Zmiany parametrów mieszaniny gazu ziemnego z wodorem w trakcie eksploatacji komory magazynowej w kawernie solnej

Nafta-Gaz ◽  
2020 ◽  
Vol 76 (11) ◽  
pp. 799-806
Author(s):  
Paweł Budak ◽  
◽  
Tadeusz Szpunar ◽  
Keyword(s):  
Hydrogen Content ◽  
Distribution Network ◽  
Calorific Value ◽  
Gas Reservoirs ◽  
Heating Value ◽  
Salt Domes ◽  
Depleted Gas Reservoirs ◽  
Salt Caverns ◽  
Short Time ◽  
Water Gas

Underground gas stores are built in depleted gas reservoirs or in salt domes or salt caverns. In the case of salt caverns, the store space for gas is created by leaching the salt using water. Gas stores in salt caverns are capable to provide the distribution network with large volumes of gas in a short time and cover the peak demand for gas. The salt caverns are also capable to store large volumes of gas in case when there is too much gas on a market. Generally, the salt caverns are used to mitigate the fluctuation of gas demand, specifically during winter. The gas provided to the distribution network must satisfy the requirements regarding its heating value, calorific value, volumetric content of hydrogen and the Wobbe number. Large hydrogen content reduces the calorific value as well as the heating value of gas and thus its content must be regulated to keep these values at the acceptable level. One should also remember that every portion of gas which was used to create the gas/hydrogen mixture may have different parameters (heating value and calorific value) because it may come from different sources. The conclusion is that the hydrogen content and the heating value must be known at every moment of gas store exploitation. The paper presents an algorithm and a computer program which may be used to calculate the hydrogen content (volumetric percentage), heating value and calorific value (plus the Wobbe number) of gas collected from the salt cavern at every moment of cavern exploitation. The possibility of the presence of non-flammable components in the mixture and their effect on the heat of combustion / calorific value were considered. An exemplary calculation is provided.

Magazynowanie wodoru w obiektach geologicznych

Nafta-Gaz ◽  
2020 ◽  
Vol 76 (11) ◽  
pp. 794-798
Author(s):  
Piotr Such ◽  
Keyword(s):  
Hydrogen Storage ◽  
Oil And Gas ◽  
Renewable Energy Sources ◽  
Distribution Networks ◽  
Extensive Study ◽  
Operational Parameters ◽  
Gas Reservoirs ◽  
Depleted Gas Reservoirs ◽  
Chemical Companies ◽  
Salt Caverns

Hydrogen economy became one of the main directions in EU’s Green Deal for making Europe climate neutral in 2050. Hydrogen will be produced with the use of renewable energy sources or it will be obtained from coking plants and chemical companies. It will be applied as ecological fuel for cars and as a mix with methane in gas distribution networks. Works connected with all aspects of hydrogen infrastructure are conducted in Poland. The key problem in creating a hydrogen system is hydrogen storage. They ought to be underground (RES) because of their potential volume. Three types of underground storages are taken into account. There are salt caverns, exploited gas reservoirs and aquifers. Salt caverns were built in Poland and now they are fully operational methane storages. Oli and Gas Institute – National Research Institute has been collaborating with the Polish Oil and Gas Company since 1998. Salt cavern storage exists and is used as methane storages. Now it is possible to use them as methane-hydrogen mixtures storages with full control of all operational parameters (appropriate algorithms are established). Extensive study works were carried out in relation to depleted gas reservoirs/aquifers: from laboratory investigations to numerical modelling. The consortium with Silesian University of Technology was created, capable of carrying out all possible projects in this field. The consortium is already able to undertake the project of adapting the depleted field to a methane-hydrogen storage or, depending on the needs, to a hydrogen storage. All types of investigations of reservoir rocks and reservoir fluids will be taken into consideration.

Evaluasi Prediksi Higher Heating Value (HHV) Biomassa Berdasarkan Analisis Proksimat

2020 ◽  
Vol 4 (1) ◽  
pp. 1-7
Author(s):  
Made Dirgantara ◽  
Karelius Karelius ◽  
Marselin Devi Ariyanti, Sry Ayu K. Tamba
Keyword(s):  
Renewable Energy ◽  
Natural Gas ◽  
Key Words ◽  
Critical Analysis ◽  
Fossil Fuels ◽  
Calorific Value ◽  
Proximate Analysis ◽  
Heating Value ◽  
Bomb Calorimeter ◽  
Hhv Prediction

Abstrak – Biomassa merupakan salah satu energi terbarukan yang sangat mudah ditemui, ramah lingkungan dan cukup ekonomis. Keberadaan biomassa dapat dimaanfaatkan sebagai pengganti bahan bakar fosil, baik itu minyak bumi, gas alam maupun batu bara. Analisi diperlukan sebagai dasar biomassa sebagai energi seperti proksimat dan kalor. Analisis terpenting untuk menilai biomassa sebagai bahan bakar adalah nilai kalori atau higher heating value (HHV). HHV secara eksperimen diukur menggunakan bomb calorimeter, namun pengukuran ini kurang efektif, karena memerlukan waktu serta biaya yang tinggi. Penelitian mengenai prediksi HHV berdasarkan analisis proksimat telah dilakukan sehingga dapat mempermudah dan menghemat biaya yang diperlukan peneliti. Dalam makalah ini dibahas evaluasi persamaan untuk memprediksi HHV berdasarkan analisis proksimat pada biomassa berdasarkan data dari penelitian sebelumnya. Prediksi nilai HHV menggunakan lima persamaan yang dievaluasi dengan 25 data proksimat biomassa dari penelitian sebelumnya, kemudian dibandingkan berdasarkan nilai error untuk mendapatkan prediksi terbaik. Hasil analisis menunjukan, persamaan A terbaik di 7 biomassa, B di 6 biomassa, C di 6 biomassa, D di 5 biomassa dan E di 1 biomassa.Kata kunci: bahan bakar, biomassa, higher heating value, nilai error, proksimat  Abstract – Biomass is a renewable energy that is very easy to find, environmentally friendly, and quite economical. The existence of biomass can be used as a substitute for fossil fuels, both oil, natural gas, and coal. Analyzes are needed as a basis for biomass as energy such as proximate and heat. The most critical analysis to assess biomass as fuel is the calorific value or higher heating value (HHV). HHV is experimentally measured using a bomb calorimeter, but this measurement is less effective because it requires time and high costs. Research on the prediction of HHV based on proximate analysis has been carried out so that it can simplify and save costs needed by researchers. In this paper, the evaluation of equations is discussed to predict HHV based on proximate analysis on biomass-based on data from previous studies. HHV prediction values using five equations were evaluated with 25 proximate biomass data from previous studies, then compared based on error value to get the best predictions. The analysis shows that Equation A predicts best in 7 biomass, B in 6 biomass, C in 6 biomass, D in 5 biomass, and E in 1 biomass. Key words: fuel, biomass, higher heating value, error value, proximate 

Production of fuels on the basis of sewage sludge through conditioning using high calorific value fractions

2008 ◽  
Vol 3 (1) ◽  
Author(s):  
Karl-Georg Schmelz ◽  
Anja Reipa ◽  
Hartmut Meyer
Keyword(s):  
Sewage Sludge ◽  
Wastewater Treatment Plants ◽  
Treatment Plant ◽  
Calorific Value ◽  
Fluidised Bed ◽  
Sludge Treatment ◽  
Heating Value ◽  
Fine Coal ◽  
Used Cars ◽  
Plastic Components

Emschergenossenschaft and Lippeverband operate 59 wastewater treatment plants which produce approx. 100,000 Mg TS of sewage sludge each year. Using sludge pressure pipelines, about 60 % of this sludge are transported to the central sludge treatment plant in Bottrop. The digested sludges are conditioned using fine coal and polymers and are dewatered using membrane filters. By adding coal, the heating value of the sludge is raised which enables autothermal combustion of the dewatered sludges in fluidised bed furnaces at the central sludge treatment plant. In order to replace coal, a fossil fuel, as conditioning agent, experiments were conducted using alternative materials with high heating values. The addition of shredder fluff agglomerates proved to be particularly successful. Shredder fluff agglomerates are a residue from the recycling of used cars and are generated in a multistage process (e.g. Volkswagen-SiCon Process) by separating the light shredder fraction (plastic components etc.) from the total shredder fluff. The fibrous material is outstandingly suitable for improving the dewaterability and for sufficiently raising the heating value of the dewatered sludge in order to enable autothermal combustion. Since first experiments showed very positive results, a full-scale long-term test-run will take place in 2007.

scholarly journals Elementary analysis and energetic potential of the municipal sewage sludges from the Gdańsk and Kościerzyna WWTPs

2018 ◽  
Vol 26 ◽  
pp. 00004
Author(s):  
Arkadiusz Ostojski
Keyword(s):  
Sewage Sludge ◽  
Water Content ◽  
Calorific Value ◽  
High Water ◽  
Municipal Sewage ◽  
Municipal Sewage Sludge ◽  
High Water Content ◽  
Sewage Sludges ◽  
Heating Value ◽  
Elementary Analysis

This paper aims to present municipal sewage sludge (MSS) elementary analysis and energetic potential based on measurement of heat of combustion (higher heating value HHV) and calculation of calorific values (lower heating value LHV). The analysis takes into the consideration water content in sewage sludge, at different utilization stages, in wastewater treatment plants in Gdańsk Wschód and Kościerzyna – Pomeranian Voivodeship. The study yielded the following results (in % dry matter): ash 19÷31 %, C - 31÷36 %, H - 5÷6 %, N - 4÷6 %, O - 28÷32 %, S – 1 %. Calorific value of stabilized sludges in Gdańsk was on average 13.8÷15 MJ/kg. In case of sludges not undergoing digestion from Kościerzyna WWTP, the calorific value was at the level of 17.5 MJ/kg. Thus, sewage sludges are good energy carriers. High water content though is the problem, as it lowers the useful effect of heat. There is no alternative for thermal sewage sludge neutralization, which is in conformity with valid Polish National Waste Management Plan (KPGO 2022).

scholarly journals Correlations to Predict Elemental Compositions and Heating Value of Torrefied Biomass

Energies ◽  
2018 ◽  
Vol 11 (9) ◽  
pp. 2443 ◽  
Author(s):  
Mahmudul Hasan ◽  
Yousef Haseli ◽  
Ernur Karadogan
Keyword(s):  
Carbon Content ◽  
Hydrogen Content ◽  
Woody Biomass ◽  
Coefficient Of Determination ◽  
Mass Yield ◽  
Solid Mass ◽  
Empirical Correlations ◽  
Heating Value ◽  
Torrefied Biomass ◽  
Data Points

Measurements reported in the literature on ultimate analysis of various types of torrefied woody biomass, comprising 152 data points, have been compiled and empirical correlations are developed to predict the carbon content, hydrogen content, and heating value of a torrefied wood as a function of solid mass yield. The range of torrefaction temperature, residence time and solid yield of the collected data is 200–300 °C, 5–60 min and 58–97%, respectively. Two correlations are proposed for carbon content with a coefficient of determination ( R 2 ) of 81.52% and 89.86%, two for hydrogen content with R 2 of 79.01% and 88.45%, and one for higher heating value with R 2 of 92.80%. The root mean square error (RMSE) values of the proposed correlations are 0.037, 0.028, 0.059, 0.043 and 0.023, respectively. The predictability of the proposed relations is examined with an additional set of experimental data and compared with the existing correlations in the literature. The new correlations can be used as a useful tool when designing torrefaction plants, furnaces, or gasifiers operating on torrefied wood.

scholarly journals Municipal solid waste higher heating value prediction from ultimate analysis using multiple regression and genetic programming techniques

2018 ◽  
Vol 37 (6) ◽  
pp. 578-589 ◽  
Author(s):  
Imane Boumanchar ◽  
Younes Chhiti ◽  
Fatima Ezzahrae M’hamdi Alaoui ◽  
Abdelaziz Sahibed-dine ◽  
Fouad Bentiss ◽  
...  
Keyword(s):  
Genetic Programming ◽  
Municipal Solid Waste ◽  
Solid Waste ◽  
Multiple Regression ◽  
Calorific Value ◽  
Heating Value ◽  
Ultimate Analysis ◽  
Msw Management ◽  
Important Challenge ◽  
Programming Techniques

Municipal solid waste (MSW) management presents an important challenge for all countries. In order to exploit them as a source of energy, a knowledge of their calorific value is essential. In fact, it can be experimentally measured by an oxygen bomb calorimeter. This process is, however, expensive. In this light, the purpose of this paper was to develop empirical models for the prediction of MSW higher heating value (HHV) from ultimate analysis. Two methods were used: multiple regression analysis and genetic programming formalism. Both techniques gave good results. Genetic programming, however, provides more accuracy compared to published works in terms of a great correlation coefficient (CC) and a low root mean square error (RMSE).

scholarly journals Characterization of Refuse Derived Fuel Production from Municipal Solid Waste: The Case Studies in Latvia and Lithuania

2020 ◽  
Vol 24 (3) ◽  
pp. 112-118
Author(s):  
Dace Âriņa ◽  
Rūta Bendere ◽  
Gintaras Denafas ◽  
Jānis Kalnačs ◽  
Mait Kriipsalu
Keyword(s):  
Municipal Solid Waste ◽  
Solid Waste ◽  
Calorific Value ◽  
Ash Content ◽  
Fuel Production ◽  
Heating Value ◽  
Refuse Derived Fuel ◽  
Morphological Composition ◽  
The Mean

AbstractThe authors determined the morphological composition of refuse derived fuel (RDF) produced in Latvia and Lithuania by manually sorting. The parameters of RDF (moisture, net calorific value, ash content, carbon, nitrogen, hydrogen, sulphur, chlorine, metals) was determined using the EN standards. Comparing obtained results with data from literature, authors have found that the content of plastic is higher but paper and cardboard is lower than typical values. Results also show that the mean parameters for RDF can be classified with the class codes: Net heating value (3); chlorine (3); mercury (1), and responds to limits stated for 3rd class of solid recovered fuel. It is recommended to separate biological waste at source to lower moisture and ash content and increase heating value for potential fuel production from waste.

scholarly journals Earthquakes and depleted gas reservoirs: which comes first?

2015 ◽  
Vol 15 (10) ◽  
pp. 2201-2208 ◽  
Author(s):  
M. Mucciarelli ◽  
F. Donda ◽  
G. Valensise
Keyword(s):  
Statistical Tests ◽  
Northern Italy ◽  
Relative Distribution ◽  
Gas Wells ◽  
Gas Reservoirs ◽  
Earthquake Sources ◽  
Hydrocarbon Traps ◽  
Depleted Gas Reservoirs ◽  
Production History ◽  
The Impact

Abstract. While scientists are paying increasing attention to the seismicity potentially induced by hydrocarbon exploitation, so far, little is known about the reverse problem, i.e. the impact of active faulting and earthquakes on hydrocarbon reservoirs. The 20 and 29 May 2012 earthquakes in Emilia, northern Italy (Mw 6.1 and 6.0), raised concerns among the public for being possibly human-induced, but also shed light on the possible use of gas wells as a marker of the seismogenic potential of an active fold and thrust belt. We compared the location, depth and production history of 455 gas wells drilled along the Ferrara-Romagna arc, a large hydrocarbon reserve in the southeastern Po Plain (northern Italy), with the location of the inferred surface projection of the causative faults of the 2012 Emilia earthquakes and of two pre-instrumental damaging earthquakes. We found that these earthquake sources fall within a cluster of sterile wells, surrounded by productive wells at a few kilometres' distance. Since the geology of the productive and sterile areas is quite similar, we suggest that past earthquakes caused the loss of all natural gas from the potential reservoirs lying above their causative faults. To validate our hypothesis we performed two different statistical tests (binomial and Monte Carlo) on the relative distribution of productive and sterile wells, with respect to seismogenic faults. Our findings have important practical implications: (1) they may allow major seismogenic sources to be singled out within large active thrust systems; (2) they suggest that reservoirs hosted in smaller anticlines are more likely to be intact; and (3) they also suggest that in order to minimize the hazard of triggering significant earthquakes, all new gas storage facilities should use exploited reservoirs rather than sterile hydrocarbon traps or aquifers.

scholarly journals Water-Gas Two-Phase Flow Behavior of Multi-Fractured Horizontal Wells in Shale Gas Reservoirs

Processes ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 664 ◽  
Author(s):  
Lei Li ◽  
Guanglong Sheng ◽  
Yuliang Su
Keyword(s):  
Organic Matter ◽  
Shale Gas ◽  
Flow Behavior ◽  
Horizontal Wells ◽  
Gas Production ◽  
Phase Flow ◽  
Gas Reservoirs ◽  
Two Phase ◽  
Fractured Horizontal Wells ◽  
Water Gas

Hydraulic fracturing is a necessary method to develop shale gas reservoirs effectively and economically. However, the flow behavior in multi-porosity fractured reservoirs is difficult to characterize by conventional methods. In this paper, combined with apparent porosity/permeability model of organic matter, inorganic matter and induced fractures, considering the water film in unstimulated reservoir volume (USRV) region water and bulk water in effectively stimulated reservoir volume (ESRV) region, a multi-media water-gas two-phase flow model was established. The finite difference is used to solve the model and the water-gas two-phase flow behavior of multi-fractured horizontal wells is obtained. Mass transfer between different-scale media, the effects of pore pressure on reservoirs and fluid properties at different production stages were considered in this model. The influence of the dynamic reservoir physical parameters on flow behavior and gas production in multi-fractured horizontal wells is studied. The results show that the properties of the total organic content (TOC) and the inherent porosity of the organic matter affect gas production after 40 days. With the gradual increase of production time, the gas production rate decreases rapidly compared with the water production rate, and the gas saturation in the inorganic matter of the ESRV region gradually decreases. The ignorance of stress sensitivity would cause the gas production increase, and the ignorance of organic matter shrinkage decrease the gas production gradually. The water film mainly affects gas production after 100 days, while the bulk water has a greater impact on gas production throughout the whole period. The research provides a new method to accurately describe the two-phase fluid flow behavior in different scale media of fractured shale gas reservoirs.

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