scholarly journals Effects of organic matter and clay content in soil on pesticide adsorption processes

2009 ◽  
Vol 24 (1) ◽  
pp. 51-57 ◽  
Author(s):  
Rada Djurovic ◽  
Jelena Gajic-Umiljendic ◽  
Tijana Djordjevic

The effect of organic matter and clay content on the adsorption of atrazine, acetochlor, clomazone, pendimethalin and oxyfluorfen in soil samples was studied. In order to determine whether and to what degree different soil properties affect the process of determination of selected pesticides, three soils with different clay and organic matter contents were used. An optimized liquid-solid extraction procedure followed by SPME measurement was applied to analyze the selected pesticides in soil samples. Detection and quantification were done by gas chromatography-mass spectrometry (GC/MS). Relative standard deviation (RSD) values for multiple analyses of soil samples fortified at 30 ?g/kg of each pesticide were below 19%. Limits of detection (LODs) for all compounds studied were less than 2 ?g/kg. The results indicate that soils with different physic-chemical properties have different effects on the adsorption of most pesticides, especially at higher concentration levels.

2012 ◽  
Vol 27 (3) ◽  
pp. 239-244 ◽  
Author(s):  
Rada Djurovic ◽  
Tijana Djordjevic ◽  
Ljiljana Radivojevic ◽  
Ljiljana Santric ◽  
Jelena Gajic-Umiljendic

A multiresidue method for simultaneous determination of four pesticides (diazinon, acetochlor, aldrine and carbofuran) belonging to different pesticide groups, extracted from soil samples, is described. The method presented is based on liquid-solid extraction (LSE) and determination of pesticides, i.e. the pesticides were extracted by methanol- acetone mixture, purified on florisil column and eluted by ethyl acetate-acetone mixture. Optimization of the main parameters affecting the LSE procedure, such as the choice of purification sorbent, as well as the elution solvent and its volume, were investigated in details and optimized. Also, validation of the proposed method was done. Gas chromatography-mass spectrometry (GC-MS) was used for detection and quantification of the pesticides studied. Relative standard deviation (RSD) and recovery values for multiple analysis of soil samples fortified with 30 ?g/kg of each pesticide were below 8% and higher than 89%, respectively. Limits of detection (LOD) for all the compounds studied were less than 4 ?g/kg.


2016 ◽  
Vol 81 (8) ◽  
pp. 923-934 ◽  
Author(s):  
Rada Djurovic-Pejcev ◽  
Tijana Djordjevic ◽  
Vojislava Bursic

A method is described for simultaneous determination of five herbicides (metribuzin, acetochlor, clomazone, oxyfluorfen and dimethenamid) belonging to different pesticides groups in soil samples. Developed headspace solid phase microextraction method (HS-SPME) in combination with liquid-solid sample preparation (LS) was optimized and applied in the analysis of some agricultural samples. Optimization of microextraction conditions, such as temperature, extraction time and sodium chloride (NaCl) content was perfor-med using 100 ?m polydimethyl-siloxane (PDMS) fiber. The extraction effi-ciencies of methanol, methanol:acetone=1:1 and methanol:acetone:hexane= =2:2:1 and the optimum number of extraction steps during the sample prepa-ration, were tested, as well. Gas chromatography-mass spectrometry (GC-MS) was used for detection and quantification, obtaining relative standard deviation (RSD) below 13%, and recovery values higher than 83% for multiple analyses of soil samples fortified at 30 ?g kg-1 of each herbicide. Limits of detection (LOD) were less than 1.2 ?g kg-1 for all the studied herbicides.


2008 ◽  
Vol 23 (4) ◽  
pp. 265-271 ◽  
Author(s):  
Rada Djurovic ◽  
Jelena Gajic-Umiljendic ◽  
Tijana Djordjevic

A solid phase microextraction (SPME) method for simultaneous determination of atrazine, acetochlor, clomazone, pendimethalin and oxyfluorfen in soil samples was developed. The method is based on a combination of conventional liquid-solid procedure and a following SPME determination of the selected pesticides. Initially, various microextraction conditions, such as the fibre type, desorption temperature and time, extraction time and NaCl content, were investigated and optimized. Then, extraction efficiencies of several solvents (water, hexane, acetonitrile, acetone and methanol) and the optimum number of extraction steps within the sample preparation step were optimized. According to the results obtained in these two sets of experiments, two successive extractions with methanol as the extraction solvent were the optimal sample preparation procedure, while the following conditions were found to be most efficient for SPME measurements: 100 ?m PDMS fibre, desorption for 7 min at 2700C, 30 min extraction time and 5% NaCl content (w/v). Detection and quantification were done by gas chromatography-mass spectrometry (GC/MS). Relative standard deviation (RSD) values for multiple analysis of soil samples fortified at 30 ?g/kg of each pesticide were below 19%. Limits of detection (LOD) for all the compounds studied were less than 2 ?g/kg.


2012 ◽  
Vol 518-523 ◽  
pp. 2348-2351
Author(s):  
Shan Shan He ◽  
Yu Jun Wang ◽  
Ling Cao ◽  
Yan Xin Wang ◽  
Chuang Ju Dong

A focused microwave-assisted extraction (FMAE) was optimized and coupled to gas chromatography–mass spectrometry for the determination of organochlorine pesticides in soil samples. According to the result, the combination of 20 min extraction time at 48 °C and a mixture of 1+1 of n-hexane-acetone as extraction solvent is the best conditions. The recovery values is 72.8%~96.4% in the above conditions. The relative standard deviation was 4.39%~13.18%. We have good recovery values when spiked 20ng, 40ng and 60ng standard into 5.00g soil sample.


Separations ◽  
2021 ◽  
Vol 8 (3) ◽  
pp. 35
Author(s):  
Jason Hoisington ◽  
Jason S. Herrington

A canister-based sampling method along with preconcentrator-Gas chromatography-Mass Spectrometry (GC-MS) analysis was applied to ethylene oxide (EtO or EO) and 75 other volatile organic compounds (VOCs) in ambient air. Ambient air can contain a large variety of VOCs, and thorough analysis requires non-discriminatory sampling and a chromatographic method capable of resolving a complex mixture. Canister collection of whole air samples allows for the collection of a wide range of volatile compounds, while the simultaneous analysis of ethylene oxide and other VOCs allows for faster throughput than separate methods. The method presented is based on US EPA Method TO-15A and allows for the detection of EtO from 18 to 2500 pptv. The method has an average accuracy of 104% and precision of 13% relative standard deviation (RSD), with an instrument run time of 32 min. In addition, a link between canister cleanliness and ethylene oxide growth is observed, and potential mechanisms and cleaning strategies are addressed.


2016 ◽  
Vol 41 (4) ◽  
pp. 735-757 ◽  
Author(s):  
NC Shil ◽  
MA Saleque ◽  
MR Islam ◽  
M Jahiruddin

Laboratory studies on soil fertility evaluation was carried out across major agroecological zones (AEZs) of Bangladesh to know the nutrient status of soils and to relate those with soil properties like pH, organic matter, CEC, and clay content. Thirty five composite soil samples were collected from intensive crop growing sites, which covered 17 AEZs of Bangladesh. After proper processing, the samples were analyzed for texture, pH, organic carbon, CEC, exchangeable cations (K, Ca, Mg and Na), total N, available P and S following standard methods. The textural class of the soils collected from AEZ 12 and 13 appeared to be mostly clay. Clay loam soil was found in AEZ 4, 8, 9, 11, 25 and 28. Loamy soil was seen in AEZ 1 while AEZ 22, 23 and 29 were mostly sandy textured. The results revealed that 65.7% of the tested soil was acidic while 25.7% was alkaline in nature. All the tested soils showed lower pHKCl compared to pHH2O thus possessed negative charge. About 68.6% of the collected soils contained low (1.10-1.70%) level of organic matter, 25.7% soils retained it at medium level (1.71-2.40) and 5.7% soils at very low level (<1.0%). All the tested soils appeared to be deficient (< 0.12%) in nitrogen content. 68.6% soil samples had the low level of available P while only 8.6% retained it an optimum amount. About 80% of the tested soils contained low level of available S (7.9- 14.7 mg kg -1) although coastal regions soils hold higher amount of available S. High CEC (20-38 cmol kg-1) was found in clay rich soils of AEZ 10, 11, 12, and 13. Study revealed that 40% of the collected soils were very low, 31.4% were low, 8.6% each of medium and optimum, and 11.4% contained high level of exchangeable K. The calcareous soils (AEZ 10, 11, 12 and 13) contained very high level of Ca. Non calcareous soils also showed fairly good level of Ca content except AEZ 1, 3, 23 and 29. Sandy textured soils of greater Dinajpur, Rangpur, Moulvibazar showed lower level of exchangeable Mg. About 86% of the tested soils had the lower (< 2%) potassium saturation percentage (KSP), which needs K application for sustainable crop production. Estimate showed that 44% variability for CEC may be attributed by clay content and the relationship was significant (p = 0.05). Again, 50.4 and 65.6% variability in exchangeable K and Mg, respectively may be governed by clay content of the soils, while such relationship for Ca was non-significant. CEC may contribute 62.2, 92.3 and 83.9% variability for exchangeable K, Ca and Mg content in soils, respectively. The fertility status of most of the studied soils (except AEZ 10, 12, 13 and to some extent 11) appeared to be low to very low, which demand judicious management in order to achieve food security and to conserve the soil fertility.Bangladesh J. Agril. Res. 41(4): 735-757, December 2016


Energies ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 7451
Author(s):  
Barbara Breza-Boruta ◽  
Karol Kotwica ◽  
Justyna Bauza-Kaszewska

Properly selected tillage methods and management of the available organic matter resources are considered important measures to enable farming in accordance with the principles of sustainable agriculture. Depending on the depth and intensity of cultivation, tillage practices affect soil chemical composition, structure and biological activity. The three-year experiment was performed on the soil under spring wheat (cv. Tybalt) short-time cultivation. The influence of different tillage systems and stubble management on the soil’s chemical and biological parameters was analyzed. Organic carbon content (OC); content of biologically available phosphorus (Pa), potassium (Ka), and magnesium (Mg); content of total nitrogen (TN), mineral nitrogen forms: N-NO3 and N-NH4 were determined in various soil samples. Moreover, the total number of microorganisms (TNM), bacteria (B), actinobacteria (A), fungi (F); soil respiratory activity (SR); and pH in 1 M KCl (pH) were also investigated. The results show that organic matter amendment is of greater influence on soil characteristics than the tillage system applied. Manure application, as well as leaving the straw in the field, resulted in higher amounts of organic carbon and biologically available potassium. A significant increase in the number of soil microorganisms was also observed in soil samples from the experimental plots including this procedure.


1987 ◽  
Vol 35 (3) ◽  
pp. 407-415 ◽  
Author(s):  
A. Kamphorst

A small rainfall simulator is described, which can be used in the field as well as in the laboratory for the determination of infiltration and erosion characterisitcs of soils. It is particularly suitable for soil conservation surveys, as it is light to carry and easy to handle in the field. A description is given of a standard procedure for the determination of topsoil erodibilities in the field and some results are presented. The method appears to be highly sensitive to soil properties influencing soil erodibility, such as clay content, organic matter content and soil pH. (Abstract retrieved from CAB Abstracts by CABI’s permission)


2016 ◽  
Vol 13 (1) ◽  
pp. 1-6
Author(s):  
Baghdad Science Journal

Soil invertebrates community an important role as part of essential food chain and responsible for the decomposition in the soil, helps soil aeration , nutrients recycling and increase agricultural production by providing the essential elements necessary for photosynthesis and energy flow in ecosystems.The aim of the present study was to investigate the soil invertebrates community in one of the date palms plantation in Aljaderia district South of Baghdad, , and their relationships with some physical and chemical properties of the soil , as Five randomly distributed replicates of soil samples were collected monthly. Invertebrates samples were sorted from the soil with two methods, direct method to isolate large invertebrates and indirectly to isolate small invertebrates using wet funnel method. The study also included the determination of physical and chemical factors of the soil (Temperature, Salinity, pH, Organic matter, Humidity, In addition to the soil texture).Monthly fluctuations in physical and chemical characteristics of the soil and the total invertebrates community study site were determined. Significant correlations the of the invertebrates community and each of temperature, organic matter, and humidity were observed. The study revealed that the temperature of the soil ranged between 5 to 25 C0 , The salinity concentration ranged between 1.1-1.9 ‰, The pH values ranged between 7.3 to 7.8 and the percentage of soil moisture ranged between 15 - 25% , Soil samples were composed of 44.6 % Clay, 19.7% Silt and 35.5% Sand.A total of 4625 individuals of soil invertebrates belonging to 16 taxa were sorted , within which the adult and larval insects were the most abundant, and from them 1283 individuals were sorted , represented 28% of the total numbers, followed by Isopoda , which 1030 individuals of them were sorted, In addition to Nematode, Oligochaetes Annelids family Enchytraeidae, and Earthworms family Lumbricida, Species of Chilopoda, Diplopoda, mites, land snails and slugs. The highest total individual number were recorded recorded durim moderate temperature months, February, March and April amounted to 838, 801 and 813 individuals, respectively.A significant correlation was mated between total number of soil invertebrates and each of temperature, organic matter and humidity. The significant difference in means was calculated according to LSD test.


Sign in / Sign up

Export Citation Format

Share Document