Two-Stage Coalescer for Oil/Water Separation

1992 ◽  
Vol 26 (9-11) ◽  
pp. 2073-2076 ◽  
Author(s):  
S. Sokolovic ◽  
R. Secerov-Sokolovic ◽  
S. Sevic

Many different types of coalescers are used for separation of oil-in-water dispersion. The investigated results of a newly developed two stage coalescer are given in this work. The proposed designofthis coalescer includes two independent stages which are set in the same coalescer body. Expanded polystyrene granules are being used in the first stage. By using this coalescent material, gravity separation and the large oil droplets, coalescence processes are at the same time being insured. The second stage of this new type of coalescer uses polyurethane foam. The surface of this layer has been previously oiled. the proposed two stage coalescer has been tested for different type of oily wastewaters. A high loaded oilywastewater has been treatedby the new coalescer separator in the field In a one year working period, a mean oil separation efficiency has been higher than 98 %. The proposed coalescer can be use for suspended solids separation at the same time. Mean separation efficiency has been 85% duringthe field test.

Nanomaterials ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 3434
Author(s):  
Haodong Zhao ◽  
Yali He ◽  
Zhihua Wang ◽  
Yanbao Zhao ◽  
Lei Sun

Emulsified oily wastewater threatens human health seriously, and traditional technologies are unable to separate emulsion containing small sized oil droplets. Currently, oil–water emulsions are usually separated by special wettability membranes, and researchers are devoted to developing membranes with excellent antifouling performance and high permeability. Herein, a novel, simple and low-cost method has been proposed for the separation of emulsion containing surfactants. Polyacrylonitrile (PAN) nanofibers were prepared via electrospinning and then coated by polydopamine (PDA) by using self-polymerization reactions in aqueous solutions. The morphology, structure and oil-in-water emulsion separation properties of the as-prepared PDA@PAN nanofibrous membrane were tested. The results show that PDA@PAN nanofibrous membrane has superhydrophilicity and almost no adhesion to crude oil in water, which exhibits excellent oil–water separation ability. The permeability and separation efficiency of n-hexane/water emulsion are up to 1570 Lm−2 h−1 bar−1 and 96.1%, respectively. Furthermore, after 10 cycles of separation, the permeability and separation efficiency values do not decrease significantly, indicating its good recycling performance. This research develops a new method for preparing oil–water separation membrane, which can be used for efficient oil-in-water emulsion separation.


Author(s):  
Asmat Ullah ◽  
Kalam Alam ◽  
Saad Ullah Khan ◽  
Victor M. Starov

A new method is proposed to increase rejection in microfiltration by applying membrane oscillation using a new type of microfiltration membranes with slotted pores. The oscillations applied to the membrane surface result in reducing membrane fouling and increasing separation efficiency. An exact mathematical solution of the flow in the surrounding solution outside the oscillating membrane is developed. The oscillation results in appearance of the lift velocity, which moves oil particles away from the membrane. The latter results in both reducing membrane fouling and increasing oil droplets rejection. This developed model was supported by the experimental results for oil water separation in produced water treatment. It was proven that oil droplet concentration reduced notably in the permeate due to the membrane oscillation and that applied shear rate caused by the membrane oscillation is also reduce pore blockage. New generation of microfiltration membranes with slotted pores was used in the experiments.


2021 ◽  
Vol 18 (4) ◽  
pp. 887-899
Author(s):  
Yanling Tian ◽  
Jiekai Feng ◽  
Zexin Cai ◽  
Jiaqi Chao ◽  
Dawei Zhang ◽  
...  

AbstractReckless discharge of industrial wastewater and domestic sewage as well as frequent leakage of crude oil have caused serious environmental problems and posed severe threat to human survival. Various nature inspired superhy-drophobic surfaces have been successfully applied in oily water remediation. However, further improvements are still urgently needed for practical application in terms of facile synthesis process and long-term durability towards harsh environment. Herein, we propose a simple one-step dodecyl mercaptan functionalization method to fabricate Super-hydrophobic-Superoleophilic Copper Mesh (SSCM). The prepared SSCM possesses excellent water repellence and oil affinity, enabling it to successfully separate various oil-water mixtures with high separation efficiency (e.g., > 99% for hexadecane-water mixture). The SSCM retains high separating ability when hot water and strong corrosive aqueous solutions are used to simulate oil-water mixtures, indicating remarkable chemical durability of the dodecyl mercaptan functionalized copper mesh. Additionally, the efficiency can be well maintained during 50 cycles of separation, and the water repellence is even stable after storage in air for 120 days, demonstrating the reusability and long-term stability of the SSCM. Furthermore, the functionalized mesh also shows good mechanical robustness towards abrasion by sandpaper, and oil-water separation efficiency of > 96% can be obtained after 10 cycles of abrasion. The reported one-step dodecyl mercaptan functionalization could be a simple method for increasing the water repellence of copper mesh, and thereby be a great candidate for treating large-scale oily wastewater in harsh environments.


2021 ◽  
Author(s):  
Steinar Asdahl ◽  
Johann Jansen van Rensburg ◽  
Martin Einarson Waag ◽  
Rune Glenna Nilssen

Abstract Traditionally, produced water from production separators is handled by multiple steps and different technologies in order to meet the required quality for either discharge or reinjection of the water. The development of the latest Compact Flotation Unit (CFU) technology has unlocked the potential for savings on cost, complexity, footprint and weight for the produced water treatment system. The developed CFU technology has proven applicable through field testing as a single treatment technology for reducing Oil-in-Water (OiW) content directly from tie-in at separator and still meet stringent requirements for outlet OiW quality. Field tests were conducted with inlet OiW concentration ranging from 200-2000 ppm, achieving results in the range 2.5 to 21 ppm only with a two-stage latest generation CFU. Compared to a traditional produced water system setup consisting of de-oiling hydrocyclones and a horizontal degassing vessel, the savings in footprint and operational weight is estimated to 54 % and 53 % respectively utilizing a two-stage CFU for a system with a design capacity of 76.000 BWPD. Furthermore, the development of the latest generation CFU technology has enabled the retrofit concept, incorporating the developed CFU internals into existing gravity separation based produced water vessels, converting them to more efficient flotation vessels with increased capacity. For brownfield and debottlenecking applications, operators are challenged by increasing water cut from maturing wells, and as a result exceeding the facilities design capacity for produced water treatment. This challenge is often further reinforced by increasingly stricter environmental legislation for OiW content for discharge or re-injection. The retrofit concept will offer a highly cost-, footprint- and weight-efficient solutions to these challenges utilizing existing vessels. Benefits of the retrofit concept: Bring proven and unique performance of the technology to other produced water separation vessels helping the operators improve the separation efficiency and increase throughput while meeting discharge requirementsShort execution time compared to installation of new process equipmentLow cost compared to installation of new process equipmentUtilization of existing equipment saves valuable footprint.


Membranes ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 709
Author(s):  
Asmat Ullah ◽  
Kamran Alam ◽  
Saad Ullah Khan ◽  
Victor M. Starov

A new method is proposed to increase the rejection in microfiltration by applying membrane oscillation, using a new type of microfiltration membrane with slotted pores. The oscillations applied to the membrane surface result in reduced membrane fouling and increased separation efficiency. An exact mathematical solution of the flow in the surrounding solution outside the oscillating membrane is developed. The oscillation results in the appearance of a lift velocity, which moves oil particles away from the membrane. The latter results in both reduced membrane fouling and increased oil droplet rejection. This developed model was supported by the experimental results for oil water separation in the produced water treatment. It was proven that the oil droplet concentration was reduced notably in the permeate, due to the membrane oscillation, and that the applied shear rate caused by the membrane oscillation also reduced pore blockage. A four-times lower oil concentration was recorded in the permeate when the membrane vibration frequency was 25 Hz, compared to without membrane vibration. Newly generated microfiltration membranes with slotted pores were used in the experiments.


2019 ◽  
Vol 2019 ◽  
pp. 1-8 ◽  
Author(s):  
Peng Hong ◽  
Zhu Liu ◽  
Yang Gao ◽  
Yubin Chen ◽  
Mingxun Zhuang ◽  
...  

Superhydrophobic sponge as potential absorbing material for oil/water separation is attracting great attention recently. However, there are still some challenges to feasibly fabricate superhydrophobic sponge with large scale and low cost. Herein, a novel photochromic superhydrophobic melamine sponge (PDMS-SP sponge) is fabricated by facilely dip-coating and thermocuring of hydroxyl-terminated polydimethylsiloxanes mixed with photochromic spiropyran. FT-IR, EDS, and XPS results confirm the successful coating of PDMS-SP upon melamine sponge. The resultant sponge not only possesses excellent water repellency with a contact angle of 154.5° and oil-water separation efficiency with an oil absorption capacity of 48–116 folds of itself weight, but also shows photochromic phenomenon between colorless and purple when it is successively exposed to UV irradiation and visible light.


Polymers ◽  
2019 ◽  
Vol 11 (5) ◽  
pp. 775 ◽  
Author(s):  
Fei Sun ◽  
Ting-Ting Li ◽  
Haitao Ren ◽  
Qian Jiang ◽  
Hao-Kai Peng ◽  
...  

This study aims to produce polypropylene (PP)/titanium dioxide (TiO2) melt-blown membranes for oil/water separation and photocatalysis. PP and different contents of TiO2 are melt-blended to prepare master batches using a single screw extruder. The master batches are then fabricated into PP/TiO2 melt-blown membranes. The thermal properties of the master batches are analyzed using differential scanning calorimetry and thermogravimetric analysis, and their particle dispersion and melt-blown membrane morphology are evaluated by scanning electron microscopy. TiO2 loaded on melt-blown membranes is confirmed by X-ray diffraction (XRD). The oil/water separation ability of the melt-blown membranes is evaluated to examine the influence of TiO2 content. Results show that the thermal stability and photocatalytic effect of the membranes increase with TiO2 content. TiO2 shows a good dispersion in the PP membranes. After 3 wt.% TiO2 addition, crystallinity increases by 6.4%, thermal decomposition temperature increases by 25 °C compared with pure PP membranes. The resultant PP/TiO2 melt-blown membrane has a good morphology, and better hydrophobicity even in acetone solution or 6 h ultraviolet irradiation, and a high oil flux of about 15,000 L·m−2·h−1. Moreover, the membranes have stabilized oil/water separation efficiency after being repeatedly used. The proposed melt-blown membranes are suitable for mass production for separating oil from water in massively industrial dyeing wastewater.


Polymers ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 442 ◽  
Author(s):  
Mingguang Yu ◽  
Qing Wang ◽  
Wenxin Yang ◽  
Yonghang Xu ◽  
Min Zhang ◽  
...  

In this paper, we present a facile and efficient strategy for the fabrication of magnetic, durable, and superhydrophobic cotton for oil/water separation. The superhydrophobic cotton functionalized with Fe3O4 magnetic nanoparticles was prepared via the in situ coprecipitation of Fe2+/Fe3+ ions under ammonia solution on cotton fabrics using polyvinylpyrrolidone (PVP) as a coupling agent and hydrophobic treatment with tridecafluorooctyl triethoxysilane (FAS) in sequence. The as-prepared cotton demonstrated excellent superhydrophobicity with a water contact angle of 155.6° ± 1.2° and good magnetic responsiveness. Under the control of the external magnetic field, the cotton fabrics could be easily controlled to absorb the oil from water as oil absorbents, showing high oil/water separation efficiency, even in hot water. Moreover, the cotton demonstrated remarkable mechanical durable properties, being strongly friction-resistant against sandpaper and finger wipe, while maintaining its water repellency. This study developed a novel and efficient strategy for the construction of magnetic, durable, and superhydrophobic biomass-based adsorbent for oil/water separation, which can be easily scaled up for practical oil absorption.


RSC Advances ◽  
2016 ◽  
Vol 6 (90) ◽  
pp. 87332-87340 ◽  
Author(s):  
Y. W. Liu ◽  
C. H. Zhang ◽  
Z. Q. Wang ◽  
X. Fu ◽  
R. Wei

Scaly structure bionic structured on the fabric with superhydrophilicity and underwater superoleophobicity. The modified fabric showed excellent separation efficiency for various oil–water mixtures which could solve oil–water separation issue.


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