Gas-Compositional Effects on Mineralogical Reactions in Carbon Dioxide Sequestration

SPE Journal ◽  
2011 ◽  
Vol 16 (04) ◽  
pp. 949-958 ◽  
Author(s):  
Prashanth Mandalaparty ◽  
Milind Deo ◽  
Joseph Moore

Summary It may be possible to lower costs of carbon capture and sequestration by keeping constituents such as sulfur dioxide (SO2) in the flue-gas stream. The reactive behavior of pure carbon dioxide (CO2) and CO2+SO2 mixtures within a geologically realistic environment was examined in this paper. The experimental apparatus consisted of a series of high-pressure reactors operated at different conditions and with different feed-gas compositions to observe changes in both the rock and water compositions. The rock consisted of equal proportions of quartz, calcite, andesine, dolomite, chlorite, and magnesite (constituents in arkose or dirty sandstone). The brine was prepared from laboratory-grade sodium chloride. Several long-term batch experiments with pure CO2 were carried out at different temperatures. Each mineral in the mixture showed evidence of participating in the geochemical reactions. Layers of calcite were seen growing on the surface of the arkose. Analcime deposits were omnipresent, occurring either as large connected aggregates or as deposits on the surfaces of other minerals (quartz). Calcite depositions were observed as amorphous masses intergrown with the feed. The CO2+SO2 mixture experiments showed growth of euhedral anhydrite crystals and pronounced dissolution patterns over the examined surfaces. The growth of these new phases would lead to significant changes in the petrophysical properties of the rock. The trends in ionic-concentration changes in the aqueous phase complemented the changes in the rock chemistry.

2021 ◽  
pp. 68-71
Author(s):  
Igor M. Ageev ◽  
Yuri M. Rybin

The advantages and disadvantages of infrared and electrochemical gas analyzers for carbon dioxide CO2 are described. The possibility of using conductometric sensors with distilled water for monitoring the CO2 content in the air has been investigated. Two identical measuring systems were manufactured, each containing two open-type conductometric cells, a matching device and a personal computer. With the help of these complexes, experiments were carried out on the simultaneous measurement of the CO2 content in the air in two places (a laboratory room and a building in a forest, located at a distance of 15 km from each other) with deliberately different daily dynamics of the CO2 level change. A special experiment was carried out, which made it possible to obtain an estimate of the inertia of conductometric cells and a conversion factor for the values of CO2 content into standard units of measurement. It is shown that the daily dynamics of changes in the electrical conductivity of distilled water in open cells corresponds to the expected dynamics of changes in the CO2 content in the rooms where the measurements were carried out. The operability of the measuring complex and the possibility of creating on its basis a device for long-term monitoring of the CO2 content in the air mixture of gases has been confirmed. The principal high selectivity of the measuring complex to CO2 in relation to other gases of the atmosphere has been established.


SPE Journal ◽  
2021 ◽  
pp. 1-17
Author(s):  
Saira ◽  
Emmanuel Ajoma ◽  
Furqan Le-Hussain

Summary Carbon dioxide (CO2) enhanced oil recovery is the most economical technique for carbon capture, usage, and storage. In depleted reservoirs, full or near-miscibility of injected CO2 with oil is difficult to achieve, and immiscible CO2 injection leaves a large volume of oil behind and limits available pore volume (PV) for storing CO2. In this paper, we present an experimental study to delineate the effect of ethanol-treated CO2 injection on oil recovery, net CO2 stored, and amount of ethanol left in the reservoir. We inject CO2 and ethanol-treated CO2 into Bentheimer Sandstone cores representing reservoirs. The oil phase consists of a mixture of 0.65 hexane and 0.35 decane (C6-C10 mixture) by molar fraction in one set of experimental runs, and pure decane (C10) in the other set of experimental runs. All experimental runs are conducted at constant temperature 70°C and various pressures to exhibit immiscibility (9.0 MPa for the C6-C10 mixture and 9.6 MPa for pure C10) or near-miscibility (11.7 MPa for the C6-C10 mixture and 12.1 MPa for pure C10). Pressure differences across the core, oil recovery, and compositions and rates of the produced fluids are recorded during the experimental runs. Ultimate oil recovery under immiscibility is found to be 9 to 15% greater using ethanol-treated CO2 injection than that using pure CO2 injection. Net CO2 stored for pure C10 under immiscibility is found to be 0.134 PV greater during ethanol-treated CO2 injection than during pure CO2 injection. For the C6-C10 mixture under immiscibility, both ethanol-treated CO2 injection and CO2 injection yield the same net CO2 stored. However, for the C6-C10 mixture under near-miscibility,ethanol-treated CO2 injection is found to yield 0.161 PV less net CO2 stored than does pure CO2 injection. These results suggest potential improvement in oil recovery and net CO2 stored using ethanol-treated CO2 injection instead of pure CO2 injection. If economically viable, ethanol-treated CO2 injection could be used as a carbon capture, usage, and storage method in low-pressure reservoirs, for which pure CO2 injection would be infeasible.


2016 ◽  
Vol 9 (6) ◽  
pp. 2445-2461 ◽  
Author(s):  
Akihiko Kuze ◽  
Hiroshi Suto ◽  
Kei Shiomi ◽  
Shuji Kawakami ◽  
Makoto Tanaka ◽  
...  

Abstract. A data set containing more than 6 years (February 2009 to present) of radiance spectra for carbon dioxide (CO2) and methane (CH4) observations has been acquired by the Greenhouse gases Observing SATellite (GOSAT, available at http://data.gosat.nies.go.jp/GosatUserInterfaceGateway/guig/GuigPage/open.do), nicknamed “Ibuki”, Thermal And Near infrared Sensor for carbon Observation Fourier Transform Spectrometer (TANSO-FTS). This paper provides updates on the performance of the satellite and TANSO-FTS sensor and describes important changes to the data product, which has recently been made available to users. With these changes the typical accuracy of retrieved column-averaged dry air mole fractions of CO2 and CH4 (XCO2 and XCH4, respectively) are 2 ppm or 0.5 % and 13 ppb or 0.7 %, respectively. Three major anomalies of the satellite system affecting TANSO-FTS are reported: a failure of one of the two solar paddles in May 2014, a switch to the secondary pointing system in January 2015, and most recently a cryocooler shutdown and restart in August 2015. The Level 1A (L1A) (raw interferogram) and the Level 1B (L1B) (radiance spectra) of version V201 described here have long-term uniform quality and provide consistent retrieval accuracy even after the satellite system anomalies. In addition, we discuss the unique observation abilities of GOSAT made possible by an agile pointing mechanism, which allows for optimization of global sampling patterns.


Energies ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1945 ◽  
Author(s):  
Lars Ingolf Eide ◽  
Melissa Batum ◽  
Tim Dixon ◽  
Zabia Elamin ◽  
Arne Graue ◽  
...  

Presently, the only offshore project for enhanced oil recovery using carbon dioxide, known as CO2-EOR, is in Brazil. Several desk studies have been undertaken, without any projects being implemented. The objective of this review is to investigate barriers to the implementation of large-scale offshore CO2-EOR projects, to identify recent technology developments, and to suggest non-technological incentives that may enable implementation. We examine differences between onshore and offshore CO2-EOR, emerging technologies that could enable projects, as well as approaches and regulatory requirements that may help overcome barriers. Our review shows that there are few, if any, technical barriers to offshore CO2-EOR. However, there are many other barriers to the implementation of offshore CO2-EOR, including: High investment and operation costs, uncertainties about reservoir performance, limited access of CO2 supply, lack of business models, and uncertainties about regulations. This review describes recent technology developments that may remove such barriers and concludes with recommendations for overcoming non-technical barriers. The review is based on a report by the Carbon Sequestration Leadership Forum (CSLF).


Aquaculture ◽  
2021 ◽  
Vol 534 ◽  
pp. 736279
Author(s):  
Do Thi Thanh Huong ◽  
Chau Huynh Thuy Tram ◽  
Nguyen Thi Kim Ha ◽  
Le Thi Hong Gam ◽  
Atsushi Ishimatsu ◽  
...  

Author(s):  
G. Hachem ◽  
J. Salazar ◽  
U. Dixekar

Carbon capture and storage (CCS) constitutes an extremely important technology that is constantly being improved to minimize the amounts of carbon dioxide (CO2) entering the atmosphere. According to the Global CCS Institute, there are more than 320 worldwide CCS projects at different phases of progress. However, current CCS processes are accompanied with a large energy and efficiency penalty. This paper models and simulates a post-combustion carbon capture system, that uses absorption as a method of separation, in Aspen Plus V7.2. Moreover, the CAPE-OPEN Simulated Annealing (SA) Capability is implemented to minimize the energy consumed by this system, and allow coal-fired power plants to use similar carbon capture systems without losing 20 to 40 % of the plant's output.


2021 ◽  
pp. 54-61
Author(s):  
N. V. Popov ◽  
◽  
I. L. Govor ◽  
M. L. Gitarskii ◽  
◽  
...  

The average weighted long-term component composition of associated petroleum gas burned at the fields in Russia is obtained, where the volume fractions of carbon dioxide (CO2) and methane (CH4) make up 0.8 and 66.4%, respectively. Based on it, the national emission factors of greenhouse gases from the flaring of associated petroleum gas are developed: the values are equal to 2.76 103 t CO2 and 0.0155 103 t CH4 per 1 106 m3 of the gas burnt. The calculations based on the emission factors led to the 37% increase in total equivalent emission of CO2 and CH4 as compared to the calculations based on the IPCC emission factors. The use of the national emission factors increases the reliability of the estimates of greenhouse gas emissions and the evaluation of their impact on climate.


Sign in / Sign up

Export Citation Format

Share Document