scholarly journals Evaluation of Neoproterozoic Source Rock Potential in SE Pakistan and Adjacent Bikaner- Nagaur Basin India Based on Integrated Geochemical, Geological, and Geophysical Data

2021 ◽  
Author(s):  
Qamar Yasin ◽  
Syrine Baklouti ◽  
Ghulam Mohyuddin Sohail ◽  
Muhammad Asif ◽  
Gong Xufei
Keyword(s):  
Source Rock ◽  
Early Stage ◽  
Seismic Inversion ◽  
Source Rocks ◽  
Maturity Index ◽  
Thermal Maturity ◽  
Index Profile ◽  
Southeastern Part ◽  
Seismic Reflection Data ◽  
Rock Eval

Abstract Discoveries of heavy crude oil in the Neoproterozoic rocks (Infracambrian rock sequence) from the Bikaner-Nagaur Basin of India emphasizes the significance to study and explore the Neoproterozoic source rocks potential in the southeastern part of Pakistan. This study evaluates the potential of the source rock in the Infracambrian rock sequence (Salt Range Formation) based on surface geochemical surveys, Rock-Eval pyrolysis, source biomarkers, geophysical characterization, and seismic inversion using machine learning for maturity index estimation. Core samples of Infracambrian rock were extracted for Rock-Eval pyrolysis and biomarker characterization. Also, 81 geo-microbial soil and gas samples were collected from the surface to explore the petroleum system and potential source rocks in the subsurface. We followed the standard laboratory procedures to investigate the origin and concentration of hydrocarbons gases at the surface, thermal maturity, the source facies, and the environment of deposition of organic matter. The results show that the investigated samples are characterized by restricted marine clay devoid of carbonate source facies with thermal maturity in the early-stage of the oil generation window. Surface geochemical samples also confirm higher concentrations of thermogenic C2-C4 hydrocarbons over the vicinity of anticlinal structures proving the existence of an effective migration path along deep-seated faults to the surface. The inverted maturity index profile demonstrates a reasonable correlation of thermal maturity with the surface geochemical survey, source biomarkers, and Rock-Eval pyrolysis. It validates the reliability of multilayer linear calculator and particle swarm optimization algorithms for inverting seismic reflection data into a maturity index profile. The obtained results indicate a higher probability of heavy and light oil along the eastern flank of Pakistan, where Infracambrian rocks are thicker and more thermally mature, and deep-seated pledged structural closures occur, in comparison to the Bikaner-Nagaur Basin, India.

scholarly journals Source Rocks Characterization Of Agbada And Akata Formations In The Niger Delta, Nigeria

2020 ◽  
Vol 1 (4) ◽  
Author(s):  
Koffi Eugene Kouadio ◽  
Selegha Abrakasa ◽  
Sunday S. Ikiensikimama ◽  
Takyi Botwe
Keyword(s):  
Organic Matter ◽  
Niger Delta ◽  
Early Stage ◽  
Source Rocks ◽  
Thermal Maturity ◽  
Petroleum Generation ◽  
Niger Delta Basin ◽  
Rock Eval ◽  
Organic Matter Abundance

The geochemical analysis was performed on twelve (12) core samples from 6 wells of different formations (Akata, Agbada, and Akata/Agbada) of the onshore  Niger Delta Basin. The study was essentially based on the results of the Rock-Eval 6 Pyrolysis to evaluate organic matter abundance, quality, and thermal maturity. The Total Organic Carbon (TOC) varies between 0.6 and 3.06 wt% and the Hydrogen Index (IH) of the studied samples ranges from 38 to 202 mgHC/g TOC, indicating predominantly Type III (gas prone) and mixed type II/III (gas and oil-prone) kerogen. This suggests terrigenous and a mixture of marine and terrigenous organic matter deposited in a paralic marine setting. The organic matter is immature to early mature according to the thermal maturity parameter (414<Tmax<432). The well Isan 9 from Agbada (6760 ft) and Agbada/Akata (8680 ft) shows petroleum generation potential of fair (2,5 < S2 < 5 mg HC/g rock) to good (5 < S2 < 10 mgHC/g rock) and poor for the  other wells. The maturation of the kerogen indicates a very early stage of maturation (Tmax= 432°C). The results indicate that the shales from Agbada and the transition zone between the upper and lower parts of the Akata Shales are more shaly and perhaps the more mature part of the Agbada formation can be the potential source rocks of Niger Delta Basin.

scholarly journals Source rock characterization of mesozoic to cenozoic organic matter rich marls and shales of the Eratosthenes Seamount, Eastern Mediterranean Sea

2018 ◽  
Vol 73 ◽  
pp. 49 ◽  
Author(s):  
Sebastian Grohmann ◽  
Susanne W. Fietz ◽  
Ralf Littke ◽  
Samer Bou Daher ◽  
Maria Fernanda Romero-Sarmiento ◽  
...  
Keyword(s):  
Organic Matter ◽  
Mediterranean Sea ◽  
Source Rock ◽  
Eastern Mediterranean ◽  
Source Rocks ◽  
Eastern Mediterranean Sea ◽  
Potential Source Rock ◽  
Levant Basin ◽  
Rock Characterization ◽  
Rock Eval

Several significant hydrocarbon accumulations were discovered over the past decade in the Levant Basin, Eastern Mediterranean Sea. Onshore studies have investigated potential source rock intervals to the east and south of the Levant Basin, whereas its offshore western margin is still relatively underexplored. Only a few cores were recovered from four boreholes offshore southern Cyprus by the Ocean Drilling Program (ODP) during the drilling campaign Leg 160 in 1995. These wells transect the Eratosthenes Seamount, a drowned bathymetric high, and recovered a thick sequence of both pre- and post-Messinian sedimentary rocks, containing mainly marine marls and shales. In this study, 122 core samples of Late Cretaceous to Messinian age were analyzed in order to identify organic-matter-rich intervals and to determine their depositional environment as well as their source rock potential and thermal maturity. Both Total Organic and Inorganic Carbon (TOC, TIC) analyses as well as Rock-Eval pyrolysis were firstly performed for the complete set of samples whereas Total Sulfur (TS) analysis was only carried out on samples containing significant amount of organic matter (>0.3 wt.% TOC). Based on the Rock-Eval results, eight samples were selected for organic petrographic investigations and twelve samples for analysis of major aliphatic hydrocarbon compounds. The organic content is highly variable in the analyzed samples (0–9.3 wt.%). TS/TOC as well as several biomarker ratios (e.g. Pr/Ph < 2) indicate a deposition under dysoxic conditions for the organic matter-rich sections, which were probably reached during sporadically active upwelling periods. Results prove potential oil prone Type II kerogen source rock intervals of fair to very good quality being present in Turonian to Coniacian (average: TOC = 0.93 wt.%, HI = 319 mg HC/g TOC) and in Bartonian to Priabonian (average: TOC = 4.8 wt.%, HI = 469 mg HC/g TOC) intervals. A precise determination of the actual source rock thickness is prevented by low core recovery rates for the respective intervals. All analyzed samples are immature to early mature. However, the presence of deeper buried, thermally mature source rocks and hydrocarbon migration is indicated by the observation of solid bitumen impregnation in one Upper Cretaceous and in one Lower Eocene sample.

Liquid hydrocarbon characterization of the lacustrine Yanchang Formation, Ordos Basin, China: Organic-matter source variation and thermal maturity

2017 ◽  
Vol 5 (2) ◽  
pp. SF225-SF242 ◽  
Author(s):  
Xun Sun ◽  
Quansheng Liang ◽  
Chengfu Jiang ◽  
Daniel Enriquez ◽  
Tongwei Zhang ◽  
...  
Keyword(s):  
Organic Matter ◽  
Source Rock ◽  
Ordos Basin ◽  
Depositional Environments ◽  
Source Rocks ◽  
Type I ◽  
Hydrocarbon Generation ◽  
Type Ii ◽  
Thermal Maturity ◽  
Yanchang Formation

Source-rock samples from the Upper Triassic Yanchang Formation in the Ordos Basin of China were geochemically characterized to determine variations in depositional environments, organic-matter (OM) source, and thermal maturity. Total organic carbon (TOC) content varies from 4 wt% to 10 wt% in the Chang 7, Chang 8, and Chang 9 members — the three OM-rich shale intervals. The Chang 7 has the highest TOC and hydrogen index values, and it is considered the best source rock in the formation. Geochemical evidence indicates that the main sources of OM in the Yanchang Formation are freshwater lacustrine phytoplanktons, aquatic macrophytes, aquatic organisms, and land plants deposited under a weakly reducing to suboxic depositional environment. The elevated [Formula: see text] sterane concentration and depleted [Formula: see text] values of OM in the middle of the Chang 7 may indicate the presence of freshwater cyanobacteria blooms that corresponds to a period of maximum lake expansion. The OM deposited in deeper parts of the lake is dominated by oil-prone type I or type II kerogen or a mixture of both. The OM deposited in shallower settings is characterized by increased terrestrial input with a mixture of types II and III kerogen. These source rocks are in the oil window, with maturity increasing with burial depth. The measured solid-bitumen reflectance and calculated vitrinite reflectance from the temperature at maximum release of hydrocarbons occurs during Rock-Eval pyrolysis ([Formula: see text]) and the methylphenanthrene index (MPI-1) chemical maturity parameters range from 0.8 to [Formula: see text]. Because the thermal labilities of OM are associated with the kerogen type, the required thermal stress for oil generation from types I and II mixed kerogen has a higher and narrower range of temperature for hydrocarbon generation than that of OM dominated by type II kerogen or types II and III mixed kerogen deposited in the prodelta and delta front.

ACCURATE RECOGNITION OF SOURCE ROCK CHARACTER IN THE JURASSIC OF THE NORTH WEST SHELF, WESTERN AUSTRALIA

1992 ◽  
Vol 32 (1) ◽  
pp. 289 ◽  
Author(s):  
John Scott
Keyword(s):  
Source Rock ◽  
Organic Material ◽  
Source Rocks ◽  
Higher Plant ◽  
Pyrolysis Gas ◽  
Screening Analysis ◽  
North West ◽  
The North ◽  
Potential Source Rock ◽  
Rock Eval

The main potential source rock intervals are generally well defined on the North West Shelf by screening analysis such as Rock-Eval. The type of product from the source rocks is not well defined, owing to inadequacies in current screening analysis techniques. The implications of poor definition of source type in acreage assessment are obvious. The type of product is dependent on the level of organic maturity of the source rock, the ability of products to migrate out of the source rock and on the type of organic material present. The type of kerogen present is frequently determined by Rock-Eval pyrolysis. However, Rock-Eval has severe limitations in defining product type when there is a significant input of terrestrial organic material. This problem has been recognised in Australian terrestrial/continental sequences but also occurs where marine source rock facies contain terrestrially-derived higher plant material. Pyrolysis-gas chromatography as applied to source rock analysis provides, by molecular typing, a better method of estimating the type of products of the kerogen breakdown than bulk chemical analysis such as Rock-Eval pyrolysis.

scholarly journals Organic geochemical and palynological studies of the Maastrichtian source rock intervals in Bida Basin, Nigeria: implications for hydrocarbon prospectivity

2020 ◽  
Vol 10 (8) ◽  
pp. 3191-3206
Author(s):  
Olusola J. Ojo ◽  
Ayoola Y. Jimoh ◽  
Juliet C. Umelo ◽  
Samuel O. Akande
Keyword(s):  
Organic Matter ◽  
Source Rock ◽  
Vitrinite Reflectance ◽  
Source Rocks ◽  
High Yield ◽  
Thermal Maturity ◽  
Hydrocarbon Source Rock ◽  
Moderate Amount ◽  
Oxic Condition ◽  
Freshwater Swamp

Abstract The Patti Formation which consists of sandstone and shale offers the best potential source beds in the Bida Basin. This inland basin is one of the basins currently being tested for hydrocarbon prospectivity in Nigeria. Fresh samples of shale from Agbaja borehole, Ahoko quarry and Geheku road cut were analysed using organic geochemical and palynological techniques to unravel their age, paleoecology, palynofacies and source bed hydrocarbon potential. Palynological data suggest Maastrichtian age for the sediments based on the abundance of microfloral assemblage; Retidiporites magdalenensis, Echitriporites trianguliformis and Buttinia andreevi. Dinocysts belonging to the Spiniferites, Deflandrea and Dinogymnium genera from some of the analysed intervals are indicative of freshwater swamp and normal sea conditions. Palynological evidence further suggests mangrove paleovegetation and humid climate. Relatively high total organic carbon TOC (0.77–8.95 wt%) was obtained for the shales which implies substantial concentration of organic matter in the source beds. Hydrocarbon source rock potential ranges from 0.19 to 0.70 mgHC/g.rock except for a certain source rock interval in the Agbaja borehole with high yield of 25.18 mgHC/g.rock. This interval also presents exceptionally high HI of 274 mgHC/g.TOC and moderate amount of amorphous organic matter. The data suggests that in spite of the favourable organic matter quantity, the thermal maturity is low as indicated by vitrinite reflectance and Tmax (0.46 to 0.48 Ro% and 413 to 475 °C, respectively). The hydrocarbon extracts show abundance of odd number alkanes C27–C33, low sterane/hopane ratio and Pr/Ph > 2. We conclude that the source rocks were terrestrially derived under oxic condition and dominated by type III kerogen. Type II organic matter with oil and gas potential is a possibility in Agbaja area of Bida Basin. Thermal maturity is low and little, or no hydrocarbon has been generated from the source rocks.

scholarly journals 3D-Basin Modelling of the Lishui Sag: Research of Hydrocarbon Potential, Petroleum Generation and Migration

Energies ◽  
2019 ◽  
Vol 12 (4) ◽  
pp. 650 ◽  
Author(s):  
Jinliang Zhang ◽  
Jiaqi Guo ◽  
Jinshui Liu ◽  
Wenlong Shen ◽  
Na Li ◽  
...  
Keyword(s):  
Source Rock ◽  
Thermal Evolution ◽  
Vitrinite Reflectance ◽  
Three Dimensional ◽  
Source Rocks ◽  
Rock Properties ◽  
Hydrocarbon Generation ◽  
Hydrocarbon Accumulation ◽  
Southeastern Part ◽  
Petroleum Generation

The Lishui Sag is located in the southeastern part of the Taibei Depression, in the East China Sea basin, where the sag is the major hydrocarbon accumulation zone. A three dimensional modelling approach was used to estimate the mass of petroleum generation and accumulated during the evolution of the basin. Calibration of the model, based on measured maturity (vitrinite reflectance) and borehole temperatures, took into consideration two main periods of erosion events: a late Cretaceous to early Paleocene event, and an Oligocene erosion event. The maturation histories of the main source rock formations were reconstructed and show that the peak maturities have been reached in the west central part of the basin. Our study included source rock analysis, measurement of fluid inclusion homogenization temperatures, and basin history modelling to define the source rock properties, the thermal evolution and hydrocarbon generation history, and possible hydrocarbon accumulation processes in the Lishui Sag. The study found that the main hydrocarbon source for the Lishui Sag are argillaceous source rocks in the Yueguifeng Formation. The hydrocarbon generation period lasted from 58 Ma to 32 Ma. The first period of hydrocarbon accumulation lasted from 51.8 Ma to 32 Ma, and the second period lasted from 23 Ma to the present. The accumulation zones mainly located in the structural high and lithologic-fault screened reservoir filling with the hydrocarbon migrated from the deep sag in the south west direction.

A NEW PERSPECTIVE ON EXPLORING THE COOPER/EROMANGA PETROLEUM PROVINCE—EVIDENCE OF OIL CHARGING FROM THE WARBURTON BASIN

2006 ◽  
Vol 46 (1) ◽  
pp. 261 ◽  
Author(s):  
C.O.E. Hallmann ◽  
K.R. Arouri ◽  
D.M. McKirdy ◽  
L. Schwark
Keyword(s):  
Source Rock ◽  
Source Rocks ◽  
Petroleum Exploration ◽  
True Nature ◽  
Hydrocarbon Biomarkers ◽  
Source Signal ◽  
History Of ◽  
Permian Coal ◽  
New Perspective ◽  
Rock Eval

The history of petroleum exploration in central Australia has been enlivened by vigorous debate about the source(s) of the oil and condensate found in the Cooper/Eromanga basin couplet. While early workers quickly recognized the source potential of thick Permian coal seams in the Patchawarra and Toolachee Formations, it took some time for the Jurassic Birkhead Formation and the Cretaceous Murta Formation to become accepted as effective source rocks. Although initially an exploration target, the Cambrian sediments of the underlying Warburton Basin subsequently were never seriously considered to have participated in the oil play, possibly due to a lack of subsurface information as a consequence of limited penetration by only a few widely spaced wells. Dismissal of the Warburton sequence as a source of hydrocarbons was based on its low generative potential as measured by total organic carbon (TOC) and Rock-Eval pyrolysis analyses. As most of the core samples analysed came from the upper part of the basin succession that has been subjected to severe weathering and oxidation, these results might not reflect the true nature of the Warburton Basin’s source rocks. We analysed a suite of source rock extracts, DST oils and sequentially extracted reservoir bitumens from the Gidgealpa field for conventional hydrocarbon biomarkers as well as nitrogen-containing carbazoles. The resulting data show that organic facies is the main control on the distribution of alkylated carbazoles in source rock extracts, oils and sequentially extracted bitumens. The distribution pattern of alkylcarbazoles allows to distinguish between rocks of Jurassic, Permian and pre-Permian age, thereby exceeding the specificity of hydrocarbon biomarkers. While no pre-Permian signature can be found in the DST oils, it is present in sequentially extracted residual oils. However, the pre-Permian molecular source signal is diluted beyond recognition during conventional extraction procedures. The bitumens that are characterised by a pre-Permian geochemical signature derive from differing pore-filling oil pulses and exhibit calculated maturities of up to 1.6% Rc, thereby proving for the first time the petroleum generative capability of source rocks in the Warburton Basin.

Petroleum Prospectivity of the Tasman Frontier

2014 ◽  
Vol 54 (2) ◽  
pp. 520
Author(s):  
Francois Bache ◽  
Vaughan Stagpoole ◽  
Rupert Sutherland ◽  
Julien Collot ◽  
Pierrick Rouillard ◽  
...  
Keyword(s):  
Source Rock ◽  
New Caledonia ◽  
Source Rocks ◽  
Rock Composition ◽  
Seismic Reflection Data ◽  
Bottom Simulating Reflector ◽  
Reflection Data ◽  
Stratigraphic Framework ◽  
Well Data ◽  
The One

The Fairway Basin lies between Australia and New Caledonia in the northern Tasman Frontier area with water depths ranging from less than 1,000–2,400 m. This basin was formed in the mid-to-late Cretaceous during the eastern Gondwana breakup and since then has received detrital and pelagic sediments. It is known for its 70,000 km2 bottom simulating reflector, interpreted as one of the world’s largest gas hydrate layers or as a regional diagenetic front. The seismic reflection data shows sedimentary thicknesses (up to 4 km) and geometries capable of trapping hydrocarbons. The authors interpreted the seismic stratigraphy and available well data in terms of paleogeography and tectonic evolution. This work allowed the discovery of a deeply buried delta, probably of the same type as the deep-water Taranaki Delta. This stratigraphic framework is used to constrain multi-1D generation modelling and to test three main hypotheses of source rocks. The most likely scenario, similar to the one accepted for the Taranaki petroleum province, are a type-III and type-II source rocks intercalated in a Cretaceous prograding series. Another possible scenario is a source rock equivalent to the east Australian Walloon Formation and the occurrence of the marine source rock in the pre-rift sequence. Although, the large modelled volumes at this stage are speculative due to limited data on source rock composition, richness and distribution, as well as on the presence and quality of reservoir and seal, this study confirms the prospectivity of the Fairway Basin and the need for more data to further assess this basin.

scholarly journals Source Rock Characterization of Silurian Tanezzuft and Devonian Awaynat Wanin Formations the Northern Edge of the Murzuq Basin, South West Libya

2020 ◽  
Vol 4 (1) ◽  
pp. 1-13
Author(s):  
Aboglila S
Keyword(s):  
Organic Matter ◽  
Source Rock ◽  
Depositional Environments ◽  
Source Rocks ◽  
Thermal Maturity ◽  
Maturity Level ◽  
Geochemical Parameters ◽  
Northern Edge ◽  
Rock Characterization ◽  
Tanezzuft Formation

Drill cutting samples (n = 92) from the Devonian Awaynat Wanin Formation and Silurian Tanezzuft Formation, sampled from three wells F1, G1 and H1, locate in the northern edge of the Murzuq basin (approximately 700 kilometers south of Tripoli). The studied samples were analyzed in the objective of their organic geochemical assessment such as the type of organic matter, depositional conditions and thermal maturity level. A bulk geochemical parameters and precise biomarkers were estimated, using chromatography-mass spectrometry (GC-MS) to reveal a diversity of their geochemical characterizations. The rock formations are having varied organic matter contents, ranged from fair to excellent. The total organic carbon (TOC) reached about 9.1 wt%, ranging from 0.6 to 2.93 wt% (Awaynat Wanin), 0.5 to 2.54 wt% (Tanezzuft) and 0.52 to 9.1 wt% (Hot Shale). The cutting samples are ranged oil-prone organic matter (OM) of hydrogen index (HI) ranged between 98 –396 mg HC/g TOC, related kerogen types are type II and II/III, with oxygen index (OI): 6 - 190 with one sample have value of 366 mg CO2/g. Thermal maturity of these source rocks is different, ranging from immature to mature and oil window in the most of Tanezzuft Formation and Hot Shale samples, as reflected from the production index data (PI: 0.08 - 034). Tmax and vitrinite reflectance Ro% data (Tmax: 435 – 454 & Ro%: 0.46 - 1.38) for the Awaynat Wanin. Biomarker ratios of specific hydrocarbons extracted from represented samples (n = 9), were moreover used to study thermal maturity level and depositional environments. Pristine/Phytane (Pr/Ph) ratios of 1.65 - 2.23 indicated anoxic to suboxic conditions of depositional marine shale and lacustrine source rock.

scholarly journals Source rock potential of the Late Miocene Metochia formation of Gavdos Island, Greece

2017 ◽  
Vol 47 (2) ◽  
pp. 871
Author(s):  
I. Pyliotis ◽  
A. Zelilidis ◽  
N. Pasadakis ◽  
G. Panagopoulos ◽  
E. Manoutsoglou
Keyword(s):  
Organic Matter ◽  
Source Rock ◽  
Late Miocene ◽  
Source Rocks ◽  
Hydrocarbon Generation ◽  
Low Oxygen ◽  
Crete Island ◽  
Good Potential ◽  
The Rich ◽  
Rock Eval

Rock-Eval method was used to analyze 53 samples from late Miocene Metochia Formation of Gavdos Island (south of Crete Island) in order to characterize the contained organic matter and to evaluate its potential as source rock. The samples were collected from Metochia Section which consists of about 100 m thick marlssapropels alternations. Organic matter analysis showed that the studied succession could be subdivided into two parts. The lower one, which is generally rich in organic matter and the upper one, which is poor. In the lower part the rich horizons in organic matter are characterized by Kerogen type II, III and IV, with low oxygen content, and with fair to very good potential for gas and/or oil hydrocarbon generation. Additionally, the studied samples are thermally immature. Taking into account that the studied area has never been buried in such a depth to reach conditions of maturation, as well as, that the studied section in Gavdos is connected with Messara basin located in the northeastern and, finally, that the main part of Gavdos basin, which is situated between Gavdos and Crete islands, has continuously encountered subsidence, we could conclude that sediments of Metochia Formation could act as source rocks but in the more deep central part of the Gavdos basin.

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