Influence of The Metamorphism Grade and Porosity of Hard Coal on Sorption and Desorption of Propane / Wpływ Stopnia Metamorfizmu I Porowatości Węgli Kamiennych Na Sorpcję I Desorpcję Propanu

Abstract In this paper results of investigations of sorption of hard coal samples collected from the extracted coal seams of Polish coal mines are presented. As sorbate propane was used. Examinations were carried out in the temperature of 298 K by means of volumetric assessment with the use of apparatus ASAP 2010 of Micromeritics. On the basis of conducted examinations it has been found out that the amount of sorbed propane depend on a type of coal, its metamorphism grade, content of oxygen element, moisture and porosity of these coals. The greatest amounts of propane are sorbed by low carbonized, high-porosity coals of high content of oxygen and moisture. Sorption of relatively high amounts of propane by these coals (ca. 10 cm3/g) is a result of the influence of polar surface of coals with molecules of propane and good availability of internal microporous structure of these coals for molecules of examined sorbate. Medium and high carbonized coals sorb insignificant amounts of propane. These coals have compact structure and non-polar character of their surface, their internal porous structure is to a minor degree available for propane molecules in conditions of carried out research. Sorption of propane in this case, takes place mainly in surface pores and on the surface of coals. Moreover, measurements of desorption isotherms of propane showing irreversible character of sorption were made. Desorption isotherms do not come together with sorption isotherms forming open hysteresis loop. Amounts of non-desorbing propane remaining in the coal depend on the type of examined coal.

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The Influence of Disintegration of Hard Coal Varieties of Different Metamorphism Grade on the Amount of Sorbed Ethane / Wpływ rozdrobnienia odmian węgla kamiennego o różnym stopniu metamorfizmu na ilości sorbowanego etanu

Archives of Mining Sciences ◽

10.2478/amsc-2013-0030 ◽

2013 ◽

Vol 58 (2) ◽

pp. 449-463 ◽

Cited By ~ 2

Author(s):

Mieczysław Żyła ◽

Agnieszka Dudzińska ◽

Janusz Cygankiewicz

Keyword(s):

Sorption Isotherms ◽

Electron Donors ◽

Hard Coal ◽

Coal Surface ◽

Compact Layer ◽

Compact Structure ◽

Small Surface ◽

Mining Works ◽

The Impact ◽

Content Of Oxygen

Ethane constitutes an explosive gas. It most often accompanies methane realizing during exploitation and mining works. In this paper the results of ethane sorption have been discussed on three grain classes of six selected hard coal samples collected from active Polish coalmines. On the basis of obtained results, it has been stated that the tested hard coals prove differentiated sorption power with reference to ethane. Te extreme amount of ethane is sorbed by low carbonized hard coal from “Jaworzno” coalmine. This sort of coal shows great porosity, and great content of oxygen and moisture. The least amount of ethane is sorbed by hard coal from “Sośnica” coalmine. This sort of coal possesses relatively a great deal of ash contents. Together with the process of coal disintegration, the amount of sorbed ethane increases for all tested coal samples. Between tested coals there are three medium carbonized samples collected from “Pniówek”, “Chwałowice” “Zofiówka” coalmines which are characterized by small surface values counted according to model BET from nitrogen sorption isotherms determined at the temperature of 77.5 K. The samples of these three coals prove the highest, from between tested coals, increase of ethane sorption occurring together with their disintegration. These samples disintegrated to 0,063-0,075 mm grain class sorb ethane in the amount corresponding with the sorption quantity of low carbonized coal from “Jaworzno” coalmine in 0.5-0.7 mm grain class. It should be marked that the low carbonized samples collected from “Jaworzno” and Wesoła” coalmines possess large specific surface and great porosity and belong to coal group of “loose” spatial structure. Regarding profusion of sorbed ethane on disintegrated medium carbonized samples from “Pniówek”, “Zofiówka”, “Chwałowice” coalmines it can be supposed that in the process of coal disintegration, breaking their “compact’ structure occurs. Loosened structure of medium carbonized coals results in increasing accessibility of ethane particles to sorption centres both electron donors and electron acceptors which are present on hard coal surface. The surface sorption centre increase may result in formation a compact layer of ethane particles on coal surface. In the formed layer, not only the strengths of vertical binding of ethane particles with the coal surface appear but also the impact of horizontal strengths appears which forms a compact layer of sorbed ethane particles. The surface layer of ethane particles may lead to explosion.

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Experimental Determination and Modeling of the Moisture-Sorption Isotherms and Isosteric Heat of Tobacco Leaves

Instrumentation Mesure Métrologie ◽

10.18280/i2m.200504 ◽

2021 ◽

Vol 20 (5) ◽

pp. 269-277

Author(s):

Foullanine Meriama ◽

Bennaceur Said ◽

Loumani Akil ◽

Mediani Ahmed ◽

Moungar Houcine ◽

...

Keyword(s):

Nicotiana Tabacum ◽

Experimental Determination ◽

Water Content ◽

Gravimetric Method ◽

Sorption Isotherms ◽

Moisture Sorption ◽

Isosteric Heat ◽

Nicotiana Tabacum L ◽

Desorption Isotherms ◽

Adsorption Desorption

During a forced convection sun drying and storage operation, the equilibrium water content of a product to be dried is critical. These figures are frequently derived using isothermal sorption curves. The calculation of isotherms is a necessary step in determining the distribution and intensity of water connections in products. for that this paper concentrates on the experimental determination of the adsorption-desorption isotherms for various temperatures (40, 50, and 60℃) of the Nicotiana Tabacum L plants. From which we had established the relationship between the water activity and the water content in the product. However, the aforementioned determination was carried out by the static gravimetric method. Eight saturated salt solutions have been utilized in applications such as (KOH, KCl, MgCl2, MgNO3, K2CO3, BaCl2, K2SO4, and NaCl). Hygroscopic equilibrium was completed after 13 days for temperature 40℃, 11 days for 50℃, and 9 days for 60℃. The overall experimental sorption curves are summarized by six models (HENDERSON, modified HALSEY, OSWIN, GAB, modified BET, and PELEG). The sorption isotherms built using the Clausius–Clapeyron equation were used to determine the net isosteric temperatures of desorption and adsorption of Nicotiana Tabacum L. The results for the adsorption-desorption isotherms found are type III according to IUAPC. Following the smoothing of the experimental results by different used models, it was found that the models of GAB and Peleg allow having the lowest mean relative errors and correlation coefficient.

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The Influences of the Rank of Coal on Methane Sorption Capacity in Coals/Wpływ Rzędu Węgla Na Pojemność Sorpcyjną Metanu W Węglach

Archives of Mining Sciences ◽

10.2478/amsc-2014-0037 ◽

2014 ◽

Vol 59 (2) ◽

pp. 509-516

Author(s):

Andrzej Olajossy

Keyword(s):

Sorption Capacity ◽

Coalbed Methane ◽

Vitrinite Reflectance ◽

Sorption Isotherms ◽

Volatile Matter ◽

Low Rank ◽

Hard Coal ◽

Petrographic Composition ◽

Methane Sorption ◽

Indian Coals

Abstract Methane sorption capacity is of significance in the issues of coalbed methane (CBM) and depends on various parameters, including mainly, on rank of coal and the maceral content in coals. However, in some of the World coals basins the influences of those parameters on methane sorption capacity is various and sometimes complicated. Usually the rank of coal is expressed by its vitrinite reflectance Ro. Moreover, in coals for which there is a high correlation between vitrinite reflectance and volatile matter Vdaf the rank of coal may also be represented by Vdaf. The influence of the rank of coal on methane sorption capacity for Polish coals is not well understood, hence the examination in the presented paper was undertaken. For the purpose of analysis there were chosen fourteen samples of hard coal originating from the Upper Silesian Basin and Lower Silesian Basin. The scope of the sorption capacity is: 15-42 cm3/g and the scope of vitrinite reflectance: 0,6-2,2%. Majority of those coals were of low rank, high volatile matter (HV), some were of middle rank, middle volatile matter (MV) and among them there was a small number of high rank, low volatile matter (LV) coals. The analysis was conducted on the basis of available from the literature results of research of petrographic composition and methane sorption isotherms. Some of those samples were in the form (shape) of grains and others - as cut out plates of coal. The high pressure isotherms previously obtained in the cited studies were analyzed here for the purpose of establishing their sorption capacity on the basis of Langmuire equation. As a result of this paper, it turned out that for low rank, HV coals the Langmuire volume VL slightly decreases with the increase of rank, reaching its minimum for the middle rank (MV) coal and then increases with the rise of the rank (LV). From the graphic illustrations presented with respect to this relation follows the similarity to the Indian coals and partially to the Australian coals.

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The Impact of the Coexistence of Methane Hazard and Rock-Bursts on the Safety of Works in Underground Hard Coal Mines

Energies ◽

10.3390/en14010128 ◽

2020 ◽

Vol 14 (1) ◽

pp. 128

Author(s):

Justyna Swolkień ◽

Nikodem Szlązak

Keyword(s):

Rock Burst ◽

Methane Concentration ◽

High Energy ◽

Hard Coal ◽

Coal Seams ◽

Safety Level ◽

Methane Drainage ◽

Innovative Methods ◽

Hard Coal Mining ◽

The Impact

Several natural threats characterize hard coal mining in Poland. The coexistence of methane and rock-burst hazards lowers the safety level during exploration. The most dangerous are high-energy bumps, which might cause rock-burst. Additionally, created during exploitation, safety pillars, which protect openings, might be the reason for the formation of so-called gas traps. In this part, rock mass is usually not disturbed and methane in seams that form the safety pillars is not dangerous as long as they remain intact. Nevertheless, during a rock-burst, a sudden methane outflow can occur. Preventing the existing hazards increases mining costs, and employing inadequate measures threatens the employees’ lives and limbs. Using two longwalls as examples, the authors discuss the consequences of the two natural hazards’ coexistence. In the area of longwall H-4 in seam 409/4, a rock-burst caused a release of approximately 545,000 cubic meters of methane into the excavations, which tripled methane concentration compared to the values from the period preceding the burst. In the second longwall (IV in seam 703/1), a bump was followed by a rock-burst, which reduced the amount of air flowing through the excavation by 30 percent compared to the airflow before, and methane release rose by 60 percent. The analyses presented in this article justify that research is needed to create and implement innovative methods of methane drainage from coal seams to capture methane more effectively at the stage of mining.

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ᶫ-Leucine Loading and Release in MIL-100 Nanoparticles

International Journal of Molecular Sciences ◽

10.3390/ijms21249758 ◽

2020 ◽

Vol 21 (24) ◽

pp. 9758

Author(s):

Ivan E. Gorban ◽

Mikhail A. Soldatov ◽

Vera V. Butova ◽

Pavel V. Medvedev ◽

Olga A. Burachevskaya ◽

...

Keyword(s):

Aqueous Solution ◽

Hydrothermal Synthesis ◽

Cell Model ◽

Metal Organic Framework ◽

Acetic Acid Solution ◽

Sorption Isotherms ◽

Microwave Assisted Synthesis ◽

High Porosity ◽

Cytotoxicity Studies ◽

Vis Spectroscopy

Synthesis of the MIL-100 metal-organic framework particles was carried out by hydrothermal (HT) and microwave (MW)-assisted methods. Transmission electron microscopy showed formation of microparticles in the course of hydrothermal synthesis and nanoparticles for microwave-assisted synthesis. Powder X-ray diffraction confirmed formation of larger crystallites for hydrothermal synthesis. Particle aggregation in aqueous solution was observed by dynamic light scattering. However, the stability of both samples could be improved in acetic acid solution. Nitrogen sorption isotherms showed high porosity of the particles. ᶫ-leucine molecule was used as a model molecule for loading in the porous micro- and nanoparticles. Loading was estimated by FTIR spectroscopy and thermogravimetric analysis. UV-VIS spectroscopy quantified ᶫ-leucine release from the particles in aqueous solution. Cytotoxicity studies using the HeLa cell model showed that the original particles were somewhat toxic, but ᶫ-leucine loading ameliorated the toxic effects, likely due to signaling properties of the amino acid.

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