Enhanced denitrification with external carbon sources in a biological anoxic filter

2012 ◽  
Vol 66 (10) ◽  
pp. 2243-2250 ◽  
Author(s):  
Wen-yi Dong ◽  
Xian-bing Zhang ◽  
Hong-jie Wang ◽  
Fei-yun Sun ◽  
Tong-zhou Liu
Keyword(s):  
Chemical Oxygen Demand ◽  
Total Nitrogen ◽  
Biomass Yield ◽  
Nitrate Nitrogen ◽  
Carbon Sources ◽  
Oxygen Demand ◽  
Brewery Wastewater ◽  
Removal Rates ◽  
Denitrification Kinetics ◽  
Kinetics Of

Three parallel biological anoxic filters (BaFs) were operated to investigate the denitrification kinetics of methanol, brewery wastewater and bakery wastewater. The experiment was conducted within the temperature range of 15–20 °C, with an influent nitrate and carbon dosage of 30 mg/L and 150 mg COD/L (COD: chemical oxygen demand). The denitrification efficiencies of brewery wastewater, bakery wastewater and methanol were 84, 66 and 74%, specific denitrification rates were 1.44, 1.11 and 1.24 kg NO3-N/m3 d, and total nitrogen (TN) removal rates were 74, 62 and 66%, respectively. The volatile attached solid (VAS) tests reveal that methanol has the minimum net biomass yield, so it needs the least carbon to nitrogen (expressed in COD to nitrate, C/N) ratio for complete denitrification. While the brewery wastewater and bakery wastewater need higher C/N ratio to remove all nitrate nitrogen, and they both may need pretreatment to remove phosphate when used as external carbon sources.

A Two Bioreactor Treating Brewery Wastewater

2010 ◽  
Vol 113-116 ◽  
pp. 1138-1142 ◽  
Author(s):  
Edith I. Madukasi ◽  
Gaung Ming Zhang
Keyword(s):  
Chemical Oxygen Demand ◽  
Total Nitrogen ◽  
Total Phosphorus ◽  
Oxygen Demand ◽  
High Energy ◽  
Brewery Wastewater ◽  
Two Stage ◽  
Dark Incubation

A two stage bioreactor was employed in bioremediation study of laboratory simulated brewery wastewater. Two weeks anaerobic dark incubation of the artificial brewery wastewater without external seeding resulted in an effluent with 138mgl-1VFA; the chemical oxygen demand decreased from 10,000 to 7,814mgl-1 total nitrogen and total phosphorus recorded 18.63 and 18.95% reductions. Further treatment of the anaerobic effluent with a photobacterium named Z08, reduced both the pollutants (COD, TN, TP) and high energy molecules (VFA) significantly by 36.8, 67.5, 27.0, and 60% respectively. Addition of 200mgl-1 NH2-CO-NH2 to the effluent yielded the best result, reducing COD, TN, TP and VFA by 67.5, 68.9, 34.2 and 82%.

scholarly journals Study on the Decontamination Effect of Biochar-Constructed Wetland under Different Hydraulic Conditions

Water ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 893
Author(s):  
Chuanjie Xing ◽  
Xiangxi Xu ◽  
Zhenghe Xu ◽  
Rongzhen Wang ◽  
Lirong Xu
Keyword(s):  
Chemical Oxygen Demand ◽  
Constructed Wetlands ◽  
Total Nitrogen ◽  
Total Phosphorus ◽  
Constructed Wetland ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Removal Rates ◽  
Hydraulic Conditions ◽  
Hydraulic Load

To explore the purification effect of biochar-constructed wetlands on rural domestic sewage, six types of biochar-constructed wetlands were constructed for experiments. Under different hydraulic conditions, the removal effects of each biochar-constructed wetland on chemical oxygen demand, ammonia nitrogen, total nitrogen, and total phosphorus in sewage were analyzed. The results showed that the removal rates of the four types of pollutants in each biochar-constructed wetland first increased and then decreased with the increase in hydraulic retention time, and the optimal hydraulic retention time range was 36–48 h. The highest removal rates of chemical oxygen demand, ammonia nitrogen, total nitrogen, and total phosphorus in the wetland were 97.34 ± 0.84%, 95.44 ± 1.29%, 98.95 ± 0.52%, and 97.78 ± 0.91%, respectively. The chemical oxygen demand (COD) removal rate of each biochar-constructed wetland increased first, then decreased with the increase in hydraulic load, and the optimal hydraulic load was 10 cm/d. The removal efficiency of ammonia nitrogen, total nitrogen, and total phosphorus of each biochar-constructed wetland gradually weakened with the increase in hydraulic load, and the optimal hydraulic load range was between 5 and 10 cm/d. Under these conditions, the highest removal rates of chemical oxygen demand, ammonia nitrogen, total nitrogen, and total phosphorus in the wetland were 92.15 ± 2.39%, 98.32 ± 0.48%, 96.69 ± 1.26%, and 92.62 ± 2.92%, respectively. Coconut shell and shell-constructed wetlands with the highest proportion of biochar in the matrix have the best removal effect on pollutants under different hydraulic conditions, and the wastewater purification effect is stronger, indicating that the addition of biochar is helpful for the removal of pollutants in constructed wetlands.

scholarly journals Digestate Liquid Fraction Treatment with Filters Filled with Recovery Materials

Water ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 21
Author(s):  
Ilaria Piccoli ◽  
Giuseppe Virga ◽  
Carmelo Maucieri ◽  
Maurizio Borin
Keyword(s):  
Chemical Oxygen Demand ◽  
Total Nitrogen ◽  
Liquid Fraction ◽  
Oxygen Demand ◽  
Ammonia Nitrogen ◽  
Green Technology ◽  
Filling Material ◽  
Community Interactions ◽  
Material Particle ◽  
N Removal

Constructed wetlands (CWs) represent a green technology for digestate liquid fraction (DLF) treatment. However, previous research has warned about their performance when treating wastewater with high suspended solid and organic loads. In addition, the high NH4-N concentration typical of this wastewater can compromise vegetation establishment and activity. In view of this, a digestate pretreatment is needed. This study aimed to test the performance of filters filled with recovery materials, such as brick and refractory material, for DLF pretreatment. The effect on DLF physical (electrical conductivity, pH, dissolved oxygen, and temperature) and chemical (total nitrogen, ammonia–nitrogen, nitrate–nitrogen, total phosphorus, soluble phosphorus, and chemical oxygen demand) characteristics was monitored during eight weekly cycles. The effect of filtration on total nitrogen and ammonia–nitrogen removal began after about one month of loading, suggesting that an activation period is necessary for bacteria. For effective N removal, the presence of multiple digestate recirculations per day through the filters appears mandatory to guarantee the alternation of nitrification and denitrification conditions. For P removal, filling material particle size appeared to be more important than its composition. Unclear performances were observed considering chemical oxygen demand. Further studies on filling media and microbial community interactions, and the long-term efficiency of filters, are desirable.

scholarly journals Effect of hydraulic retention time on chemical oxygen demand and total nitrogen removal in intermittently aerated constructed wetlands

2020 ◽  
Vol 15 (3) ◽  
pp. 1 ◽  
Author(s):  
Isabela Pires da Silva ◽  
Gabriela Barbosa da Costa ◽  
João Gabriel Thomaz Queluz ◽  
Marcelo Loureiro Garcia
Keyword(s):  
Chemical Oxygen Demand ◽  
Constructed Wetlands ◽  
Total Nitrogen ◽  
Total Phosphorus ◽  
Constructed Wetland ◽  
Retention Time ◽  
Hydraulic Retention Time ◽  
Subsurface Flow ◽  
Oxygen Demand ◽  
Intermittent Aeration

   This study evaluated the effect of hydraulic retention time on chemical oxygen demand (COD) and total nitrogen (TN) removal in an intermittently aerated constructed wetlands. Two horizontal subsurface-flow constructed wetlands were used: one without aeration and the other aerated intermittently (1 hour with aeration/7 hours without aeration). Both systems were evaluated treating domestic wastewater produced synthetically. The flow rate into the two CWs was 8.6 L day-1 having a hydraulic retention time of 3 days. The results show that the intermittently aerated constructed wetland were highly efficient in removing COD (98.25%), TN (83.60%) and total phosphorus (78.10%), while the non-aerated constructed wetland showed lower efficiencies in the removal of COD (93.89%), TN (48.60%) and total phosphorus (58.66). These results indicate, therefore, that intermittent aeration allows the simultaneous occurrence of nitrification and denitrification processes, improving the removal of TN in horizontal subsurface-flow constructed wetlands. In addition, the use of intermittent aeration also improves the performance of constructed wetlands in removing COD and total phosphorus.

Characteristics of granular sludge in a single upflow sludge blanket reactor treating high levels of nitrate and simple organic compounds

2004 ◽  
Vol 50 (8) ◽  
pp. 217-224 ◽  
Author(s):  
C.-Y. Lee ◽  
H.-S. Shin ◽  
S.-J. Hwang
Keyword(s):  
Chemical Oxygen Demand ◽  
Organic Compounds ◽  
Layered Structure ◽  
Microscopic Examination ◽  
Oxygen Demand ◽  
Granular Sludge ◽  
Pseudomonas Sp ◽  
Microbial Composition ◽  
Removal Rates ◽  
Sludge Flotation

Simultaneous denitrification and methanogenesis were accomplished in a single upflow sludge blanket (USB) reactor. More than 99% and 95% of nitrate and chemical oxygen demand (COD) removal rates were obtained at a loading of 600 mg NO3-N/L·d and 3,300 mg COD/L·d, respectively. The specific denitrification rate (SDR) increased as COD/NO3-N ratios decreased. Maximum SDR with acetate could reach 1.05 g NO3-N/gVSS·d. Significant sludge flotation was observed at the top of the reactor due to the change of microbial composition and the formation of hollow granules. Granules became fluffy and buoyant due to the growth of denitrifiers. Microscopic examination showed that granules exhibited layered structure and they were mainly composed of Methanosarcina sp., Pseudomonas sp., and rod-shaped bacteria.

Treatment of slaughterhouse plant wastewater by using a membrane bioreactor

2011 ◽  
Vol 64 (1) ◽  
pp. 214-219 ◽  
Author(s):  
Levent Gürel ◽  
Hanife Büyükgüngör
Keyword(s):  
Organic Carbon ◽  
Chemical Oxygen Demand ◽  
Membrane Bioreactor ◽  
Nitrate Nitrogen ◽  
Oxygen Demand ◽  
Organic Substances ◽  
Slaughterhouse Wastewater ◽  
Treated Effluent ◽  
Nitrogen Concentrations ◽  
Removal Efficiencies

The use of a membrane bioreactor (MBR) for removal of organic substances and nutrients from slaughterhouse plant wastewater was investigated. The chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) concentrations of slaughterhouse wastewater were found to be approximately 571 mg O2/L, 102.5 mg/L, and 16.25 mg PO4-P/L, respectively. A submerged type membrane was used in the bioreactor. The removal efficiencies for COD, total organic carbon (TOC), TP and TN were found to be 97, 96, 65, 44% respectively. The COD value of wastewater was decreased to 16 mg/L (COD discharge standard for slaughterhouse plant wastewaters is 160 mg/L). TOC was decreased to 9 mg/L (TOC discharge standard for slaughterhouse plant wastewaters is 20 mg/L). Ammonium, and nitrate nitrogen concentrations of treated effluent were 0.100 mg NH4-N/L, and 80.521 mg NO3-N/L, respectively. Slaughterhouse wastewater was successfully treated with the MBR process.

Purification Effect of Lolium multiflorum Ecological Floating Beds System in Urban Malodorous River at Low Temperature

2012 ◽  
Vol 518-523 ◽  
pp. 2686-2689
Author(s):  
Yu Hong Chai ◽  
Wen Yao Yan ◽  
Ming Xin Wang
Keyword(s):  
Low Temperature ◽  
Chemical Oxygen Demand ◽  
Total Nitrogen ◽  
Growth Rates ◽  
Low Temperatures ◽  
Lolium Multiflorum ◽  
Oxygen Demand ◽  
Total Biomass ◽  
Water Plant ◽  
Natural Rivers

An ecological floating beds system was constructed to treat natural urban malodorous river in Changzhou at low temperature. Taking Lolium multiflorum as an example of water plant, the characteristics and contribution of its uptake to total nitrogen (TN), NH4+-N, total phosphorus (TP) and chemical oxygen demand (CODMn) in the system were studied in a period of 80 days. Significant growth of the plant Lolium multiflorum was observed with total biomass ranging from 53 g to 785 g, and the highest growth rates were 8.82 and 9.23 for biomass of above water and under water part, respectively. Different concentrations of TN, NH4+-N, TP and COD were found between in the floating beds and out the floating beds. The highest removal rates of TN, NH4+-N, TP and CODMn using Lolium multiflorum ecological floating beds system were 16.8%, 33.0%,10.8% and 17.8%, respectively. The purification effect of ecological floating beds shows it can be well applied to cleaning natural rivers at low temperatures.

scholarly journals Community-based wastewater treatment systems and water quality of an Indonesian village

2013 ◽  
Vol 12 (1) ◽  
pp. 196-209 ◽  
Author(s):  
H. S. Lim ◽  
L. Y. Lee ◽  
S. E. Bramono
Keyword(s):  
Water Quality ◽  
Wastewater Treatment ◽  
Chemical Oxygen Demand ◽  
Total Nitrogen ◽  
Oxygen Demand ◽  
Small Scale ◽  
Irrigation Canals ◽  
Community Based ◽  
E Coli ◽  
The Impact

This paper examines the impact of community-based water treatment systems on water quality in a peri-urban village in Yogyakarta, Indonesia. Water samples were taken from the wastewater treatment plants (WWTPs), irrigation canals, paddy fields and wells during the dry and wet seasons. The samples were tested for biological and chemical oxygen demand, nutrients (ammonia, nitrate, total nitrogen and total phosphorus) and Escherichia coli. Water quality in this village is affected by the presence of active septic tanks, WWTP effluent discharge, small-scale tempe industries and external sources. We found that the WWTPs remove oxygen-demanding wastes effectively but discharged nutrients, such as nitrate and ammonia, into irrigation canals. Irrigation canals had high levels of E. coli as well as oxygen-demanding wastes. Well samples had high E. coli, nitrate and total nitrogen levels. Rainfall tended to increase concentrations of biological and chemical oxygen demand and some nutrients. All our samples fell within the drinking water standards for nitrate but failed the international and Indonesian standards for E. coli. Water quality in this village can be improved by improving the WWTP treatment of nutrients, encouraging more villagers to be connected to WWTPs and controlling hotspot contamination areas in the village.

scholarly journals Removal of organic and inorganic nutrients in a constructed rhizofiltration system using macrophytes and microbial biofilms

2016 ◽  
Author(s):  
◽  
Mathews Simon Mthembu
Keyword(s):  
Wastewater Treatment ◽  
Dissolved Oxygen ◽  
Greenhouse Gases ◽  
Chemical Oxygen Demand ◽  
Total Nitrogen ◽  
Oxygen Demand ◽  
Nitrogen And Phosphorus ◽  
Microbial Biofilms ◽  
Reference Sections ◽  
Reference Section

Many households in developing countries are still without proper sanitation systems. The problems are even more prevalent in rural communities where there are no septic systems in place for the treatment of wastewater. This has resulted in the urgent need for the development and implementation of innovative wastewater treatment systems that are inexpensive, environmental friendly and are able to reduce contaminants to levels that pose no harm to the communities. Constructed rhizofiltration systems have been explored for this purpose. They have been used for many decades in many countries with varying degrees of success at the primary, secondary and tertiary levels of wastewater treatment. Poor optimization of this technology has been due to limited information available about the roles played by the whole system as well as by each component involved in the treatment technology. The current work elucidates the role played by macrophytes and microbial biofilms in the removal of nutrients in the rhizofiltration system. Factors affecting waste removal as well as environmental friendliness of the system were also investigated. The rhizofiltration system was constructed in Durban and was divided into planted (planted with Phragmites australis and Kyllinga nemoralis) and unplanted (reference) section. Dissolved oxygen (DO), pH, water temperature, total dissolved solids (TDS), electrical conductivity (EC) and salinity were monitored. The removal efficiency of nutrients was measured using spectrophotometric methods by measuring the concentration of ammonia, nitrate, nitrite, phosphate and orthophosphate in the wastewater pre- and post-treatment. The total organic carbon, chemical oxygen demand (COD), total Kehldjahl nitrogen, biological oxygen demand (BOD), ammonia, nitrate and the flow rate of wastewater into the system from the settling tank were used for the estimation of carbon dioxide, methane and nitrous oxide emitted from the rhizofilter using the 2009 EPA formulae. Both the planted and reference sections of the system removed nutrients with varying efficiencies. The reduction of nutrients in the rhizofilter was found to be seasonal, with most nutrients removed during the warm seasons. The system also retained more nutrients when wastewater containing low levels of nutrients was used. The unpaired t-test was used to determine the differences between nutrient removals between planted and reference sections. Higher reduction efficiencies of nutrients were obtained in the planted section. Up to 65% nitrite and 99% nitrate were removed while up to 86% total phosphorus was removed in a form of orthophosphate (86%). Removal of total nitrogen was shown to increase under high temperature conditions, while the same conditions decreased the total phosphorus removal. High temperatures also increased the performance of the system. The reduction of nutrients in the system corresponded to reduction of the chemical oxygen demand which also positively correlated to the dissolved oxygen concentration. Considering the discharge limits for all nutrients, the discharges in the effluent of the planted section were within the allowable limits as per South Africa’s Department of Water affairs and Forestry in 2012 but not in 2013. The results obtained in 2013 were due to increased nutrient loading introduced into the system. Diverse microbial communities occurred in the treatment system, with more diversity in the planted section. These organisms were supported by macrophytes in the planted section, and were responsible for nitrogen and phosphorus transformation. This explains why total nitrogen and phosphorus reduction was higher in the planted compared to the reference section. Both the planted and the reference sections of the rhizofiltration system produced the greenhouse gases. When the two sections were compared, the planted section produced more gases. Gases emitted by both sections were lower when compared to emission from sludge treatment reed beds and other conventional systems of wastewater treatments. These findings indicated that constructed rhizofiltration is a cleaner form of waste treatment, producing significantly less greenhouse gases and affecting less of a climate change. Findings of this work have revealed that rhizofiltration technology can be used as a low-cost alternative technology for the treatment of wastewater, using the combination of macrophytes and microbial biofilms. Macrophytes accumulated nitrogen and phosphorus as well as supported diverse microorganisms that metabolized and reduced nutrients in the rhizofiltration unit.

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