A New Benzotriazole Phosphite Ammonium Salt Derivative (PN) Extreme Pressure Additive to Improve Gear Oil Tribological Properties

2021 ◽  
Author(s):  
Fengqi Fan ◽  
Qi Liu ◽  
Kang Zhou ◽  
Liping Wang ◽  
Binbin Wei ◽  
...  
Keyword(s):  
High Temperature ◽  
Ammonium Salt ◽  
Adhesive Wear ◽  
Friction Reduction ◽  
Extreme Pressure ◽  
Ball Surface ◽  
Gear Oil ◽  
Failure Temperature ◽  
Ball Test ◽  
Better Than

Abstract In this paper, a new benzotriazole phosphite ammonium salt derivative extreme pressure additive called PN was synthesized. Four-ball experiments and SRV experiments were used to test the high temperature and extreme pressure performance of PN additive, and comparisons were made with the commonly used additives including ZDDP and T304. The results show that the COF and wear amount of the PN additive in the four-ball experiment were much smaller than that of the ZDDP and T304 additives. The COF of the PN additive in the RSV experiment changed slightly with temperature, and it had better high temperature extreme pressure performance in friction reduction than the traditional ZDDP and T304 additives. When the temperature was 120oC, the COF of PN was about 30% lower than that of traditional additives. Thermogravimetric analysis showed that the failure temperature of PN additives was within 180-200oC, and the thermal stability was better than that of ZDDP and T304. After the four-ball test, SEM was used to observe the morphology of wear spots on the ball surface. It was found that the wear spots containing PN additive had slight adhesive wear, while those containing ZDDP and T304 showed serious adhesion and ploughing wear, and the surface appeared peeling and tearing. XPS was used to detect the chemical composition of friction surface containing PN additive, and thus the formation process of film on frictional surface was analyzed.

URANUS 52N

Alloy Digest ◽  
1994 ◽  
Vol 43 (5) ◽  
Keyword(s):  
Stainless Steel ◽  
Corrosion Resistance ◽  
High Temperature ◽  
Flue Gas ◽  
Crevice Corrosion ◽  
Heat Treating ◽  
Flue Gas Desulfurization ◽  
Temperature Performance ◽  
Aisi Type ◽  
Better Than

Abstract URANUS 52N is a nitrogen-alloyed duplex stainless steel improved in stress-corrosion cracking resistance and with pitting and crevice corrosion resistance better than AISI Type 317L. Applications include handling phosphoric acid contaminated with chlorides and in flue gas desulfurization scrubbers. This datasheet provides information on composition, physical properties, and tensile properties. It also includes information on high temperature performance and corrosion resistance as well as forming, heat treating, and joining. Filing Code: SS-566. Producer or source: Creusot-Marrel.

scholarly journals Effect of Size of Multiwalled Carbon Nanotubes Dispersed in Gear Oils for Improvement of Tribological Properties

2018 ◽  
Vol 2018 ◽  
pp. 1-13 ◽  
Author(s):  
Kodanda Rama Rao Chebattina ◽  
V. Srinivas ◽  
N. Mohan Rao
Keyword(s):  
Carbon Nanotubes ◽  
Raman Spectroscopy ◽  
Ball Milling ◽  
Multiwalled Carbon Nanotubes ◽  
Tribological Properties ◽  
Extreme Pressure ◽  
Multiwalled Carbon ◽  
Pristine Mwcnts ◽  
Gear Oil ◽  
The Stability

The aim of the paper is to investigate the effect of size of multiwalled carbon nanotubes (MWCNTs) as additives for dispersion in gear oil to improve the tribological properties. Since long pristine MWCNTs tend to form clusters compromising dispersion stability, they are mildly processed in a ball mill to shorten the length and stabilized with a surfactant before dispersing in lubricant. Investigations are made to assess the effect of ball milling on the size and structure of MWCNTs using electron microscopy and Raman spectroscopy. The long and shortened MWCNTs are dispersed in EP 140 gear oil in 0.5% weight. The stability of the dispersed multiwalled carbon nanotubes is evaluated using light scattering techniques. The antiwear, antifriction, and extreme pressure properties of test oils are evaluated on a four-ball wear tester. It is found that ball milling of MWCNTs has a strong effect on the stability and tribological properties of the lubricant. From Raman spectroscopy, it is found that ball milling time of up to 10 hours did not produce any defects on the surface of MWCNTs. The stability of the lubricant and the antiwear, antifriction, and extreme pressure properties have improved significantly with dispersion shortened MWCNTs. Ball milling for longer periods produces defects on the surface of MWCNTs reducing their advantage as oil additives.

scholarly journals Fe2O3 enhanced high-temperature arsenic resistance of CeO2–La2O3/TiO2 catalyst for selective catalytic reduction of NOx with NH3

RSC Advances ◽  
2021 ◽  
Vol 11 (16) ◽  
pp. 9395-9402
Author(s):  
Na Wang ◽  
Changfei Ye ◽  
Huidong Xie ◽  
Chang Yang ◽  
Jinhong Zhou ◽  
...  
Keyword(s):  
High Temperature ◽  
Selective Catalytic Reduction ◽  
Catalytic Reduction ◽  
Arsenic Resistance ◽  
No Conversion ◽  
Tio2 Catalyst ◽  
Reduction Of Nox ◽  
Better Than

The NO conversion of the CeLa0.5Fe0.2/Ti is obviously better than that of the commercial vanadium-based catalyst with regard to arsenic resistance and it has good N2 selectivity, and good SO2 resistance.

A Novel Gemini Cationic Viscoelastic Surfactant-Based Fluid for High Temperature Well Stimulation Applications

2021 ◽  
Author(s):  
Dawn Friesen ◽  
Brian Seymour ◽  
Aaron Sanders
Keyword(s):  
Thermal Stability ◽  
High Temperature ◽  
Chain Length ◽  
Surfactant Concentration ◽  
Gemini Surfactant ◽  
Alkyl Chain ◽  
Friction Reduction ◽  
Fluid Viscosity ◽  
Viscoelastic Surfactant ◽  
The Impact

Abstract Viscoelastic surfactant (VES)-based fracturing fluids can reduce the risk of formation damage when compared with conventional polymer-based fracturing systems. However, many VES systems lose viscoelasticity rapidly under high-temperature conditions, leading to high fluid leakoff and problems in proppant placement. A gemini cationic VES-based system offering thermal stability above 250°F and its efficiency in friction reduction is presented in this paper. Rheology measurements were conducted on viscoelastic cationic gemini surfactant fluids as a function of temperature (70 – 300°F) and surfactant concentration. The length of surfactant alkyl chain was varied to investigate the impact of surfactant chain length on VES fluid viscosity at elevated temperatures. The effect of flow rate on friction reduction capability of the surfactant fluid was measured on a friction flow loop. Foam rheology measurements were conducted to evaluate the VES fluid's ability to maintain high temperature viscosity with reduced surfactant concentration. A gemini cationic surfactant was used to prepare a viscoelastic surfactant system that could maintain viscosity over 50 cP at a shear rate of 100 s−1up to at least 250°F. With this system, viscoelastic gel viscosity was maintained without degradation for over 18 hours at 250°F, and the fluid showed rapid shear recovery throughout. Decreasing the average alkyl chain length on the surfactant reduced the maximum working temperature of the resulting viscoelastic gel and showed the critical influence of surfactant structure on the resulting fluid performance. The presence of elongated, worm-like micelles in the fluid provided polymer-like friction reduction even at low surfactant concentrations, with friction reduction of over 70% observed during pumping (relative to fresh water) up to a critical Reynolds number. Energized fluids could also be formulated with the gemini surfactant to give foam fluids suitable for hydraulic fracturing or wellbore cleanouts. The resulting viscoelastic surfactant foams had viscosities over 50 cP up to at least 300°F with both nitrogen and carbon dioxide as the gas phase. The information presented in this paper is important for various field applications where thermal stability of the treatment fluid is essential. This will hopefully expand the use of VES-based systems as an alternative to conventional polymer systems in oilfield applications where a less damaging viscosified fluid system is required.

Analysis of Traction Characteristics of Grease-Lubricated Sliding Bearing

2013 ◽  
Vol 655-657 ◽  
pp. 640-643
Author(s):  
Bo Yuan Yang ◽  
Xiaofan Yan ◽  
Bing Su
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Room Temperature ◽  
Extreme Pressure ◽  
Test Rig ◽  
Sliding Bearing ◽  
Traction Coefficient ◽  
Lubrication Effect ◽  
Lubricated Sliding

Adopting the test rig of traction characteristics of grease-lubricated sliding bearing, the practical condition of sliding bearing was simulated and the traction coefficient of DGG Grease under different temperature, velocity and load was tested. Besides, the traction characteristics of the grease were also elaborated. The results indicate that the traction coefficient increases when the temperature gradually rises from room temperature while it gradually decreases when the temperature exceeds 85°C. Under the condition of high temperature and high pressure, the extreme pressure additive has obvious effects, the traction coefficient reducing and maintaining constant, so a better lubrication effect is realized.

scholarly journals Tribochemistry and EP Activity Assessment of Mo-S Complexes in Lithium-Base Greases

2008 ◽  
Vol 2008 ◽  
pp. 1-6 ◽  
Author(s):  
Tarunendr Singh
Keyword(s):  
Electron Spectroscopy ◽  
Auger Electron ◽  
Wear Scar ◽  
Extreme Pressure ◽  
Flash Temperature ◽  
Wear Scar Diameter ◽  
Activity Assessment ◽  
Temperature Parameter ◽  
Ball Test ◽  
Base Grease

The blends of bis(1,5-diaryl-2,4-dithiomalonamido)dioxomolybdenum(VI) complexes in lithium-base grease are evaluated for their extreme pressure activity in a “four-ball test” using 12.7 mm diameter alloy steel ball specimen. The additive, bis(1,5-di-p-methoxyphenyl-2,4-dithiomalonamido)dioxomolybdenum(VI) and bis(1,5-di-p-chloro-phenyl-2,4-dithiomalonamido)dioxomolybdenum(VI) exhibited lower values of wear-scar diameter at higher load and higher values of weld load, flash temperature parameter, and pressure wear index as compared with lithium-base grease without additives. The greases fortified with the developed additives prevent rusting and corrosion of bearings while grease containing no additives did not pass these tests as per the standard tests. These greases have also better oxidation protection as compared to the grease that has no additive. The topography and tribochemistry of the wear-scar surface are carried out by means of scanning electron microscopy and Auger electron spectroscopy techniques, respectively.

scholarly journals Study on Tribological Properties and Mechanisms of Different Morphology WS2 as Lubricant Additives

Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1522 ◽  
Author(s):  
Ningning Hu ◽  
Xiuheng Zhang ◽  
Xianghui Wang ◽  
Na Wu ◽  
Songquan Wang
Keyword(s):  
Wear Resistance ◽  
Optimum Condition ◽  
Lubricating Oil ◽  
Stribeck Curve ◽  
Extreme Pressure ◽  
Friction Process ◽  
Wide Range ◽  
The Coefficient Of Friction ◽  
The Relationship ◽  
Better Than

In the present work, the relationship curve of the coefficient of friction (COF) with varying loads of different morphology WS2 lubricating additives in the friction process at various sliding speeds was studied. On this basis, wear marks and elements on the wear surfaces after friction were analyzed, and then the anti-wear and mechanism effects of WS2 of different forms in the lubrication process were discussed. Meanwhile, the Stribeck curve was used to study the lubrication state of the lubricating oil in the friction process. It was revealed that the COF of lubricating oil containing lamellar WS2 decreased by 29.35% at optimum condition and the minimum COF was concentrated at around 100 N. The COF of lubricating oil containing spherical WS2 decreased by 30.24% and the minimum coefficient was concentrated at 120 N. The extreme pressure property of spherical WS2 was better than that of lamellar WS2, and the wear resistance of spherical WS2 was more stable when the load was over 80 N. The different morphology of WS2 additives can play anti-wear and anti-friction roles within a wide range of sliding speeds.

scholarly journals Surface Josephson plasma waves in a high-temperature superconductor

2020 ◽  
Vol 5 (1) ◽  
Author(s):  
Qianbo Lu ◽  
Anthony T. Bollinger ◽  
Xi He ◽  
Robert Sundling ◽  
Ivan Bozovic ◽  
...  
Keyword(s):  
High Temperature ◽  
High Temperature Superconductor ◽  
Near Field ◽  
Low Loss ◽  
Surface And Interface ◽  
Field Coupling ◽  
Non Invasive ◽  
Crystal Film ◽  
Enhanced Superconductivity ◽  
Better Than

Abstract Electron density oscillations with acoustic dispersions and sustained at boundaries between different media provide information about surface and interface properties of heterostructures. In ultrathin metallic films these plasmonic excitations are heavily damped. Superconductivity is predicted to reduce dissipation allowing detection of these resonances. Emerging low-loss interface Cooper-pair waves have been studied before, however, the observation of surface-confined Josephson plasmons in highly anisotropic superconductors has remained elusive. Here, we report on generation and coupling to these excitations in an ultrathin single-crystal film of high-temperature superconductor La1.85Sr0.15CuO4. The film becomes brighter than Au below the critical temperature when probed with sub-gap THz photons. We show that the enhanced signal in the superconducting state, which can be visualized with a spatial resolution better than λ/3000, originates from near-field coupling of light to surface Josephson plasmons. Our results open a path towards non-invasive investigation of enhanced superconductivity in artificial multilayers, buried interface states in topological heterostructures, and non-linear phenomena in Josephson devices.

A Novel Ceramic Thermocouple Used in High-Temperature Measurement

2011 ◽  
Vol 197-198 ◽  
pp. 328-332
Author(s):  
Li Chao Feng ◽  
Ning Xie ◽  
Wen Zhu Shao ◽  
Yu Sheng Cui ◽  
Liang Zhen
Keyword(s):  
High Temperature ◽  
Powder Metallurgy ◽  
Temperature Measurement ◽  
Powder Metallurgy Method ◽  
Simple Relationship ◽  
Response Characteristics ◽  
Sic Ceramics ◽  
High Temperature Measurement ◽  
Holding Temperature ◽  
Better Than

MoSi2and SiC ceramics were prepared by traditional powder metallurgy method. A novel ceramic thermocouple (CTC) used in the high temperature and high corrosion environment was assembled by SiC as the cathode and MoSi2as the anode. The thermo-emf of CTC was tested from 25 °C to 1600 °C in air. The results show that there is a simple relationship between the thermo-emf of CTC and the temperature. By holding temperature for 70 h at 1500 °C, the deviation of thermo-emf is ±0.37%, and better than 0.75% which is the criteria of industry thermocouple. And also the response characteristics of CTC were analyzed.

Effect of CaO Addition on High Temperature Tensile Properties of Mg Casting Alloys

2009 ◽  
Vol 620-622 ◽  
pp. 291-294 ◽  
Author(s):  
Jung Ho Seo ◽  
Shae K. Kim
Keyword(s):  
Solid Solution ◽  
High Temperature ◽  
Tensile Properties ◽  
Alloy Element ◽  
Good Effect ◽  
Casting Alloys ◽  
Ca Addition ◽  
High Temperature Tensile ◽  
High Temperature Tensile Properties ◽  
Better Than

The microstructure, hardness and tensile properties of Mg-3Al, Mg-3Al-1.2Ca(AX31), Mg-3Al-1.2CaO(AO31), Mg-9Al, Mg-9Al-1.2Ca(AX91) and Mg-9Al-1.2CaO(AO91) alloys were investigated to identify the effect of CaO addition compared with Ca addition. The results show that the alloy element CaO has a good effect on high temperature tensile properties and CaO added alloys have superior high temperature performance compared with Ca added alloys. Addition of CaO results in the precipitation of Al2Ca phase (C15 phase) on the grain boundaries. This phase precipitated by the reduction of CaO leads to the refinement of a microstructure and improvement of tensile properties at elevated temperature similar to the Ca added Mg alloys. When added into molten Mg Ca makes solid solution in the Mg matrix up to 0.8wt %. But in case of CaO addition the thermally stable compound is precipitated directly without making solid solution with Mg matrix. Therefore, the high temperature tensile properties of CaO added Mg casting alloys are better than Ca added one at the same adding contents (1.2wt.%).

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