scholarly journals Effect of the electrodeposition potential on the magnetic properties of FeCoNi films

2019 ◽  
Vol 37 (3) ◽  
pp. 389-394
Author(s):  
Setia Budi ◽  
Sukro Muhab ◽  
Agung Purwanto ◽  
Budhy Kurniawan ◽  
Azwar Manaf
Keyword(s):  
Magnetic Properties ◽  
Saturation Magnetization ◽  
Sulfate Solution ◽  
Synthesis Process ◽  
Magnetic Characteristics ◽  
Soft Magnetic ◽  
X Ray ◽  
Ni Content ◽  
The Mean ◽  
Feconi Alloy

AbstractThe effect of electrodeposition potential on the magnetic properties of the FeCoNi films has been reported in this paper. The FeCoNi electrodeposition was carried out from sulfate solution using potentiostatic technique. The obtained FeCoNi films were characterized by X-ray diffractometer (XRD), atomic absorption spectrometer (AAS) and vibrating sample magnetometer (VSM). It has been shown that the electrodeposition potential applied during the synthesis process determines the magnetic characteristics of FeCoNi films. The more negative potential is applied, the higher Ni content is in the FeCoNi alloy. At the same time, Co and Fe showed almost similar trend in which the content decreased with an increase in applied potential. The mean crystallite size of FeCoNi films was ranging from 11 nm to 15 nm. VSM evaluation indicated that the FeCoNi film is a ferromagnetic alloy with magnetic anisotropy. The high saturation magnetization of FeCoNi film was ranging from 86 A·m2/kg to 105 A·m2/kg. The film is a soft magnetic material which was revealed by a very low coercivity value in the range of 1.3 kA/m to 3.7 kA/m. Both the saturation magnetization and coercivity values decreased at a more negative electrodeposition potential.

Influence of Alloying Additions on Enhancement of Soft Magnetic Properties Effect and Crystallization in FeXSiB (X=Cu, V, Co, Zr, Nb) Amorphous Alloys

2007 ◽  
Vol 130 ◽  
pp. 171-174 ◽  
Author(s):  
Z. Stokłosa ◽  
G. Badura ◽  
P. Kwapuliński ◽  
Józef Rasek ◽  
G. Haneczok ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Amorphous Alloys ◽  
Crystallization Process ◽  
Annealing Temperature ◽  
Magnetic Measurements ◽  
X Ray Diffraction ◽  
Soft Magnetic ◽  
X Ray ◽  
Second Stage ◽  
Transmission Electron

The crystallization and optimization of magnetic properties effects in FeXSiB (X=Cu, V, Co, Zr, Nb) amorphous alloys were studied by applying X-ray diffraction methods, high resolution transmission electron microscopy (HRTEM), resistometric and magnetic measurements. The temperatures of the first and the second stage of crystallization, the 1h optimization annealing temperature and the Curie temperature were determined for different amorphous alloys. Activation energies of crystallization process were obtained by applying the Kissinger method. The influence of alloy additions on optimization effect and crystallization processes was carefully examined.

scholarly journals Ferromagnetic Properties of N-Doped and Undoped TiO2 Rutile Single-Crystal Wafers with Addition of Tungsten Trioxide

Materials ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 1934 ◽  
Author(s):  
Jing Xu ◽  
Haiying Wang ◽  
Zhongpo Zhou ◽  
Zhaorui Zou
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Saturation Magnetization ◽  
Photoelectron Spectroscopy ◽  
Oxygen Vacancies ◽  
Tio2 Surface ◽  
Doped Tio2 ◽  
X Ray ◽  
N Doping ◽  
Tio2 Rutile

In this work, undoped, N-doped, WO3-loaded undoped, and WO3-loaded with N-doped TiO2 rutile single-crystal wafers were fabricated by direct current (DC) magnetron sputtering. N-doping into TiO2 and WO3 loading onto TiO2 surface were used to increase and decrease oxygen vacancies. Various measurements were conducted to analyze the structural and magnetic properties of the samples. X-ray diffraction results showed that the N-doping and WO3 loading did not change the phase of all samples. X-ray photoelectron spectroscopy results revealed that W element loaded onto rutile single-crystal wafers existed in the form of WO3. UV-Vis spectrometer results showed that the absorption edge of WO3-loaded undoped and WO3-loaded with N-doped TiO2 rutile single-crystal wafers had red shift, resulting in a slight decrease in the corresponding band gap. Photoluminescence spectra indicated that oxygen vacancies existed in all samples due to the postannealing atmosphere, and oxygen vacancies density increased with N-doping, while decreasing with WO3 loading onto TiO2 surface. The magnetic properties of the samples were investigated, and the saturation magnetization values were in the order N-doped > WO3-loaded with N-doped > undoped > WO3-loaded undoped rutile single-crystal wafers, which was the same order as the oxygen vacancy densities of these samples. N-doping improved the saturation magnetization values, while WO3-loaded decreased the saturation magnetization values. This paper reveals that the magnetic properties of WO3-loaded with N-doped rutile single-crystal wafers originate from oxygen vacancies.

scholarly journals Synthesis of nanosized nickel zinc ferrite using electric arc furnace dust and ferrous pickle liquor

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ayman Galal ◽  
Olfat Sadek ◽  
Moataz Soliman ◽  
Shaker Ebrahim ◽  
M. Anas
Keyword(s):  
Magnetic Properties ◽  
Zinc Ferrite ◽  
Electric Arc Furnace ◽  
Electric Arc ◽  
Arc Furnace ◽  
X Ray ◽  
Electric Arc Furnace Dust ◽  
Nickel Zinc ◽  
Ni Content ◽  
Pickle Liquor

AbstractElectric arc furnace dust (EAFD) and waste pickle liquor (WPL); two major side products of the steel industry with negative environmental impact were used for the synthesis of nickel zinc ferrite (NZF); the important magnetic ceramic material of versatile industrial applications. The structural and magnetic properties of the prepared material were examined which showed good magnetic properties (high saturation magnetization and low coercivity) compared with those synthesized from pure reagents. In the applied process, nano sized nickel zinc ferrite (NZF) with a composition of Nix(Zn + impurities)1−xFe2O4 (where x = 0, 0.25, 0.5, 0.75 and impurities of manganese, magnesium, and calcium were prepared using zinc-containing electric arc furnace dust (EAFD) and waste pickle liquor (WPL). The chemical compositions of the prepared samples were determined using X-ray fluorescence (XRF) analysis. The optimum acetic acid concentration for EAFD treatment was found 2% v/v that decreased Ca content of EAFD by 70.6% without loss of Fe and Zn. The structural and morphological characterization was done by X-ray diffraction (XRD), Fourier transform infrared (FTIR) and Field Emission Scanning Electron Microscope (FESEM) to confirm the formation of Ni–Zn ferrite nanoparticles and estimate the particle sizes. The maximum saturation magnetization (Ms) of 73.89 emu/g was achieved at 0.5 Ni content and the minimum coercivity of 2.55 Oe was obtained at 0.25 Ni content.

scholarly journals Effects of La on Thermal Stability, Phase Formation and Magnetic Properties of Fe–Co–Ni–Si–B–La High Entropy Alloys

Metals ◽  
2021 ◽  
Vol 11 (12) ◽  
pp. 1907
Author(s):  
Jiaming Li ◽  
Jianliang Zuo ◽  
Hongya Yu
Keyword(s):  
Thermal Stability ◽  
Magnetic Properties ◽  
Saturation Magnetization ◽  
Phase Formation ◽  
Crystallization Temperature ◽  
High Entropy Alloys ◽  
Soft Magnetic Properties ◽  
Soft Magnetic ◽  
High Entropy ◽  
Bcc Phase

The microstructure, phase formation, thermal stability and soft magnetic properties of melt-spun high entropy alloys (HEAs) Fe27Co27Ni27Si10−xB9Lax with various La substitutions for Si (x = 0, 0.2, 0.4, 0.6, 0.8, and 1) were investigated in this work. The Fe27Co27Ni27Si10−xB9La0.6 alloy shows superior soft magnetic properties with low coercivity Hc of ~7.1 A/m and high saturation magnetization Bs of 1.07 T. The content of La has an important effect on the primary crystallization temperature (Tx1) and the secondary crystallization temperature (Tx2) of the alloys. After annealing at relatively low temperature, the saturation magnetization of the alloy increases and the microstructure with a small amount of body-centered cubic (BCC) phase embedded in amorphous matrix is observed. Increasing the annealing temperature reduces the magnetization due to the transformation of BCC phase into face-centered cubic (FCC) phase.

Formation, and mechanical and magnetic properties of bulk ferromagnetic Fe-Nb-B-Y-(Zr, Co) alloys

2006 ◽  
Vol 21 (4) ◽  
pp. 1019-1024 ◽  
Author(s):  
J.M. Park ◽  
J.S. Park ◽  
D.H. Kim ◽  
J-H. Kim ◽  
E. Fleury
Keyword(s):  
Magnetic Properties ◽  
Saturation Magnetization ◽  
Amorphous Alloys ◽  
Amorphous Structure ◽  
Glass Forming Ability ◽  
Partial Replacement ◽  
Soft Magnetic ◽  
Glass Forming ◽  
Mold Casting ◽  
Co Alloys

Fe element was partially substituted by Zr and Co in an attempt to enhance the glass-forming ability, and mechanical and soft magnetic properties of Fe74-xNb6B17Y3(Zr, Co)x (x = 3, 5, 8) amorphous alloys. Both partial replacements resulted in the enhancement of the glass-forming ability, and 3-mm diameter rods with a fully amorphous structure were prepared by a copper mold casting method. Zr and Co containing Fe-based bulk amorphous alloys exhibited high compressive fracture strength of about 4 and 3.5 GPa, respectively. However, Zr and Co induced different effects on the magnetic properties. Whereas the partial replacement of Fe by Zr was found to decrease dramatically the saturation magnetization, the partial replacement of Fe by Co provided an increase of about 25% of the saturation magnetization.

scholarly journals Preparation of ε-Fe(Si)3N Powder Using a Salt Bath Nitriding Reaction and a Study on the Soft Magnetic Properties of the Powder

Materials ◽  
2019 ◽  
Vol 12 (2) ◽  
pp. 228
Author(s):  
Yuhua Xu ◽  
Zhenghou Zhu ◽  
Hui Zhao ◽  
Jia Zhou
Keyword(s):  
Magnetic Properties ◽  
Temperature Dependence ◽  
Saturation Magnetization ◽  
Salt Bath ◽  
Soft Magnetic Properties ◽  
Soft Magnetic ◽  
Temperature Range ◽  
Nitriding Reaction ◽  
Salt Bath Nitriding ◽  
Fesi Alloy

In this paper, a single phase ε-Fe(Si)3N powder was successfully synthesized through the salt bath nitriding reaction method. The flaky FeSi alloy powder was used as the iron source, and non-toxic CO(NH2)2 was used as the nitrogen source. The nitridation mechanism, the preparation technology, the soft magnetic properties, and the magnetization temperature dependence of the powder were studied. The research result showed that ε-Fe(Si)3N alloy powders were synthesized in a high temperature nitrification system after the surface of flaky FeSi alloy powders were activated by a high-energy ball mill. The optimum nitriding process was nitridation for 1 h at 550 °C. The ε-Fe(Si)3N powder had good thermal stability at less than 478.8 °C. It was shown that ε-Fe(Si)3N powder has good soft magnetic properties, and the saturation magnetization of the powder was up to 139 emu/g. The saturation magnetization of ε-Fe(Si)3N powder remains basically constant in the temperature range of 300–400 K. In the temperature range of 400–600 K, the saturation magnetization decreases slightly with the increase of temperature, indicating that the magnetic ε-Fe(Si)3N powder has good magnetization temperature dependence.

Effects of Reactive Gas Compositions on the Magnetic Properties and Microstructures of FeTaNC Films

1996 ◽  
Vol 441 ◽  
Author(s):  
Tae-Hyuk Koh ◽  
Dong-Hoon Shin ◽  
Woon Choi ◽  
Dong-Hoon Ahn ◽  
Seoung-Eui Nam ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Magnetic Flux ◽  
Magnetic Flux Density ◽  
Magnetic Characteristics ◽  
Soft Magnetic Properties ◽  
Soft Magnetic ◽  
Distinctive Difference ◽  
Co Addition ◽  
Soft Magnetism ◽  
Reactive Gas

AbstractSoft magnetic properties and microstructure evolutions of FeTaNC films were investigated, and compared with those of FeTaN and FeTaC films. Effects of substrate species (glass vs. CaTiO3) on the magnetic properties were also investigated. Co-addition of N and C enhances the grain refinements and soft magnetism compared with N or C only addition. Good soft magnetic characteristics of coercivity of 0.17 Oe, permeability of 4000 (5 MHz), and magnetic flux density of 17 kG can be obtained in the FeTaNC films with the relatively wide process ranges. While these values appear to be similar to those of FeTaN films on glass substrate, the most distinctive difference between FeTaNC and FeTaN (or C) films is the effects of substrate. Whereas FeTaNC films show good magnetic characteristics on both glass and CaTiO3 substrates, FeTaN (or C) films show substantial degradation on the CaTiO3 substrate.

Mechanically Driven Alloying and Magnetic Properties in Immiscible Mn80Bi20 Nanocrystalline Powders

2013 ◽  
Vol 873 ◽  
pp. 217-220
Author(s):  
Min Xu ◽  
Qun Jiao Wang
Keyword(s):  
Magnetic Properties ◽  
Mechanical Alloying ◽  
Saturation Magnetization ◽  
Ball Milling ◽  
Solid Solubility ◽  
Milling Time ◽  
Early Stage ◽  
Nanocrystalline Powders ◽  
X Ray Diffraction ◽  
X Ray

The paper has described the formation of nanocrystalline Mn80Bi20powders by mechanical alloying and studied the changes of structure and magnetic properties of the powders during the process of ball milling by using X-ray diffraction and saturation magnetization σsmeasurements. The solid solubility of bismuth in manganese increases with milling time and tends to a stable value after 80h milling. The σsof Mn80Bi20increases abruptly with milling time at the early stage and begins to decrease after 15h. At the time of 15h, the σsreaches a maximum, which is about 7Am2/kg. The result shows an interesting information that the antiferromagnetic Mn and the diamagnetic Bi produce ferromagnetic Mn80Bi20in process of mechanical alloying.

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