Preparation of a novel chloromethylated polystyrene-2-mercapto-1,3,4-thiadiazole chelating resin and its adsorption properties and mechanism for separation and recovery of Hg(II) from aqueous solutions

2017 ◽  
Vol 76 (7) ◽  
pp. 1915-1924 ◽  
Author(s):  
Huihua Zhou ◽  
Jianjun Zheng ◽  
Hui Wang ◽  
Jianxin Wang ◽  
Xiaoguang Song ◽  
...  
Keyword(s):  
Adsorption Properties ◽  
Adsorption Kinetic ◽  
Chelating Resin ◽  
Order Model ◽  
Adsorption Capacities ◽  
Thiourea Solution ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
One Step ◽  
The Cost

With an efficient methodology, a novel chloromethylated polystyrene-g-2-mercapto-1,3,4-thiadiazole chelating resin (MTR resin) was prepared via a one-step reaction. The structure of MTR resin was characterized by elements analysis, Fourier transform infrared spectroscopy, thermogravimetric analysis, and scanning electron microscopy. Meanwhile, the adsorption properties of the resin for Hg(II) were investigated by batch and column experiments. The results showed that the resin possessed much better adsorption capability for Hg(II) than for other metal ions. The statically and the dynamic saturated adsorption capacities were 343.8 mg/g and 475.1 mg/g. The adsorption kinetic and equilibrium data were well fitted to the second-order model and the Langmuir isotherm model, respectively. Desorption of mercury from the resin can be achieved using 30 mL of 2 mol/L HCl-5% thiourea solution with a desorption ratio of 92.3%. Compared with other absorbents, MTR resin was greatly conserve natural resources and reduce the cost.

Synthesis and characterization of a novel chloromethylated polystyrene-g-2-adenine chelating resin and its application to preconcentrate and detect the concentration of mercury ions in edible mushroom samples

2016 ◽  
Vol 94 (9) ◽  
pp. 751-758 ◽  
Author(s):  
Song Li ◽  
Yuping Feng ◽  
Lei Fang ◽  
Xuming Zheng ◽  
Desui Chen ◽  
...  
Keyword(s):  
Accurate Determination ◽  
Edible Mushroom ◽  
Edible Mushrooms ◽  
Chelating Resin ◽  
Mercury Ions ◽  
Adsorption Capacities ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
Simple Technology

Edible mushrooms are widely usedtoday but the heavy metal pollution of edible mushrooms is not conducive to its industrialization. A novel chloromethylated polystyrene-g-2-adenine chelating resin (AR resin) with simple technology, high adsorption capacity, significant selectivity, and good regenerability was synthesized. Combined with the UV-Vis method, it was applied to mercury preconcentration and determination. The results indicated that the AR resin is essentially free from interferences, which can contribute to accurate determination in waters and foods. Optimization of the resin synthesis was carried out by using response surface methodology. The adsorption properties of the resin for Hg(II) were investigated by batch and column experiments. The statically and dynamic saturated adsorption capacities were 383.4 and 417.0 mg/g. The adsorption kinetic and equilibrium data were well fitted to the second-order model and the Langmuir isotherm model, respectively. Furthermore, the resin and its metal complexes were studied by Fourier transform infrared spectroscopy and thermogravimetric analysis.

scholarly journals Adsorption capability of brewed tea waste in waters containing toxic lead(II), cadmium (II), nickel (II), and zinc(II) heavy metal ions

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Hakan Çelebi ◽  
Gülden Gök ◽  
Oğuzhan Gök
Keyword(s):  
Heavy Metals ◽  
Adsorption Process ◽  
Low Cost ◽  
Adsorption Capacities ◽  
Tea Waste ◽  
Optimum Ph ◽  
Effects Of Ph ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
Adsorption Capability

Abstract Recently, the search for low-cost eco-friendly adsorbents has become one of the main objectives of researchers. The aim of this study was to test the removal of four heavy metals, namely lead (Pb), zinc (Zn), nickel (Ni) and cadmium (Cd), from a simulated watery solution using brewed tea waste as a potentially suitable adsorbent. The effects of pH levels (2.0–6.0), adsorbent amount (0.1–5.0 g), contact times (1–150 min.) were examined throughout the adsorption process. The results of the experiments showed that the heavy metals elimination yields had an inverse relationship with pH and a linear relationship between the other parameters. The optimum pH for the removal of the heavy metals was between 4.0 and 5.0 in the case of the brewed tea waste. Equilibrium times of 2, 10, 30 and 5 min were required for the adsorption of Pb, Zn, Ni, Cd onto Camellia sinensis, respectively. Based on the results of this study it can be said that brewed tea waste has a high potential to remove heavy metals from aqueous solutions. The maximum adsorption capacities were calculated as 1.197, 1.457, 1.163 and 2.468 mg/g, for Pb, Zn, Ni and Cd, respectively, by fitting the equilibrium data to the Langmuir isotherm model.

Adsorption of Copper Ions from Wastewater by Carboxymethylcellulose Sulfate

2011 ◽  
Vol 393-395 ◽  
pp. 1098-1101 ◽  
Author(s):  
Yan Yu ◽  
Feng Yuan Huang
Keyword(s):  
Contact Time ◽  
Copper Concentration ◽  
Adsorption Process ◽  
Ph Value ◽  
Copper Ions ◽  
Adsorption Capacities ◽  
Monolayer Adsorption ◽  
Optimum Ph ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model

In the present paper, the ability of carboxymethylcellulose sulfate (CMC-S) for Cu(II) removal was studied. The influence of factors, such as the pH value, the initial copper concentrations, and the contact time, were investigated in detail. Atomic absorption spectrophotometer was applied to determined the concentration of Cu(II). The results showed that the adsorption process was strongly dependent on the pH value and the initial copper concentration. The optimum pH value was in the range of 6-7. The theoretical adsorption capacities for Cu(II) was 127.7 mg/g. The equilibrium data was well fitted to the Langmuir isotherm model at 25°C, which can be explained as a monolayer adsorption.

scholarly journals Adsorption of Nickel and Chromium Ions by Amine-Functionalized Silica Aerogel

2018 ◽  
Vol 156 ◽  
pp. 03014
Author(s):  
Sudarat Sertsing ◽  
Thanaphat Chukeaw ◽  
Sitthiphong Pengpanich ◽  
Bawornpong Pornchuti
Keyword(s):  
Silica Aerogel ◽  
Solution Concentration ◽  
Functionalized Silica ◽  
Solution Ph ◽  
Chromium Ions ◽  
Amine Functionalized ◽  
Adsorption Capacities ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
Adsorption Equilibrium Data

In this study, silica aerogel was synthesized by drying at atmospheric pressure and modified further with aminopropyl triethoxysilane (APTES). The amine-functionalized silica aerogel was investigated as an adsorbent for removal of nickel and chromium ions. The effect of contact time, solution pH, and initial solution concentration were studied. The equilibrium was achieved within 60 min. The optimum pH was found to be 4. Adsorption equilibrium data were agreed fairly well with Langmuir isotherm model. Adsorption capacities for nickel and chromium ions were found to be 40.32 mg/g and 46.08 mg/g, respectively.

scholarly journals Kush - A Potential Biosorbent in the removal of Cd (II) and Zn (II) from aqueous solution

2012 ◽  
Vol 27 ◽  
pp. 107-114
Author(s):  
Jagjit Kour ◽  
P. L. Homagai ◽  
M. R. Pokherel ◽  
K. N. Ghimire
Keyword(s):  
Low Cost ◽  
Freundlich Isotherm ◽  
Isotherm Models ◽  
Order Kinetic ◽  
Waste Streams ◽  
Adsorption Capacities ◽  
Optimum Ph ◽  
Equilibrium Data ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order

The industrial discharge of heavy metals into waters' course is one of the major pollution problems affecting water quality. Therefore, they must be removed prior to their discharge into waste streams. An efficient and low-cost bioadsorbent has been investigated from Desmostachya bipinnata (Kush) by charring with concentrated sulphuric acid and functionalized with dimethylamine.It was characterised by SEM, FTIR and elemental analysis. The effect of pH, initial concentration and contact time of the metal solution was monitered by batch method. The maximum adsorption capacities were determined for Cd and Zn at their optimum pH 6. The equilibrium data were analysed using Langmuir and Freundlich isotherm models. Langmuir isotherm model fitted well and the rate of adsorption followed the pseudo second order kinetic equation.DOI: http://dx.doi.org/10.3126/jncs.v27i1.6669 J. Nepal Chem. Soc., Vol. 27, 2011 107-114  

scholarly journals High Removal Efficiency of Diatomite-Based X Zeolite for Cu2+ and Zn2+

Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6525
Author(s):  
Guangyuan Yao ◽  
Yuqiang Liu ◽  
Shuilin Zheng ◽  
Ya Xu
Keyword(s):  
Ion Exchange ◽  
Adsorption Process ◽  
Interface Properties ◽  
Order Model ◽  
Adsorption Capacities ◽  
Adsorption Data ◽  
X Zeolite ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Kinetics And Isotherms

Diatomite-based X zeolite was obtained and its crystallinity, morphology, and interface properties were investigated by XRD, BET, SEM, EDS, and XRF. The obtained X zeolite possessed a unique meso-microporous structure and showed good ion exchange properties for Cu2+ and Zn2+. The pseudo-second-order model and Langmuir isotherm model can best describe the adsorption kinetics and isotherms of Cu2+ and Zn2+, respectively. The maximal adsorption capacities of X zeolite for Cu2+ and Zn2+ were 146 and 195 mg/g at 323 K, respectively. Meanwhile, the adsorption process for Cu2+ and Zn2+ were chemical adsorption and ion exchange, respectively. Furthermore, the adsorption data turned out to be an endothermic and spontaneous process. Compared with other reported materials, the adsorption capacity of X zeolite synthesized from diatomite was among the highest. Therefore, it could be a promising adsorbent for the disposal of wastewater that contains metal ions.

scholarly journals Preparation of hydrogel reinforced with bentonite by gamma irradiation for metal absorption

2021 ◽  
Vol 10 (4) ◽  
pp. 48-55
Author(s):  
Tran To Uyen ◽  
Trinh Thi Tu Anh ◽  
Tamikazu Kume ◽  
Cao Dong Vu ◽  
Nguyen Minh Hiep ◽  
...  
Keyword(s):  
Gamma Irradiation ◽  
Adsorption Process ◽  
Absorption Spectrometry ◽  
Order Model ◽  
Adsorption Capacities ◽  
Dose Concentration ◽  
Langmuir Isotherm Model ◽  
Pseudo Second Order ◽  
Aas Method ◽  
Irradiation Technology

A natural-based sodium carboxymethyl cellulose (CMC) hydrogel reinforced with bentonite was prepared by using gamma irradiation technology. This is a novel hydrogel that uses natural polymer to absorb metal ions in wastewater. The influence of dose, concentration of CMC and bentonite on the sorption of hydrogels was investigated by atomic absorption spectrometry (AAS) method. According to the Langmuir isotherm model, the maximum adsorption capacities of CMC/bentonite hydrogel for Cu2+ and Pb2+ were 181.82 mg/g and 204.08 mg/g at room temperature, respectively. The pseudo-second-order model which describes the adsorption process of Cu2+ and Pb2+ was also studied

scholarly journals One-Step Preparation of Graphene Oxide/Cellulose Nanofibril Hybrid Aerogel for Adsorptive Removal of Four Kinds of Antibiotics

2017 ◽  
Vol 2017 ◽  
pp. 1-10 ◽  
Author(s):  
Jin Wang ◽  
Qiufang Yao ◽  
Chengmin Sheng ◽  
Chunde Jin ◽  
Qingfeng Sun
Keyword(s):  
Graphene Oxide ◽  
Adsorption Property ◽  
Isotherm Models ◽  
Cellulose Nanofibril ◽  
Order Model ◽  
Adsorption Capacities ◽  
Effective Removal ◽  
3D Network ◽  
Pseudo Second Order ◽  
One Step

Via a one-step ultrasonication method, cellulose nanofibril/graphene oxide hybrid (GO-CNF) aerogel was successfully prepared. The as-prepared GO-CNF possessed interconnected 3D network microstructure based on GO nanosheets grown along CNF through hydrogen bonds. The aerogel exhibited superior adsorption capacity toward four kinds of antibiotics. The removal percentages (R%) of these antibiotics were 81.5%, 79.5%, 79.1%, and 73.9% for Doxycycline (DXC), Chlortetracycline (CTC), Oxytetracycline (OTC), and tetracycline (TC), respectively. Simultaneously, the adsorption isotherms were well fitted to Langmuir model and kinetics study implied that the adsorption process was attributed to pseudo-second-order model. The maximum theoretical adsorption capacities of GO-CNF were 469.7, 396.5, 386.5, and 343.8 mg·g−1 for DXC, CTC, OTC, and TC, respectively, calculated by the Langmuir isotherm models. After five cycles, importantly, the regenerated aerogels still could be used with little degradation of adsorption property. Consequently, the as-synthesized GO-CNF was a successful application of effective removal of antibiotics.

Synthesis of carboxylated chitosan and its adsorption properties for cadmium (II), lead (II) and copper (II) from aqueous solutions

2009 ◽  
Vol 60 (2) ◽  
pp. 467-474 ◽  
Author(s):  
K. L. Lv ◽  
Y. L. Du ◽  
C. M. Wang
Keyword(s):  
Aqueous Solutions ◽  
Ph Value ◽  
Order Model ◽  
Adsorption Capacities ◽  
Kinetic Rates ◽  
Experimental Parameters ◽  
Exothermic Process ◽  
Equilibrium Data ◽  
Pseudo Second Order ◽  
Adsorption Equilibrium Data

Carboxylated chitosan (CKCTS) was prepared for the removal of Cd(II), Pb(II), and Cu(II) from aqueous solutions. The effects of experimental parameters such as pH value, initial concentration, contact time and temperature on the adsorption were studied. From the results we can see that the adsorption capacities of Cd(II), Pb(II), and Cu(II) increase with increasing pH of the solution. The kinetic rates were best fitted to the pseudo-second-order model. The adsorption equilibrium data were fitted well with the Langmuir isotherm, which revealed that the maximum adsorption capacities for monolayer saturation of Cd(II), Pb(II), and Cu(II) were 0.555, 0.733 and 0.827 mmol/g, respectively. The adsorption was an exothermic process.

scholarly journals Synthesis of citric acid-modified resins and their adsorption properties towards metal ions

2018 ◽  
Vol 5 (8) ◽  
pp. 171667 ◽  
Author(s):  
Xiong Liu ◽  
Longqi Xu ◽  
Yaqing Liu ◽  
Wenqi Zhou
Keyword(s):  
Citric Acid ◽  
Metal Ion ◽  
Adsorption Properties ◽  
Langmuir Model ◽  
Ion Concentration ◽  
First Order ◽  
Adsorption Capacities ◽  
Equilibrium Data ◽  
Pseudo First Order ◽  
Order Rate Equation

Types of resins anchored on citric acid were synthesized and identified. The citric acid-modified resins PS-CA, PS-O-CA and PS-N-CA were synthesized by anchoring citric acid on PS-Cl, PS-OH and PS-NH 2 , respectively. The PS-CA, PS-O-CA and PS-N-CA were used to adsorb Fe 3+ , Al 3+ , Cu 2+ , Pb 2+ , Cd 2+ and Hg 2+ . The influences of pH, adsorption time and metal ion concentration on the adsorption capacities of the resins were investigated. After optimization, PS-CA was a good adsorbent to Fe 3+ , Cu 2+ , Pb 2+ and Cd 2+ with q m values of 143.9 mg g −1 , 77.4 mg g −1 , 18.9 mg g −1 and 119.9 mg g −1 , respectively. PS-N-CA was a good adsorbent to Al 3+ and Hg 2+ with q m values of 176.6 mg g −1 and 114.9 mg g −1 , respectively. The adsorption kinetics and adsorption isotherm experiments indicated that the pseudo-first-order rate equation was more appropriate for characterizing the kinetic data and the Langmuir model was more suitable for fitting the equilibrium data. The reusability of the citric acid-modified resins was also evaluated and these resins exhibited considerable reusability.

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