scholarly journals Geochemical Classification and Geotectonic Setting of Granitic Gneisses from Southeastern Margin of Western Nigeria Basement

2021 ◽  
Vol 3 (2) ◽  
Author(s):  
Mohammed Olatoye Adepoju ◽  
Yinusa Ayodele Asiwaju-Bello
Keyword(s):  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Calc Alkaline ◽  
Granitic Gneiss ◽  
Basement Complex ◽  
Southwestern Nigeria ◽  
Inductively Coupled ◽  
Continental Arc ◽  
Southeastern Margin ◽  
Geochemical Classification

Chemical whole-rock major oxides and some trace element analyses were done on granitic gneiss rocks located on the southeastern margin of western Nigeria Basement Complex, exposed in parts of Dagbala-Atte District, southwestern Nigeria. This was meant to classify the rocks and to understand the tectonic setting in order to evaluate their crustal evolution. The chemical analyses were done using inductively-coupled plasma mass spectrometer. From the results obtained, these rocks classified into calc-alkaline to shoshonite series with metaluminous to peraluminous varieties, they are I-type granitoids of feroan composition. The granitic gneisses formed from metamorphism of granite and granodiorite. Tectonically, most of the rock samples plotted in the field of island arc, continental arc and continental-collisional granitoids, which indicated that the protolith granite and granodiorite are orogenic and are arc related inferring arc tectonic setting.

scholarly journals Geochemistry of Fluvial Sediments from Geregu, Southwest Nigeria

2017 ◽  
Vol 64 (1) ◽  
pp. 35-52 ◽  
Author(s):  
Emmanuel E. Adiotomre ◽  
Innocent O. Ejeh ◽  
Edwin O. Adaikpoh
Keyword(s):  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Passive Margin ◽  
Fluvial Sediments ◽  
Geochemical Analysis ◽  
Sediment Samples ◽  
Inductively Coupled ◽  
Southwest Nigeria ◽  
Plasma Mass Spectrometry ◽  
Quartz Grains

Abstract Geochemical analysis of fluvial sediments on the banks of River Ero using inductively coupled plasma mass spectrometry illustrates their maturity, provenance and tectonic setting. The analysed sediment samples show low SiO2/Al2O3 ratios of 2.92-2.99 (units FL_A, FL_B and FL_E) and high SiO2/Al2O3 ratios of 4.064-4.852 (units FL_C, FL_D, FL_F and FL_G). Sediments were geochemically classified as shales (units FL_A, FL_B and FL_E) and greywackes (units FL_C, FL_D, FL_F and FL_G). Variability in sediment maturity (FL_F > FL_G >FL_C >FL_D >FL_A > FL_B > FL_E) parallels a decreasing order in the ratios of SiO2/Al2O3 and K2O/Al2O3, as well as the proportion of quartz grains and matrix components. Evidence from Al2O3/TiO2, K2O, Rb, La/Co, Th/Co, Cr/ Th, Th/Cr, La/Th-Hf, Th-Hf-Co and rare earth element contents of sediment samples suggest felsic protoliths of upper continental crust in a passive margin tectonic setting. An insignificant contribution of mafic components from the source is, however, inferred based on the Ni and Cr contents of the sediment samples. Combined Eu anomalies <0.85 and (Gd/Yb)n ratios <2.0 (1.53- 1.82, average 1.65) suggest post-Archean protoliths.

scholarly journals Provenance Studies of Sandstone Facies Exposed Near Igbile Southwestern Nigeria: Petrographic and Geochemical Approach

2014 ◽  
Vol 6 (2) ◽  
pp. 47 ◽  
Author(s):  
Ikhane P. R. ◽  
Akintola A. I. ◽  
Bankole S. I. ◽  
Oyinboade Y. T.
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Source Area ◽  
Rock Fragment ◽  
Petrographic Analysis ◽  
Humid Climate ◽  
Southwestern Nigeria ◽  
Plagioclase Feldspar

The petrography, as well as the major, trace and rare earth element compositions of ten (10) sandstone samples of Maastrichtian Afowo Formation exposed near Igbile, Southwestern Nigeria, have been investigated to determine their provenance, source area weathering conditions, paleoclimate and tectonic setting using petrographic analysis and Inductively Coupled Plasma - Mass Spectrometry (ICP-MS). Results of the petrographic analysis revealed that quartz is the most dominant detrital mineral with (86%) followed by weathered plagioclase feldspar (5.10%) and rock fragments (10.9%). The quartz grain is sub-angular to sub-rounded in shape and the sandstones were classified as quartz arenites, sublitharenites and subarkoses based on framework composition of quartz, feldspar and rock fragment plots. This suggests a recycled orogen source for the sandstones and deposition in a humid climate, evidenced by the weathered feldspars. Eleven (11) major, seventeen (17) trace and fourteen (14) rare earth elements were obtained from the geochemical analysis. The major elements values range in concentration from 0.01%–81.39% with SiO2 being the dominant oxide followed by Al2O3 and Fe2O3 constituting over 95% of the major oxides; K2O, TiO2, Na2O, CaO, MgO and P2O5 made up the remaining 5%. The average ratio of SiO2/Al2O3 valued 4.31 for the sandstone is appreciably high indicating that it has been heavily weathered. The trace elements range in concentration from 0.2 ppm–1651.2 ppm with Zr being the most dominant element an indication of orogenic recycling. The rare earth elements range in concentration from 0.01 ppm–163.7 ppm with Ce having the highest concentration, depicting that the sandstones were deposited in an oxidizing environment. Also, the trace element relationship illustrated from the spider plot shows chemical coherence and uniformity of the sandstones. The chondrite normalized rare earth elements (REE) plot shows enrichment in the Light REE over the heavy REE for the sediment with strong negative Eu anomaly values between (0.57–0.69) suggesting a felsic provenance derived from upper continental crust for the sandstones.

scholarly journals Geochemistry of the Um Had Plutonites, Central Eastern Desert, Egypt: Implications for Magma Evolution, and Tectonic Setting

2014 ◽  
Vol 6 (2) ◽  
pp. 36 ◽  
Author(s):  
Nedal Qaoud
Keyword(s):  
Tectonic Setting ◽  
Active Continental Margin ◽  
Eastern Desert ◽  
Island Arc ◽  
Water Vapour Pressure ◽  
Calc Alkaline ◽  
Magma Evolution ◽  
Basement Complex ◽  
Central Eastern Desert ◽  
Pan African

Geochemistry of gabbroid and granitoid plutonites from the Um Had area indicates island arc subalkaline basic magma with tholeiitic affinity and calc-alkaline, metaluminous and slightly peraluminous magma, respectively. Although different in age both plutonite types were emplaced under compressional regime, where subduction-related environment was dominant. They were formed under relatively low to moderate water-vapour pressure (1–5 k-bars) at moderate depths (20–30 km). Biotite granites were formed at a relatively high temperature range (800–840 °C), while biotite-muscovite granites were formed under relatively moderate temperature conditions (760–800 °C). These two units may represent evolution from island arc to active continental margin. It is suggested that island arc gabbros might have sourced the late subduction-related calc-alkaline granitoids during the waning stages of the pan-African orogeny. The I-type nature of the investigated plutonites in the study area and elsewhere suggests the juvenile character of the basement complex of the Eastern Desert of Egypt.

scholarly journals Rare Earth Elements Assessment in the Granitoids of Part of Southwestern Nigeria

2020 ◽  
Vol 1 (5) ◽  
Author(s):  
Victoria B. Omotunde ◽  
Akinade S. Olatunji ◽  
Maryam O. Abdus-Salam
Keyword(s):  
Rare Earth ◽  
Rare Earth Elements ◽  
Inductively Coupled Plasma ◽  
Granite Gneiss ◽  
Biotite Granite ◽  
Geochemical Data ◽  
Southwestern Nigeria ◽  
Lithological Mapping ◽  
Inductively Coupled ◽  
Gneiss Granite

The Rare Earth Elements (REE) composition of granitoids in and around Ila-Orangun area Southwestern Nigeria was assessed in order to ascertain their potential for possible exploitation. Detailed lithological mapping of the area was undertaken followed by whole rock geochemical analysis of representative samples of the granitoids using Inductively Coupled Plasma Mass Spectrometry (ICP-MS) technique. Petrographic study of the samples was carried out as well as the interpretation of the geochemical data using diverse geochemical discrimination plots. The rock units mapped were biotite granite gneiss, granite gneiss and hornblende biotite granite. Biotite hornblende gneiss, quartzite, talc-chlorite-tremolite-schist, mica schist and pegmatites were the surrounding country rocks. The REE concentrations (in ppm) revealed higher concentrations of the light REEs compared to the heavy REEs. The fractionation ratio, (La/Yb)N ranged from 4.35-15.04 (granite gneiss) and 13.78-18.48 (hornblende biotite granite) indicating enrichment in LREEs over the HREEs. The spider plot for the REEs also showed that the granitoids are LREE-enriched and HREE-depleted suggesting fractional crystallisation and a distinct negative Eu anomaly indicating plagioclase fractionation. Enrichment plot also revealed that the REEs in the granitoids are significantly enriched. Comparison with other areas showed that the granitoids of the study area especially the hornblende biotite granite has higher concentrations of REEs and may be a possible pointer of REE mineralisation.

scholarly journals Evidence of Carboniferous arc magmatism preserved in the Chicxulub impact structure

2021 ◽  
Author(s):  
Catherine H. Ross ◽  
Daniel F. Stockli ◽  
Cornelia Rasmussen ◽  
Sean P.S. Gulick ◽  
Sietze J. de Graaff ◽  
...  
Keyword(s):  
Inductively Coupled Plasma ◽  
Impact Structure ◽  
Continuous Section ◽  
Northern Margin ◽  
Scientific Drilling ◽  
Inductively Coupled ◽  
Basement Rocks ◽  
Continental Arc ◽  
Nw Gondwana ◽  
Chicxulub Impact

Determining the nature and age of the 200-km-wide Chicxulub impact target rock is an essential step in advancing our understanding of the Maya Block basement. Few age constraints exist for the northern Maya Block crust, specifically the basement underlying the 66 Ma, 200 km-wide Chicxulub impact structure. The International Ocean Discovery Program-International Continental Scientific Drilling Program Expedition 364 core recovered a continuous section of basement rocks from the Chicxulub target rocks, which provides a unique opportunity to illuminate the pre-impact tectonic evolution of a terrane key to the development of the Gulf of Mexico. Sparse published ages for the Maya Block point to Mesoproterozoic, Ediacaran, Ordovician to Devonian crust are consistent with plate reconstruction models. In contrast, granitic basement recovered from the Chicxulub peak ring during Expedition 364 yielded new zircon U-Pb laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) concordant dates clustering around 334 ± 2.3 Ma. Zircon rare earth element (REE) chemistry is consistent with the granitoids having formed in a continental arc setting. Inherited zircon grains fall into three groups: 400−435 Ma, 500−635 Ma, and 940−1400 Ma, which are consistent with the incorporation of Peri-Gondwanan, Pan-African, and Grenvillian crust, respectively. Carboniferous U-Pb ages, trace element compositions, and inherited zircon grains indicate a pre-collisional continental volcanic arc located along the Maya Block’s northern margin before NW Gondwana collided with Laurentia. The existence of a continental arc along NW Gondwana suggests southward-directed subduction of Rheic oceanic crust beneath the Maya Block and is similar to evidence for a continental arc along the northern margin of Gondwana that is documented in the Suwannee terrane, Florida, USA, and Coahuila Block of NE México.

scholarly journals Trace elements characterisation in floodplain soils underlain by crystalline rocks, akure, southwestern Nigeria

2019 ◽  
Vol 7 (1) ◽  
pp. 31 ◽  
Author(s):  
Asowata I.T ◽  
Omokolade O.G
Keyword(s):  
Trace Elements ◽  
Inductively Coupled Plasma ◽  
Mesh Size ◽  
Emission Spectrometry ◽  
Southwestern Nigeria ◽  
Inductively Coupled ◽  
Floodplain Soils ◽  
Plasma Emission Spectrometry ◽  
Icp Ms ◽  
Two Samples

The results of the floodplain soils study on the spatial distribution of selected trace elements in top soils (0 – 30 cm) and sub soils (> 30 – 100 cm) near Ala River, Akure metropolis, are reported. The objectives of this study are to determine the concentration of trace elements in the top and bottom soils, and identify the possible enrichment sources of these elements in the floodplain area. Forty two samples (top soil 21; sub soil 21) were collected for the study. The samples were air dried at room temperature, disaggregated and sieved using 53 µg mesh size. The prepared samples were further digested using modified aqua regia of (1:1:1 HNO3: HCL: H2O). The digests were subjected to elemental analysis using Inductively Coupled Plasma-Emission Spectrometry (ICP-MS). The trace elements concentration in ppm exhibited the following distribution pattern. Cu range in ppm from 6.0 – 53.0 mean 27.43; Pb, 10.0 – 165.0, mean 58.43; Zn, 29.0 – 479.0 mean 223.1; Ni, 10.0 – 20.0, mean 14.86; Co, 16.0 – 33.0, mean 24.29; Mn, 250.0 – 1615.0, mean 983.29; Th 9.0 – 19.0, mean 14.43; V, 35.0 – 89.0, mean 73.05; La 26.0 – 84.0, mean 56.76 and Cr 11.0 – 60.0 mean 40.43. While the result for the sub soils range in ppm, Cu from 3.0 – 51.0, mean 21.24; Pb, 7.0 – 208.0, mean 56.33; Zn, 21.0 - 460.0. mean 149.14; Ni, 8.0 – 29.0, mean 13.76; Co, 12.0 – 37.0, mean 23.95; Mn, 138.0 – 2283.0, mean 806.43; Th 9.0 – 28.0, mean 17.48; V, 40.0 – 105.0, mean 68.71; La 25.0 – 96.0, mean 61.00 and Cr 12.0 – 58.0 mean 35.38. The results of both the top soils and sub soils showed higher concentration metal enrichment than the average shale values. The relative elemental mean concentration is such that Mn> Zn > V > La > Pb > Cr > Co > Cu > Th > Ni in that order. Elements such as Cu, Zn, Pb, V, Mn, Th and Cr had relatively moderate to very strong correlation coefficient (r = 0.54 0.97) with each other, which apparently indicate that these elements are of same source of enrichment in the floodplain. Pb, Zn, V, La, Th and Cr are elements that are of significant environmental concerns.   

Geochemical Characteristics of the Campano-Maastrictian Sediments of the Anambra Basin, Southeastern Nigeria - Implication For Provenance, Paleodepositional Environment, Maturity and Tectonic Setting

2021 ◽  
Author(s):  
Michael Edirin Okiotor ◽  
EDeh Desiree Ogueh
Keyword(s):  
Inductively Coupled Plasma ◽  
Tectonic Setting ◽  
Passive Margin ◽  
Source Rocks ◽  
Sediment Provenance ◽  
Southeastern Nigeria ◽  
Inductively Coupled ◽  
Anambra Basin ◽  
Plasma Mass Spectrometry ◽  
Chemical Index Of Alteration

Abstract The present study investigates the Anambra Basin shales to determine the provenance and maturity of the sediments using standard geochemical techniques. Twelve (12) representative samples recovered from shale sequences of The Mamu Formation and Nkporo Group of The Anambra Basin were studied to determine the sediment provenance, paleoenvironment, diagenetic conditions, maturity as well as the tectonic setting. To consider in detail and establish the inherent constituents of the Major minerals, Trace and Rare Earth elements, Inductively Coupled Plasma Mass Spectrometry (ICP-MS) analyses techniques was employed. The detrital minerals determined are Al2O3 (18.27% and 21.16%), TiO2 (1.73% and 1.63%) and Fe2O3 (2.78% \ and 2.85%), for Nkporo Group and Mamu Formation respectively. The enrichment of SiO2, Al2O3 and TiO2 (1.14, 1.94, 3.67 respectively) supported by Chemical Index of Alteration (CIA) of 93.54 & 39.55 and Rb/Sr ratio of 0.57 & 0.40, indicate that the Anambra Basin sediments are matured. TiO2/AL2O3 binary plots, Th/Co Vs La/Sc crossplots, Th-Sc-Zr triplots and Cr, Ni concentration suggest mixed provenance of felsic to mafic source rocks for these sediments. From the log (K2O/Na2O) Vs SiO2 crossplots, a passive margin tectonic setting was determined for these sediments.

scholarly journals Petrography and Geochemistry of the Banded Iron Formation of the Gangfelum Area, Northeastern Nigeria

2017 ◽  
Vol 7 (1) ◽  
pp. 25
Author(s):  
Anthony Temidayo Bolarinwa
Keyword(s):  
Iron Oxide ◽  
Inductively Coupled Plasma ◽  
Optical Emission ◽  
Iron Formation ◽  
Icp Oes ◽  
Banded Iron Formation ◽  
Basement Complex ◽  
Inductively Coupled ◽  
Iron Precipitation ◽  
Icp Ms

The Gangfelum Banded Iron Formation (BIF) is located within the basement complex of northeastern Nigeria. It is characterized by alternate bands of iron oxide and quartz. Petrographic studies show that the BIF consist mainly of hematite, goethite subordinate magnetite and accessory minerals including rutile, apatite, tourmaline and zircon. Chemical data from inductively coupled plasma optical emission spectrometer (ICP-OES) and inductively coupled plasma mass spectrometer (ICP-MS) show that average Fe2O3(t) is 53.91 wt.%. The average values of Al2O3 and CaO are 1.41 and 0.05 wt.% respectively, TiO2 and MnO are less than 0.5 wt. % each. The data suggested that the BIF is the oxide facies type. Trace element concentrations of Ba (67-332 ppm), Ni (28-35 ppm), Sr (13-55 ppm) and Zr (16-25 ppm) in the Gangfelum BIF are low and similar to the Maru and Muro BIF in northern Nigeria and also the Algoma iron formation from North America, the Orissa iron oxide facies of India and the Itabirite from Minas Gerais in Brazil. The evolution of the Gangfelum BIF involved metamorphism of chemically precipitated or rhythmically deposited iron-rich sediments into hematite-quartz rocks. The banding of the BIF suggested a break in iron precipitation probably due to iron oxide deficiency. 

Neoproterozoic Jiangnan Orogeny in southeast Guizhou, South China: evidence from U–Pb ages for detrital zircons from the Sibao Group and Xiajiang Group

2016 ◽  
Vol 53 (3) ◽  
pp. 219-230 ◽  
Author(s):  
Xiao Ma ◽  
Kunguang Yang ◽  
Xuegang Li ◽  
Chuangu Dai ◽  
Hui Zhang ◽  
...  
Keyword(s):  
South China ◽  
Detrital Zircon ◽  
Inductively Coupled Plasma ◽  
Detrital Zircons ◽  
North India ◽  
Yangtze Block ◽  
Inductively Coupled ◽  
Two Samples ◽  
Southeastern Margin ◽  
Depositional Age

The Jiangnan Orogeny generated regional angular unconformities between the Xiajiang Group and the underlying Sibao Group in the western Jiangnan Orogen along the southeastern margin of the Yangtze Block in southeast Guizhou, South China. Laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS) U–Pb zircon dating of two samples of the Motianling granitic pluton yielded U–Pb zircon ages of 826.2 ± 3.4 and 825.5 ± 6.1 Ma, with an average age of 825.6 ± 3.0 Ma, which is considered the minimum depositional age of the Sibao Group. The U–Pb ages of the youngest detrital zircon grains from the Sibao Group and the Xiajiang Group yielded average ages of 834.9 ± 3.8 and 794.6 ± 4.2 Ma, respectively. The depositional age of the Sibao Group can be constrained at 825–835 Ma, and deposition of the Xiajiang Group did not begin before ca. 800 Ma. These results suggest that the Jiangnan Orogeny, which led to the assembly of the Yangtze and Cathaysia blocks, ended at 795–835 Ma on the western segment of the Jiangnan Orogen. The detrital zircon distribution spectrums of the Sibao and Xiajiang groups suggest a provenance from Neoproterozoic basement sedimentary sequences along with a mixture of local Neoproterozoic subduction-related felsic granitoids, distant plutons from the western Yangtze Block and eastern Jiangnan Orogen, and recycled materials from the interior of the Yangtze Block. By comparing the basin evolution histories and magmatic and metamorphic events along the continental margins of the Rodinia supercontinent, it is proposed that the South China Block might have been located at the periphery, adjacent to North India and East Antarctica, rather than in the interior of Rodinia in Neoproterozoic time.

Age and geological context of the Barby Formation, a key volcanic unit in the Mesoproterozoic Sinclair Supergroup of southern Namibia

2019 ◽  
Vol 122 (4) ◽  
pp. 519-540
Author(s):  
T. Malobela ◽  
B. Mapani ◽  
M. Harris ◽  
D.H. Cornell ◽  
A. Karlsson ◽  
...  
Keyword(s):  
Mass Spectrometer ◽  
Inductively Coupled Plasma ◽  
Cell Mass ◽  
Active Continental Margin ◽  
Volcanic Rocks ◽  
Granite Gneiss ◽  
Crustal Material ◽  
Calc Alkaline ◽  
Inductively Coupled ◽  
Rock Types

Abstract Volcanic and sedimentary rocks of the Sinclair Supergroup occur in the Konkiep Terrane of Southern Namibia. Three volcanic and sedimentary cycles are recognised. In this work we describe and date volcanic rocks of the Barby Formation, a key unit in the Sinclair area. The coeval Spes Bona Syenite and the Tiras Granite Gneiss are also described and dated. The rock types in the Barby Formation are rhyolites, basaltic trachyandesites, trachybasalts and trachydacites as well as volcanoclastic rocks. The rocks are largely undeformed and partly altered by deuteric and contact metamorphic processes but not regionally metamorphosed. Our samples represent both the calc-alkaline and alkaline trends documented in previous work. U-Pb ion probe and laser ablation inductively coupled plasma (LA-ICP) multicollector mass spectrometer Lu-Hf microbeam analyses were made of zircon and baddeleyite grains from four samples. A felsic tuff sample from the base of the Barby Formation has a 207Pb/206Pb zircon age of 1214 ± 5 Ma (2σ). A rhomb porphyry sample from the top of an 8.5 km-thick stratigraphic section gives a 207Pb/206Pb baddeleyite age of 1217 ± 2 Ma. The Spes Bona Syenite which intrudes the top of the Barby Formation has a 207Pb/206Pb baddeleyite age of 1217 ± 3 Ma and an indistinguishable LA-ICP collision cell mass spectrometer Rb-Sr biotite isochron age of 1238 ± 20 Ma, showing that there was no &gt;350°C regional metamorphic event. Multi-element diagrams for the calc-alkaline samples show a dominant signature of reworked crust which is superimposed on a possible subduction signature. However the alkaline samples contain clear subduction signatures which are not seen in the underlying 1.37 Ga Kumbis rhyolite. The Barby Formation samples and coeval Spes Bona Syenite have Lu-Hf crustal residence ages between 1682 and 1873 Ma, suggesting that both of these units formed from a mixture of juvenile mantle-derived and older crustal material. The Barby Formation is considered to have originated due to a subduction event which took place during the assembly of the Rodinia supercontinent. The duration of the Barby magmatic episode is constrained to a maximum 9 m.y. period between 1219 and 1210 Ma, and during this period the Konkiep Terrane was an active continental margin. The 1204 ± 9 Ma Tiras Granite Gneiss is slightly younger than the Barby Formation and intruded across the Lord Hills Shear Zone, which is the suture between the hardly metamorphosed Konkiep Terrane and the highly metamorphosed Grunau Terrane of the Namaqua-Natal Province. Its intrusion reflects the end of subduction-related volcanism, due to the collision of Namaqua terranes with the Konkiep Terrane.

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