The Influence of Disintegration of Hard Coal Varieties of Different Metamorphism Grade on the Amount of Sorbed Ethane / Wpływ rozdrobnienia odmian węgla kamiennego o różnym stopniu metamorfizmu na ilości sorbowanego etanu

2013 ◽  
Vol 58 (2) ◽  
pp. 449-463 ◽  
Author(s):  
Mieczysław Żyła ◽  
Agnieszka Dudzińska ◽  
Janusz Cygankiewicz

Ethane constitutes an explosive gas. It most often accompanies methane realizing during exploitation and mining works. In this paper the results of ethane sorption have been discussed on three grain classes of six selected hard coal samples collected from active Polish coalmines. On the basis of obtained results, it has been stated that the tested hard coals prove differentiated sorption power with reference to ethane. Te extreme amount of ethane is sorbed by low carbonized hard coal from “Jaworzno” coalmine. This sort of coal shows great porosity, and great content of oxygen and moisture. The least amount of ethane is sorbed by hard coal from “Sośnica” coalmine. This sort of coal possesses relatively a great deal of ash contents. Together with the process of coal disintegration, the amount of sorbed ethane increases for all tested coal samples. Between tested coals there are three medium carbonized samples collected from “Pniówek”, “Chwałowice” “Zofiówka” coalmines which are characterized by small surface values counted according to model BET from nitrogen sorption isotherms determined at the temperature of 77.5 K. The samples of these three coals prove the highest, from between tested coals, increase of ethane sorption occurring together with their disintegration. These samples disintegrated to 0,063-0,075 mm grain class sorb ethane in the amount corresponding with the sorption quantity of low carbonized coal from “Jaworzno” coalmine in 0.5-0.7 mm grain class. It should be marked that the low carbonized samples collected from “Jaworzno” and Wesoła” coalmines possess large specific surface and great porosity and belong to coal group of “loose” spatial structure. Regarding profusion of sorbed ethane on disintegrated medium carbonized samples from “Pniówek”, “Zofiówka”, “Chwałowice” coalmines it can be supposed that in the process of coal disintegration, breaking their “compact’ structure occurs. Loosened structure of medium carbonized coals results in increasing accessibility of ethane particles to sorption centres both electron donors and electron acceptors which are present on hard coal surface. The surface sorption centre increase may result in formation a compact layer of ethane particles on coal surface. In the formed layer, not only the strengths of vertical binding of ethane particles with the coal surface appear but also the impact of horizontal strengths appears which forms a compact layer of sorbed ethane particles. The surface layer of ethane particles may lead to explosion.

2013 ◽  
Vol 58 (3) ◽  
pp. 867-879 ◽  
Author(s):  
Agnieszka Dudzińska ◽  
Mieczysław Żyła ◽  
Janusz Cygankiewicz

Abstract In this paper results of investigations of sorption of hard coal samples collected from the extracted coal seams of Polish coal mines are presented. As sorbate propane was used. Examinations were carried out in the temperature of 298 K by means of volumetric assessment with the use of apparatus ASAP 2010 of Micromeritics. On the basis of conducted examinations it has been found out that the amount of sorbed propane depend on a type of coal, its metamorphism grade, content of oxygen element, moisture and porosity of these coals. The greatest amounts of propane are sorbed by low carbonized, high-porosity coals of high content of oxygen and moisture. Sorption of relatively high amounts of propane by these coals (ca. 10 cm3/g) is a result of the influence of polar surface of coals with molecules of propane and good availability of internal microporous structure of these coals for molecules of examined sorbate. Medium and high carbonized coals sorb insignificant amounts of propane. These coals have compact structure and non-polar character of their surface, their internal porous structure is to a minor degree available for propane molecules in conditions of carried out research. Sorption of propane in this case, takes place mainly in surface pores and on the surface of coals. Moreover, measurements of desorption isotherms of propane showing irreversible character of sorption were made. Desorption isotherms do not come together with sorption isotherms forming open hysteresis loop. Amounts of non-desorbing propane remaining in the coal depend on the type of examined coal.


2014 ◽  
Vol 59 (2) ◽  
pp. 509-516
Author(s):  
Andrzej Olajossy

Abstract Methane sorption capacity is of significance in the issues of coalbed methane (CBM) and depends on various parameters, including mainly, on rank of coal and the maceral content in coals. However, in some of the World coals basins the influences of those parameters on methane sorption capacity is various and sometimes complicated. Usually the rank of coal is expressed by its vitrinite reflectance Ro. Moreover, in coals for which there is a high correlation between vitrinite reflectance and volatile matter Vdaf the rank of coal may also be represented by Vdaf. The influence of the rank of coal on methane sorption capacity for Polish coals is not well understood, hence the examination in the presented paper was undertaken. For the purpose of analysis there were chosen fourteen samples of hard coal originating from the Upper Silesian Basin and Lower Silesian Basin. The scope of the sorption capacity is: 15-42 cm3/g and the scope of vitrinite reflectance: 0,6-2,2%. Majority of those coals were of low rank, high volatile matter (HV), some were of middle rank, middle volatile matter (MV) and among them there was a small number of high rank, low volatile matter (LV) coals. The analysis was conducted on the basis of available from the literature results of research of petrographic composition and methane sorption isotherms. Some of those samples were in the form (shape) of grains and others - as cut out plates of coal. The high pressure isotherms previously obtained in the cited studies were analyzed here for the purpose of establishing their sorption capacity on the basis of Langmuire equation. As a result of this paper, it turned out that for low rank, HV coals the Langmuire volume VL slightly decreases with the increase of rank, reaching its minimum for the middle rank (MV) coal and then increases with the rise of the rank (LV). From the graphic illustrations presented with respect to this relation follows the similarity to the Indian coals and partially to the Australian coals.


Energies ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 128
Author(s):  
Justyna Swolkień ◽  
Nikodem Szlązak

Several natural threats characterize hard coal mining in Poland. The coexistence of methane and rock-burst hazards lowers the safety level during exploration. The most dangerous are high-energy bumps, which might cause rock-burst. Additionally, created during exploitation, safety pillars, which protect openings, might be the reason for the formation of so-called gas traps. In this part, rock mass is usually not disturbed and methane in seams that form the safety pillars is not dangerous as long as they remain intact. Nevertheless, during a rock-burst, a sudden methane outflow can occur. Preventing the existing hazards increases mining costs, and employing inadequate measures threatens the employees’ lives and limbs. Using two longwalls as examples, the authors discuss the consequences of the two natural hazards’ coexistence. In the area of longwall H-4 in seam 409/4, a rock-burst caused a release of approximately 545,000 cubic meters of methane into the excavations, which tripled methane concentration compared to the values from the period preceding the burst. In the second longwall (IV in seam 703/1), a bump was followed by a rock-burst, which reduced the amount of air flowing through the excavation by 30 percent compared to the airflow before, and methane release rose by 60 percent. The analyses presented in this article justify that research is needed to create and implement innovative methods of methane drainage from coal seams to capture methane more effectively at the stage of mining.


Energies ◽  
2018 ◽  
Vol 11 (12) ◽  
pp. 3309 ◽  
Author(s):  
Zia Ullah ◽  
Jin Hur

Contemporary research has shown impetus in the diagnostics of permanent magnet (PM) type machines. The manufacturers are now more interested in building diagnostics features in the control algorithms of machines to make them more salable and reliable. A compact structure, exclusive high-power density, high torque density, and efficiency make the PM machine an attractive option to use in industrial applications. The impact of a harsh operational environment most often leads to faults in PM machines. The diagnosis and nipping of such faults at an early stage have appeared as the prime concern of manufacturers and end users. This paper reviews the recent advances in fault diagnosis techniques of the two most frequently occurring faults, namely inter-turn short fault (ITSF) and irreversible demagnetization fault (IDF). ITSF is associated with a short circuit in stator winding turns in the same phase of the machine, while IDF is associated with the weakening strength of the PM in the rotor. A detailed literature review of different categories of fault indexes and their strengths and weaknesses is presented. The research trends in the fault diagnosis and the shortcomings of available literature are discussed. Moreover, potential research directions and techniques applicable for possible solutions are also extensively suggested.


2018 ◽  
Vol 140 (6) ◽  
Author(s):  
Halina Pawlak-Kruczek ◽  
Robert Lewtak ◽  
Zbigniew Plutecki ◽  
Marcin Baranowski ◽  
Michal Ostrycharczyk ◽  
...  

The paper presents the experimental and numerical study on the behavior and performance of an industrial scale boiler during combustion of pulverized bituminous coal with various shares of predried lignite. The experimental measurements were carried out on a boiler WP120 located in CHP, Opole, Poland. Tests on the boiler were performed during low load operation and the lignite share reached over to 36% by mass. The predried lignite, kept in dedicated separate bunkers, was mixed with bituminous coal just before the coal mills. Computational fluid dynamic (CFD) simulation of a cofiring scenario of lignite with hard coal was also performed. Site measurements have proven that cofiring of a predried lignite is not detrimental to the boiler in terms of its overall efficiency, when compared with a corresponding reference case, with 100% of hard coal. Experiments demonstrated an improvement in the grindability that can be achieved during co-milling of lignite and hard coal in the same mill, for both wet and dry lignite. Moreover, performed tests delivered empirical evidence of the potential of lignite to decrease NOx emissions during cofiring, for both wet and dry lignite. Results of efficiency calculations and temperature measurements in the combustion chamber confirmed the need to predry lignite before cofiring. Performed measurements of temperature distribution in the combustion chamber confirmed trend that could be seen in the results of CFD. CFD simulations were performed for predried lignite and demonstrated flow patterns in the combustion chamber of the boiler, which could prove useful in case of any further improvements in the firing system. CFD simulations reached satisfactory agreement with the site measurements in terms of the prediction of emissions.


2021 ◽  
Vol 24 (1) ◽  
pp. 38-54
Author(s):  
Tadeusz A. Grzeszczyk ◽  
Waldemar Izdebski ◽  
Michał Izdebski ◽  
Tadeusz Waściński

Poland is not one of the leaders in the use of renewable energy sources (RES), and most energy is still produced using hard coal and lignite. Therefore, there are noteworthy emissions of air pollution (including ashes and greenhouse gases), and the Polish energy sector is characterized by a substantial degree of carbonization, which, as a result, threatens to expressively increase the costs of electricity production, leading to financial penalties imposed by the EU. The aim of this paper is to analyze socio-economic factors influencing the development of the RES sector in Poland. According to this aim, expert research was carried out, in which the factors influencing development potential of RES were assessed at two levels (level II – 5 factors, level III – 15 factors) according to the factor tree analysis. Based on the analysis of the level II factors, it can be concluded that the development of the RES sector in Poland will depend to a decisive extent on factors such as: EU decisions and Polish legislation affecting the development of the RES sector in Poland, prices and availability of conventional energy carriers. Other two factors – regional policy on ecology and ecological awareness in Poland – have so far little impact on the development of this sector in the state. The analysis of the level III factors shows that the greatest impact on the development of the RES sector in Poland is the influence of European lobbying of manufacturers of machinery and equipment for renewable energy production on EU law, the impact of Polish lobbying of conventional energy producers on Polish law in the production of renewable energy and the influence of European lobbying of renewable energy producers into EU law.


2010 ◽  
Vol 645-648 ◽  
pp. 783-786
Author(s):  
Tatsunori Sugimoto ◽  
Masataka Satoh ◽  
Tohru Nakamura ◽  
K. Mashimo ◽  
Hiroshi Doi ◽  
...  

The impact of CF4 plasma treatment on the surface roughening of SiC has been investigated for N ion implanted SiC(0001) which is implanted with the energy range from 15 to 120 keV at a dose of 9.2 x 1014/cm2. The N ion implanted sample, which is processed by CF4 plasma, shows small surface roughness of 1.6 nm after annealing at 1700 oC for 10 min, while the sample without CF4 plasma treatment shows the large surface roughness (6.6nm) and micro step structure. XPS measurements reveals that CF4 plasma treatment is effective to dissolved the residual oxide on the surface of SiC which is not removed by BHF acid of SiO2 layer on SiC. It is strongly suggested that the formation of micro step structure with the increase of the surface roughness is promoted by the residual oxide such as SiCOx, on SiC.


1998 ◽  
Vol 26 ◽  
pp. 307-312 ◽  
Author(s):  
H. Conway

Measurements and observations by others indicate that a potential slab avalanche consists of a relatively cohesive slab of snow overlying a thin weak layer that coniains flaws where locally the shear stress from the overburden is not fully supported. Under favorable conditions, snow will shear strain-soften, which provides the basis for applying a slip-weakening model to examine the size of flaw needed to initiate sub-critical crack propagation along the weak layer. Using typical values for snow properties, the model predicts sub-critical crack growth can initiate from a relatively small flaw well before the shear stress from the overburden approaches the peak shear strength at tin-bed. The occurrence of small flaws or imperfections in the basal layer would explain field measurements which usually indicate that avalanching occurs before the applied shear stress exceeds the shear strength at the basal layer.Widespread slab-avalanche activity often increases significantly soon after the onset of rain on new snow. Measurements of temperature and mechanical properties show that only the upper 0.15 m or less of the slab has been altered at the time of avalanching; alterations at the sliding layer have not yet been detected. Results from the slip-weakening model indicate that the rain-induced alterations would reduce the size of flaw needed to initiate sub-critical crack growth by 10–20%. The observations and model results show clearly the importance of the slab properties; it is evident that both the slab and the weak layer act together to control slope stability. A further implication is that the stability of freshly deposited snow is often close to critical, because a relatively small surface perturbation is often sufficient to cause avalanching. This is not surprising, because it is well known from field observations that new snow on slopes should be treated with caution.


Energies ◽  
2020 ◽  
Vol 13 (8) ◽  
pp. 1951 ◽  
Author(s):  
Małgorzata Wzorek

The paper assesses the impact of combustion of biofuels produced based on municipal sewage sludge in stoker-fired boilers on the amount of pollutant emissions and examines the tendency of ash deposition of biofuels formed during the combustion process. The combustion tests were performed in a laboratory system enabling simulation of a combustion process present in stoker-fired boilers. The study was conducted for three types of biofuels; i.e., fuel from sewage sludge and coal slime (PBS fuel), sewage sludge and meat and bone meal (PBM fuel) and fuel based on sewage sludge and sawdust (PBT) with particle size of 35 mm and 15 mm. This paper describes and compares the combustion process of biofuels with different granulation and composition and presents the results of changes in emission values of NOx, SO2, CO, and CO2. The emission results were compared with the corresponding results obtained during combustion of hard coal. The results showed that biofuels with lower particle sizes were ignited faster and the shortest ignition time is achieved for fuel based on sewage sludge and coal slime-PBS fuel. Also, the highest NO and SO2 emissions were obtained for PBS fuel. During the combustion of fuel based on sewage sludge and meat and bone meal (PBM), on the other hand, the highest CO2 emissions were observed for both granulations. Biofuels from sludge show a combustion process that is different compared to the one for hard coal. The problems of ash fouling, slagging, and deposition during biofuels combustion were also identified. The tendency for ash slagging and fouling is observed, especially for fuel from sewage sludge and meat and bone meal (PBM) and fuel based on sewage sludge and sawdust (PBT) ashes which consist of meat and bone meal and sawdust which is typical for biomass combustion.


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