scholarly journals Experimental study of the flux Law of flat ceramic membranes under different pressures

2020 ◽  
Vol 15 (2) ◽  
pp. 416-425
Author(s):  
Sun Chuanwen ◽  
Wang Haiqiao ◽  
Yu Qi ◽  
Chen Shiqiang ◽  
Li Xun ◽  
...  
Keyword(s):  
Functional Relationship ◽  
Ceramic Membrane ◽  
Water Flux ◽  
Ceramic Membranes ◽  
Operating Conditions ◽  
Operating Pressure ◽  
Flux Variation ◽  
Filtration Process ◽  
Membrane Flux ◽  
Flux Model

Abstract The flux performance of ceramic membranes is the basis for their efficient use. To study ceramic membrane flux variation, different filtration operating conditions were tested and the functional relationship between the membrane's clean water flux and the operating pressure within a given range obtained. The membrane's critical pressure and flux were determined by using pressure increments, and the flux variation law under different pressures determined experimentally. Analysis of the flux law and the membrane parameters enabled establishment of the flux model of filtration process and a model of flux stabilization after the deposition layer formed. The applicability of the model was proved by comparing and verifying the experimental data.

scholarly journals Study on the preparation and properties of talcum-fly ash based ceramic membrane supports

2020 ◽  
Author(s):  
Chao Cheng ◽  
Hongming Fu ◽  
Heng Zhang ◽  
Haiping Chen ◽  
Dan Gao
Keyword(s):  
Corrosion Resistance ◽  
Fly Ash ◽  
Flue Gas ◽  
Power Plants ◽  
Ceramic Membrane ◽  
Low Cost ◽  
Water Flux ◽  
Ceramic Membranes ◽  
Operating Conditions ◽  
Water Recovery

Abstract Ceramic membrane method for moisture recovery from flue gas of thermal power plants is of considerable interest due to its excellent selection performance and corrosion resistance. However, manufacturing costs of commercial ceramic membranes are still relatively expensive, which promotes the development of new methods of preparing low-cost ceramic membranes. In this study, a method for the preparation of porous ceramic membrane supports is proposed. Low-cost fly ash from power plants is the main material of the membrane supports, and talcum is the additive. The fabrication process of the ceramic membrane supports is described in detail. The properties of the supports were fully characterized, including surface morphology, phase composition, pore diameter distribution and porosity. Corrosion resistance and mechanical strength of the supports were measured. The obtained ceramic membrane support displays a pore size of about 5 µm and porosity of 37.8%. Furthermore, the water recovery performance of the supports under different operating conditions was experimentally studied. The experimental results show that, the recovered water flux varies with operating conditions. In the study, the maximum recovered water flux reaches 5.22 kg/(m2·h). The findings provide a guidance for the ceramic membrane supports application of water recovery from flue gas.

scholarly journals Study on the Preparation and Properties of Talcum-Fly Ash Based Ceramic Membrane Supports

Membranes ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 207
Author(s):  
Chao Cheng ◽  
Hongming Fu ◽  
Jun Wu ◽  
Heng Zhang ◽  
Haiping Chen
Keyword(s):  
Fly Ash ◽  
Flue Gas ◽  
Power Plants ◽  
Ceramic Membrane ◽  
Low Cost ◽  
Thermal Power ◽  
Water Flux ◽  
Ceramic Membranes ◽  
Operating Conditions ◽  
Water Recovery

Ceramic membrane method for moisture recovery from flue gas of thermal power plants is of considerable interest due to its excellent selection performance and corrosion resistance. However, manufacturing costs of commercial ceramic membranes are still relatively expensive, which promotes the development of new methods for preparing low-cost ceramic membranes. In this study, a method for the preparation of porous ceramic membrane supports is proposed. Low-cost fly ash from power plants is the main material of the membrane supports, and talcum is the additive. The fabrication process of the ceramic membrane supports is described in detail. The properties of the supports were fully characterized, including surface morphology, phase composition, pore diameter distribution, and porosity. The mechanical strength of the supports was measured. The obtained ceramic membrane supports displays a pore size of about 5 μm and porosity of 37.8%. Furthermore, the water recovery performance of the supports under different operating conditions was experimentally studied. The experimental results show that the recovered water flux varies with operating conditions. In the study, the maximum recovered water flux reaches 5.22 kg/(m2·h). The findings provide a guidance for the ceramic membrane supports application of water recovery from flue gas.

scholarly journals A Review on Current Development of Membranes for Oil Removal from Wastewaters

Membranes ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 65 ◽  
Author(s):  
Brian Bolto ◽  
Jianhua Zhang ◽  
Xing Wu ◽  
Zongli Xie
Keyword(s):  
Ceramic Membrane ◽  
Ceramic Membranes ◽  
Current Situation ◽  
Polymeric Membranes ◽  
Operating Conditions ◽  
Oil Removal ◽  
Organic Polymers ◽  
Current Development ◽  
Flux Decline ◽  
Successful Approach

The current situation with the problems associated with the removal of oil from wastewaters by membranes is being explored. Many types of membranes have been investigated—organic polymers, inorganic or ceramic species and hybrids of the two. Polymeric membranes can be designed to facilitate the passage of oil, but the more successful approach is with hydrophilic types that encourage the passage of water. Ceramic membranes have an advantage here as they are less often irreversibly fouled and give a higher recovery of oil, with a lower flux decline. Furthermore, they can be cleaned up by a simple heating procedure. More attention should be given to understanding the mechanism of fouling so that operating conditions can be optimised to further reduce fouling and further decrease the flux decline, as well as assisting in the design of antifouling membranes. Another obstacle to ceramic membrane use is the high cost of manufacture. Cheaper starting materials such as clays have been surveyed.

scholarly journals Chemical and microstructural analyses for heavy metals removal from water media by ceramic membrane filtration

2016 ◽  
Vol 75 (2) ◽  
pp. 439-450 ◽  
Author(s):  
Asmaa Ali ◽  
Abdelkader Ahmed ◽  
Ali Gad
Keyword(s):  
Heavy Metals ◽  
Chemical Analysis ◽  
Membrane Filtration ◽  
Ceramic Membrane ◽  
Low Cost ◽  
Ceramic Membranes ◽  
Filtration Process ◽  
X Ray ◽  
Before And After ◽  
Water Media

This study aims to investigate the ability of low cost ceramic membrane filtration in removing three common heavy metals namely; Pb2+, Cu2+, and Cd2+ from water media. The work includes manufacturing ceramic membranes with dimensions of 15 by 15 cm and 2 cm thickness. The membranes were made from low cost materials of local clay mixed with different sawdust percentages of 0.5%, 2.0%, and 5.0%. The used clay was characterized by X-ray diffraction (XRD) and X-ray fluorescence analysis. Aqueous solutions of heavy metals were prepared in the laboratory and filtered through the ceramic membranes. The influence of the main parameters such as pH, initial driving pressure head, and concentration of heavy metals on their removal efficiency by ceramic membranes was investigated. Water samples were collected before and after the filtration process and their heavy metal concentrations were determined by chemical analysis. Moreover, a microstructural analysis using scanning electronic microscope (SEM) was performed on ceramic membranes before and after the filtration process. The chemical analysis results showed high removal efficiency up to 99% for the concerned heavy metals. SEM images approved these results by showing adsorbed metal ions on sides of the internal pores of the ceramic membranes.

scholarly journals Characterization and Beneficiation of Ethiopian Kaolin for use in Fabrication of Ceramic Membrane

2021 ◽  
Author(s):  
Tsegahun Mekonnen Zewdie ◽  
Indah Prihatiningtyas ◽  
Abhishek Dutta ◽  
Nigus Gabbiye Habtu ◽  
Bart Van der Bruggen
Keyword(s):  
Oxalic Acid ◽  
Mass Loss ◽  
Acid Concentration ◽  
Contact Time ◽  
Ceramic Membrane ◽  
Substantial Reduction ◽  
Ceramic Membranes ◽  
Operating Conditions ◽  
Iron Extraction ◽  
Thermally Treated

Abstract Kaolin (china clay) is a rock material that is very rich in kaolinite. A kaolin ore from Debre Tabor, Ethiopia containing 59.2 wt.% SiO2, 24.9 wt.% Al2O3, 2.4 wt.% Fe2O3, and 8.22 wt.% loss on ignition (LOI) was physically beneficiated, chemically leached, and thermally treated for possible industrial use, especially for ceramic membrane fabrication. The leaching experiments were carried out using oxalic acid solutions as leaching reagents for the iron extraction process. The effect of acid concentration, reaction temperature, and contact time on iron leaching was investigated. It was determined that the rate of iron extraction increased with the oxalic acid concentration, leaching temperature, and contact time. A substantial reduction of iron oxide (2.4 to 0.36 wt. %) from the raw kaolin was observed at operating conditions of 2.0 M oxalic acid, the temperature of 120°C, and contact time of 120 min. A maximum kaolin whiteness index of 81.4 % was achieved through this leaching process. Finally, the physically beneficiated, chemically leached, and thermally treated kaolin raw material was used to fabricate a low-cost kaolin-based ceramic membrane. After firing at 1100°C the ceramic membrane was found to have a mass loss of 11.04 ± 0.05%, water absorption of 8.9 ± 0.4 %, linear shrinkage of 14.5 ± 0.05%. It was demonstrated to be chemically stable, having less than 3 % mass loss in acid solution, and less than 1 % mass loss in alkali solution. The newly developed membranes have thus properties comparable to commercial ceramic membranes.

scholarly journals Fabrication, Optimization, and Performance of a TiO2 Coated Bentonite Membrane for Produced Water Treatment: Effect of Grafting Time

Membranes ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 739
Author(s):  
Mohamad Izrin Mohamad Esham ◽  
Abdul Latif Ahmad ◽  
Mohd Hafiz Dzarfan Othman
Keyword(s):  
Produced Water ◽  
Ceramic Membrane ◽  
Average Pore Size ◽  
Pure Water ◽  
Sol Gel ◽  
Water Flux ◽  
Ceramic Membranes ◽  
Average Pore ◽  
Pure Water Flux ◽  
And Performance

The main problem usually faced by commercial ceramic membranes in the treatment of produced water (PW) is low water flux even though ceramic membrane was well-known with their excellent mechanical, thermal, and chemical properties. In the process of minimizing the problem faced by commercial ceramic membranes, titanium dioxide (TiO2) nanocomposites, which synthesized via a sol-gel method, were deposited on the active layer of the hydrolysed bentonite membrane. This paper studied the influence of grafting time of TiO2 nanocomposite on the properties and performance of the coated bentonite membranes. Several characterizations, which are Fourier transform infrared (FTIR), scanning electron microscopy (SEM), energy-dispersive X-ray Spectroscopy (EDX), contact angle, porosity, and average pore size, were applied to both pristine and coated bentonite membranes to compare the properties of the membranes. The deposition of TiO2 nanoparticles on the surface of the coated bentonite membranes was successfully confirmed by the characterization results. The pure water flux performance showed an increment from 262.29 L h−1 m−² bar−1 (pristine bentonite membrane) to 337.05 L h−1 m−² bar−1 (Ti-Ben 30) and 438.33 L h−1 m−² bar−1 (Ti-Ben 60) as the grafting time increase but when the grafting time reached 90 min (Ti-Ben 90), the pure water flux was decreased to 214.22 L h−1 m−² bar−1 which is lower than the pristine membrane. The oil rejection performance also revealed an increase in the oil rejection performance from 95 to 99%. These findings can be a good example to further studies and exploit the advantages of modified ceramic membranes in PW treatment.

Ceramic membranes for direct river water treatment applying coagulation and microfiltration

2006 ◽  
Vol 6 (4) ◽  
pp. 89-98 ◽  
Author(s):  
A. Loi-Brügger ◽  
S. Panglisch ◽  
P. Buchta ◽  
K. Hattori ◽  
H. Yonekawa ◽  
...  
Keyword(s):  
Drinking Water ◽  
Water Treatment ◽  
Pilot Study ◽  
River Water ◽  
Membrane Filtration ◽  
Ceramic Membrane ◽  
Drinking Water Treatment ◽  
Ceramic Membranes ◽  
Operating Conditions ◽  
Optimum Operating

A new ceramic membrane has been designed by NGK Insulators Ltd., Japan, to compete in the drinking water treatment market. The IWW Water Centre, Germany, investigated the operational performance and economical feasibility of this ceramic membrane in a one year pilot study of direct river water treatment with the hybrid process of coagulation and microfiltration. The aim of this study was to investigate flux, recovery, and DOC retention performance and to determine optimum operating conditions of NGK's ceramic membrane filtration system with special regards to economical aspects. Temporarily, the performance of the ceramic membrane was challenged under adverse conditions. During pilot plant operation river water with turbidities between 3 and 100 FNU was treated. Membrane flux was increased stepwise from 80–300 l/m2h resulting in recoveries between 95.9 and 98.9%. A DOC removal between about 20–35% was achieved. The pilot study and the subsequent economical evaluation showed the potential to provide a reliable and cost competitive process option for water treatment. The robustness of the ceramic membrane filtration process makes it attractive for a broad range of water treatment applications and, due to low maintenance requirements, also suitable for drinking water treatment in developing countries.

Preliminary study of osmotic membrane bioreactor: effects of draw solution on water flux and air scouring on fouling

2010 ◽  
Vol 62 (6) ◽  
pp. 1353-1360 ◽  
Author(s):  
Jian-Jun Qin ◽  
Kiran A. Kekre ◽  
Maung H. Oo ◽  
Guihe Tao ◽  
Chee L. Lay ◽  
...  
Keyword(s):  
Osmotic Pressure ◽  
Membrane Bioreactor ◽  
Water Flux ◽  
Forward Osmosis ◽  
Operating Conditions ◽  
Draw Solution ◽  
Membrane Flux ◽  
Osmotic Membrane Bioreactor ◽  
Flux Decline ◽  
Preliminary Study

Preliminary study on a novel osmotic membrane bioreactor (OMBR) was explored. Objective of this study was to investigate the effects of draw solution on membrane flux and air scouring at the feed side on fouling tendency in a pilot OMBR system composing the anoxic/aerobic and forward osmosis (FO) processes. Domestic sewage was the raw feed, FO membrane from HTI and NaCl/MgSO4 draw solutions were used in the experiments. Fluxes of 3 l/m2/h (LMH) and 7.2 LMH were achieved at osmotic pressure of 5 and 22.4 atm, respectively. No significant flux decline was observed at 3 LMH over 190 h and at 7.2 LMH over 150 h when air scouring was provided at the feed side of the membrane. However, without air scouring, the flux at 22.4 atm osmotic pressure declined by 30% after 195 h and then levelled off. The potential advantages of the fouling reversibility with air scouring under the operating conditions of the pilot OMBR and better water quality in OMBR over the conventional MBR were preliminarily demonstrated.

Influence of operating conditions on performance of ceramic membrane used for water treatment

2014 ◽  
Vol 68 (2) ◽  
Author(s):  
Agnieszka Urbanowska ◽  
Małgorzata Kabsch-Korbutowicz
Keyword(s):  
Organic Matter ◽  
Water Treatment ◽  
Flow Velocity ◽  
Natural Organic Matter ◽  
Ceramic Membrane ◽  
Operating Time ◽  
Ceramic Membranes ◽  
Operating Conditions ◽  
Human Consumption ◽  
Permeate Flux

AbstractThe removal of natural organic matter (NOM) is a critical aspect of potable water treatment because NOM compounds are precursors of harmful disinfection by-products, hence should be removed from water intended for human consumption. Ultrafiltration using ceramic membranes can be a suitable process for removal of natural substances. Previously reported experiments were dedicated to evaluating the suitability of ultrafiltration through ceramic membrane for water treatment with a focus on the separation of natural organic matter. The effects of the membrane operating time and linear flow velocity on transport and separation properties were also examined. The experiments, using a 7-channel 300 kDa MWCO ceramic membrane, were carried out with model solutions and surface water at trans-membrane pressure of 0.2–0.5 MPa. The results revealed that a loose UF ceramic membrane can successfully eliminate natural organic matter from water. The permeability of the membrane was strongly affected by the composition of the feed stream, i.e. the permeate flux decreased with an increase in the NOM concentration. The permeate flux also decreased over the period of the operation, while this parameter did not influence the effectiveness of separation, i.e. the removal of NOM. It was observed that the increased cross-flow velocity resulted in the decrease in the membrane-fouling intensity and slightly improved the retention of contaminants.

scholarly journals Impact of Membrane Pore Size on the Clarification Performance of Grape Marc Extract by Microfiltration

Membranes ◽  
2019 ◽  
Vol 9 (11) ◽  
pp. 146 ◽  
Author(s):  
Mora ◽  
Pérez ◽  
Quezada ◽  
Herrera ◽  
Cassano ◽  
...  
Keyword(s):  
Pore Size ◽  
Ceramic Membranes ◽  
Operating Conditions ◽  
Operating Pressure ◽  
Permeate Flux ◽  
Membrane Pore ◽  
Grape Marc ◽  
Fouling Mechanism ◽  
Pore Blocking ◽  
Membrane Pore Size

The influence of membrane pore size on the permeate flux, fouling mechanism, and rejection of soluble and suspended solids, as well as of phenolics and anthocyanins, in the clarification of grape marc extract by microfiltration (MF) was studied. MF was operated by using three monotubular ceramic membranes with a pore size of 0.14, 0.2, and 0.8 µm, respectively, according to a batch concentration configuration in selected operating conditions (2.25 bar as operating pressure, 4.93 L/min as feed flow rate, and 25 °C as operating temperature). No significant differences in the permeate flux values were appreciated despite the difference in pore size. The mathematical analyses of the flux behavior revealed that intermediate pore blocking is the predominant mechanism for 0.14 and 0.2 µm membranes, whereas complete pore blocking prevails for the 0.8 µm membrane. Differences in the fouling mechanism were associated with differences in the total phenols rejection: the highest rejection was observed for the 0.8 µm membrane followed by 0.2 and 0.14 µm membranes. All selected membranes showed low rejection of sugars, with values lower than 10%, and no retention towards anthocyanins. All the clarified extracts showed a turbidity lower than 4.87 NTU. Based on the experimental results, the 0.14 µm membrane appeared as the best option for the clarification of grape marc extract.

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