scholarly journals Removal of copper and zinc from plating wastewater by megnatic separation method

Author(s):  
Thuy Thi Xuan Le ◽  
Thuy Thi Xuan Le ◽  
Quyen Hong Ho ◽  
Mai Thi Sao Nguyen

Copper (Cu) and Zinc (Zn) are two popular heavy metals using in the mining operation, metallurgic industry, metal plating facilities, etc., and their effecs on the environment and human health are quite seriously. Application of a new adsorbent γ-PGM (-poly glutamic acid coated magnetite) is one of the new methods to separate toxic heavy metals Cu and Zn from water and wastewater. This study showed that 0.2 g/L γ-PGM at pH 6 with the shaking speed 200 rpm in 10 minutes were the best conditions for removal of Cu and Zn. The efficient removal of Cu and Zn was 99.91 % and 99.75 %, respectively. Besides, regeneration the ability of γ-PGM particles reached to 12 times while using hydrochloric acid HCl 0.1 N for 1 hour for desorption of the materials which is the best optimal conditions for separating Cu2 + and Zn2 + ions from the surface of γ-PGM particles. The results indicated that γ-PGM was the potential material for the application to the heavy metals removal in water and wastewater with various outstanding characteristics.

2019 ◽  
Vol 22 ◽  
pp. 102
Author(s):  
F. K. Pappa ◽  
C. Tsabaris ◽  
H. Kaberi ◽  
C. Zeri ◽  
I. Pashalidis ◽  
...  

The mining operation and tailing deposits in Stratoni region, Northern part of Greece, make monitoring activities necessary both in the terrestrial and coastal areas. As a part of a preliminary monitoring action, in summer of 2012, surface sediment samples in the coastal area of Stratoni (in Ierissos Gulf) were collected and measured aiming a) to obtain concentration levels of (Natural Occurring Radioactive Materials) NORM and heavy metals (e.g. As, Zn, Cu, Pb and Mn,), b) to identify minerals composition and c) to determine the distribution of the grain size. The activity concentrations of 238U, 232Th daughters and 40K were found between (20-100) Bq/kg, (20-35) Bq/kg and (420-700) Bq/kg, respectively. The concentrations of the most toxic heavy metals were found, (8-4100) ppm for As, (30-4000) ppm for Zn, (7-200) ppm for Cu, (40-1700) ppm for Pb and (400-26000) ppm for Mn. In addition, granulometric analysis reveals mostly sandy and sandy-mud sediments (97 – 53% content of sand). In general, enhanced levels of heavy metals and radionuclides were located near the load-out pier area of the coastal region. So, the input mechanisms of them (via local streams, rainfall, floods or others) into the sea and their levels has to be periodically investigated through more concerted monitoring actions.


Water ◽  
2021 ◽  
Vol 13 (19) ◽  
pp. 2659
Author(s):  
Muhammad Zaim Anaqi Zaimee ◽  
Mohd Sani Sarjadi ◽  
Md Lutfor Rahman

Natural occurrence and anthropogenic practices contribute to the release of pollutants, specifically heavy metals, in water over the years. Therefore, this leads to a demand of proper water treatment to minimize the harmful effects of the toxic heavy metals in water, so that a supply of clean water can be distributed into the environment or household. This review highlights several water treatment methods that can be used in removing heavy metal from water. Among various treatment methods, the adsorption process is considered as one of the highly effective treatments of heavy metals and the functionalization of adsorbents can fully enhance the adsorption process. Therefore, four classes of adsorbent sources are highlighted: polymeric, natural mineral, industrial by-product, and carbon nanomaterial adsorbent. The major purpose of this review is to gather up-to-date information on research and development on various adsorbents in the treatment of heavy metal from water by emphasizing the adsorption capability, effect of pH, isotherm and kinetic model, removal efficiency and the contact of time of every adsorbent.


Processes ◽  
2020 ◽  
Vol 8 (6) ◽  
pp. 645 ◽  
Author(s):  
Mohamed A. Tahoon ◽  
Saifeldin M. Siddeeg ◽  
Norah Salem Alsaiari ◽  
Wissem Mnif ◽  
Faouzi Ben Rebah

The discharge of toxic heavy metals including zinc (Zn), nickel (Ni), lead (Pb), copper (Cu), chromium (Cr), and cadmium (Cd) in water above the permissible limits causes high threat to the surrounding environment. Because of their toxicity, heavy metals greatly affect the human health and the environment. Recently, better remediation techniques were offered using the nanotechnology and nanomaterials. The attentions were directed toward cost-effective and new fabricated nanomaterials for the application in water/wastewater remediation, such as zeolite, carbonaceous, polymer based, chitosan, ferrite, magnetic, metal oxide, bimetallic, metallic, etc. This review focused on the synthesis and capacity of various nanoadsorbent materials for the elimination of different toxic ions, with discussion of the effect of their functionalization on the adsorption capacity and separation process. Additionally, the effect of various experimental physicochemical factors on heavy metals adsorption, such as ionic strength, initial ion concentration, temperature, contact time, adsorbent dose, and pH was discussed.


2020 ◽  
Vol 17 (1) ◽  
pp. 4-22
Author(s):  
Saifeldin M. Siddeeg ◽  
Mohamed A. Tahoon ◽  
Norah S. Alsaiari ◽  
Muhamad Shabbir ◽  
Faouzi B. Rebah

Background: Nanomaterials offer promising remediation techniques for water containing toxic pollutants especially heavy metals. Method: A complete analysis of the application of nano-adsorbents for heavy metals removal from water has been reviewed. The effect of their functionalization on the adsorption capacity, the reusability, and the surface area has also been discussed. Result: In particular, the focus was on the applications of graphene oxide, carbon, silica, titanium dioxide, and iron oxide for water treatment. Additionally, the effect of functional groups on heavy metal selectivity has been discussed as well. Conclusion: This article will provide environmental engineers and academicians with information related to the latest engineered nanomaterials employed for the treatment of wastewater containing toxic heavy metals.


2009 ◽  
Vol 36 (4) ◽  
pp. 709-719 ◽  
Author(s):  
Siranee Sreesai ◽  
Suthipong Sthiannopkao

Utilization of zeolite industrial wastewater as a sorbent and (or) precipitant to remove Cu and Zn from copper-brass pipe industrial wastewater was conducted. These wastewaters were sampled and values for pH, temperature, biochemical oxygen demand (BOD5), chemical oxygen demand (COD), total solids (TS), total dissolved solids (TDS), total suspended solids (TSS), and heavy metals were determined. In addition, the sorption isotherms of Cu and Zn in copper-brass pipe industrial wastewater onto solids of zeolite industrial wastewater at various dilutions of copper-brass pipe industrial wastewater were explored. The relationship between Cu and Zn concentrations and their removal efficiencies under different conditions of wastewater pH, contact times, and ratios between copper-brass pipe industrial wastewater and zeolite industrial wastewater was examined. Zeolite industrial wastewater contained various carbonate compounds that contributed to high pH and TDS values, and low heavy metals contamination whereas copper-brass pipe industrial wastewater had a low pH value and was contaminated with heavy metals, especially Cu and Zn. Application of zeolite industrial wastewater significantly increased the pH of copper-brass pipe industrial wastewater and consequently removed Cu and Zn. The increase in pH of the wastewater mixture significantly enhanced the heavy metals removal. The Langmuir equation described sorption isotherms of Cu and Zn onto solids of zeolite industrial wastewater at neutral pH (6–7) while the Freundlich equation fitted well at pH > 12. The maximum Cu (97%–98%) and Zn (92%–96%) removal efficiencies occurred at the original pH 12.8 of zeolite industrial wastewater, at the ratio of copper-brass pipe industrial wastewater to zeolite industrial wastewater 3:1 (vol.:vol.) and at 30 min contact time.


1970 ◽  
Vol 7 (5) ◽  
pp. 59-64
Author(s):  
Krishnasis Chakraborty ◽  
Suraj Chaudhary

Heavy metals are identically Pb, Cd and micronutrients elements like Ca, Mg, Al, Cu and Zn were quantitatively estimated using Flame Atomic Absorption Spectrometry (FAAS). Similarly, heavy metals such as As and Hg were quantitatively estimated by Hydride Generation Technique i.e. Cold Vapor Atomic Absorption Spectrometry method expending nitrogen as carrier gas in 30 herbal cosmetic preparations available in Indian markets. The results designate that among the toxic heavy metals. In the present study, Arsenic was found significantly well below the permissible limit, but Cd was found above the permissible limit in the all samples. Trace elements like Ca and Mg were found in higher amount than compare to Al, Cu, and Zn. Presence of trace elements can corroborate to be beneficial but existence of toxic heavy metals in such amounts certainly has adverse effects on the consumer health who always take the herbal products in an impression of being safe because of the natural origin. In conclusion, execution of strict and isolated regulatory guidelines and promotion of Good Analytical Practice (GAP), Good Manufacturing Practices (GMP) and Good Agricultural and Control Practices (GACP) is suggested for herbal cosmetics by WHO and other regulatory agencies. This study presents the status of heavy metals and trace elements in marketed herbal cosmetic formulations and provides a simple and convenient AAS method which can effectively be adopted at Industrial level for the quality control and standardization of herbal cosmetic preparations and other related products.  


2019 ◽  
Vol 81 (5) ◽  
Author(s):  
Najaa Syuhada Mohamad Thani ◽  
Rozidaini Mohd Ghazi ◽  
Mohd Faiz Mohd Amin ◽  
Zulhazman Hamzah

Water pollution by toxic heavy metals is a global environmental problem. It has led to the development of alternative technologies for heavy metals removal from contaminated sites. Constructed wetland microcosm by using Alocasia puber is a possible treatment method for wastewater containing heavy metals. Synthetic wastewater with heavy metals Cd, Cr, Cu, Ni, and Zn were used in this study. Several heavy metals concentrations (5 mg/L, 10 mg/L and 100 mg/L) were used in the systems. Six different hydraulic retention times (HRTs) (2, 4, 6, 8, 10 and 12 days) were tested in the present study. The results obtained showed removal efficiencies of heavy metals of >99% after day 12. The removal of Ni from 10 mg/L solutions (initial concentrations) recorded the best removal efficiency. Heavy metal translocation factor (TF) was found to be less than 1 for all metals tested, which confirmed the significance of roots as heavy metals accumulator compared to stems or leaves of A, puber. Therefore, this study concluded that A, puber has a great potential as an important component in constructed wetlands for water contaminated with heavy metals.


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