scholarly journals Dielectric Permittivity of Rigid Rapeseed Oil Polyol Polyurethane Biofoams and Petrochemical Foams at Low Frequencies

2020 ◽  
Vol 8 (9) ◽  
pp. 1151-1170
Author(s):  
Ilze Beverte ◽  
Vairis Shtrauss ◽  
Aldis Kalpinsh ◽  
Uldis Lomanovskis ◽  
Ugis Cabulis ◽  
...  
2017 ◽  
Vol 866 ◽  
pp. 272-276
Author(s):  
Naphat Albutt ◽  
Suejit Pechprasarn ◽  
Phimonkhae Chobdee ◽  
Thanapong Sareein

The dielectric permittivity (ε) of Y2NiMnO6 ceramics prepared by sintering at 1400 °C over 6 to 24 hours was investigated. The response of the ceramics was measured from 1 kHz to 3 MHz, with the influence of a fixed dc bias from 0 to 1.5 V and temperature from 40 °C to -60 oC. Increasing dc bias was found to reduce ε' at low frequencies, while at higher frequencies the dc bias had less influence on ε'. At 40 °C a sharp transition from high to low ε' occurred starting at ~100 kHz, as the temperature of the ceramic was lowered, the transition shifted to lower frequencies. This behaviour is attributed to the charge ordering of Ni2+ and Mn4+ ions and the thermal effect on the ions energy.


2011 ◽  
Vol 20 (5) ◽  
pp. 096369351102000 ◽  
Author(s):  
S.N. Georga

The dielectric response of 10 and 15phr epoxy/HfO2 nanocomposite systems has been studied in a wide frequency and temperature range. The experimental results show an enhancement of the dielectric permittivity with increasing filler concentration. The dielectric spectra reveal the presence of α-relaxation and a weak MWS effect. In the high frequency range the real part of the electrical conductivity obeys the Universal Dielectric Response (UDR), whereas at low frequencies and high temperatures DC conductivity is observed. VFT (Vogel-Fulcher-Tamann) parameters are calculated for all measured specimens.


1993 ◽  
Vol 17 ◽  
pp. 276-280 ◽  
Author(s):  
Shuji Fujita ◽  
Shinji Mae ◽  
Takeshi Matsuoka

Dielectric anisotropy in ice Ih was investigated at 9.7 GHz with the waveguide method. The measurement of dielectric permittivity was made using single crystals collected from Mendenhall Glacier, Alaska. The result of the measurement shows that ϵ′‖c, the real part of dielectric permittivity parallel to the c axis, is larger than ϵ′⊥c the real part of dielectric permittivity perpendicular to the c axis. This tendency is similar to that at low frequencies in the region of the Debye relaxation dispersion. It can be proposed that ϵ′‖c>ϵ′⊥c in the HF, VHF and microwave frequency range. ϵ′‖c and ϵ′‖c depend slightly upon temperature but the dielectric anisotropy, ∆ϵ′=ϵ′‖c-ϵ′⊥c, is constant and becomes 0.037 (±0.007). Based on the present results, a simple caculation indicates that the maximum power reflection coefficient caused by the dielectric anisotropy is about −50 ∼ −80 dB, which is significantly larger than the power reflection coefficient observed in the ice sheet by radio-echo sounding, about −70 ∼ −80 dB. This leads to a conclusion that dielectric anisotropy is one of the dominant causes of internal reflections.


2022 ◽  
Vol 962 (1) ◽  
pp. 012028
Author(s):  
A O Orlov ◽  
S V Tsyrenzhapov

Abstract In this work, low-frequency characteristics of wetted nanoporous silicate materials were measured, as well as the specimen’s own low-frequency electric fluctuations at the frequencies of 1…100 Hz. The measurements at low frequencies were conducted at different voltages of the probing signal. A capacity cell was used in making the measurements. In the experiments, at the temperatures below –25…–30 °C, non-linearity of the medium was discovered. The experiments on the study of the specimen’s own electric fluctuations at these temperatures revealed their essential increase. These temperatures are below the point of phase transition of supercooled water to recently discovered ferroelectric ice 0. Based on the measurements made, a conclusion was made regarding formation of this modification of ice in the nanosize pores of the wetted materials under study. Ice 0 is a ferroelectric; therefore, its formation from deeply supercooled water may have a significant impact on the electric parameters of wetted bodies at the temperatures below –23 °C. At the interface of such ice with another dielectric, a thin layer with practically metallic conductivity emerges. Such a layer influences not only the non-linear dependence of dielectric permittivity on the electric field but also increases attenuation of electromagnetic radiation in a medium.


2020 ◽  
Vol 13 (3) ◽  
pp. 201-210

Abstract: Lead-free Sr0.6Ca0.4TiO3 (SCT) ceramic was prepared by the solid state reaction route. X-Ray diffraction technique showed the phase purity and identified the orthorhombic perovskite structure of the material. Scanning Electronic Microscopy observation evidenced homogeneous morphology and dense microstructure for the ceramic. The dielectric and conductivity properties of the sample were studied using complex impedance measurement technique in a wide range of frequencies and temperatures: from 100 Hz to 1.8 GHz and from 25°C to 550°C. The ceramic exhibits a stable dielectric permittivity and low dielectric losses in frequency and temperature up to 200°C. This is very interesting in view of developing high-quality lead-free ceramic capacitors for applications requiring high temperatures; for example, in cars. The increase in dielectric permittivity for temperatures higher than 200°C may be related to oxygen vacancies that are heat-activated in the material. Dielectric losses show the existence of a dielectric relaxation at low temperatures and low frequencies. Conductivity measurement investigated at high temperatures show on one hand high AC conductivity values attributed to the high temperature jumping process and on the other hand two electrical conductivity mechanisms above 400° C in the material. Keywords: Strontium calcium titanate, Ceramic, Structure, Dielectric properties, Conductivity.


2005 ◽  
Vol 19 (07n09) ◽  
pp. 1443-1448 ◽  
Author(s):  
Yasuhito Misono ◽  
Shoichi Furukawa ◽  
Hitomi Yosinaga ◽  
Junko Sugiyama ◽  
Keishi Negita

Varying the electric field strength (E), the ER effect, the dielectric permittivity, and the electrical conductivity were simultaneously measured on the Ba 0.75 Sr 0.25 TiO 3 suspension. It was found that at high E the ER effect increased with the frequency (f), while at low E it once decreased and then increased with increase in f. At high E, the dielectric permittivity at low frequencies was much larger than that at high frequencies, indicating that an electrode polarization was formed as a result of accumulations of ions, which were dissociated from the liquid at high E, near the electrodes. This electrode polarization was further confirmed in the time dependence of the electrical conductivity after the electric field was switched on. From these results it is suggested that the E-dependent frequency dependence of the ER effect may be due to the electrode polarization, which causes larger shielding of the applied electric field at lower f while smaller shielding at higher f.


1993 ◽  
Vol 17 ◽  
pp. 276-280 ◽  
Author(s):  
Shuji Fujita ◽  
Shinji Mae ◽  
Takeshi Matsuoka

Dielectric anisotropy in ice Ih was investigated at 9.7 GHz with the waveguide method. The measurement of dielectric permittivity was made using single crystals collected from Mendenhall Glacier, Alaska. The result of the measurement shows that ϵ′ ‖c , the real part of dielectric permittivity parallel to the c axis, is larger than ϵ′ ⊥c the real part of dielectric permittivity perpendicular to the c axis. This tendency is similar to that at low frequencies in the region of the Debye relaxation dispersion. It can be proposed that ϵ′ ‖c >ϵ′ ⊥c in the HF, VHF and microwave frequency range. ϵ′ ‖c and ϵ′ ‖c depend slightly upon temperature but the dielectric anisotropy, ∆ϵ′=ϵ′ ‖c -ϵ′ ⊥c , is constant and becomes 0.037 (±0.007). Based on the present results, a simple caculation indicates that the maximum power reflection coefficient caused by the dielectric anisotropy is about −50 ∼ −80 dB, which is significantly larger than the power reflection coefficient observed in the ice sheet by radio-echo sounding, about −70 ∼ −80 dB. This leads to a conclusion that dielectric anisotropy is one of the dominant causes of internal reflections.


2016 ◽  
Vol 723 ◽  
pp. 459-463
Author(s):  
Evgeniy N. Lushin ◽  
Rene Alejandro Castro

Structural features and dielectric behavior of polymeric systems based on tetrazole are investigated after combining them with potassium nitrate (KNO3) and potassium chloride (KCl). It was found that the salt additives added to the system exist in the form of the singular crystallites that is the closed inclusions chaotically distributed inside polymeric matrix. Injection of potassium nitrate increases the value of dielectric permittivity on the studied interval of frequencies. Potassium chloride reduces the value of dielectric permittivity of the polymeric system in the field of high frequencies, and increases it in the field of low frequencies. Addition of salt increases the specific conductivity of composites that indicates increase in degree of dissociation of ionogenic substances. In the studied systems, ionogenic substances, besides salt additives, including water and remains of catalysts.


2006 ◽  
Vol 514-516 ◽  
pp. 216-220
Author(s):  
Juras Banys ◽  
Jan Macutkevic ◽  
Algirdas Brilingas ◽  
Vytautas Samulionis ◽  
K. Bormanis ◽  
...  

Dielectric properties of 0.4PbZn1/3Nb2/3O3-0.3PbSc1/2Nb1/2O3-0.3PbMg1/3Nb2/3O3- (0.4PZN- 0.3PSN-0.3PMN) ceramics are presented for 200 < T < 500 K and 20 Hz < ν < 1 MHz. Dielectric constant is very high (more 14000) in the vicinity of the peak. Anomalous broad dielectric relaxation have been observed near the temperature of the maximum permittivity, Tm (at 1 kHz). External bias field considerably lowers the value of dielectric losses at low frequencies due to decrease of polar nano regions contribution to the dielectric permittivity.


2015 ◽  
Vol 233-234 ◽  
pp. 371-374 ◽  
Author(s):  
Alexander P. Nosov ◽  
Mikhail A. Semkin ◽  
A.E. Teplykh ◽  
S.G. Bogdanov ◽  
Natali V. Urusova ◽  
...  

Multiferroic composites of (x)NiFe2O4 + (1-x)BaTiO3 with x = 0.2, 0.3 and 0.4 and (x)CoFe2O4 + (1-x)BaTiO3 with x = 0.2, and 0.4 have been synthesized by mixing NiFe2O4 (CoFe2O4) spinel and BaTiO3 piezoelectric. Distribution of Ni (Co) ions on 8a and 16d positions of spinel lattice (space group Fd-3m) is determined by neutron powder diffraction. Wave vector of magnetic structure of the spinel is k = 0. The dielectric permittivity of the composites was measured for the frequency range 102 – 105 Hz. At low frequencies the dielectric permittivity decreased from ~940 for x = 0.2 to ~360 for 0.4.


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