scholarly journals Chemical and microstructural analyses for heavy metals removal from water media by ceramic membrane filtration

2016 ◽  
Vol 75 (2) ◽  
pp. 439-450 ◽  
Author(s):  
Asmaa Ali ◽  
Abdelkader Ahmed ◽  
Ali Gad

This study aims to investigate the ability of low cost ceramic membrane filtration in removing three common heavy metals namely; Pb2+, Cu2+, and Cd2+ from water media. The work includes manufacturing ceramic membranes with dimensions of 15 by 15 cm and 2 cm thickness. The membranes were made from low cost materials of local clay mixed with different sawdust percentages of 0.5%, 2.0%, and 5.0%. The used clay was characterized by X-ray diffraction (XRD) and X-ray fluorescence analysis. Aqueous solutions of heavy metals were prepared in the laboratory and filtered through the ceramic membranes. The influence of the main parameters such as pH, initial driving pressure head, and concentration of heavy metals on their removal efficiency by ceramic membranes was investigated. Water samples were collected before and after the filtration process and their heavy metal concentrations were determined by chemical analysis. Moreover, a microstructural analysis using scanning electronic microscope (SEM) was performed on ceramic membranes before and after the filtration process. The chemical analysis results showed high removal efficiency up to 99% for the concerned heavy metals. SEM images approved these results by showing adsorbed metal ions on sides of the internal pores of the ceramic membranes.

2010 ◽  
Vol 18 (5) ◽  
pp. 28-31
Author(s):  
R.B. Simmons

In recent years there has been a virtual explosion in the world of art glass. New glass formulations have brought a host of new colors into the marketplace, and the availability of low-cost, high-quality torches and other tools has brought art glass to the hobbyist. In addition to burn risks and possible cutting injury, there are a number of less obvious hazards that should be known to novice glass workers. One of these is the presence of heavy metals in or on glass surfaces and possibly in the atmosphere immediately surrounding the work area, presenting both potential skin contact and inhalation hazards. This study examines the metallic surfaces generated on five glass colors commonly used in art glass jewelry.


Membranes ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 711
Author(s):  
Wan Fan ◽  
Dong Zou ◽  
Jingrui Xu ◽  
Xianfu Chen ◽  
Minghui Qiu ◽  
...  

Support is a necessary foundation for ceramic membranes to achieve high performance. Finding the optimum balance between high performance and low cost is still a significant challenge in the fabrication of ceramic supports. In this study, low-cost fly ash-based ceramic supports with enhanced performance were prepared by the addition of bauxite. The pore structure, mechanical strength, and shrinkage of fly ash/bauxite supports could be tuned by optimizing the bauxite content and sintering temperature. When the sintering temperature and bauxite content were controlled at 1300 °C and 40 wt%, respectively, the obtained membrane supports exhibited a high pure water permeance of approximately 5.36 m3·m−2·h−1·bar−1 and a high bending strength of approximately 69.6 MPa. At the same time, the optimized ceramic supports presented a typical mullite phase and excellent resistance to acid and alkali. This work provides a potential route for the preparation of ceramic membrane supports with characteristics of low cost and high performance.


Author(s):  
Lili Song ◽  
Bo Zhu ◽  
Veeriah Jegatheesan ◽  
Stephen R. Gray ◽  
Mikel C. Duke ◽  
...  

Materials ◽  
2019 ◽  
Vol 12 (14) ◽  
pp. 2253 ◽  
Author(s):  
Magdalena Tuchowska ◽  
Barbara Muir ◽  
Mariola Kowalik ◽  
Robert P. Socha ◽  
Tomasz Bajda

Montmorillonite—the most popular mineral of the smectite group—has been recognized as a low-cost, easily available mineral sorbent of heavy metals and other organic and inorganic compounds that pollute water. The aim of this work was to determine the sorption mechanism and to identify the reaction products formed on the surface of montmorillonite and organo-montmorillonite after sorption of molybdates (Mo(VI)) and tungstates (W(VI)). Montmorillonites are often modified to generate a negative charge on the surface. The main objective of the study was to investigate and compare the features of Na-montmorillonite (Na-M), montmorillonite modified with dodecyl trimethyl ammonium bromide (DDTMA-M), and montmorillonite modified with didodecyl dimethyl ammonium bromide (DDDDMA-M) before and after sorption experiments. The material obtained after sorption was studied by X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The XRD pattern showed the presence of a new crystallic phase in the sample that was observed under an SEM as an accumulation of crystals. The FTIR spectra showed bands related to Mo–O and W–O vibration (840 and 940 cm−1, respectively). The obtained results suggest that molybdenum(VI) and tungsten(VI) ions sorb onto the organo-montmorillonite in the form of alkylammonium molybdates and tungstates.


2019 ◽  
Vol 16 (3) ◽  
Author(s):  
Anggit Prameitya ◽  
Darjati . ◽  
Ernita Sari

Water is the element of life that is essential for survival. Along with the rapid growth of the human being, the demand for water increases. Now this, many water sources are contaminated, clean one of the impacts that cause pollution is that there is content of Fe in the water. Fe is the secondary contaminants that become problems in the provision of clean water is especially groundwater. The content of Fe exceeds quality raw processing must be done first before used to clean water. This research aims to analyze Fe levels before and after filtration is done using ceramic membrane media with a thickness of 5 cm and 7 cm in well water.This research is experimental research, using design research True Experiment with form One Group Pretest-Posttest. The object of this research that is well water containing Fe levels with a total of 32 Research sample sample. Further data obtained were analyzed using analytical test in Paired-Samples T Test.The results showed that the ceramic membrane filter media thickness 5 cm and 7 cm is capable of lowering the average rate of 8.11 Fe mg/l be 5.9 mg/l and 3.6 mg/l. The results of statistical tests using Paired T-test Test earned the result that there is a difference Fe levels before and after treatment using ceramic membrane filter media with variations in the thickness of 5 cm and 7 cm.The conclusion of this research is the ceramic membrane thickness 7 cm has the difference decreased most in lowering levels of Fe on well water. It is recommended to increase the creativity in applying appropriate technology in filtration method. Keywords: water well, levels of Fe, ceramic membranes


2020 ◽  
Author(s):  
Chao Cheng ◽  
Hongming Fu ◽  
Heng Zhang ◽  
Haiping Chen ◽  
Dan Gao

Abstract Ceramic membrane method for moisture recovery from flue gas of thermal power plants is of considerable interest due to its excellent selection performance and corrosion resistance. However, manufacturing costs of commercial ceramic membranes are still relatively expensive, which promotes the development of new methods of preparing low-cost ceramic membranes. In this study, a method for the preparation of porous ceramic membrane supports is proposed. Low-cost fly ash from power plants is the main material of the membrane supports, and talcum is the additive. The fabrication process of the ceramic membrane supports is described in detail. The properties of the supports were fully characterized, including surface morphology, phase composition, pore diameter distribution and porosity. Corrosion resistance and mechanical strength of the supports were measured. The obtained ceramic membrane support displays a pore size of about 5 µm and porosity of 37.8%. Furthermore, the water recovery performance of the supports under different operating conditions was experimentally studied. The experimental results show that, the recovered water flux varies with operating conditions. In the study, the maximum recovered water flux reaches 5.22 kg/(m2·h). The findings provide a guidance for the ceramic membrane supports application of water recovery from flue gas.


2006 ◽  
Vol 6 (4) ◽  
pp. 89-98 ◽  
Author(s):  
A. Loi-Brügger ◽  
S. Panglisch ◽  
P. Buchta ◽  
K. Hattori ◽  
H. Yonekawa ◽  
...  

A new ceramic membrane has been designed by NGK Insulators Ltd., Japan, to compete in the drinking water treatment market. The IWW Water Centre, Germany, investigated the operational performance and economical feasibility of this ceramic membrane in a one year pilot study of direct river water treatment with the hybrid process of coagulation and microfiltration. The aim of this study was to investigate flux, recovery, and DOC retention performance and to determine optimum operating conditions of NGK's ceramic membrane filtration system with special regards to economical aspects. Temporarily, the performance of the ceramic membrane was challenged under adverse conditions. During pilot plant operation river water with turbidities between 3 and 100 FNU was treated. Membrane flux was increased stepwise from 80–300 l/m2h resulting in recoveries between 95.9 and 98.9%. A DOC removal between about 20–35% was achieved. The pilot study and the subsequent economical evaluation showed the potential to provide a reliable and cost competitive process option for water treatment. The robustness of the ceramic membrane filtration process makes it attractive for a broad range of water treatment applications and, due to low maintenance requirements, also suitable for drinking water treatment in developing countries.


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