Simulation Studies of Steam Reforming of Methane using Ni-Al2O3 Catalysts

2010 ◽  
Vol 8 (1) ◽  
Author(s):  
Giane Gonçalves Lenzi ◽  
Ervin Kaminski Lenzi ◽  
Cláudio Vilas Boas Fávero ◽  
Marcelo Kaminski Lenzi ◽  
Regina Maria Matos Jorge ◽  
...  
Keyword(s):  
Sol Gel ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Co2 Production ◽  
Simulation Studies ◽  
One Dimensional ◽  
Wgs Reaction ◽  
Different Characteristics ◽  
Water Gas ◽  
Al2o3 Catalyst

This paper reports the results of reforming methane into synthesis gas using industrial Ni-Al2O3 catalyst (75% NiO wt.) and Ni-Al2O3 produced by the sol gel method (8% Ni wt.). A mathematical investigation on the performance of a one-dimensional model of catalytic conventional fixed-bed reactor was developed and implemented for the process. The results indicated that the industrial catalyst favored the water gas shift (WGS) reaction increasing CO2 production. However in temperatures of 773 and 973 K the yield (H2/CH4,reacted) was more efficient for the sol-gel catalyst. This result is possibly due to the different characteristics as specific surface area and temperature reduction. The model validation for the adjustment parameters U and a1 was more efficient for temperature profiles (2% error) than for mole fraction (10% error).

scholarly journals The Demonstration of the Superiority of the Dual Ni-Based Catalytic System for the Adjustment of the H2/CO Ratio in Syngas for Green Fuel Technologies

Catalysts ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1056
Author(s):  
Suntorn Sangsong ◽  
Tanakorn Ratana ◽  
Sabaithip Tungkamani ◽  
Thana Sornchamni ◽  
Monrudee Phongaksorn ◽  
...  
Keyword(s):  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Co2 Reforming ◽  
High Temperature Water ◽  
Wgs Reaction ◽  
One Step ◽  
Water Gas ◽  
Green Fuel ◽  
Heat Released ◽  
Temperature Water

A novel dual Ni-based catalytic process (DCP) to control the H2/CO ratio of 2 in the syngas product within one step at temperature <700 °C was created and constructed. With the sequence of the catalysts located in the single reactor, the endothermic combined steam and CO2 reforming of methane (CSCRM) reaction and the exothermic ultra-high-temperature water–gas shift (UHT-WGS) reaction work continuously. During the process, the H2/CO ratio is raised suddenly at UHT-WGS after the syngas is produced from CSCRM, and CSCRM utilizes the heat released from UHT-WGS. Due to these features, DCP is more compact, enhances energy efficiency, and thus decreases the capital cost compared to reformers connecting with shift reactors. To prove this propose, the DCP tests were done in a fixed-bed reactor under various conditions (temperature = 500, 550, and 600 °C; the feed mixture (CH4, CO2, H2O, and N2) with H2O/(CH4 + CO2) ratio = 0.33, 0.53, and 0.67). According to the highest CH4 conversion (around 65%) with carbon tolerance, the recommended conditions for producing syngas with the H2/CO ratio of 2 as a feedstock of Fischer–Tropsch synthesis include the temperature of 600 °C and the H2O/(CH4 + CO2) ratio of 0.53.

scholarly journals Effect of CO2 partial pressure on dry reforming of ethanol for hydrogen production

2018 ◽  
Vol 1 (1) ◽  
pp. 6-10
Author(s):  
Fahim Fayaz ◽  
Ahmad Ziad Sulaiman ◽  
Sharanjit Singh ◽  
Sweeta Akbari
Keyword(s):  
Partial Pressure ◽  
Fixed Bed ◽  
Dry Reforming ◽  
Fixed Bed Reactor ◽  
Bet Surface Area ◽  
Impregnation Method ◽  
X Ray Diffraction ◽  
Co2 Partial Pressure ◽  
Temperature Programmed ◽  
Al2o3 Catalyst

The effect of CO2 partial pressure on ethanol dry reforming was evaluated over 5%Ce-10%Co/Al2O3 catalyst at = PCO2 = 20-50 kPa, PC2H5OH = 20 kPa, reaction temperature of 973 K under atmospheric pressure. The catalyst was prepared by using impregnation method and tested in a fixed-bed reactor. X-ray diffraction measurements studied the formation of Co3O4, spinel CoAl2O4 and CeO2, phases on surface of 5%Ce-10%Co/Al2O3 catalyst. CeO2, CoO and Co3O4 oxides were obtained during temperature–programmed calcination. Ce-promoted 10%Co/Al2O3 catalyst possessed high BET surface area of 137.35 m2 g-1. C2H5OH and CO2 conversions was improved with increasing CO2 partial pressure from 20-50 kPa whilst the optimal selectivity of H2 and CO was achieved at 50 kPa.

scholarly journals Production of CO2 in crude oil bioremediation in clay soil

2005 ◽  
Vol 48 (spe) ◽  
pp. 249-255 ◽  
Author(s):  
Sandro José Baptista ◽  
Magali Christe Cammarota ◽  
Denize Dias de Carvalho Freire
Keyword(s):  
Crude Oil ◽  
Petroleum Hydrocarbons ◽  
Clay Soil ◽  
Fixed Bed ◽  
Bacterial Count ◽  
Fixed Bed Reactor ◽  
Total Petroleum Hydrocarbons ◽  
Co2 Production ◽  
Oil And Grease ◽  
Before And After

The aim of the present work was to evaluate the biodegradation of petroleum hydrocarbons in clay soil a 45-days experiment. The experiment was conducted using an aerobic fixed bed reactor, containing 300g of contaminated soil at room temperature with an air rate of 6 L/h. The growth medium was supplemented with 2.5% (w/w) (NH4)2SO4 and 0.035% (w/w) KH2PO4. Biodegradation of the crude oil in the contaminated clay soil was monitored by measuring CO2 production and removal of organic matter (OM), oil and grease (OandG), and total petroleum hydrocarbons (TPH), measured before and after the 45-days experiment, together with total heterotrophic and hydrocarbon-degrading bacterial count. The best removals of OM (50%), OandG (37%) and TPH (45%) were obtained in the bioreactors in which the highest CO2 production was achieved.

scholarly journals Supercritical Transesterification of Palm Oil and Hydrated Ethanol in a Fixed Bed Reactor with a CaO/Al2O3 Catalyst

Energies ◽  
2012 ◽  
Vol 5 (4) ◽  
pp. 1062-1080 ◽  
Author(s):  
Ruengwit Sawangkeaw ◽  
Pornicha Tejvirat ◽  
Chawalit Ngamcharassrivichai ◽  
Somkiat Ngamprasertsith
Keyword(s):  
Palm Oil ◽  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Al2o3 Catalyst

scholarly journals Investigation on the simultaneous removal of COS, CS2 and O2 from coke oven gas by hydrogenation on a Pd/Al2O3 catalyst

2020 ◽  
Vol 10 (9) ◽  
pp. 2961-2969
Author(s):  
Eva Kamp ◽  
Holger Thielert ◽  
Olaf von Morstein ◽  
Sven Kureti ◽  
Norman Schreiter ◽  
...  
Keyword(s):  
Fixed Bed ◽  
Coke Oven ◽  
Fixed Bed Reactor ◽  
Organosulfur Compounds ◽  
Simultaneous Removal ◽  
Coke Oven Gas ◽  
Al2o3 Catalyst

Simultaneous hydrogenation of organosulfur compounds and O2 by Pd/Al2O3 catalyst was studied in a fixed bed reactor and by DRIFTS.

Modeling and Optimization of MeOH to DME in Isothermal Fixed-bed Reactor

2010 ◽  
Vol 8 (1) ◽  
Author(s):  
Mohammad Farsi ◽  
Abdolhossein Jahanmiri ◽  
Reza Eslamloueyan
Keyword(s):  
Fixed Bed ◽  
Methanol Conversion ◽  
Fixed Bed Reactor ◽  
Methanol Dehydration ◽  
Algebraic Equations ◽  
Optimal Temperature ◽  
Heterogeneous Model ◽  
One Dimensional ◽  
Shell And Tube ◽  
Green Fuel

Dimethyl ether (DME) is a green fuel that commercially produced in an adiabatic fixed bed reactor by methanol dehydration. In the present work, a shell and tube fixed bed reactor is modeled and optimized for DME production. The reactor is modeled based on mass and energy conservation equations as well as auxiliary equations. In order to estimate the DME production and temperature profile along the reactor, a one dimensional heterogeneous model consist of a set of nonlinear differential and algebraic equations has been solved numerically. Also, The DME production in the isothermal reactor is maximized by adjusting the optimal temperature distribution along the reactor using genetic algorithm. Then, the performance of the proposed isothermal reactor is compared with industrial adiabatic fixed bed reactor. Results showed the higher DME production rate and methanol conversion in the optimized reactor.

Synthesis of CeO2 Supported BaCoO3 Perovskites for Chemical-Looping Methane Reforming to Syngas and Hydrogen

2017 ◽  
Author(s):  
Haoran Ding ◽  
Yongqing Xu ◽  
Linyi Xiang ◽  
Qiyao Wang ◽  
Cheng Shen ◽  
...  
Keyword(s):  
Photoelectron Spectroscopy ◽  
Sol Gel ◽  
Fixed Bed ◽  
Gas Production ◽  
Fixed Bed Reactor ◽  
Methane Reforming ◽  
Chemical Looping ◽  
X Ray ◽  
Syngas Production ◽  
Fuel Reactor

In order to reduce the hotspots in partial oxidation of methane, CeO2 supported BaCoO3 perogvskite-type oxides were synthesized using a sol-gel method and applied in chemical-looping steam methane reforming (CL-SMR). The synthesized BaCoO3-CeO2 was characterized by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). XRD and XPS results suggested that the obtained BaCoO3 was pure crystalline perovskite, its crystalline structure and lattice oxygen could regenerate after calcining. The reactivity of perovskite-type oxides in CL-SMR was evaluated using a fixed-bed reactor. Gas production rates and H2/CO ratios showed that the optimal reaction temperature was about 860 °C and the properly reaction time in fuel reactor was about 180s when Weight Hourly Space Velocity (WHSV) was 23.57 h−1. The syngas production in fuel reactor were 265.11 ml/g, hydrogen production in reforming reactor were 82.53 ml/g. (CSPE)

Low-concentration methane combustion over a Cu/γ-Al2O3 catalyst: effects of water

RSC Advances ◽  
2015 ◽  
Vol 5 (24) ◽  
pp. 18915-18921 ◽  
Author(s):  
Haojie Geng ◽  
Zhongqing Yang ◽  
Jingyu Ran ◽  
Li Zhang ◽  
Yunfei Yan ◽  
...  
Keyword(s):  
Methane Oxidation ◽  
Fixed Bed ◽  
Methane Combustion ◽  
Fixed Bed Reactor ◽  
Low Concentration ◽  
Influence Of Water ◽  
Al2o3 Catalyst

The influence of water on low-concentration methane oxidation over a Cu/γ-Al2O3 catalyst was investigated in a fixed bed reactor.

Experimental and Simulation Studies of TAME Synthesis in a Fixed-Bed Reactor

2007 ◽  
Vol 46 (4) ◽  
pp. 1105-1113 ◽  
Author(s):  
Manuela V. Ferreira ◽  
Ana M. Ribeiro ◽  
José M. Loureiro
Keyword(s):  
Fixed Bed ◽  
Fixed Bed Reactor ◽  
Simulation Studies
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