scholarly journals Study of The Sorption of The Total Phenolic Compounds From Olive Mill Wastewater By Natural Soils: Conventional and Under Microwave Irradiation Kinetics.

Author(s):  
Malika Arabi ◽  
Abdelhamid Elias ◽  
Yasmine Ait Younes ◽  
Ziane Kamel ◽  
Idir Toumert ◽  
...  

Abstract The elimination of total phenolic compounds (TPC) from olive mill wastewater was studied by sorption under the conditions: conventional and under microwave irradiation on previously characterized soils. The sorption process has been studied in batch using inorganic materials in their natural states for sustainable development.The characterizations of the soils have shown variability in potential of hydrogen (4.6-8.9) in total nitrogen between 0.5 and 2.5% and in mineral matter which varies between 5.86 and 15.16%. On the other hand, the mineralogical characterization showed that the three soils are composed of several clay and non-clay minerals.The experimental data were analyzed using reaction models and diffusion models. The pseudo second order kinetic model provides the best correlation. It best represents the kinetics of adsorption by the natural adsorbents N1, N3 and R.The sorption models of LANGMUIR, FREUNDLICH and DUBININ-RADUSHKEVICH were used for the mathematical description of the conventional adsorption equilibrium. The best correlations were obtained with the model of LANGMUIR (r2 > 0.95) on soils N1 and N3 unlike the models of FREUNDLICH and DUBININ-RADUSHKEVICH (r2 < 0.65). The soil R can be represented by the model of FREUNDLICH (r2 ≥ 0.96) and the model of LANGMUIR (r2 > 0.93). The latter is confirmed by the value of the dimensionless coefficient RL. Removal rates of TPC were calculated. The value obtained (71 %) showed that the soil N1 is a good adsorbent. The results are satisfactory and promising.

2021 ◽  
Vol 2021 ◽  
pp. 1-16
Author(s):  
Khansaa Al-Essa ◽  
Ethar M. Al-Essa

Olive mill wastewater (OMW) is nowadays considered a serious environmental problem, especially within the Mediterranean region. With this in mind, water shortages are also a very serious and prevalent concern in third world countries. The aim of this study is to investigate the feasibility of using Jordanian bentonite, a simple and natural clay, as a possible adsorbent to decrease the negative characteristics of raw OMW, as an approach to the development of a methodology that addresses the OMW problem without affecting freshwater resources. The purified bentonite was activated by sodium ions at room temperature. FTIR, XRD, TGA, and BET surface area measurements were performed. OMW was contacted with both purified and activated bentonite in the batch technique to figure out the optimum parameters for the adsorption process. Physiochemical parameters of OMW were measured before and after treatment. The maximum adsorption qm was found as 8.81 mg/g at 323 K for the total phenolic compounds. The Langmuir and Freundlich models were utilized to describe the equilibrium isotherms and both models fit well. The parameters of thermodynamic show that the adsorption process was feasible, spontaneous, and endothermic in nature. These promising results along with the sodium activation of bentonite significantly improve bentonite’s adsorption capacity.


2017 ◽  
Vol 2017 ◽  
pp. 1-9 ◽  
Author(s):  
Saleh Abu-Lafi ◽  
Mahmoud Sami Al-Natsheh ◽  
Reem Yaghmoor ◽  
Fuad Al-Rimawi

The production of olive oil generates massive quantities of by-product called olive mill wastewater (OMWW). The uncontrolled disposal of OMWW poses serious environmental problems. The OMWW effluent is rich in several polyphenolic compounds. Liquid-liquid extraction of OMWW using ethyl acetate solvent was used to enrich phenolic compounds under investigation. Total phenolic and flavonoid content and antioxidant activity of the extract were determined. HPLC coupled to photodiode array (PDA) detector was used to analyze the main three phenolic compounds of OMWW, namely, hydroxytyrosol, tyrosol, and oleuropein. The antimicrobial activity of the extract was also investigated. Additionally, the OMWW extract was used as natural preservative and antioxidants for olive oil. Results showed that OMWW is very rich in phenolic compounds and has strong antioxidant activity. HPLC analysis showed that the extract contains mainly hydroxytyrosol and tyrosol but no oleuropein. The OMWW extract showed also positive activities as antibacterial (gram positive and gram negative) and antifungal as well as activities against yeast. The addition of OMWW extract to olive oil samples has an effect on the stability of olive oil as reflected by its acid value, peroxide value, K232 and K270, and total phenolic content.


2018 ◽  
Vol 2018 ◽  
pp. 1-10 ◽  
Author(s):  
Khansaa Al-Essa

Jordanian bentonite was activated by hydrochloric acid at room temperature. FTIR, XRD, TGA, and BET surface area analyses of the samples were carried out to examine the structure of bentonite before and after acid activation. It is found that the octahedral cations were removed, which altered the chemical composition of the bentonite. Difference of surface area was noticed (66.2 to 287.8 m2 g−1), which was caused by structural changes in the bentonite. We aimed to investigate the effectiveness of activated bentonite in OMWW treatment. Batch and column techniques were applied. Crude and treated OMWW samples were characterized; physiochemical parameters, total phenolic compounds, and heavy metal ions concentrations were measured. Several parameters that affected the adsorption capacity were studied: the pH value of the solution, temperature, and the adsorbent dose. It was found that the maximum removal of total phenolic compounds and heavy metal ions (Zn, Fe, and Mn) was at pH 6. Adsorption capacity of phenolic compounds was enhanced with an increase in the temperature of the solution and also with the adsorbent dose. The optimum adsorbent concentration needed for the maximum removal of total phenolic compounds is 1 g of activated bentonite/0.01 L of OMWW. The percentage removal exceeded 99% for Zn, Fe, and Mn ions, while it reached 65.2 and 61.5 for K+ and Na+ ions, respectively. Finally, the percentage removal of pollutants was increased by using activated bentonite. This study will provide valuable insight into the effect of activated bentonite towards the treatment and recyclability of OMWW, which is essential for the local olive mill industry.


2020 ◽  
Vol 3 (1) ◽  
pp. 47
Author(s):  
Nadezhda Petkova ◽  
Manol Ognyanov ◽  
Blaga Inyutin ◽  
Petar Zhelev ◽  
Panteley Denev

Crab apple (Malus baccata (L.) Borkh.) was mainly distributed in Europe as an ornamental plant, but the nutritional properties of its edible fruits were not fully revealed. The aim of the current study was to characterize the phytochemical composition of ripen carb apple fruits and to evaluate their nutritional and antioxidant potentials. The fruits were assayed for moisture and ash content, proteins, lipids, carbohydrates, titratable acidity (TA), pH, total phenolic compounds and natural pigments. Among the analyzed carbohydrates cellulose was found in the highest content (6% dw), followed by sugars (sucrose, glucose and fructose) and 1.8 % dw uronic acids. The total chlorophylls and carotenoids contents in their fruits were 6.51 and 4.80 μg/g fw, respectively. Total monomeric anthocyanins were not detected. The highest content of total phenolic compounds (2.67 mg GAE/g fw) was found in 95 % ethanol extract from fruits, while the total flavonoids were relatively low – 0.1 mg QE/g fw. DPPH assay (17.27 mM TE/g fw) and FRAP assay (14.34 mM TE/g fw) demonstrated in vitro antioxidant activities of crabapple. Malus baccata fruits were evaluated as a rich source of dietary fibers and phenolic compounds with significant antioxidant potential that could be used in human nutrition.


Antioxidants ◽  
2021 ◽  
Vol 10 (3) ◽  
pp. 398
Author(s):  
Muneera D. F. AlKahtani ◽  
Yaser M. Hafez ◽  
Kotb Attia ◽  
Emadeldeen Rashwan ◽  
Latifa Al Husnain ◽  
...  

Drought stress deleteriously affects growth, development and productivity in plants. So, we examined the silicon effect (2 mmol) and proline (10 mmol) individually or the combination (Si + proline) in alleviating the harmful effect of drought on total phenolic compounds, reactive oxygen species (ROS), chlorophyll concentration and antioxidant enzymes as well as yield parameters of drought-stressed sugar beet plants during 2018/2019 and 2019/2020 seasons. Our findings indicated that the root diameter and length (cm), root and shoot fresh weights (g plant−1) as well as root and sugar yield significantly decreased in sugar beet plants under drought. Relative water content (RWC), nitrogen (N), phosphorus (P) and potassium (K) contents and chlorophyll (Chl) concentration considerably reduced in stressed sugar beet plants that compared with control in both seasons. Nonetheless, lipid peroxidation (MDA), electrolyte leakage (EL), hydrogen peroxide (H2O2) and superoxide (O2●−) considerably elevated as signals of drought. Drought-stressed sugar beet plants showed an increase in proline accumulation, total phenolic compounds and up-regulation of antioxidant enzymes catalase (CAT) and superoxide dismutase (SOD) activity to mitigate drought effects. Si and proline individually or the combination Si + proline considerably increased root and sugar yield, sucrose%, Chl concentration and RWC, MDA and EL were remarkably reduced. The treatments led to adjust proline and total phenolic compounds as well as CAT and SOD activity in stressed sugar beet plants. We concluded that application of Si + proline under drought stress led to improve the resistance of sugar beet by regulating of proline, antioxidant enzymes, phenolic compounds and improving RWC, Chl concentration and Nitrogen, Phosphorus and Potassium (NPK) contents as well as yield parameters.


2021 ◽  
pp. 1-10
Author(s):  
Leandro Marcolino Vieira ◽  
Renata de Almeida Maggioni ◽  
Jéssica de Cássia Tomasi ◽  
Erik Nunes Gomes ◽  
Ivar Wendling ◽  
...  

Abstract Ilex paraguariensis, commonly known as yerba mate, is a tree species native to South America. Its commercial value is due to the manufacturing of teas, with potential also in the pharmacological and cosmetic industries. Vegetative propagation of yerba mate is considered an innovation to the traditional production systems based on sexual propagation. The present study aimed to evaluate the rhizogenic potential and chemical attributes of mini-cuttings from 15 yerba mate genotypes, as well as to verify the correlation between phytochemical and rooting-related variables. Mini-cuttings were collected from a pre-existing mini-clonal hedge and the experimental design was completely randomized, with 15 treatments (genotypes), four replications and 10 mini-cuttings per plot. After 120 days, mini-cuttings were assessed regarding rooting, mortality, callogenesis and leaf retention percentages, percentage of mini-cuttings with both calluses and roots, number of roots and average root length. At the time of collection, subsamples from each plot were used for phytochemical analyses including total phenolic compounds, protein, caffeine and theobromine contents and antioxidant activity. Rooting percentages ranged from 5 to 72.5%, with significant variation among genotypes. Adventitious rooting and phytochemical profile of yerba mate mini-cuttings are genotype-dependent. Leaf retention is a relevant factor in the rooting of yerba mate mini-cuttings and the levels of total phenolic compounds, antioxidants and theobromine present in mini-cuttings are negatively correlated components to Ilex paraguariensis adventitious rooting.


Fermentation ◽  
2021 ◽  
Vol 7 (3) ◽  
pp. 137
Author(s):  
Luis F. Castro ◽  
Abigail D. Affonso ◽  
Renata M. Lehman

Specialty malts are commonly used in brewing to provide flavor, aroma, and color to wort and beer. The use of specialty malts contributes to the variety of beer products; therefore, it is important to understand their effect on the characteristics of wort and beer. This study investigates the impact of various specialty malts on wort and beer properties. A control beer was prepared with 100% base malt, and four beer treatments were prepared with the addition of kilned, roasted, and caramel specialty malts. For each treatment, 20% of the base malt was substituted with the various specialty malts when preparing the wort. The fermentable sugars and free amino nitrogen (FAN) content for each wort were analyzed. Alcohol by volume (ABV), international bitterness units (IBU), diacetyl, and polyphenol content of each prepared beers were subsequently analyzed. Results showed that wort prepared with the addition of roasted and caramel malts contained a lower concentration of fermentable sugars and FAN than wort prepared with the base and kilned malts. Beers prepared with the addition of roasted and caramel malts exhibited the lowest levels of ABV, as well as the lowest levels of diacetyl. These beers also exhibited higher levels of total phenolic compounds compared to the other beer samples. No change was observed in IBU levels as a result of brewing with the different specialty malts. This study illustrates how the use of specialty malts impacts wort and beer properties, providing useful information to aid in the production of quality beer products.


Molecules ◽  
2020 ◽  
Vol 26 (1) ◽  
pp. 46
Author(s):  
Mariana de Oliveira Silva ◽  
John Nonvignon Bossis Honfoga ◽  
Lorena Lucena de Medeiros ◽  
Marta Suely Madruga ◽  
Taliana Kênia Alencar Bezerra

Coffee husks (Coffea arabica L.) are characterized by exhibiting secondary metabolites such as phenolic compounds, which can be used as raw material for obtaining bioactive compounds of interest in food. The objective of this study is to evaluate different methods for obtaining the raw material and extracting solutions of bioactive compounds from coffee husks. Water bath and ultrasound-assisted extraction methods were used, using water (100%) or ethanol (100%) or a mixture of both (1:1) as extracting solutions and the form of the raw material was in natura and dehydrated. The extracts were evaluated by their antioxidant potential using DPPH radicals, ABTS, and iron reduction (ferric reducing antioxidant power (FRAP)), and later total phenolic compounds, total flavonoids, and condensed tannins were quantified the phenolic majority compounds were identified. It was verified that the mixture of water and ethanol (1:1) showed better extraction capacity of the compounds with antioxidant activity and that both conventional (water bath) or unconventional (ultrasound) methods showed satisfactory results. Finally, a satisfactory amount of bioactive compounds was observed in evaluating the chemical composition (total phenolic compounds, total flavonoids, condensed tannins, as well as the analysis of the phenolic profile) of these extracts. Corroborating with the results of the antioxidant activities, the best extracting solution was generally the water and ethanol mixture (1:1) using a dehydrated husk and water bath as the best method, presenting higher levels of the bioactive compounds in question, with an emphasis on chlorogenic acid. Thus, it can be concluded that the use of coffee husk as raw material to obtain extracts of bioactive compounds is promising. Last, the conventional method (water bath) and the water and ethanol mixture (1:1) stood out among the methods and extracting solutions used for the dehydrated coffee husk.


Sign in / Sign up

Export Citation Format

Share Document