the differences in wettabilities and mechanisms of water repellency, it is necessary to have a systematic understanding of how efficient the surfaces are when the aerodynamic force is applied to remove the adhered water droplets. In the present study, a comprehensive experimental campaign was conducted to characterize the transient runback behaviors of wind-driven water droplets over the surfaces of test plates coated with different hydro-/icephobic coatings (i.e., SHS, SLIPS and PDMS). A high-resolution Particle Image Velocimetry (PIV) system was used to achieve quantitative measurements of the velocity field of the airflow around the wind-driven water droplets on the test surfaces with different wettabilities. With the detailed PIV measurements of the airflow field around the runback water droplets and the droplet profiles, the aerodynamic forces and the adhesion forces acting on the water droplets were estimated. While Fig. 1 shows the experimental setup used in the present study, Fig. 2 to Fig. 3 given some of the typical measurement results. More measurement results and comprehensive analysis and discussions will be provided in the full version of this research paper.

scholarly journals Is contact angle a cause or an effect? – A cautionary tale

2020 ◽  
Vol 146 ◽  
pp. 03004
Author(s):  
Douglas Ruth
Keyword(s):  
Contact Angle ◽  
Solid Surface ◽  
Contact Angles ◽  
Two Dimensions ◽  
Experimental Results ◽  
Flow In Porous Media ◽  
Two Dimensional ◽  
Wide Range ◽  
Fluid Drop ◽  
Surrounding Fluid

The most influential parameter on the behavior of two-component flow in porous media is “wettability”. When wettability is being characterized, the most frequently used parameter is the “contact angle”. When a fluid-drop is placed on a solid surface, in the presence of a second, surrounding fluid, the fluid-fluid surface contacts the solid-surface at an angle that is typically measured through the fluid-drop. If this angle is less than 90°, the fluid in the drop is said to “wet” the surface. If this angle is greater than 90°, the surrounding fluid is said to “wet” the surface. This definition is universally accepted and appears to be scientifically justifiable, at least for a static situation where the solid surface is horizontal. Recently, this concept has been extended to characterize wettability in non-static situations using high-resolution, two-dimensional digital images of multi-component systems. Using simple thought experiments and published experimental results, many of them decades old, it will be demonstrated that contact angles are not primary parameters – their values depend on many other parameters. Using these arguments, it will be demonstrated that contact angles are not the cause of wettability behavior but the effect of wettability behavior and other parameters. The result of this is that the contact angle cannot be used as a primary indicator of wettability except in very restricted situations. Furthermore, it will be demonstrated that even for the simple case of a capillary interface in a vertical tube, attempting to use simply a two-dimensional image to determine the contact angle can result in a wide range of measured values. This observation is consistent with some published experimental results. It follows that contact angles measured in two-dimensions cannot be trusted to provide accurate values and these values should not be used to characterize the wettability of the system.

scholarly journals Superhydrophobicity in perfection: the outstanding properties of the lotus leaf

2011 ◽  
Vol 2 ◽  
pp. 152-161 ◽  
Author(s):  
Hans J Ensikat ◽  
Petra Ditsche-Kuru ◽  
Christoph Neinhuis ◽  
Wilhelm Barthlott
Keyword(s):  
Chemical Composition ◽  
Water Repellency ◽  
Contact Angles ◽  
Dense Layer ◽  
Lotus Effect ◽  
Nano Structure ◽  
Lotus Leaf ◽  
Water Drops ◽  
The Impact ◽  
Unique Chemical

Lotus leaves have become an icon for superhydrophobicity and self-cleaning surfaces, and have led to the concept of the ‘Lotus effect’. Although many other plants have superhydrophobic surfaces with almost similar contact angles, the lotus shows better stability and perfection of its water repellency. Here, we compare the relevant properties such as the micro- and nano-structure, the chemical composition of the waxes and the mechanical properties of lotus with its competitors. It soon becomes obvious that the upper epidermis of the lotus leaf has developed some unrivaled optimizations. The extraordinary shape and the density of the papillae are the basis for the extremely reduced contact area between surface and water drops. The exceptional dense layer of very small epicuticular wax tubules is a result of their unique chemical composition. The mechanical robustness of the papillae and the wax tubules reduce damage and are the basis for the perfection and durability of the water repellency. A reason for the optimization, particularly of the upper side of the lotus leaf, can be deduced from the fact that the stomata are located in the upper epidermis. Here, the impact of rain and contamination is higher than on the lower epidermis. The lotus plant has successfully developed an excellent protection for this delicate epistomatic surface of its leaves.

Contact Angles and Solid Surface Tensions

2010 ◽  
pp. 491-554 ◽  
Author(s):  
Robert David ◽  
Jan Spelt ◽  
Junfeng Zhang ◽  
Daniel Kwok
Keyword(s):  
Solid Surface ◽  
Contact Angles ◽  
Surface Tensions

scholarly journals Coral-like silicone nanofilament coatings with extremely low ice adhesion

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Davide Bottone ◽  
Valentina Donadei ◽  
Henna Niemelä ◽  
Heli Koivuluoto ◽  
Stefan Seeger
Keyword(s):  
Energy Efficient ◽  
Efficient Solution ◽  
Water Repellent ◽  
Cold Environment ◽  
Adhesion Test ◽  
Porous Surfaces ◽  
Water Wettability ◽  
The Stability ◽  
Effect Of Surface ◽  
Ice Adhesion

AbstractPassive icephobic surfaces can provide a cost and energy efficient solution to many icing problems that are currently handled with expensive active strategies. Water-repellent surface treatments are promising candidates for this goal, but commonly studied systems, such as superhydrophobic surfaces and Slippery Liquid Infused Porous Surfaces (SLIPS), still face challenges in the stability and durability of their properties in icing environments. In this work, environmental icing conditions are simulated using an Icing Wind Tunnel, and ice adhesion is evaluated with a Centrifugal Adhesion Test. We show that superhydrophobic coral-like Silicone Nanofilament (SNF) coatings exhibit extremely low ice adhesion, to the point of spontaneous ice detachment, and good durability against successive icing cycles. Moreover, SNFs-based SLIPS show stably low ice adhesion for the whole duration of the icing test. Stability of surface properties in a cold environment is further investigated with water wettability at sub-zero surface temperature, highlighting the effect of surface chemistry on superhydrophobicity under icing conditions.

Design Parameters for Superhydrophobicity and Superoleophobicity

MRS Bulletin ◽  
2008 ◽  
Vol 33 (8) ◽  
pp. 752-758 ◽  
Author(s):  
Anish Tuteja ◽  
Wonjae Choi ◽  
Gareth H. McKinley ◽  
Robert E. Cohen ◽  
Michael F. Rubner
Keyword(s):  
Surface Tension ◽  
Surface Topography ◽  
Leaf Surface ◽  
Contact Angles ◽  
Design Parameters ◽  
Lotus Leaf ◽  
General Design ◽  
Composite Interface

AbstractRecent experiments have revealed that the wax on the lotus leaf surface, by itself, is weakly hydrophilic, even though the lotus leaf is known to be superhydrophobic. Conventional understanding suggests that a surface of such waxy composition should not be able to support superhydrophobicity and high contact angles between a liquid and the surface. Here, we show that the unexpected superhydrophobicity is related to the presence of “reentrant texture” (that is, a multivalued surface topography) on the surface of the lotus leaf. We exploit this understanding to enable the development of superoleophobic surfaces (i.e., surfaces that repel extremely low-surface-tension liquids, such as various alkanes), where essentially no naturally oleophobic materials exist. We also develop general design parameters that enable the evaluation of the robustness of the composite interface on a particular surface. Based on these design parameters, we also rank various superhydrophobic and superoleophobic substrates discussed in the literature, with particular emphasis on surfaces developed from inherently hydrophilic or oleophilic materials.

Wetting Behavior and Drainage of Water Droplets on Microgrooved Brass Surface

2011 ◽  
Author(s):  
M. A. Rahman ◽  
A. M. Jacobi
Keyword(s):  
Aspect Ratio ◽  
End Milling ◽  
Contact Angle Hysteresis ◽  
Contact Angles ◽  
Milling Process ◽  
Water Droplets ◽  
Sliding Angle ◽  
Flat Surfaces ◽  
Micro End Milling ◽  
Water Drops

In the present study, we report the contact angle hysteresis and drainage behavior of water drops on a number of brass surfaces with parallel microgrooves and compare them to the flat baseline surfaces. Parallel micro-grooves with different groove dimensions are fabricated by micro end-milling process without any modification of the surface chemistry. Advancing and receding contact angles in both parallel and perpendicular direction of the grooves and also the drainage behavior of water droplets on the microgrooved surfaces is found to be considerably affected by change in groove geometry parameters. Very high hysteresis is observed for both low (< 0.2) and high aspect ratio (> 0.7) of grooves and also for surfaces with lower groove spacing due to the droplets being in a Wenzel state. For intermediate aspect ratio (0.25–0.70) and larger spacing of the grooves, droplets remain in a Cassie state and the hysteresis is lower in both directions than that on the flat surfaces. Variation of critical sliding angle (angle at the point of incipient sliding of water droplets due to gravity) with groove geometry is investigated for a range of water droplet volume of 15 to 75 μl. Droplets of all volumes are found to slide much more readily on grooved surfaces than when placed on the flat baseline surfaces. Height and spacing of the grooves are also found to have significant influence on the sliding of the water droplets, as critical inclination angle decreased with groove height and increased with groove spacing. The results from this study may be useful in a broad range of applications where water retention plays an important role.

Micro/Meso Scale Modelling of Two-Phase Flow on Functional Surfaces: A Numerical Simulation of Water Droplets on Natural Hydrophobic Surfaces With Micro Roughness

2009 ◽  
Author(s):  
Y. Y. Yan
Keyword(s):  
Two Phase Flow ◽  
Contact Angles ◽  
Phase Flow ◽  
Fluid Interface ◽  
Water Droplets ◽  
Hydrophobic Surfaces ◽  
Two Phase ◽  
Partial Wetting ◽  
Scale Modelling ◽  
Meso Scale

A micro/meso scale modelling of two-phase droplets move on hydrophilic/hydrophobic surfaces with micro roughness is reported. The physical model is basically of two-phase flow interacting with the surfaces of different hydrophobicity or wettability. Numerical modelling based on the lattice Boltzmann method (LBM) is developed and applied to the computational calculation and simulation. The LBM modelling deals with surface tension dominated behaviour of water droplets in air spreading on a hydrophilic surface with hydrophobic strips of different sizes and contact angles under different physical and interfacial conditions, and aims to find quantitative data and physical conditions of the biomimetic approaches. The current LBM can be applied to simulate two-phase fluids with large density ratio (up to 1000), and meanwhile deal with interactions between a fluid-fluid interface and a partial wetting wall. In the simulation, the interactions between the fluid-fluid interface and the partial wetting wall with different hydrophobic strips such as single strip, intersecting stripes, and alternating & parallel stripes, of different sizes and contact angles are considered and tested numerically; the phenomena of droplets spreading and breaking up, and the effect of hydrophobic strips on the surface wettability or self-cleaning characteristics are simulated, reported and discussed.

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