scholarly journals Paper strength improvement by inclusion of nano-lignocellulose to Chemi-thermomechanical pulp

2014 ◽  
Vol 29 (2) ◽  
pp. 309-316 ◽  
Author(s):  
Sinke H. Osong ◽  
Sven Norgren ◽  
Per Engstrand
Keyword(s):  
Strength Properties ◽  
Thermomechanical Pulp ◽  
Paper Strength ◽  
Chemical Pulp ◽  
Bleached Kraft Pulp ◽  
Tear Index ◽  
Air Resistance ◽  
Thermomechanical Pulping ◽  
Pulp Fibres ◽  
Sheet Density

Abstract So far, chemical pulp fibres have been utilized as conventional stock materials for nanocellulose production. The main aim of this work is to use stock materials from mechanical or chemi-thermomechanical pulping process to produce lignin containing nanofibres, which are referred to as nano-ligno-cellulose (NLC) in this study. The present study shows the influence on handsheets of chemi-thermomechanical pulp (CTMP) fibres blended with NLC. For comparison reasons, nanocellulose (NC) from bleached kraft pulp (BKP) was produced in a similar approach as NLC. Both the NLC and the NC were blended with their respective pulp fibres and their corresponding handsheets properties were evaluated with respect to sheet density. It was found that the handsheets of pulp fibres blended with NLC/NC improved the mechanical properties of handsheets with only a slight effect in relation to the sheet density. Improvements in strength properties of handsheets such as z-strength, tensile index, tear index, burst index, Emodulus, strain at break, tensile stiffness, air resistance were observed.

scholarly journals High strength paper from high yield pulps by means of hot-pressing

2020 ◽  
Vol 35 (2) ◽  
pp. 195-204
Author(s):  
Tove Joelsson ◽  
Gunilla Pettersson ◽  
Sven Norgren ◽  
Anna Svedberg ◽  
Hans Höglund ◽  
...  
Keyword(s):  
Tensile Strength ◽  
Hot Pressing ◽  
Kraft Pulp ◽  
High Strength ◽  
Strength Properties ◽  
High Yield ◽  
Thermomechanical Pulp ◽  
Wet Strength ◽  
Chemical Pulp ◽  
Bleached Kraft Pulp

AbstractThe hypothesis is that it should be possible to modify papermaking conditions in line with the softening properties of high yield pulp fibres and achieve similar strength properties to conventional chemical pulp based paper. We therefore investigated the rheological and physical properties of high yield pulp based papers during hot-pressing. Our results confirm that increased temperature combined with sufficient pressure enables permanent densification by softening of lignin, producing very high tensile strength. This treatment also significantly improved the wet tensile strength in comparison to bleached kraft pulp without using wet strength agents. The high yield pulps used here were spruce based thermomechanical pulp, chemi-thermomechanical pulp, and high temperature chemi-thermomechanical pulp, and birch-aspen based neutral sulphite semi chemical pulp, with spruce-pine based bleached kraft pulp as reference. Rapid Köhten sheets of 150\hspace{0.1667em}\text{g}/{\text{m}^{2}} and 50 % dryness were hot-pressed in a cylinder-press at 20–200 °C, 7 MPa, and 1 m/min. The mechanical properties showed great improvements in these high yield pulp papers, with tensile index increased to 75 kNm/kg and compression strength index to 45 kNm/kg; levels close to and better than bleached kraft. Wet strength increased to 16 Nm/g compared to 5 Nm/g for bleached kraft.

Influence of cellulose supramolecular structure on strength properties of chemical pulp

Holzforschung ◽  
2014 ◽  
Vol 68 (8) ◽  
pp. 861-866 ◽  
Author(s):  
Per Tomas Larsson ◽  
Lennart Salmén
Keyword(s):  
Supramolecular Structure ◽  
Strength Properties ◽  
Cellulose Microfibrils ◽  
Kraft Pulps ◽  
Chemical Pulp ◽  
Chemical Pulps ◽  
Fiber Wall ◽  
Tear Index ◽  
Pulp Strength ◽  
Selective Increase

Abstract The industrially produced chemical pulps have lower strength properties than those obtained under laboratory conditions, and this difference is referred to as the strength delivery (SD) problem. In this study, the hypothesis was put forward that the SD could, at least in part, be accounted for by the supramolecular structure of the cellulose microfibrils of the fiber wall. To test the hypothesis, two bleached softwood kraft pulps (BSKP) were manufactured from the same starting material with different degrees of cellulose aggregation, but the pulps were otherwise as similar as possible in other controllable respects. The chemical and physical properties, including the pulp strength, were tested. A selective increase of the degree of cellulose microfibril aggregation resulted in a pulp with a decreased tear index (TI) at a specified tensile index, and this decrease was similar in magnitude to what is typically encountered in SD. Accordingly, the current experimental study succeeded in mimicking the SD problem. The lateral fibril aggregate dimensions (LFAD) seem to play a pivotal role and it can be safely concluded in general that the supramolecular structure of cellulose in the fibers may be an important factor contributing to the SD problem.

Application of DSA to improve strength of thermomechanical pulp blended paper

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Cheol Woo Lee ◽  
Jeong Yong Ryu
Keyword(s):  
Kraft Pulp ◽  
High Strength ◽  
Thermomechanical Pulp ◽  
Paper Strength ◽  
Bleached Kraft Pulp ◽  
Degree Of Refining ◽  
Strength Improvement

Abstract A more efficient application of a dry strength agent (DSA) was investigated to improve the strength of thermomechanical pulp (TMP) blended paper. Strength improvement by DSA application was more effective for hardwood bleached kraft pulp (Hw-BKP) than TMP. The degree of strength improvement of DSA further increased with the increasing degree of refining of Hw-BKP. The strength of the paper was decreased by the fines fractionation of TMP, but the strength improvement efficiency of DSA for the fines fractionated TMP increased. In order to increase the strength of TMP mixed paper using DSA, it is expected that DSA should be adsorbed only to Hw-BKP with high strength improvement efficiency, not TMP fines. When the DSA was mixed with Hw-BKP before contact with other stocks, it was confirmed that the effect of improving the strength by the DSA is the best. The strength improving effect increased as TMP fines were removed. Therefore, to improve the strength of the paper containing TMP in Hw-BKP by adding a DSA, it is preferable to selective apply the DSA to Hw-BKP while blending only the fibers of TMP by fractionation.

Spruce fiber properties after high-temperature thermomechanical pulping (HT-TMP)

Holzforschung ◽  
2014 ◽  
Vol 68 (2) ◽  
pp. 195-201 ◽  
Author(s):  
Iina Solala ◽  
Toni Antikainen ◽  
Mehedi Reza ◽  
Leena-Sisko Johansson ◽  
Mark Hughes ◽  
...  
Keyword(s):  
Energy Consumption ◽  
High Temperature ◽  
Matrix Material ◽  
Specific Energy Consumption ◽  
Electrical Energy ◽  
Strength Properties ◽  
Thermomechanical Pulp ◽  
Wall Region ◽  
Fiber Properties ◽  
Thermomechanical Pulping

Abstract Spruce was submitted to high-temperature (150°C–170°C) refining for 2 or 5 min to produce thermomechanical pulp (TMP) fibers with decreased electrical energy consumption. The pulp was characterized in terms of specific energy consumption as well as tensile and surface properties. The fibers from high-temperature TMP contained more surface lignin even if all sample types usually broke at the S1–S2 cell wall region. They also produced significantly weaker paper sheets, whereas their dry zero-span strength did not suffer substantial losses, indicating decreased fiber-fiber bonding. Tensile strength properties were also determined of a bisphenol-A-epichlorohydrin-based epoxy resin mixed with 5% fiber as a test for fiber-matrix compatibility in composite applications. Based on these preliminary results, high-temperature TMP shows potential for composite reinforcement due to its lower tendency to aggregate and its better compatibility with the tested matrix material.

scholarly journals MODIFIKASI PERMUKAAN SERAT LBKP DAN HASIL DEINKING DENGAN KARBOKSIMETIL SELULOSA

2016 ◽  
Vol 2 (02) ◽  
Author(s):  
Sonny Kurnia Wirawan ◽  
Nina Elyani ◽  
Jenni Rismijana
Keyword(s):  
Physical Properties ◽  
Carboxymethyl Cellulose ◽  
Kraft Pulp ◽  
Fiber Strength ◽  
Fiber Quality ◽  
Strength Properties ◽  
Sem Analysis ◽  
Tensile Index ◽  
Bleached Kraft Pulp ◽  
Tear Index

The strength properties of paper are strongly affected by fiber quality. The objective of this study was to assess the effect of modification fiber by carboxymethylation of leaf bleached kraft pulp (LBKP) and deinked pulp (DIP) by using carboxymethyl cellulose (CMC). Carboxymethylation was carried out by addition of various concentration of CMC and cationic agent of CaCl2. Handsheets with 70 gsm were made from the stock, and the physical properties were tested as the tensile index, stretch, tensile energy absorption (TEA), tearing index, and bursting index as well as SEM analysis. The results showed that the highest increase of fiber strength of LBKP and DIP was achieved by addition of 1% CMC and 9.19% CaCl2. For LBKP, the increasing of tensile index was 18.1%, stretch 27%, TEA 30.2%, tear index 7,8 % and burst index 16,7%. Whereas for DIP, the increasing of tensile index reached 29.9%, stretch 22.2%, TEA 61.2%, tear index 20.7% and burst index 63.1%. From the results of SEM analysis showed that the addition of CMC and CaCl2 increased fiber bonding.Keywords: CMC, LBKP, DIP ABSTRAK Sifat kekuatan kertas sangat dipengaruhi oleh kualitas serat. Tujuan penelitian ini adalah untuk mengetahui pengaruh modifikasi serat kraft putih kayu daun (LBKP) dan serat hasil deinking (DIP) dengan karboksimetilasi menggunakan karboksimetil selulosa (CMC). Modifikasi secara karboksimetilasi dilakukan dengan variasi penambahan CMC dan sebagai cationic agent CaCl2. Lembaran dibuat dari stok dengan gramatur 70 gsm, kemudian dilakukan pengujian fisik dengan parameter indeks tarik, regang, TEA, indeks sobek dan indeks retak. Selain itu lembaran juga diuji morfologi dan SEM. Hasil penelitian menunjukan peningkatan kekuatan lembaran tertinggi dicapai oleh LBKP maupun DIP, pada kondisi penambahan 1% CMC and 9.19% CaCl2. Untuk LBKP peningkatan indeks tarik adalah 18,1%, regang 27%, TEA 30,2%, indeks sobek 7,8 % dan indeks retak 16,7%. Sedangkan untuk DIP, peningkatan indeks tarik mencapai 29,9%, regang 22,2%, TEA 61,2%, indeks sobek 20,7% dan indeks retak 63,1%. Hasil analisa SEM menunjukan bahwa dengan penambahan CMC dan CaCl2, mengakibatkan terjadi peningkatan ikatan antar serat.Kata kunci: CMC, LBKP, DIP

scholarly journals THE EFFECT OF ORGANOSOLV TREATMENT ON THE PHYSICOCHEMICAL PROPERTIES OF PULP AND PAPER FROM HORSE GRASS (ANDROPOGON TECTORUM).

2020 ◽  
Vol 45 (6) ◽  
Author(s):  
O. Otitoju ◽  
A.O. Ashogbon
Keyword(s):  
Fiber Length ◽  
Fiber Diameter ◽  
Good Alternative ◽  
Strength Properties ◽  
Cooking Time ◽  
Pulp And Paper ◽  
Paper Strength ◽  
Ethanoic Acid ◽  
Tear Index ◽  
Alternative Sources

The delignification of horse grass (HG) was carried out using methanol and water (organosolv pulping); varying the cooking conditions at 30min, 60min and 90min with ratios: 1:1, 1:2 and 1:3, Methanol-water, cooked in autoclave at 1050C. The pulp obtained were selected and macerated in equal volume of glacial acetic acid (ethanoic acid) and hydrogen peroxide (1:1) at a temperature 1000C, to investigate the fiber length; fiber diameter; lumen with their derived indices and paper strength properties was determined according to TAPPI standard methods, T 494 om-96. The best fiber length of 3.21mm, tear index 31.43 mN.m2/g, tensile index 97.79Nm/g and bulk index 5.15 kPa.m2/g was obtained at 1:3 methanol: H2O at 105°C with cooking time of 60 min. Therefore, it was established that high quality papers of different grades can be produced from horse grass with acceptable strength properties using low concentration of methanol/water pulping with moderate time at boiling temperature. The research concluded that methanol-water was excellently good for pulping of horse grass fibers. The above results showed that horse grass is a good alternative sources of fibers to produce pulp and paper.

The effect of MFC on the pressability and paper properties of TMP and GCC based sheets

2012 ◽  
Vol 27 (2) ◽  
pp. 388-396 ◽  
Author(s):  
Collin Hii ◽  
Øyvind W. Gregersen ◽  
Gary Chinga-Carrasco ◽  
Øyvind Eriksen
Keyword(s):  
Strength Properties ◽  
Microfibrillated Cellulose ◽  
Thermomechanical Pulp ◽  
Paper Properties ◽  
Fibre Network ◽  
Air Resistance ◽  
Wet Pressing ◽  
Solids Content ◽  
Ground Calcium Carbonate ◽  
Scanning Electron

Abstract Different qualities of microfibrillated cellulose (MFC) were blended with thermomechanical pulp (TMP) and ground calcium carbonate (GCC) filler. The addition of MFC reduced the drainage of the pulp suspension but improved strength properties. Wet pressing experiments showed that optimal use of MFC and filler could enhance the strength and optical properties without reducing the solids content after wet pressing. Field-emission scanning electron microscopy (FESEM) revealed that MFC adsorbed onto and contributed to the bonding of the filler particles and fibres. The MFC binds the filler-MFC-fines aggregates to the fibre network and partially filled the pore network. As a result, MFC addition increased the air resistance and internal bonding of the sheet.

scholarly journals EFEKTIVITAS BERBAGAI INDIKATOR PENGGILINGAN UNTUK MEMPREDIKSI KUALITAS KERTAS

2016 ◽  
Vol 1 (02) ◽  
Author(s):  
Hana Rachmanasari ◽  
Taufan Hidayat
Keyword(s):  
Kraft Pulp ◽  
Wood Pulp ◽  
Strength Properties ◽  
Raw Material ◽  
Fiber Morphology ◽  
Mechanical Pulp ◽  
Chemical Pulp ◽  
Bleached Kraft Pulp ◽  
Drainage Rate

The experiments of refining have been done using PFI mill and Beater, at 300 mL CSF of freenessas fixed parameters. Research was aims to determine the effective indicators of refining to predict the quality of the paper. The raw material used were wood pulp, non wood pulp, chemical pulp, mechanical pulp, Leaf Bleached Kraft Pulp (LBKP) and Needle Bleached Kraft Pulp (NBKP). The parameters which analyzed for each equipments were fibers classification, fiber morphology, dimensions of its derivatives and as the value of the drainage rate. The strenght of handsheets formed from the fibers were tested including tensile, bursting, and tearing strength. According to the results of correlation analysis, the most effective and sensitive indicators of refining towards strength properties of paper, in the wo different refining methods, is the felting power slenderness with correlation values above 0.8.Key words : refining, fiber classification, fiber morphology, the strength properties, correlation valueABSTRAKTelah dilakukan percobaan penggilingan menggunakan PFI mill dan Valley Beater, pada freeness 300 mL CSF sebagai parameter tetap. Penelitian ini bertujuan untuk mengetahui beberapa indikator penggilingan yang efektif untuk memprediksi kualitas kertas. Bahan baku terdiri dari pulp kayu, pulp non kayu, pulp kimia, pulp mekanis, pulp kayudaun dan pulp kayujarum. Parameter yang dianalisa untuk masing-masing hasil penggilingan adalah klasifikasi serat, morfologi serat dan dimensi turunannya serta nilai laju drainase. Selanjutnya dilakukan uji sifat kekuatan yang meliputi ketahanan tarik, retak dan sobek. Berdasarkan hasil analisa korelasi terhadap data penelitian, indikator penggilingan yang paling efektif dan sensitif terhadap sifat kekuatan kertas pada dua metode penggilingan berbeda adalah kelangsingan dengan nilai korelasi di atas 0,8.Kata kunci : penggilingan, klasifikasi serat, morfologi serat, sifat kekuatan, nilai korelasi  

scholarly journals KARAKTERISTIK PULP KIMIA MEKANIS DARI KENAF (Hibiscus cannabinus L.) UNTUK KERTAS LAINER

2016 ◽  
Vol 4 (01) ◽  
Author(s):  
Teddy Kardiansyah ◽  
Susi Sugesty
Keyword(s):  
Kraft Pulp ◽  
Sodium Hydroxide Solution ◽  
Strength Properties ◽  
Hibiscus Cannabinus ◽  
Paper Strength ◽  
Physical Strength ◽  
Tear Index ◽  
Virgin Pulp ◽  
Kenaf Bast ◽  
Crush Strength

Liner paper is commonly used for packaging because of its high bursting and ring crush strength. To meet these properties, liner paper strength relies on about 10-40% content of NUKP (Needle Unbleached Kraft Pulp). Currently, Indonesia does not produce NUKP, so it must be imported and the price is expensive. Liners paper in Indonesia is usually made from waste paper (old corrugated containers) that has unacceptable strength properties. To improve the strength properties, virgin pulp should be used. This study aimed to make virgin pulp from kenaf by chemimechanical process. Its physical strength was tested as a NUKP substitute. The results show that Kenaf mechanical pulp from Kenaf bast treated by using 6% sodium hydroxide solution fulfills the NUKP specifications according to SNI- 6106-1999, i.e. a fiber length of 4.24 mm, a freeness of 760 mL CSF, a tensile index of 66.54 Nm/g, a burst index of 5.72 kPam2/g, and a tear index of 18.09 mNm2/g.Keywords: nonwood, chemimechanical pulp, kenaf, bast, core  ABSTRAK Kertas lainer merupakan kertas industri yang digunakan untuk kemasan, dengan sifat ketahanan retak dan ketahanan tekan lingkar (ring crush) yang tinggi. Untuk mendapatkan kedua sifat tersebut maka biasanya kekuatan kertas lainer bertumpu pada penggunaan NUKP (pulp kraft serat panjang belum putih) dengan proporsi sekitar 10 – 40%. Saat ini Indonesia tidak memproduksi NUKP sehingga kebutuhan NUKP harus diimpor dan harganya mahal. Kertas lainer di Indonesia pada saat ini hampir semuanya dibuat dari karton bekas, disamping itu pengolahan karton bekas memiliki masalah pada kekuatan lembaran. Jika pembuatan karton menggunakan serat asli (virgin pulp), maka masalah kekuatan lembaran dapat diatasi. Penelitian ini bertujuan untuk membuat pulp dari Kenaf dengan proses kimia mekanis. Bahan baku nonkayu yaitu kenaf dibuat pulp mekanis dengan menggunakan proses Chemimechanical Pulp (CMP). Selanjutnya pulp mekanis yang diperoleh diuji kekuatan fisiknya untuk melihat potensinya sebagai pulp NUKP. Pulp mekanis kenaf yang berasal dari kulit kenaf dengan penggunaan natrium hidroksida (NaOH) 6% telah memenuhi spesifikasi pulp NUKP sesuai dengan SNI 6106-1999, yaitu panjang serat 4,24 mm, freeness 760 mL CSF, indeks tarik 66,54 Nm/g, indeks retak 5,72 kPam2/g dan indeks sobek 18,09 mNm2/g.Kata kunci: non kayu, pulp kimia mekanis, kenaf, kulit, batang tanpa kulit

Pilot trials of hemicelluloses extraction prior to thermomechanical pulp production: Part 1

TAPPI Journal ◽  
2011 ◽  
Vol 10 (5) ◽  
pp. 21-28 ◽  
Author(s):  
CARL HOUTMAN ◽  
ERIC HORN
Keyword(s):  
Oxalic Acid ◽  
Energy Savings ◽  
Wood Chip ◽  
Strength Properties ◽  
Thermomechanical Pulp ◽  
Sugar Solution ◽  
Bisulfite Treatment ◽  
Pilot Trials ◽  
Pulp Production ◽  
Production Part

Pilot data indicate that wood chip pretreatment with oxalic acid reduced the specific energy required to make thermomechanical pulp. A combined oxalic acid/bisulfite treatment resulted in 21% refiner energy savings and 13% increase in brightness for aspen. A low level of oxalic acid treatment was effective for spruce. Energy savings of 30% was observed with no significant change in strength properties. Adding bisulfite did not significantly increase the brightness of the spruce pulp. For pine, the optimum treatment was a moderate level of oxalic acid, which resulted in 34% energy savings and an increase in strength properties. For all of these treatments 1–3 w/w % carbohydrates were recovered, which can be fermented to produce ethanol. The extract sugar solution contained significant quantities of arabinose.

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