scholarly journals Spatiotemporally Programmable Metasurfaces via Viscoelastic Shell Snapping

Author(s):  
Yuzhen Chen ◽  
Tianzhen Liu ◽  
Lihua Jin

Many species can dynamically alter their skin textures to enhance their motility and survivability. Despite the enormous efforts on designing bio-inspired materials with tunable surface textures, developing spatiotemporally programmable and reconfigurable textural morphing without complex control remains challenging. Here we propose a design strategy to achieve metasurfaces with such properties. The metasurfaces comprise an array of unit cells with broadly tailored temporal responses. By arranging the unit cells differently, the metasurfaces can exhibit various spatiotemporal responses, which can be easily reconfigured by disassembling and rearranging the unit cells. Specifically, we adopt viscoelastic shells as the unit cells, which can be pneumatically actuated to a concave state, and recover the initial convex state some time after the load is removed. We computationally and experimentally show that the recovery time can be widely tuned by the geometry and material viscoelasticity of the shells. By assembling such shells with different recovery time, we build metasurfaces with pre-programmed spatiotemporal textural morphing under simple pneumatic actuation, and demonstrate temporal evolution of patterns, such as digit numbers and emoji, and spatiotemporal control of friction. This work opens up new avenues in designing spatiotemporal morphing metasurfaces that could be employed for programming mechanical, optical and electrical properties. Corresponding author: Lihua Jin, Email:   [email protected]  

2021 ◽  
Author(s):  
Caleb Meredith ◽  
Alexander Castonguay ◽  
Yu-Jen Chiu ◽  
Allan M. Brooks ◽  
Pepijn Moerman ◽  
...  

<p>The study of active colloidal microswimmers with tunable phoretic and self-organizational behaviors is important for understanding out-of-equilibrium systems and the design of functional, adaptive matter. Solubilizing, self-propelling droplets have emerged as a rich chemical platform for exploration of active behaviors, but isotropic droplets rely on spontaneous symmetry breaking to sustain motion. The introduction of permanent asymmetry, e.g. in the form of a biphasic Janus droplet, has not been explored previously as a comprehensive design strategy for active droplets, despite the widespread use of Janus structures in motile solid particles. Here, we uncover the chemomechanical framework underlying the self-propulsion of active, biphasic Janus oil droplets solubilizing in aqueous surfactant. We elucidate how droplet propulsion is influenced by the degree of oil mixing, droplet shape, and oil solubilization rates for a range of oil combinations. A key finding is that for droplets containing both a mobile (solubilizing) and non-mobile oil, the degree of partitioning of the mobile oil across the Janus droplets’ oil-oil interface plays a pivotal role in determining the droplet speed and swimming direction. As a result, we observe propulsion speeds of Janus droplets more than an order-of-magnitude faster than chasing pairs of single emulsion droplets which lack an oil-oil interface. In addition, spatiotemporal control over droplet swimming speed and orientation is demonstrated through the application of local thermal gradients applied via induced via joule heading and laser spot illumination. We also explore the interactions between collections of Janus droplets including the spontaneous formation of multi-droplet spinning clusters that rotate predictably based on symmetry. Our findings provide key insights as to how the chemistry and structure of multiphase fluids can be harnessed to design microswimmers with programmable active and collective behaviors.</p><br>


2008 ◽  
Vol 4 (S257) ◽  
pp. 57-59
Author(s):  
I. Dorotovič ◽  
K. Kudela ◽  
M. Lorenc ◽  
T. Pintér ◽  
M. Rybanský

AbstractIn our recent paper (Dorotovič et al. 2008a) we focused on a study of the Forbush decrease (FD) of January 17–18 and 21–22, 2005. It was shown that the corresponding recovery time can depend on the density of high-energy protons in the CME matter. In this paper we identified several additional events in the period between 1995 and 2007. We found that the majority of FDs studied is accompanied by an abrupt count increase in the proton channel P1 and by a simultaneous decrease in the channel P7 (GOES). However, the analysis of temporal evolution of all FDs did not confirm the hypothesis on different recovery time after FD as a function of the energy distribution of the particles penetrating into radiation belts of the Earth.


2021 ◽  
Author(s):  
Caleb Meredith ◽  
Alexander Castonguay ◽  
Yu-Jen Chiu ◽  
Allan M. Brooks ◽  
Pepijn Moerman ◽  
...  

<p>The study of active colloidal microswimmers with tunable phoretic and self-organizational behaviors is important for understanding out-of-equilibrium systems and the design of functional, adaptive matter. Solubilizing, self-propelling droplets have emerged as a rich chemical platform for exploration of active behaviors, but isotropic droplets rely on spontaneous symmetry breaking to sustain motion. The introduction of permanent asymmetry, e.g. in the form of a biphasic Janus droplet, has not been explored previously as a comprehensive design strategy for active droplets, despite the widespread use of Janus structures in motile solid particles. Here, we uncover the chemomechanical framework underlying the self-propulsion of active, biphasic Janus oil droplets solubilizing in aqueous surfactant. We elucidate how droplet propulsion is influenced by the degree of oil mixing, droplet shape, and oil solubilization rates for a range of oil combinations. A key finding is that for droplets containing both a mobile (solubilizing) and non-mobile oil, the degree of partitioning of the mobile oil across the Janus droplets’ oil-oil interface plays a pivotal role in determining the droplet speed and swimming direction. As a result, we observe propulsion speeds of Janus droplets more than an order-of-magnitude faster than chasing pairs of single emulsion droplets which lack an oil-oil interface. In addition, spatiotemporal control over droplet swimming speed and orientation is demonstrated through the application of local thermal gradients applied via induced via joule heading and laser spot illumination. We also explore the interactions between collections of Janus droplets including the spontaneous formation of multi-droplet spinning clusters that rotate predictably based on symmetry. Our findings provide key insights as to how the chemistry and structure of multiphase fluids can be harnessed to design microswimmers with programmable active and collective behaviors.</p><br>


2018 ◽  
Vol 140 (8) ◽  
pp. 2805-2811 ◽  
Author(s):  
Cai Sun ◽  
Gang Xu ◽  
Xiao-Ming Jiang ◽  
Guan-E Wang ◽  
Pei-Yu Guo ◽  
...  

Author(s):  
R.M. Glaeser ◽  
S.B. Hayward

Highly ordered or crystalline biological macromolecules become severely damaged and structurally disordered after a brief electron exposure. Evidence that damage and structural disorder are occurring is clearly given by the fading and eventual disappearance of the specimen's electron diffraction pattern. The fading and disappearance of sharp diffraction spots implies a corresponding disappearance of periodic structural features in the specimen. By the same token, there is a oneto- one correspondence between the disappearance of the crystalline diffraction pattern and the disappearance of reproducible structural information that can be observed in the images of identical unit cells of the object structure. The electron exposures that result in a significant decrease in the diffraction intensity will depend somewhat upon the resolution (Bragg spacing) involved, and can vary considerably with the chemical makeup and composition of the specimen material.


Author(s):  
Eugene J. Amaral

Examination of sand grain surfaces from early Paleozoic sandstones by electron microscopy reveals a variety of secondary effects caused by rock-forming processes after final deposition of the sand. Detailed studies were conducted on both coarse (≥0.71mm) and fine (=0.25mm) fractions of St. Peter Sandstone, a widespread sand deposit underlying much of the U.S. Central Interior and used in the glass industry because of its remarkably high silica purity.The very friable sandstone was disaggregated and sieved to obtain the two size fractions, and then cleaned by boiling in HCl to remove any iron impurities and rinsed in distilled water. The sand grains were then partially embedded by sprinkling them onto a glass slide coated with a thin tacky layer of latex. Direct platinum shadowed carbon replicas were made of the exposed sand grain surfaces, and were separated by dissolution of the silica in HF acid.


Author(s):  
T. Schober

Nb, Ta and V are prototype substances for the study of the endothermic reactions of H with metals. Such metal-hydrogen reactions have gained increased importance due to the application of metal-hydrides in hydrogen- und heat storage devices. Electron microscopy and diffraction were demonstrated to be excellent methods in the study of hydride morphologies and structures (1). - Figures 1 and 2 show the NbH and TaH phase diagrams (2,3,4). EM techniques have contributed substantially to the elucidation of the structures and domain configurations of phases β, ζ and ε (1,4). Precision length measurement techniques of distances in reciprocal space (5) recently led to a detailed understanding of the distortions of the unit cells of phases ζ and ε (4). In the same work (4) the existence of the new phase η was shown. It is stable near -68 °C. The sequence of transitions is thus below 70 %.


Author(s):  
A. F. Marshall ◽  
J. W. Steeds ◽  
D. Bouchet ◽  
S. L. Shinde ◽  
R. G. Walmsley

Convergent beam electron diffraction is a powerful technique for determining the crystal structure of a material in TEM. In this paper we have applied it to the study of the intermetallic phases in the Cu-rich end of the Cu-Zr system. These phases are highly ordered. Their composition and structure has been previously studied by microprobe and x-ray diffraction with sometimes conflicting results.The crystalline phases were obtained by annealing amorphous sputter-deposited Cu-Zr. Specimens were thinned for TEM by ion milling and observed in a Philips EM 400. Due to the large unit cells involved, a small convergence angle of diffraction was used; however, the three-dimensional lattice and symmetry information of convergent beam microdiffraction patterns is still present. The results are as follows:1) 21 at% Zr in Cu: annealed at 500°C for 5 hours. An intermetallic phase, Cu3.6Zr (21.7% Zr), space group P6/m has been proposed near this composition (2). The major phase of our annealed material was hexagonal with a point group determined as 6/m.


Author(s):  
W. Chiu ◽  
M.F. Schmid ◽  
T.-W. Jeng

Cryo-electron microscopy has been developed to the point where one can image thin protein crystals to 3.5 Å resolution. In our study of the crotoxin complex crystal, we can confirm this structural resolution from optical diffractograms of the low dose images. To retrieve high resolution phases from images, we have to include as many unit cells as possible in order to detect the weak signals in the Fourier transforms of the image. Hayward and Stroud proposed to superimpose multiple image areas by combining phase probability distribution functions for each reflection. The reliability of their phase determination was evaluated in terms of a crystallographic “figure of merit”. Grant and co-workers used a different procedure to enhance the signals from multiple image areas by vector summation of the complex structure factors in reciprocal space.


Author(s):  
W. Baumeister ◽  
R. Rachel ◽  
R. Guckenberger ◽  
R. Hegerl

IntroductionCorrelation averaging (CAV) is meanwhile an established technique in image processing of two-dimensional crystals /1,2/. The basic idea is to detect the real positions of unit cells in a crystalline array by means of correlation functions and to average them by real space superposition of the aligned motifs. The signal-to-noise ratio improves in proportion to the number of motifs included in the average. Unlike filtering in the Fourier domain, CAV corrects for lateral displacements of the unit cells; thus it avoids the loss of resolution entailed by these distortions in the conventional approach. Here we report on some variants of the method, aimed at retrieving a maximum of information from images with very low signal-to-noise ratios (low dose microscopy of unstained or lightly stained specimens) while keeping the procedure economical.


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