Kinetics of pyrolysis and properties of carbon black from a scrap tire

2006 ◽  
Vol 60 (6) ◽  
Author(s):  
Z. Koreňová ◽  
M. Juma ◽  
J. Annus ◽  
J. Markoš ◽  
L’. Jelemenský
Keyword(s):  
Carbon Black ◽  
Pore Size ◽  
Rubber Particle ◽  
Ash Content ◽  
Process Conditions ◽  
Nitrogen Flow ◽  
Scrap Tire ◽  
Second Stage ◽  
Wide Range ◽  
Kinetics Of

AbstractThe pyrolysis of rubber from the sidewall and tread of a passenger car tire was carried out in a nitrogen flow at a wide range of final temperatures. Derivative thermogravimetric analysis (DTG) was applied to examine the kinetics at the different process conditions of completed pyrolysis. Two characteristic stages were observed in the DTG curves. The first stage corresponded to the decomposition of processing oil, plastifier, and additives, whereas the rubber polymer was decomposed in the second stage. Several properties of the carbon black formed by the pyrolysis such as ash content, specific surface area, and pore size distribution were determined. A change of the internal structure of the rubber particle in the meso-and macroregions of the pore size was observed.

Pyrolytic Characteristics and Kinetic Parameters Evaluation of Cassava Stalks Using Thermogravimetric Analyzer

2020 ◽  
Vol 851 ◽  
pp. 137-141
Author(s):  
Sukarni Sukarni ◽  
M. Rifqi Ramadhan
Keyword(s):  
Reaction Order ◽  
Frequency Factor ◽  
Differential Method ◽  
Nitrogen Flow ◽  
Nitrogen Flow Rate ◽  
Kinetic Evaluation ◽  
Thermogravimetric Analyzer ◽  
Second Stage ◽  
Factor Log ◽  
Kinetics Of

Pyrolytic characteristics and kinetics of cassava stalks as a renewable energy source were delved via a thermogravimetric (TG) analyzer. About 10 mg powder of the sample was heated up in the TG cavity under inert conditions with 50 ml.min-1 nitrogen flow rate and operated at 20 °C min-1 of heating program. The pyrolysis process of cassava stalks was taken place into three main stages, in which the peak reaction occurred at the second stage with 70% of the mass was degraded. The differential method of Arrhenius kinetic evaluation resulted in the values of reaction order (n) that was 0.99, activation energy that was 89.46 kJ/mol and logarithmic frequency factor (log A) was 7.7 min-1.

Kinetics of Biological Phosphorus Release

1985 ◽  
Vol 17 (11-12) ◽  
pp. 57-71 ◽  
Author(s):  
M. C. Wentzel ◽  
P. L. Dold ◽  
G. A. Ekama ◽  
G v. R. Marais
Keyword(s):  
Flow Regime ◽  
Mass Fraction ◽  
Phosphorus Release ◽  
P Uptake ◽  
Process Conditions ◽  
Anaerobic Reactor ◽  
P Release ◽  
Wide Range ◽  
Biological Phosphorus ◽  
Kinetics Of

Experimental observations indicate that the magnitude of biological excess P uptake is linked strongly to the magnitude of P release in the anaerobic reactor. A theory describing the kinetics of P release is presented in terms of the readily biodegradable COD in the influent, the non-polyP heterotrophic mass, the anaerobic mass fraction and the reactor flow regime. Observed P release conforms well to that predicted over a wide range of wastewater characteristics and process conditions.

Processing in an Internal Mixer as Affected by Carbon Black Properties

1976 ◽  
Vol 49 (1) ◽  
pp. 12-27 ◽  
Author(s):  
E. S. Dizon
Keyword(s):  
Carbon Black ◽  
Surface Area ◽  
Performance Optimization ◽  
High Surface ◽  
High Surface Area ◽  
Quantitative Measure ◽  
Second Stage ◽  
Processing Cost ◽  
Wide Range ◽  
High Structure

Abstract This paper has attempted to review current knowledge on mixing fundamentals from a carbon black standpoint. The mixing parameters discussed include volume fill factor, specific energy of mixing, temperature buildup, and flow characteristics. Together, these parameters define the economics of mixing in terms of mixing capacity, energy expenditure, limitations imposed by dump temperature on second-stage operations, and extruder flow requirements. The four parameters in turn were related to basic carbon black properties by way of mixing profiles. Ten currently available tread blacks which exhibit a wide range of tread wear resistance have been characterized in terms of the processability criteria. A processability rating system based on the most simple equipment requirement (a Banbury followed immediately by a second-stage mill or an extruder) was applied to the ten blacks. Comparison of the processability ratings with the tread wear ratings clearly demonstrates that a valid assessment of carbon black utility must include processing cost in addition to performance capability. As in many rubber properties, there is clearly an inverse relationship between performance quality and processability. High-structure, high-surface-area blacks that are desirable from a performance standpoint require the highest processing cost. The question of uniformity was also discussed, and it was concluded that the present specifications controlling carbon black surface area and structure are adequate in minimizing processing variations. The challenge to processing technology from a carbon black standpoint then involves the reduction in the cost of processing high-structure, high-surface-area blacks. At this stage, a quantitative measure of the processing characteristics of the currently available tread blacks at least allows a rational product selection in terms of optimum performance and processing cost. In the meantime, it is evident that significant advances in carbon black technology are still needed if performance optimization is to be reconciled with the economics of processing.

Electron microscopy study of reactively sputter-deposited Ti/N films on silicon

1992 ◽  
Vol 50 (2) ◽  
pp. 1362-1363
Author(s):  
V. C. Kannan ◽  
A. K. Singh ◽  
R. B. Irwin ◽  
S. Chittipeddi ◽  
F. D. Nkansah ◽  
...  
Keyword(s):  
Integrated Circuits ◽  
Large Scale ◽  
Hexagonal Phase ◽  
Microscopy Study ◽  
Electron Microscopy Study ◽  
Process Conditions ◽  
Tin Films ◽  
Wide Range ◽  
Fcc Phase ◽  
Circuits Vlsi

Titanium nitride (TiN) films have historically been used as diffusion barrier between silicon and aluminum, as an adhesion layer for tungsten deposition and as an interconnect material etc. Recently, the role of TiN films as contact barriers in very large scale silicon integrated circuits (VLSI) has been extensively studied. TiN films have resistivities on the order of 20μ Ω-cm which is much lower than that of titanium (nearly 66μ Ω-cm). Deposited TiN films show resistivities which vary from 20 to 100μ Ω-cm depending upon the type of deposition and process conditions. TiNx is known to have a NaCl type crystal structure for a wide range of compositions. Change in color from metallic luster to gold reflects the stabilization of the TiNx (FCC) phase over the close packed Ti(N) hexagonal phase. It was found that TiN (1:1) ideal composition with the FCC (NaCl-type) structure gives the best electrical property.

Scintigraphic studies in rats. Kinetics of insulin analogues covering wide range of receptor affinities

Diabetes ◽  
1991 ◽  
Vol 40 (5) ◽  
pp. 628-632 ◽  
Author(s):  
I. Jensen ◽  
V. Kruse ◽  
U. D. Larsen
Keyword(s):  
Insulin Analogues ◽  
Wide Range ◽  
Kinetics Of

Application of the ceramic membrane with hydrophobic skin layer to separation of activated sludge

1997 ◽  
Vol 35 (8) ◽  
pp. 137-144 ◽  
Author(s):  
Tsuyoshi Nomura ◽  
Takao Fujii ◽  
Motoyuki Suzuki
Keyword(s):  
Activated Sludge ◽  
Pore Size ◽  
Ceramic Membrane ◽  
Membrane Separation ◽  
Porous Ceramic ◽  
Porous Membrane ◽  
Skin Layer ◽  
Gas Permeation ◽  
Wide Range ◽  
Cake Layer

Porous membrane of poly(tetrafluoroethylene) (PTFE) was formed on the surface of porous ceramic tubes by means of heat treatment of the PTFE particles deposit layer prepared by filtering PTFE microparticles emulsified in aqueous phase. By means of inert gas permeation, pore size was determined and compared with scanning electron micrograph observation. Also rejection measurement of aqueous dextran solutions of wide range of molecular weights showed consistent results regarding the pore size. Since the membrane prepared by this method is stable and has unique features derived from PTFE, it is expected that the membrane has interesting applications in the field of water treatment. Membrane separation of activated sludge by this composite membrane and original ceramics membrane showed that the PTFE membrane gives better detachability of the cake layer formed on the membrane. This might be due to the hydrophobic nature of the PTFE skin layer.

Phase equilibria modeling of biorefinery-related systems: a systematic review

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Marcos L. Corazza ◽  
Julia Trancoso
Keyword(s):  
Phase Equilibria ◽  
Phase Behavior ◽  
Fossil Fuel ◽  
Process Conditions ◽  
Design And Optimization ◽  
Waste Reuse ◽  
Wide Range ◽  
Prisma Statement ◽  
Fuel Substitution ◽  
The Subject

Abstract The search for sustainable ideas has gained prominence in recent decades at all levels of society since it has become imperative an economic, social, and environmental development in an integrated manner. In this context, biorefineries are currently present as the technology that best covers all these parameters, as they add the benefits of waste reuse, energy cogeneration, and fossil fuel substitution. Thus, the study of the various applicable biological matrices and exploring the technical capabilities of these processes become highly attractive. Thermodynamic modeling acts in this scenario as a fundamental tool for phase behavior predictions in process modeling, design, and optimization. Thus, this work aimed to systematize, using the PRISMA statement for systematic reviews, the information published between 2010 and 2020 on phase equilibria modeling in systems related to biorefineries to organize what is already known about the subject. As a result, 236 papers were categorized in terms of the year, country, type of phase equilibria, and thermodynamic model used. Also, the phase behavior predictions of different thermodynamic models under the same process conditions were qualitatively compared, establishing PC-SAFT as the model that best represents the great diversity of interest systems for biorefineries in a wide range of conditions.

scholarly journals Wear Resistance of (Ti,Al)N Metallic Coatings for Extremal Working Conditions

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 157
Author(s):  
Jarosław Mikuła ◽  
Daniel Pakuła ◽  
Ludwina Żukowska ◽  
Klaudiusz Gołombek ◽  
Antonín Kříž
Keyword(s):  
Wear Resistance ◽  
Functional Properties ◽  
Tool Life ◽  
Cutting Tools ◽  
Hard Coatings ◽  
Metallographic Analysis ◽  
Process Conditions ◽  
Tool Materials ◽  
Coated Materials ◽  
Wide Range

The article includes research results for the functional properties achieved for a wide range of sintered tool materials, including sintered carbides, cermets and three types of Al2O3 oxide tool ceramics ((Al2O3 + ZrO2, Al2O3 + TiC and Al2O3 + SiC(w)) with (Ti,Al)N coating deposited in the cathodic arc evaporation (CAE-PVD) method and comparison with uncoated tool materials. For all coated samples, a uniform wear pattern on tool shank was observed during metallographic analysis. Based on the scanning electron microscope (SEM) metallographic analysis, it was found that the most common types of tribological defects identified in tested materials are: mechanical defects and abrasive wear of the tool side, crater formation on the tool face, cracks on the tool side, chipping on the cutting edge and built-up edge from chip fragments. Deposition of (Ti,Al)N coating on all tested substrates increases the wear resistance and also limits the exceeding of critical levels of permanent stresses. It even increases the tool life many times over. Such a significant increase in tool life results, among other things, from a large increase in microhardness of PVD coated materials compared to uncoated samples, increased resistance to thermal and chemical abrasion, improved chip formation and removal process conditions. Use of hard coatings applied to sintered tool materials is considered to be one of the most important achievements in improving the functional properties of cutting tools and can still be developed by improving the coating structure solutions (sorted and nanocrystalline structures) and extending the range of coating applications (Ti,Al)N in a variety of substrates.

A New Flexible Rapid Thermal Processing System

1995 ◽  
Vol 389 ◽  
Author(s):  
K. C. Saraswat ◽  
Y. Chen ◽  
L. Degertekin ◽  
B. T. Khuri-Yakub
Keyword(s):  
Control System ◽  
Real Time ◽  
Processing System ◽  
Process Conditions ◽  
Temperature Uniformity ◽  
Real Time Control ◽  
Wafer Temperature ◽  
Time Control ◽  
Wide Range ◽  
Optical Flux

ABSTRACTA highly flexible Rapid Thermal Multiprocessing (RTM) reactor is described. This flexibility is the result of several new innovations: a lamp system, an acoustic thermometer and a real-time control system. The new lamp has been optimally designed through the use of a “virtual reactor” methodology to obtain the best possible wafer temperature uniformity. It consists of multiple concentric rings composed of light bulbs with horizontal filaments. Each ring is independently and dynamically controlled providing better control over the spatial and temporal optical flux profile resulting in excellent temperature uniformity over a wide range of process conditions. An acoustic thermometer non-invasively allows complete wafer temperature tomography under all process conditions - a critically important measurement never obtained before. For real-time equipment and process control a model based multivariable control system has been developed. Extensive integration of computers and related technology for specification, communication, execution, monitoring, control, and diagnosis demonstrates the programmability of the RTM.

scholarly journals Combining experimental and simulation data of molecular processes via augmented Markov models

2017 ◽  
Vol 114 (31) ◽  
pp. 8265-8270 ◽  
Author(s):  
Simon Olsson ◽  
Hao Wu ◽  
Fabian Paul ◽  
Cecilia Clementi ◽  
Frank Noé
Keyword(s):  
Force Field ◽  
Structural Changes ◽  
Markov Models ◽  
Force Fields ◽  
Divide And Conquer ◽  
Simulation Data ◽  
Wide Range ◽  
Simulation And Experiment ◽  
Kinetics Of

Accurate mechanistic description of structural changes in biomolecules is an increasingly important topic in structural and chemical biology. Markov models have emerged as a powerful way to approximate the molecular kinetics of large biomolecules while keeping full structural resolution in a divide-and-conquer fashion. However, the accuracy of these models is limited by that of the force fields used to generate the underlying molecular dynamics (MD) simulation data. Whereas the quality of classical MD force fields has improved significantly in recent years, remaining errors in the Boltzmann weights are still on the order of a few kT, which may lead to significant discrepancies when comparing to experimentally measured rates or state populations. Here we take the view that simulations using a sufficiently good force-field sample conformations that are valid but have inaccurate weights, yet these weights may be made accurate by incorporating experimental data a posteriori. To do so, we propose augmented Markov models (AMMs), an approach that combines concepts from probability theory and information theory to consistently treat systematic force-field error and statistical errors in simulation and experiment. Our results demonstrate that AMMs can reconcile conflicting results for protein mechanisms obtained by different force fields and correct for a wide range of stationary and dynamical observables even when only equilibrium measurements are incorporated into the estimation process. This approach constitutes a unique avenue to combine experiment and computation into integrative models of biomolecular structure and dynamics.

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