scholarly journals Hydrogeochemical and Isotopic Investigations on the Origins of Groundwater Salinization in Çarşamba Coastal Aquifer (North Turkey)

2021 ◽  
Author(s):  
Abdourazakou MAMAN HASSAN ◽  
Arzu Ersoy
Keyword(s):  
Transition Zone ◽  
Coastal Aquifer ◽  
Major Ions ◽  
Coastal Region ◽  
Environmental Isotopes ◽  
Classification Systems ◽  
Physical Parameters ◽  
Rock Interaction ◽  
Hydrogeochemical Process ◽  
Groundwater Samples

Abstract The aim of this study is to determine the origins of salinization and the main hydrogeochemical process that controls the chemistry of Çarşamba coastal aquifer in Turkey. Therefore, a total of 33 groundwater samples and three seawater samples were analyzed in the coastal region of Çarşamba Plain in July 2019 and for these samples’ physical parameters, major ions and environmental isotopes (δ18O, δ2H and 3H) values were determined. Piper, Chadha, Gibbs diagrams and Stuyfzand Classification Systems were used to determine the origins of salinization and the key hydrogeochemical process controlling the groundwater chemistry. According to Stuyfzand classification system, the study showed that the freshwater and fresh-brackish water main types are the most widespread in the study area. Six water subtypes were observed in the study area that include CaHCO3, CaMix, NaMix, NaCl, NaHCO3 and MgHCO3. In addition, the subtypes CaMix indicated the locations of the transition zone, where the groundwater rich in Ca and HCO3 and gradually enriched in Na changes from CaMix with HCO3 as dominant anion to eventually CaCl and NaCl subtypes. Furthermore, the subtypes NaMix, NaHCO3 and MgHCO3 showed the locations of the transition zone where the flushing of the saline aquifer by freshwater takes place. All groundwater samples from study area had a positive cation exchange code and show that four hydrogeochemical facies composed of CaHCO3; Ca-Mg-Cl and NaCl and NaHCO3. Besides, groundwater samples have been influenced by two main mechanisms: the water-rock interaction and evaporation-crystallization. According to δ18O, δ2H and 3H analysis, the water samples have meteoric origin, shallow circulation, and a short residence time.

scholarly journals Characterization of Recharge Mechanisms and Sources of Groundwater Salinization in Ras Jbel Coastal Aquifer (Northeast Tunisia) Using Hydrogeochemical Tools, Environmental Isotopes, GIS, and Statistics

2017 ◽  
Vol 2017 ◽  
pp. 1-20 ◽  
Author(s):  
Jamila Hammami Abidi ◽  
Boutheina Farhat ◽  
Abdallah Ben Mammou ◽  
Naceur Oueslati
Keyword(s):  
Coastal Aquifer ◽  
Isotope Composition ◽  
Exchange Process ◽  
Environmental Isotopes ◽  
Return Flow ◽  
Groundwater Salinization ◽  
Rock Interaction ◽  
Ion Exchange Process ◽  
Recharge Sources ◽  
Groundwater Samples

Groundwater is among the most available water resources in Tunisia; it is a vital natural resource in arid and semiarid regions. Located in north-eastern Tunisia, the Metline-Ras Jbel-Raf Raf aquifer is a mio-plio-quaternary shallow coastal aquifer, where groundwater is the most important source of water supply. The major ion hydrochemistry and environmental isotope composition (δ18O, δ2H) were investigated to identify the recharge sources and processes that affect the groundwater salinization. The combination of hydrogeochemical, isotopic, statistical, and GIS approaches demonstrates that the salinity and the groundwater composition are largely controlled by the water-rock interaction particularly the dissolution of evaporate minerals and the ion exchange process, the return flow of the irrigation water, agricultural fertilizers, and finally saltwater intrusion which started before 1980 and which is partially mitigated by the artificial recharge since 1993. As for the stable isotope signatures, results showed that groundwater samples lay on and around the local meteoric water line LMWL; hence, this arrangement signifies that the recharge of the Ras Jbel aquifer is ensured by recent recharge from Mediterranean air masses.

scholarly journals Temporal Hydrogeochemical Dynamics and Source Apportionment in Groundwater of a Complex Lithology.

2021 ◽  
Author(s):  
Ganesh N ◽  
Vasudevan U ◽  
Devaraj N ◽  
Mahalakshmi K ◽  
Banajarani Panda ◽  
...  
Keyword(s):  
Major Ions ◽  
Anthropogenic Activities ◽  
Integrated Approach ◽  
Physical Parameters ◽  
Groundwater Samples ◽  
Different Seasons ◽  
Geostatistical Techniques ◽  
Geochemical Investigation ◽  
Recommended Level ◽  
Future Management

Abstract The present research reports the level of major ions and other physical parameters like pH, EC and TDS and possible sources of contamination in groundwater from south India. A total of 138 groundwater samples were collected during four different seasons and analyzed for physical parameters and other major ions. Many samples are above or approaching the recommended level of ions for safe drinking water. The groundwater quality has been determined by considering 11 parameters and classified into 5 different categories based upon water quality index (WQI) value. The groundwater of the study area is approaching towards pollution which has to consider for future management of the resource. Different geochemical diagrams like Gibbs and Piper are used to evaluate the process affecting the composition of groundwater. Again, the geostatistical techniques applied to confirm the processes through an integrated approach. Based on result of geochemical investigation, the contamination sources in the groundwater of this region are likely to be from (a) Anthropogenic activities (b) Weathering (c) Agricultural fertilizers. Continuous consumption of such water may pose serious health risk to the residents.

STUDY OF EVOLUTION OF THE SEAWATER INTRUSION IN COASTAL AQUIFERS. CASE STUDY: THE COASTAL AQUIFER SYSTEM OF NW ACHAIA

2004 ◽  
Vol 36 (4) ◽  
pp. 1952 ◽  
Author(s):  
K. Βουδούρης ◽  
K. Νίκας ◽  
A. Αντωνάκος
Keyword(s):  
Seawater Intrusion ◽  
Coastal Aquifers ◽  
Coastal Aquifer ◽  
Chemical Analyses ◽  
Salinity Distribution ◽  
Aquifer System ◽  
Hydrogeochemical Process ◽  
Groundwater Samples ◽  
Hydrochemical Types

Seawater intrusion problems are recorded in coastal aquifers, which constitute the main sources of drinking water and agricultural irrigation in many countries. The aim of this work is to describe the evolution of the salinity distribution by seawater intrusion, based on results from chemical analyses, of 29 groundwater samples in the NWAchaia area (Peloponnesus, Greece). The study of these data indicates that aquifer waters in large part of area reflect salinization related to seawater intrusion. The occurrence of Ca-CI hydrochemical types of groundwater indicates active seawater intrusion. Cation exchange is the most noticeable hydrogeochemical process in the movement of the saline front in the coastal aquifer. Geographical distribution of Careact index was mapped. The areas with advance or decline of the seawater intrusion front are defined from this map.

Hydro-Geochemistry of Deep Aquifers in Coal Mines in Northern Anhui Province, China: Implications for Water Rock Interaction and Water Source Discrimination

2012 ◽  
Vol 524-527 ◽  
pp. 604-607
Author(s):  
Lin Hua Sun ◽  
He Rong Gui ◽  
Man Li Lin
Keyword(s):  
Discriminant Analysis ◽  
Major Ions ◽  
Coal Mines ◽  
Water Source ◽  
Anhui Province ◽  
Rock Interaction ◽  
Source Discrimination ◽  
Deep Aquifers ◽  
Chemical Signatures ◽  
Groundwater Samples

Thirty-eight groundwater samples from three deep seated aquifers (the Quaternary, the Coal bearing and the Taiyuan Fm aquifers) had been collected from three coal mines in northern Anhui Province, China for analyzing their major ions, and the statistical methods (correlation, cluster and discriminant analysis) had been processed for evaluating the source of ions and relationship between aquifers. The results suggest that: (1) the chemical signatures of the groundwater are mainly controlled by dissolution of plagioclase, K-feldspar and calcite; (2) the aquifers had been mixed with each other, especially the mixing between the Quaternary aquifer and the Taiyuan Fm aquifer. Discriminant analysis has produced two functions and a diagram, which can be used for water source discrimination.

Multivariate statistical analysis of the hydro-geochemical characteristics for Mining groundwater: a case study from Baishan mining, northern Anhui Province, China

2013 ◽  
Vol 8 (1) ◽  
pp. 131-141 ◽  
Author(s):  
Song Chen ◽  
Xue Hai Fu ◽  
He Rong Gui ◽  
Lin Hua Sun
Keyword(s):  
Major Ions ◽  
High Ratio ◽  
Anhui Province ◽  
High Concentration ◽  
Fisher Discriminant Analysis ◽  
Multivariate Statistical ◽  
Rock Interaction ◽  
Fisher Discriminant ◽  
Groundwater Samples ◽  
Multivariate Statistical Approach

Major ions were analyzed for twenty five groundwater samples collected from diverse aquifer in Baishan mining, northern Anhui province, China. Conventional graphical and multivariate statistical approach were completed to identify the hydro-geochemical process and water-rock interaction, that be combined with the Cluster Analysis (CA) and Fisher discriminant analysis to recognize the sealed samples, the result showed: the diverse samples have vary ions inheriting from aquifer, samples collected from Sandstone aquifer (SA) is characterized by the high concentration of Na+ + K+, for the feldspar weathering is dominant; Ordovician limestone aquifer (OA) waters have abundance Ca2+ and Mg2+, for the dissolution of calcite and dolomite obviously; the dissolution of calcite and other calcareous concretions are dominant in Taiyuan formation water (TA) and Quaternary aquifer (QA) for the high ratio of Ca2+/Mg2+, otherwise the varied content of SO42– and HCO3− could distinguish the two aquifer water. Twenty five groundwater samples, containing six sealed samples, had been subdivided in to four groups by the CA, what are corresponded with four aquifers. Fisher discriminant functions were obtained and the efficiency was acceptable for the error rate 4% in all twenty five samples.

scholarly journals Potential interplay of Uranium with geochemical variables and mineral saturation states in groundwater

2021 ◽  
Vol 11 (4) ◽  
Author(s):  
Thivya Chandrasekar ◽  
Chidambaram Sabarathinam ◽  
Prasanna Mohan Viswanathan ◽  
Thilagavathi Rajendiran ◽  
Mahalakshmi Mathivanan ◽  
...  
Keyword(s):  
Major Ions ◽  
Saturation Index ◽  
Flood Plain ◽  
Temporal Variations ◽  
Southwest Monsoon ◽  
Physical Parameters ◽  
Northeast Monsoon ◽  
Saturation State ◽  
Rock Interaction ◽  
Different Seasons

AbstractUranium (U) is formed by the interaction of groundwater in aquifer and the surrounding rocks. The area chosen for this study is a hard rock terrain of various lithology in South India, which releases U in groundwater and affect the groundwater quality. Hence, this study was conducted to understand the geochemistry and temporal variations of U in groundwater with respect to saturation state of minerals for different seasons namely Pre-monsoon (PRM), Northeast monsoon (NEM), Southwest monsoon (SWM) and Post-monsoon (POM). A total of 216 groundwater samples were collected, representing various lithology (Fissile hornblende biotite gneiss, Charnockite, Quartzite, Granite and Flood Plain Alluvium) in the study area. The collected samples were analyzed for physical parameters such as Electrical conductivity, Total dissolved solids, pH and major ions. U was measured using Laser Fluorimeter. The study infers that weathering in SWM, ion exchange in PRM and POM and anthropogenic process in NEM were the three major processes that could dominate the hydrogeochemistry of U. The higher concentration of U has been highlighted, and the water–rock interaction has been studied to know the sources of origin and it has been plotted through bivariate and ternary diagrams. The saturation index study was made and calculated for uranium, carbonate, sulfate, silicate and phosphate minerals using PHREEQC Programme. Uraninite and Coffinite are the dominant saturated states of U minerals which tend to attain near saturation to saturation state irrespective of seasons. With the increase in U concentration irrespective of seasons, it was noticed that the saturation state of minerals is also increasing. Overall, the weathering process and the lithological impact are the sources for higher concentration of U and their minerals occurring in the study area. The outcome of the study will help the policy makers for sustainable management to safeguard the groundwater resource in this region.

scholarly journals Water Quality and Hydrogeochemical Characteristics of Some Karst Water Sources in Apuseni Mountains, Romania

Water ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 857
Author(s):  
Maria-Alexandra Hoaghia ◽  
Ana Moldovan ◽  
Eniko Kovacs ◽  
Ionut Cornel Mirea ◽  
Marius Kenesz ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Chemistry ◽  
Major Ions ◽  
Anthropogenic Activities ◽  
Water Sources ◽  
Main Process ◽  
Karst Water ◽  
Rock Interaction ◽  
Apuseni Mountains ◽  
Karst Waters

Human activities and natural factors determine the hydrogeochemical characteristics of karst groundwaters and their use as drinking water. This study assesses the hydrogeochemical characteristics of 14 karst water sources in the Apuseni Mountains (NW Romania) and their potential use as drinking water sources. As shown by the Durov and by the Piper diagrams, the chemical composition of the waters is typical of karst waters as it is dominated by HCO3− and Ca2+, having a circumneutral to alkaline pH and total dissolved solids ranging between 131 and 1092 mg L−1. The relation between the major ions revealed that dissolution is the main process contributing to the water chemistry. Limestone and dolostone are the main Ca and Mg sources, while halite is the main Na and Cl source. The Gibbs diagram confirmed the rock dominance of the water chemistry. The groundwater quality index (GWQI) showed that the waters are of excellent quality, except for two waters that displayed medium and good quality status. The quality of the studied karst waters is influenced by the geological characteristics, mainly by the water–rock interaction and, to a more limited extent, by anthropogenic activities. The investigated karst waters could be exploited as drinking water resources in the study area. The results of the present study highlight the importance of karst waters in the context of good-quality water shortage but also the vulnerability of this resource to anthropogenic influences.

scholarly journals High-Arsenic Groundwater in Paleochannels of the Lower Yellow River, China: Distribution and Genesis Mechanisms

Water ◽  
2021 ◽  
Vol 13 (3) ◽  
pp. 338
Author(s):  
Chuanshun Zhi ◽  
Wengeng Cao ◽  
Zhen Wang ◽  
Zeyan Li
Keyword(s):  
Yellow River ◽  
The Yellow River ◽  
Rock Interaction ◽  
Lower Yellow River ◽  
The Lower Yellow River ◽  
Groundwater Samples ◽  
Groundwater Systems ◽  
Different Sources ◽  
High Arsenic ◽  
High Arsenic Groundwater

High–arsenic (As) groundwater poses a serious threat to human health. The upper and middle reaches of the Yellow River are well–known areas for the enrichment of high–arsenic groundwater. However, little is known about the distribution characteristics and formation mechanism of high-As groundwater in the lower reach of the Yellow River. There were 203 groundwater samples collected in different groundwater systems of the lower Yellow River for the exploration of its hydrogeochemical characteristics. Results showed that more than 20% of the samples have arsenic concentrations exceeding 10 μg/L. The high-As groundwater was mainly distributed in Late Pleistocene–Holocene aquifers, and the As concentrations in the paleochannels systems (C2 and C4) were significantly higher than that of the paleointerfluve system (C3) and modern Yellow River affected system (C5). The high-As groundwater is characterized by high Fe2+ and NH4+ and low Eh and NO3−, indicating that reductive dissolution of the As–bearing iron oxides is probably the main cause of As release. The arsenic concentrations strikingly showed an increasing tendency as the HCO3− proportion increases, suggesting that HCO3− competitive adsorption may facilitate As mobilization, too. In addition, a Gibbs diagram showed that the evaporation of groundwater could be another significant hydrogeochemical processes, except for the water–rock interaction in the study area. Different sources of aquifer medium and sedimentary structure may be the main reasons for the significant zonation of the As spatial distribution in the lower Yellow River.

scholarly journals Geochemical and isotopic evidence of groundwater salinization processes in the Essaouira region, north-west coast, Morocco

2021 ◽  
Vol 3 (7) ◽  
Author(s):  
Otman EL Mountassir ◽  
Mohammed Bahir ◽  
Driss Ouazar ◽  
Abdelghani Chehbouni ◽  
Paula M. Carreira
Keyword(s):  
Groundwater Recharge ◽  
West Coast ◽  
Exchange Process ◽  
Environmental Isotopes ◽  
Annual Rainfall ◽  
Groundwater Salinization ◽  
Rock Interaction ◽  
North West ◽  
The North ◽  
Water Rock Interaction

AbstractThe city of Essaouira is located along the north-west coast of Morocco, where groundwater is the main source of drinking, domestic and agricultural water. In recent decades, the salinity of groundwater has increased, which is why geochemical techniques and environmental isotopes have been used to determine the main sources of groundwater recharge and salinization. The hydrochemical study shows that for the years 1995, 2007, 2016 and 2019, the chemical composition of groundwater in the study area consists of HCO3–Ca–Mg, Cl–Ca–Mg, SO4–Ca and Cl–Na chemical facies. The results show that from 1995 to 2019, electrical conductivity increased and that could be explained by a decrease in annual rainfall in relation to climate change and water–rock interaction processes. Geochemical and environmental isotope data show that the main geochemical mechanisms controlling the hydrochemical evolution of groundwater in the Cenomanian–Turonian aquifer are the water–rock interaction and the cation exchange process. The diagram of δ2H = 8 * δ18O + 10 shows that the isotopic contents are close or above to the Global Meteoric Water Line, which suggests that the aquifer is recharged by precipitation of Atlantic origin. In conclusion, groundwater withdrawal should be well controlled to prevent groundwater salinization and further intrusion of seawater due to the lack of annual groundwater recharge in the Essaouira region.

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