scholarly journals Chemical and isotopic signatures of hot springs from east-central Sonora State, Mexico: a new prospection survey of promissory low-to-medium temperature geothermal systems

2018 ◽  
Vol 35 (2) ◽  
pp. 116-141 ◽  
Author(s):  
Erika Almirudis ◽  
Edgar R. Santoyo-Gutiérrez ◽  
Mirna Guevara ◽  
Francisco Paz-Moreno ◽  
Enrique Portugal

A promissory low-to-medium temperature geothermal system located in Sonora (Mexico) has been studied. In the present work, a detailed geochemical survey was carried out to understand the hydrogeochemical signatures of hot spring waters. A field work campaign was conducted for collecting water samples from twelve hot springs placed in four major zones (NW, NE, C, and S). The collected samples were analysed by chemical and isotopic methods for determining their chemical (major and trace elements) and isotopic (18O/16O and D/H) compositions. Using geochemometric analyses of the fluid composition and fractionation, depletion and enrichment processes exhibited by major and trace elements were analysed. Hydrogeochemical classification was used to indicate the presence of sodium-sulphate (Na-SO4) waters in the North (NW and NE) and South hydrothermal zones; whereas calcium-magnesium-bicarbonate (Ca-Mg-HCO3) waters were identified for the Central zone. Some hot spring waters located in the NE zone were also typified as sodium-bicarbonate (Na-HCO3). In relation to the isotopic signatures of 18O/16O and D/H, four water samples from NE and C zones lie near to the global meteoric water line; whereas the remaining eight samples showed a shift for both oxygen and deuterium isotopes. A mixing line with a small shift of δ18O was identified and used as a proxy to discriminate waters with different isotopic signatures. After applying a geochemometric outliers detection/rejection and an iterative ANOVA statistical test, the mean temperature inferred from the most reliable solute geothermometers was 149±40 °C, which suggests to be considered as the minimum value of the reservoir temperature. As most of the hot spring waters fall outside of the full equilibrium curve, the original reservoir conditions were corrected by using a mixing conductive model, which predicted a deep equilibrium temperature of 210±11 °C. As this temperature is considerably higher than the mean temperature inferred from the geothermometers, it was suggested as an optimistic maximum reservoir temperature of the Sonora geothermal system. Using 150 °C and 200 °C as rounded-off reservoir temperatures (or min-max estimates), geochemical equilibria modelling based on fluid-mineral stability diagrams was carried out. An equilibrium process among local hydrothermal waters and albite-potassium feldespar and muscovite-prehnite-laumontite mineral assemblages was found. These minerals were proposed as representative mineral assemblages of low-grade metamorphism, which seems to indicate that the geothermal fluid equilibria were probably reached within the intermediate to acidic volcanic rocks from the Tarahumara Formation.

2021 ◽  
Vol 13 (1) ◽  
pp. 820-834
Author(s):  
Jun Ma ◽  
Zhifang Zhou

Abstract The exploration of the origin of hot spring is the basis of its development and utilization. There are many low-medium temperature hot springs in Nanjing and its surrounding karst landform areas, such as the Tangshan, Tangquan, Lunshan, and Xiangquan hot springs. This article discusses the origin characters of the Lunshan hot spring with geological condition analysis, hydrogeochemical data, and isotope data. The results show that the hot water is SO4–Ca type in Lunshan area, and the cation content of SO4 is high, which are related to the deep hydrogeological conditions of the circulation in the limestone. Carbonate and anhydrite dissolutions occur in the groundwater circulation process, and they also dominate the water–rock interaction processes in the geothermal reservoir of Lunshan. The hot water rising channels are deeply affected by the NW and SN faults. Schematic diagrams of the conceptual model of the geothermal water circulation in Lunshan are plotted. The origin of Tangshan, Tangquan, and Xiangquan hot springs are similar to the Lunshan hot spring. In general, the geothermal water in karst landforms around Nanjing mainly runs through the carbonate rock area and is exposed near the core of the anticlinal structure of karst strata, forming SO4–Ca/SO4–Ca–Mg type hot spring with the water temperature less than 60°C. The characters of the hot springs around Nanjing are similar, which are helpful for the further research, development, and management of the geothermal water resources in this region.


1996 ◽  
Vol 76 (2) ◽  
pp. 165-171 ◽  
Author(s):  
Z. Q. Lin ◽  
W. H. Hendershot ◽  
P. H. Schuepp ◽  
G. G. Kennedy ◽  
P. Dutilleul

Major and trace elements (Al, As, Ba, Ca, Cd Co, Cr Cs, Cu Eu Fe, Hf, K, La, Lu, Mg, Mn, Na, Ni, Pb, Rb, Sb, Sc, Si, Sm, Sr, Ta, Tb, Th, Ti, U, V, Yb and Zn) in forest soils from three acid-deposition-affected locations in southern Quebec were investigated. Total element concentrations in the surface layer (0–20 cm) of the Podzolic soils were mostly well within the range of element concentrations in Podzols reported worldwide but showed higher mean values for most elements. The mean concentrations of elements (except Zn, at 124 μg g−1) were also generally comparable to the respective elemental baseline data established for Canadian soils. Element concentrations (μg g−1) of Cs (6.2) Sc (19 8) V (106) Rb (194) K (26 500) and Al (76 900) in the surface soils were significantly higher at the 940-m elevation than the concentrations from the sites at 650 and 770 m along the Roundtop Mountain slope, but Ca (1120) and Ni (4.4) were lowest at the 940-m elevation A similar trend with elevation was not observed at the other mountain location (White Peak). Enrichment-factor (EF) analysis showed significant element enrichment (EF ≥ 10) for Cd, Rb and Sb but impoverishment (EF ≤ 0.1) for Ca, Cu and Ni in topsoils. Key words: Major and trace elements, surface soils, acid deposition


Author(s):  
Bolormaa Ch ◽  
Oyuntsetseg D ◽  
Bolormaa O

In this study, we collected hot spring water sample from Otgontenger, Tsetsuukh, Zart, Ulaan Khaalga and Khojuul in Zavkhan province. The purpose of this study is to determine the temperature of geothermal water and its depth which based on the hydrochemical component. Hot spring water analyses showed that temperature ranges between 33.4 to 45.5°C, pH ranges 8.40 to 9.56, and the total dissolved solid amount was 170 to 473 mg/L. From the result of hydrochemical analyses, hot spring samples were included in SO4-Na and HCO3-Na type. In comparison to other hot spring samples, Tsetsuukh hot spring has shown negative oxidation reduction potential, -0.8 mV and dissolved hydrogen, 0.22 mg/L. Therefore, it has a higher ability for medical treatment than other hot spring water due to its reduction state. The reservoir temperature of these hot springs is calculated by several geothermometer methods, and temperatures ranged between 102оC to 149оC. According to this result, it assumed that geothermal water with low temperature which has the ability to use for room heating and producing energy by the binary system. Thus, we determined that reservoir depth is 1.3 to 3.7 km using annual average surface and reservoir temperature, and regional geothermal gradient. Завхан аймгийн халуун рашаануудын химийн найрлага, геотермометрийн судалгаа Хураангуй: Бид энэхүү судалгааны ажлаар Завхан аймгийн нутагт орших Отгонтэнгэр, Зарт, Цэцүүх, Улаан хаалга, Хожуулын халуун рашаануудын гидрохимийн найрлагыг нарийвчлан тогтоосоны үндсэн дээр тухайн рашаануудын газрын гүний халуун усны температур болон гүнийг тогтоох зорилго тавин ажиллаа. Завхан аймгийн рашаанууд нь халуун 33.4-45.5°C температуртай, шүлтлэг орчинтой (pH 8.4-9.56), 170-473 мг/л хүртэл эрдэсжилттэй, HCO3-Na болон SO4-Na-ийн төрлийн халуун рашааны ангилалд хамаарагдаж байна. Эдгээр рашаануудаас Цэцүүхийн халуун рашааны исэлдэн ангижрах потенциал нь -0.8 мВ, ууссан устөрөгчийн агуулга 0.22 мг/л илэрсэн нь судалгаанд хамрагдсан бусад рашаануудтай харьцуулахад ангижрах төлөвт оршиж байгаа бөгөөд илүү эмчилгээний идэвхтэй болохыг харуулж байна. Судалгаанд хамрагдсан халуун рашаануудын гүний температурыг химийн найрлагаас нь хамааруулан хэд хэдэн геотермометрийг ашиглан тооцоход дунджаар 102-149oС байсан ба энэ нь бага температуртай усны ангилалд хамаарагдаж байгаа учир тухайн халуун усны нөөцийг өрөө тасалгаа халаах болон бинари системийг ашиглан цахилгаан гаргаж авах боломжтой байна. Мөн Завхан аймгийн халуун рашаануудын газрын гүний халуун усны нөөц нь газрын гадаргаас доош 1.3-3.7 км-ийн гүнд байрладаг болохыг орд дээрх температур, газрын гүний халуун усны температур болон бүс нутгийн геотермал градиентад үндэслэн тооцоолон тодорхойллоо. Түлхүүр үг: Гидрохими, халуун рашаан, геотермометр, гүний температур.


2012 ◽  
Vol 3 ◽  
pp. 34-40
Author(s):  
Hendrik Tjiawi ◽  
Andrew C. Palmer ◽  
Grahame J. H. Oliver

 The existence of hot springs coupled with the apparent anomalous high heat flow has sparked interest in the potential for geothermal development in Singapore. This geothermal resource may be potentially significant and could be exploited through Engineered Geothermal System (EGS) technology, i.e. a method to create artificial permeability at depth in granitic or sandstone formations as found under Singapore. The apparently ever-increasing fossil fuel price has made the cost of using the EGS technology more viable than it was in the past. Thus, to assess the resource, a numerical model for the geothermal reservoir has been constructed. Mass and heat flows in the system are simulated in 2D with AUTOUGH2.2, and the graphical interface processed through MULGRAPH2.2. Natural state calibration was performed to match both the observed and the expected groundwater profile, and also to match the hot water upflow at the Sembawang hot spring, with simulated flowrate matching the hot spring natural flowrate. The simulation gives an encouraging result of 125 - 150 °C hot water at depth 1.25 – 2.75 km.


2014 ◽  
Vol 886 ◽  
pp. 489-495
Author(s):  
Ze De Liang ◽  
Shu Jie Wang

The main geothermal resources in China are low or medium-temperature geothermal resources, these are more than 3000 hot springs, which of above 60 °C account for 24 percent of total, those are more than 720. In these hot springs bases for tourism and leisure and spa medical, the demand of electricity and air-conditioning is relatively large, so these is a very important practical significance to develop low or medium-temperature geothermal resources technology. If hot springs geothermal system uses lithium bromide-water azeotropic binary mixtures as working fluid, which not only reduces the heat loss of temperature difference, but also plays the advantages in thermodynamics and environmental aspects. Three systems of this article described all use water vapor as the working fluid, their characteristics are analyzed and compared, respectively. By analysis found that: when the demand is only for power generation and non-condensable gas content in hot springs geothermal water is not too high, the single-stage flash evaporation electrical system is more favorable; because of hot springs primarily for leisure travel and medical care function, and the demand for air conditioning and refrigeration is also large, so the combined system is more favorable.


2020 ◽  
Vol 1 (1) ◽  
pp. 56-63
Author(s):  
Fajar Rizki Widiatmoko ◽  
Mochammad Nur Hadi ◽  
Dedi Kusnadi ◽  
Sachrul Iswahyudi ◽  
Fadlin Fadlin

Wae Sano volcano is included in the inner Banda arc, Mount Wae Sano is a type C volcano and formed the Sano Nggoang crater lake. The magmatism activity produces geothermal manifestations such as; hot spring, rock alteration, and sulfur deposits, the hottest water temperature is 81 0C, with neutral pH, but the Sano Nggoang Lake water has acid pH. It becomes interesting to examine the characteristics of the geothermal system in that area. The research was conducted by Volcanostratigraphic studies to reconstruct the geological process and Geochemical sampling of hot springs, lake water, ground air, and the soil side to understand the subsurface characterization. The result showing some period of volcano products, with the youngest come from the product of Sano Nggoang 2 that spills its product to on the north-east side of Poco Dedeng volcano. The geochemical analysis shows all manifestations originate from one reservoir, chloride water type, NaCl type of the lake water with a few SO4 influence, presumably, the hot springs supply is influenced by seawater, the estimation of the reservoir has a temperature about ± 230 0C, with dacite and the rich organic sedimentary rock, and located at ± 1456 m from the manifestation, the isothermal section shows the rate of temperature increase at 97.07 m / 10 0C. The hypothetical resource is counted about 1,488.6 kWe.


2012 ◽  
Vol 6 (2) ◽  
pp. 33-36
Author(s):  
Helda Handayani

Suli hot springs area has a low level of acidity or neutral pH ranges (7,2–7,7). It is also supported by a high chloride concentration value, which ranges (208,87-226,27) ppm. Thisshows that the area on station 1, 2, 3, and 4 are located in areas with water flow into the upper reservoir (upflow) and belongs to hot water domination reservoir tipe (water heatedreservoir). Reservoir temperature is calculated by the formula geotermometer (SiO2)p considered whether applied in the four kinds geotermometer equation because it gives the calculation results are not much different temperature and has a value of rms-error is less than 2%. Reservoir temperature at a hot springs station Suli possible temperature (161 ± 0,9)oC. Reservoir temperature at station 2 hot spring Suli possible hot water temperature (172 ± 1,0)oC. Reservoir temperature at station 3 hot springs Suli possible temperature (171 ±0,9)oC. Reservoir temperature at station 4 hot springs Suli possible temperature (169 ± 1,0)oC.


Author(s):  
Mochamad Iqbal ◽  
Bella Restu Juliarka ◽  
Wijayanti Ashuri ◽  
Bilal Al Farishi

Natar Hot Spring is one of the geothermal manifestations that is located in Lampung Province, Indonesia. About 6 km to the east, another hot spring appears with temperature around 40°C with neutral pH called Cisarua Hot Spring. The Natar Hot Spring itself having temperature 47-54°C with 6.23 pH. Based on the geologic map, the appearance of these hot spring is caused by Lampung-Panjang Fault which trending northwest-southeast. Morphology of the research area is showing a flat terrain topography which composed of Quaternary volcanic rock and metamorphic rock in the basement. The nearest volcano that expected to be the heat source of the geothermal system is the Quaternary extinct volcano called Mt. Betung which is located about 15 km to the southwest. The aim of the study is to analyze the geochemistry of the manifestations and calculate the reservoir temperature. Geochemistry analysis result shows both manifestations are bicarbonate which is formed as a steam-heated water or steam condensates. Geothermometer calculation shows that the geothermal reservoir has temperature 150-160°C with approximately 300 m in depth. All manifestations are originated from meteoric water according to stable isotope analysis D and δ18O data and interacting with carbonate-metamorphic rock beneath the surface based on 13C isotope value. A further geophysics study is needed to determine where the heat comes from.


2003 ◽  
Vol 40 (11) ◽  
pp. 1443-1446 ◽  
Author(s):  
Allan Pentecost ◽  
B Jones ◽  
R W Renaut

The response of researchers to a questionnaire on the definitions of hot, thermal, warm, and cold springs is provided. Two important benchmarks are recognized, the human body temperature and the mean annual local air temperature. While no scheme can claim to provide an objective, unbiased classification, waters emerging with a temperature in excess of the core human body temperature of 36.7 °C should be defined as hot springs. The term "thermal spring" is not recommended as it cannot be defined satisfactorily for all springs. The term "warm spring" is not considered utilitarian.


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