scholarly journals Potential interplay of Uranium with geochemical variables and mineral saturation states in groundwater

2021 ◽  
Vol 11 (4) ◽  
Author(s):  
Thivya Chandrasekar ◽  
Chidambaram Sabarathinam ◽  
Prasanna Mohan Viswanathan ◽  
Thilagavathi Rajendiran ◽  
Mahalakshmi Mathivanan ◽  
...  

AbstractUranium (U) is formed by the interaction of groundwater in aquifer and the surrounding rocks. The area chosen for this study is a hard rock terrain of various lithology in South India, which releases U in groundwater and affect the groundwater quality. Hence, this study was conducted to understand the geochemistry and temporal variations of U in groundwater with respect to saturation state of minerals for different seasons namely Pre-monsoon (PRM), Northeast monsoon (NEM), Southwest monsoon (SWM) and Post-monsoon (POM). A total of 216 groundwater samples were collected, representing various lithology (Fissile hornblende biotite gneiss, Charnockite, Quartzite, Granite and Flood Plain Alluvium) in the study area. The collected samples were analyzed for physical parameters such as Electrical conductivity, Total dissolved solids, pH and major ions. U was measured using Laser Fluorimeter. The study infers that weathering in SWM, ion exchange in PRM and POM and anthropogenic process in NEM were the three major processes that could dominate the hydrogeochemistry of U. The higher concentration of U has been highlighted, and the water–rock interaction has been studied to know the sources of origin and it has been plotted through bivariate and ternary diagrams. The saturation index study was made and calculated for uranium, carbonate, sulfate, silicate and phosphate minerals using PHREEQC Programme. Uraninite and Coffinite are the dominant saturated states of U minerals which tend to attain near saturation to saturation state irrespective of seasons. With the increase in U concentration irrespective of seasons, it was noticed that the saturation state of minerals is also increasing. Overall, the weathering process and the lithological impact are the sources for higher concentration of U and their minerals occurring in the study area. The outcome of the study will help the policy makers for sustainable management to safeguard the groundwater resource in this region.

2021 ◽  
Vol 7 ◽  
Author(s):  
Josephine Dianne L. Deauna ◽  
Kevin Matthew B. Yatco ◽  
Cesar L. Villanoy ◽  
Marie Antonette Juinio-Meñez

Stocks of commercially valuable sea cucumber species have declined in most tropical countries, which supply majority of the global demand. This work aimed to locate priority sites for the management of Holothuria scabra and Stichopus horrens in the western central Philippines. A passive larval dispersal model was run under four monsoonal regimes (Northeast monsoon, dry-transition, Southwest monsoon, and early Northeast monsoon), and the results subjected to the Infomap network detection algorithm. Three clusters of closely related geographical nodes were identified [southeastern Palawan (Group I), western Panay and eastern Mindoro (Group II), and northern and western Palawan with western Mindoro (Group III)]. Remotely sensed habitat data were used to parameterize the degree of connectivity observed among sites (H. scabra spawning and settlement requires the presence of seagrass and mangrove, while S. horrens requires corals and seagrass). Local retention, self-recruitment, settlement success and sink diversity were then calculated for each node with suitable habitat. The locations were ranked according to each metric and those with higher larval export rates, a higher diversity of larval sources and a high degree of successful larval contribution to other sites were deemed crucial for the management of wild populations. Sixteen high-priority sites were identified, distributed mainly along northern Palawan and western Panay. Six sites were common for both species at different seasons, and no single location fulfilled all stated criteria across the four seasons and both sea cucumber species considered. The priority sites for management could serve as broodstock selection and juvenile restocking areas for aquaculture production clusters, which when properly implemented, could lead to an increase in sea cucumber production and contribute to natural populations. On a broader scale, the designation of closely related clusters and incorporation of habitat requirements to dispersal data provided critical input for the delineation of ecologically meaningful management units for sea cucumbers within the region.


2021 ◽  
Author(s):  
Abdourazakou MAMAN HASSAN ◽  
Arzu Ersoy

Abstract The aim of this study is to determine the origins of salinization and the main hydrogeochemical process that controls the chemistry of Çarşamba coastal aquifer in Turkey. Therefore, a total of 33 groundwater samples and three seawater samples were analyzed in the coastal region of Çarşamba Plain in July 2019 and for these samples’ physical parameters, major ions and environmental isotopes (δ18O, δ2H and 3H) values were determined. Piper, Chadha, Gibbs diagrams and Stuyfzand Classification Systems were used to determine the origins of salinization and the key hydrogeochemical process controlling the groundwater chemistry. According to Stuyfzand classification system, the study showed that the freshwater and fresh-brackish water main types are the most widespread in the study area. Six water subtypes were observed in the study area that include CaHCO3, CaMix, NaMix, NaCl, NaHCO3 and MgHCO3. In addition, the subtypes CaMix indicated the locations of the transition zone, where the groundwater rich in Ca and HCO3 and gradually enriched in Na changes from CaMix with HCO3 as dominant anion to eventually CaCl and NaCl subtypes. Furthermore, the subtypes NaMix, NaHCO3 and MgHCO3 showed the locations of the transition zone where the flushing of the saline aquifer by freshwater takes place. All groundwater samples from study area had a positive cation exchange code and show that four hydrogeochemical facies composed of CaHCO3; Ca-Mg-Cl and NaCl and NaHCO3. Besides, groundwater samples have been influenced by two main mechanisms: the water-rock interaction and evaporation-crystallization. According to δ18O, δ2H and 3H analysis, the water samples have meteoric origin, shallow circulation, and a short residence time.


2021 ◽  
Author(s):  
Ganesh N ◽  
Vasudevan U ◽  
Devaraj N ◽  
Mahalakshmi K ◽  
Banajarani Panda ◽  
...  

Abstract The present research reports the level of major ions and other physical parameters like pH, EC and TDS and possible sources of contamination in groundwater from south India. A total of 138 groundwater samples were collected during four different seasons and analyzed for physical parameters and other major ions. Many samples are above or approaching the recommended level of ions for safe drinking water. The groundwater quality has been determined by considering 11 parameters and classified into 5 different categories based upon water quality index (WQI) value. The groundwater of the study area is approaching towards pollution which has to consider for future management of the resource. Different geochemical diagrams like Gibbs and Piper are used to evaluate the process affecting the composition of groundwater. Again, the geostatistical techniques applied to confirm the processes through an integrated approach. Based on result of geochemical investigation, the contamination sources in the groundwater of this region are likely to be from (a) Anthropogenic activities (b) Weathering (c) Agricultural fertilizers. Continuous consumption of such water may pose serious health risk to the residents.


Water ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 857
Author(s):  
Maria-Alexandra Hoaghia ◽  
Ana Moldovan ◽  
Eniko Kovacs ◽  
Ionut Cornel Mirea ◽  
Marius Kenesz ◽  
...  

Human activities and natural factors determine the hydrogeochemical characteristics of karst groundwaters and their use as drinking water. This study assesses the hydrogeochemical characteristics of 14 karst water sources in the Apuseni Mountains (NW Romania) and their potential use as drinking water sources. As shown by the Durov and by the Piper diagrams, the chemical composition of the waters is typical of karst waters as it is dominated by HCO3− and Ca2+, having a circumneutral to alkaline pH and total dissolved solids ranging between 131 and 1092 mg L−1. The relation between the major ions revealed that dissolution is the main process contributing to the water chemistry. Limestone and dolostone are the main Ca and Mg sources, while halite is the main Na and Cl source. The Gibbs diagram confirmed the rock dominance of the water chemistry. The groundwater quality index (GWQI) showed that the waters are of excellent quality, except for two waters that displayed medium and good quality status. The quality of the studied karst waters is influenced by the geological characteristics, mainly by the water–rock interaction and, to a more limited extent, by anthropogenic activities. The investigated karst waters could be exploited as drinking water resources in the study area. The results of the present study highlight the importance of karst waters in the context of good-quality water shortage but also the vulnerability of this resource to anthropogenic influences.


2021 ◽  
Vol 13 (15) ◽  
pp. 8303
Author(s):  
Vu Tuan Anh ◽  
Pham Ba Trung ◽  
Kim-Anh Nguyen ◽  
Yuei-An Liou ◽  
Minh-Thu Phan

This paper aims to identify the causes and sources of erosion and deposition at small estuaries in southern central Vietnam under human intervention. The jetty built at the Tam Quan river mouth (Binh Dinh Province, Vietnam) serves as the base for the study. After its completion at the end of 2009, the hydrodynamic and erosion-deposition processes in the region have been significantly altered. Inside the estuary, the waves are not influenced, but the currents are increased during the ebb tide period and decreased during the flood tide timeframe. During the southwest monsoon, the jetty could cause an increase in the deposition process in both frequency and area, whereas the erosion process tends to narrow the area and increase the frequency on the north coast. In contrast, both deposition and erosion processes are increased on the southern coast. About 5859 m3 of sediments are deposited in the channel gate mainly by local sources. During the northeast monsoon, both deposition and erosion processes are located over a narrow area with frequency increased on the north coast, whereas the deposition process is narrowed with higher frequency on the southern coast. The total amount of sediment deposited at the estuary is 56,446 m3, of which 74.2% is from the onsite erosion material, 15.8% from the river and 10% from the longshore transportation. Generally, due to mainly erosion-deposition processes, sediment volume is accumulated during the northeast monsoon with amount 9.6 times more than that the southwest monsoon. The erosion-deposition processes are contributed to by poor practical management and local human activities inland and in the coastal regions, as well as the natural situation, resulting in serious impacts on society, the economy and the environment. Hence, the governance of the erosion-deposition processes and sediment load in small estuaries appear to contribute to the master plan for the local sustainable development of society and the economy.


2021 ◽  
Author(s):  
Sobia Shahzad ◽  
Mumtaz Hussain ◽  
Hassan Munir ◽  
Muhammad Arfan

Abstract Exploring extractable phytochemicals from locally adapted sisal plant vegetation vary seasonally at different locations. This study elaborated proximate composition and phytochemical heterogeneity in sisal due to varying environmental conditions analyzed from five districts, i.e., Chakwal, Khushab, Rawalpindi, Faisalabad, and Layyah in Punjab, Pakistan. Extensive surveying and plant sampling across two years 2017-18 and 2018-19, during mid-spring, summer, autumn, and winter seasons were carried out for understanding the seasonal impact on sisal. The present study was designed in a randomized complete block design (RCBD) and analyzed considering seasonal, yearly, and locational impact. The spatial differences in phytochemicals concentration were strongly associated with environmental conditions prevailing in different seasons. Autumn season reflected saponins, tannins, and flavonoids in higher concentrations during 2018-19 while steroids and terpenoids were higher during spring 2018-19. While Spatio-temporal variations in the proximate analysis were more apparent in different samples collected from different districts. Data recorded for the Khushab district and autumn season reflected the higher composition of a proximate analysis and phytochemical contents as compared to other seasons. Overall, the spatial differences in phytochemicals concentration were strongly associated with soils and environmental conditions prevailing in different seasons in selected districts.


Atmosphere ◽  
2018 ◽  
Vol 9 (10) ◽  
pp. 378 ◽  
Author(s):  
Channa Rodrigo ◽  
Sangil Kim ◽  
Il Jung

This study aimed to determine the predictability of the Weather Research and Forecasting (WRF) model with different model physics options to identify the best set of physics parameters for predicting heavy rainfall events during the southwest and northeast monsoon seasons. Two case studies were used for the evaluation: heavy precipitation during the southwest monsoon associated with the simultaneous onset of the monsoon, and a low pressure system over the southwest Bay of Bengal that produced heavy rain over most of the country, with heavy precipitation associated with the northeast monsoon associated with monsoon flow and easterly disturbances. The modeling results showed large variation in the rainfall estimated by the model using the various model physics schemes, but several corresponding rainfall simulations were produced with spatial distribution aligned with rainfall station data, although the amount was not estimated accurately. Moreover, the WRF model was able to capture the rainfall patterns of these events in Sri Lanka, suggesting that the model has potential for operational use in numerical weather prediction in Sri Lanka.


Author(s):  
S. Salihin ◽  
T. A. Musa ◽  
Z. Mohd Radzi

This paper provides the precise information on spatial-temporal distribution of water vapour that was retrieved from Zenith Path Delay (ZPD) which was estimated by Global Positioning System (GPS) processing over the Malaysian Peninsular. A time series analysis of these ZPD and Integrated Water Vapor (IWV) values was done to capture the characteristic on their seasonal variation during monsoon seasons. This study was found that the pattern and distribution of atmospheric water vapour over Malaysian Peninsular in whole four years periods were influenced by two inter-monsoon and two monsoon seasons which are First Inter-monsoon, Second Inter-monsoon, Southwest monsoon and Northeast monsoon.


Author(s):  
S. Supharatid ◽  
J. Nafung ◽  
T. Aribarg

Abstract Five mainland SEA countries (Cambodia, Laos, Myanmar, Vietnam, and Thailand) are threatened by climate change. Here, the latest 18 Coupled Model Intercomparison Project Phase 6 (CMIP6) is employed to examine future climate change in this region under two SSP-RCP (shared socioeconomic pathway-representative concentration pathway) scenarios (SSP2-4.5 and SSP5-8.5). The bias-corrected multi-model ensemble (MME) projects a warming (wetting) over Cambodia, Laos, Myanmar, Vietnam, and Thailand by 1.88–3.89, 2.04–4.22, 1.88–4.09, 2.03–4.25, and 1.90–3.96 °C (8.76–20.47, 12.69–21.10, 9.54–21.10, 13.47–22.12, and 7.03–15.17%) in the 21st century with larger values found under SSP5-8.5 than SSP2-4.5. The MME model displays approximately triple the current rainfall during the boreal summer. Overall, there are robust increases in rainfall during the Southwest Monsoon (3.41–3.44, 8.44–9.53, and 10.89–17.59%) and the Northeast Monsoon (−2.58 to 0.78, −0.43 to 2.81, and 2.32 to 5.45%). The effectiveness of anticipated climate change mitigation and adaptation strategies under SSP2-4.5 results in slowing down the warming trends and decreasing precipitation trends after 2050. All these findings imply that member countries of mainland SEA need to prepare for appropriate adaptation measures in response to the changing climate.


2013 ◽  
Vol 17 (7) ◽  
pp. 2917-2928 ◽  
Author(s):  
G. Mongelli ◽  
S. Monni ◽  
G. Oggiano ◽  
M. Paternoster ◽  
R. Sinisi

Abstract. Throughout the Mediterranean, salinization threatens water quality, especially in coastal areas. This salinization is the result of concomitant processes related to both seawater intrusion and water–rock interaction, which in some cases are virtually indistinguishable. In the Nurra region of northwestern Sardinia, recent salinization related to marine water intrusion has been caused by aquifer exploitation. However, the geology of this region records a long history from the Palaeozoic to the Quaternary, and is structurally complex and comprises a wide variety of lithologies, including Triassic evaporites. Determining the origin of the saline component of the Jurassic and Triassic aquifers in the Nurra region may provide a useful and more general model for salinization processes in the Mediterranean area, where the occurrence of evaporitic rocks in coastal aquifers is a common feature. In addition, due to intensive human activity and recent climatic change, the Nurra has become vulnerable to desertification and, in common with other Mediterranean islands, surface water resources periodically suffer from severe shortages. With this in mind, we report new data regarding brackish and surface waters (outcrop and lake samples) of the Na-Cl type from the Nurra region, including major ions and selected trace elements (B, Br, I, and Sr), in addition to isotopic data including δ18O, δD in water, and δ34S and δ18O in dissolved SO4. To identify the origin of the salinity more precisely, we also analysed the mineralogical and isotopic composition of Triassic evaporites. The brackish waters have Cl contents of up to 2025 mg L−1 , and the ratios between dissolved ions and Cl, with the exception of the Br / Cl ratio, are not those expected on the basis of simple mixing between rainwater and seawater. The δ18O and δD data indicate that most of the waters fall between the regional meteoric water line and the global meteoric water line, supporting the conclusion that they are meteoric in origin. A significant consequence of the meteoric origin of the Na-Cl-type water studied here is that the Br / Cl ratio, extensively used to assess the origin of salinity in fresh water, should be used with care in carbonate aquifers that are near the coast. Overall, δ34S and δ18O levels in dissolved SO4 suggest that water–rock interaction is responsible for the Na-Cl brackish composition of the water hosted by the Jurassic and Triassic aquifers of the Nurra, and this is consistent with the geology and lithological features of the study area. Evaporite dissolution may also explain the high Cl content, as halite was detected within the gypsum deposits. Finally, these Na-Cl brackish waters are undersaturated with respect to the more soluble salts, implying that in a climate evolving toward semi-arid conditions, the salinization process could intensify dramatically in the near future.


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