scholarly journals Effect of Soil Properties on forms of potassium in Some Soils of Homs Governorate

Author(s):  
Sameer M. Shamsham ◽  
Reem F. Nasra ◽  
Rawaa Z. Ayoush

The study was conductedto determine the forms of potassium in soils (water soluble K, exchangeable K, available K, non-exchangeable K, lattice K, total K) in some of Homs soils using standard laboratory procedures. The soils were ASHRAFIA, MARANA, MOUKHTARIA, ROUGHAMA, SANKARY, MASTORAH, SADAD, ARQAYA, GDAIDA, SAYED. The samples were analyzed for mechanical composition of soil viz., sand, silt, clay and chemical composition viz., pH, EC, O.M., and analyzed the different forms of potassium. The amount of water soluble, exchangeable, available, non-exchangeable, lattice and total-K in soils; ranged from 1.49 – 145.92, 244.46 – 787.71, 245.95 – 954.83, 11.10 – 836.57, 3678.08 – 18041.08 and 4583.00 – 19643 mg/Kg. The study showed that lattice K is the largest part of total K in the soils, while the water soluble K is the lowest part of total K.The total K and lattice K showed significant and positive correlation with pH.  Water-soluble K concentrations positively correlated with organic matter and sand. The available K showed significant and positive correlation with sand.

2020 ◽  
pp. 6-12
Author(s):  
Tahsina Sharmin Hoque ◽  
Shafia Afrin ◽  
Israt Jahan ◽  
Md. Joinul Abedin Mian ◽  
Mohammad Anwar Hossain

Soil depth can significantly influence the availability of nutrients in soil. An experiment was conducted with seven soil samples from seven land use types to observe the effect of soil depth on soil properties under various land use systems. Soil pH, electrical conductivity (EC), organic matter, available phosphorus (P), available sulphur (S) and different forms of potassium (K) such as water soluble, exchangeable and non-exchangeable were determined from the soil samples collected from four soil depths (viz. 0-10, 10-20, 20-30 and 30-40 cm). Soil pH varied from 6.30-7.39 irrespective of depths and land uses and it increased with increasing soil depth. Electrical conductivity of the soils ranged from 42-310 µS cm-1 and organic matter status of most of the soils was very low to medium in level. Both EC and organic matter content decreased with the increase of soil depth. Available P concentration showed no specific changing trend with soil depth whereas available S concentration under different land use systems decreased with increasing soil depth. The concentrations of water soluble, exchangeable and non-exchangeable K in soils varied from 12.30-39.60, 20.90-53.16 and 163.30-684.30 mg kg-1, respectively and showed no specific changing pattern with soil depth. Water soluble K content was higher in rice growing fertilizer and manure-treated soil but higher exchangeable and non-exchangeable K contents were observed in banana growing soil. In rice growing soils, nutrient concentration is mostly higher in nitrogen (N), P and K + farm yard manure (FYM) - treated plots compared to rice growing control plots.


Author(s):  
TN Shila ◽  
MS Islam ◽  
MMM Hoque ◽  
MH Kabir ◽  
MR Jamil ◽  
...  

The study was conducted to investigate the soil properties and pesticide intensity in rice, banana and brinjal growing agricultural land of Delduar and Sakhipur upazila of Tangail district during July 2019 to June 2020. Forty five soil samples were collected from different crop land at the study area and analyzed in the Soil Resource Development Institute to determine the soil properties as pH, total organic matter (OM), total nitrogen (N), available phosphorus (P), available sulfur (S), available zinc (Zn), exchangeable potassium (K), exchangeable magnesium (Mg) and exchangeable calcium (Ca). However, pesticide used intensity was also evaluated through questionnaire survey with farmers and stakeholders in the study area. Results showed that pH, OM, available N, exchangeable Ca and exchangeable Mg content were significantly higher in rice growing land than banana and brinjal. On the other hand, available P, exchangeable K and available Zn content were substantially higher in brinjal growing land than rice and banana. The OM showed significant positive correlation with soil pH, available N, available S, exchangeable Mg and exchangeable Ca (r=0.37, 0.99, 0.31, 0.59 and 0.63, respectively), indicated rice growing land built up these soil properties through increasing soil OM. The available P showed significant and positive correlation with K and Zn (r=0.55 and 0.74, respectively), but negative correlation with exchangeable Mg and exchangeable Ca (r=-0.53 and -0.32, respectively). The exchangeable K showed significant and positive correlation with available Zn (r=0.45) but negative correlation with exchangeable Mg (r=-0.37). The Mg showed significant negative correlation with available Zn (r=-0.45) but positive correlation with exchangeable Ca (r=0.87). Results also revealed that pesticide used intensity was higher in brinjal followed by banana and minimum in rice crop. Study suggests that farmers require up-to-date information on soil nutrient status so that they may use the proper utilization of fertilizers and avoid using excessive amounts of fertilizers and pesticides in their crop land. Int. J. Agril. Res. Innov. Tech. 11(2): 85-94, Dec 2021


2016 ◽  
Vol 8 (2) ◽  
pp. 67
Author(s):  
M. Al-Jabri

Agricultural lands of Donggala region are extensively distributed in alluvial plain. However, information on soil properties and fertility constraints has not been known in detail. An investigation of soil resources was conducted in September 2003 and December 2004 to characterize surface soil properties of alluvial plain and to evaluate soil fertility constraints. For this study, 55 representative soil profiles consisting of 187 soil samples were selected for physical, chemical, and mineralogical analyses. The soil profiles were classified as soil groups of Ustifluvents, Haplustepts, Eutrudepts, and Endoaquepts. All the soil physical and chemical data were calculated as weighted average based on top 30 cm soil layer analyses. The results showed that soil texture ranged from sandy loam to loam. In ustic moisture regime, the average pH was neutral (7.0-7.2), but in udic moisture regime it was slightly acid (5.5-6.2). In all soil groups, the organic carbon content was very low to low (0.58-1.44%), P retention was very low (3-18%), and soil cation exchange capacity (CEC) was very low to low (9-14 cmol(+) kg-1). In contrast, all the soil groups showed very high content of potential phosphate (81- 118 mg P2O5 100 g-1) and potassium (338-475 mg K2O 100 g-1), but the available phosphate and potassium were 16-47 mg kg-1 P and 0.18-0.35 cmol(+) kg-1, respectively, which were considered to be low to medium range. The very high P2O5 and K2O were probably derived from weathered mica-schist and granite rocks, but low exchangeable K was probably due to K fixation. The sand mineral fraction was composed of relatively high (> 20%) weatherable minerals of acid parent materials, such as orthoclase and sanidine, while the clay mineral was composed of smectite and illite. The low soil-CEC, low organic matter, and exchangeable K contents were the main soil fertility constraints. Therefore, soil management should be directed to organic matter application to increase soil carbon content, CEC, and nutrient availability. Fertilizer recommendation for wetland rice and several upland crops is suggested based on the soil properties.


2020 ◽  
Vol 8 (1) ◽  
pp. 101-106
Author(s):  
Cahyo Bagus Susanto ◽  
Syahrul Kurniawan

Entisol of Wajak Malang has low base saturation and organic matter and slightly acid. The result of the analysis also showed that soil has nutrient P with high criteria; however, N, K, Ca, Mg, Na contents are low to very low criteria. Application of humic acid at the first planting can leave residual nutrients and can still be used in the second planting. Besides urea-humic, goat manure can also be because it can improve soil properties, organic matter and nutrients contents. The purpose of this study was to explore the effect of the application of urea-humic residue with goat manure on the availability of phosphorus, potassium and the growth of okra on an Entisol of Wajak Malang. The combination of treatments consisted of: U1 (soil residue urea-humic 100% + goat manure), UH1 (soil residue of urea-humic 75% + goat manure), UH2 (soil residue of urea-humic 100% + goat manure), UH3 (soil residue of urea-humic 125% + goat manure), UH4 (soil residue if urea-humic 150% + goat manure). The five treatments were arranged in a completely randomized design with three replicates. The results showed that urea-humic residue with application goat manure had no significant effect on available P, exchangeable K in the soil, plants height and leaf number of okra on 4, 6 and 8 weeks after planting.


2021 ◽  
Vol 21 (24) ◽  
pp. 18147-18174
Author(s):  
Nabil Deabji ◽  
Khanneh Wadinga Fomba ◽  
Souad El Hajjaji ◽  
Abdelwahid Mellouki ◽  
Laurent Poulain ◽  
...  

Abstract. Field measurements were conducted to determine aerosol chemical composition at a newly established remote high-altitude site in North Africa at the Atlas Mohammed V (AMV) atmospheric observatory located in the Middle Atlas Mountains. The main objectives of the present work are to investigate the variations in the aerosol composition and better assess global and regional changes in atmospheric composition in North Africa. A total of 200 particulate matter (PM10) filter samples were collected at the site using a high-volume (HV) collector in a 12 h sampling interval from August to December 2017. The chemical composition of the samples was analyzed for trace metals, water-soluble ions, organic carbon (OC/EC), aliphatic hydrocarbons, and polycyclic aromatic hydrocarbon (PAH) contents. The results indicate that high-altitude aerosol composition is influenced by both regional and transregional transport of emissions. However, local sources play an important role, especially during low wind speed periods, as observed for November and December. During background conditions characterized by low wind speeds (avg. 3 m s-1) and mass concentrations in the range from 9.8 to 12 μg m-3, the chemical composition is found to be dominated by inorganic elements, mainly suspended dust (61 %) and ionic species (7 %), followed by organic matter (7 %), water content (12 %), and unidentified mass (11 %). Despite the proximity of the site to the Sahara, its influence on the atmospheric composition at this high-altitude site was mainly seasonal and accounted for only 22 % of the sampling duration. Biogenic organics contributed up to 7 % of the organic matter with high contributions from compounds such as heneicosane, hentriacontane, and nonacosane. The AMV site is dominated by four main air mass inflows, which often leads to different aerosol chemical compositions. Mineral dust influence was seasonal and ranged between 21 % and 74 % of the PM mass, with peaks observed during the summer, and was accompanied by high concentrations of SO42- of up to 3.0 μg m-3. During winter, PM10 concentrations are low (<30 μg m-3), the influence of the desert is weaker, and the marine air masses (64 %) are more dominant with a mixture of sea salt and polluted aerosol from the coastal regions (Rabat and Casablanca). During the daytime, mineral dust contribution to PM increased by about 42 % because of road dust resuspension. In contrast, during nighttime, an increase in the concentrations of alkanes, PAHs, alkane-2-ones, and anthropogenic metals such as Pb, Ni, and Cu was found due to variations in the boundary layer height. The results provide the first detailed seasonal and diurnal variation of the aerosol chemical composition, which is valuable for long-term assessment of climate and regional influence of air pollution in North Africa.


2014 ◽  
Vol 14 (7) ◽  
pp. 10393-10427
Author(s):  
A. S. Willoughby ◽  
A. S. Wozniak ◽  
P. G. Hatcher

Abstract. The chemical composition of organic aerosols in the atmosphere is strongly influenced by human emissions, and the effect these have on the environment, human health, and climate change is determined by the molecular nature of these chemical species. The complexity of organic aerosol samples limits the ability to study the chemical composition, and, therefore, the associated properties and the impacts they have. Many studies address the water-soluble fraction of organic aerosols, and have had much success in identifying specific molecular formulas for thousands of compounds present. However, little attention is given to the water-insoluble portion, which can contain most of the fossil material that is emitted through human activity. Here we compare the organic aerosols present in water extracts and organic solvent extracts (pyridine and acetonitrile) of an ambient aerosol sample collected in a rural location that is impacted by natural and anthropogenic emission sources. A semi-quantitative method was developed using proton nuclear magnetic resonance spectroscopy to determine that the amount of organic matter extracted by pyridine is comparable to that of water. Electrospray ionization Fourier transform ion cyclotron resonance mass spectra show that pyridine extracts a molecularly unique fraction of organic matter compared to water or acetonitrile, which extract chemically similar organic matter components. The molecular formulas unique to pyridine were less polar, more aliphatic, and reveal formulas containing sulfur to be an important component of insoluble aerosol organic matter.


SOIL ◽  
2016 ◽  
Vol 2 (1) ◽  
pp. 83-99 ◽  
Author(s):  
Emmanuel Frossard ◽  
Nina Buchmann ◽  
Else K. Bünemann ◽  
Delwende I. Kiba ◽  
François Lompo ◽  
...  

Abstract. Stoichiometric approaches have been applied to understand the relationship between soil organic matter dynamics and biological nutrient transformations. However, very few studies have explicitly considered the effects of agricultural management practices on the soil C : N : P ratio. The aim of this study was to assess how different input types and rates would affect the C : N : P molar ratios of bulk soil, organic matter and microbial biomass in cropped soils in the long term. Thus, we analysed the C, N, and P inputs and budgets as well as soil properties in three long-term experiments established on different soil types: the Saria soil fertility trial (Burkina Faso), the Wagga Wagga rotation/stubble management/soil preparation trial (Australia), and the DOK (bio-Dynamic, bio-Organic, and “Konventionell”) cropping system trial (Switzerland). In each of these trials, there was a large range of C, N, and P inputs which had a strong impact on element concentrations in soils. However, although C : N : P ratios of the inputs were highly variable, they had only weak effects on soil C : N : P ratios. At Saria, a positive correlation was found between the N : P ratio of inputs and microbial biomass, while no relation was observed between the nutrient ratios of inputs and soil organic matter. At Wagga Wagga, the C : P ratio of inputs was significantly correlated to total soil C : P, N : P, and C : N ratios, but had no impact on the elemental composition of microbial biomass. In the DOK trial, a positive correlation was found between the C budget and the C to organic P ratio in soils, while the nutrient ratios of inputs were not related to those in the microbial biomass. We argue that these responses are due to differences in soil properties among sites. At Saria, the soil is dominated by quartz and some kaolinite, has a coarse texture, a fragile structure, and a low nutrient content. Thus, microorganisms feed on inputs (plant residues, manure). In contrast, the soil at Wagga Wagga contains illite and haematite, is richer in clay and nutrients, and has a stable structure. Thus, organic matter is protected from mineralization and can therefore accumulate, allowing microorganisms to feed on soil nutrients and to keep a constant C : N : P ratio. The DOK soil represents an intermediate situation, with high nutrient concentrations, but a rather fragile soil structure, where organic matter does not accumulate. We conclude that the study of C, N, and P ratios is important to understand the functioning of cropped soils in the long term, but that it must be coupled with a precise assessment of element inputs and budgets in the system and a good understanding of the ability of soils to stabilize C, N, and P compounds.


2021 ◽  
Author(s):  
Yange Deng ◽  
Hiroaki Fujinari ◽  
Hikari Yai ◽  
Kojiro Shimada ◽  
Yuzo Miyazaki ◽  
...  

Abstract. Filter-based offline analysis of atmospheric aerosol hygroscopicity coupled to composition analysis provides information complementary to that obtained from online analysis. However, its application itself and comparison to online analysis have remained limited to date. In this study, daily submicrometer aerosol particles (PM0.95, 50 % cutoff diameter: 0.95 μm) were collected onto quartz fiber filters in Okinawa Island, a receptor of East Asian outflow, in the autumn of 2015. The chemical composition of water-soluble matter (WSM) in PM0.95 and PM0.95 itself, and their respective hygroscopicities were characterized through the offline use of an aerosol mass spectrometer and a hygroscopicity tandem differential mobility analyzer. Thereafter, results were compared with those obtained from online analyses. Sulfate dominated the WSM mass (60 %), followed by water-soluble organic matter (WSOM, 20 %) and ammonium (13 %). WSOM accounted for most (93 %) of the mass of extracted organic matter (EOM) and the atomic O to C ratios (O : C) of WSOM and EOM were high (mean ± standard deviation were, respectively, 0.84 ± 0.08 and 0.79 ± 0.08), both of which indicate highly aged characteristics of the observed aerosol. The hygroscopic growth curves showed clear hysteresis for most samples. At 85 % RH, the calculated hygroscopicity parameter κ of the WSM (κWSM), WSOM, EOM, and PM0.95 (κPM0.95) were, respectively, 0.50 ± 0.03, 0.22 ± 0.12, 0.20 ± 0.11, and 0.47 ± 0.03. An analysis using the thermodynamic E-AIM model shows, on average, that inorganic salts and WSOM respectively contributed 88 % and 12 % of the κWSM (or κPM0.95). High similarities were found between offline and online analysis for chemical compositions that are related to particle hygroscopicity (the mass fractions and O : C of organics, and the degree of neutralization), and also for aerosol hygroscopicity. As possible factors governing the variation of κWSM, the influences of WSOM abundance and the neutralization of inorganic salts were assessed. At high RH (70–90 %), the hygroscopicity of WSM and PM0.95 was affected considerably by the presence of organic components; at low RH (20–50 %), the degree of neutralization could be important. This study not only characterized aerosol hygroscopicity at the receptor site of East Asian outflow, but also shows that the offline hygroscopicity analysis is an appropriate method, at least for aerosols of the studied type. The results encourage further applications to other environments and to more in-depth hygroscopicity analysis, in particular for organic fractions.


2014 ◽  
Vol 14 (18) ◽  
pp. 10299-10314 ◽  
Author(s):  
A. S. Willoughby ◽  
A. S. Wozniak ◽  
P. G. Hatcher

Abstract. The chemical composition of organic aerosols in the atmosphere is strongly influenced by human emissions. The effect these have on the environment, human health, and climate change is determined by the molecular nature of these chemical species. The complexity of organic aerosol samples limits the ability to study the chemical composition, and therefore the associated properties and the impacts they have. Many studies have addressed the water-soluble fraction of organic aerosols and have had much success in identifying specific molecular formulas for thousands of compounds present. However, little attention is given to the water-insoluble portion, which can contain most of the fossil material that is emitted through human activity. Here we compare the organic aerosols present in water extracts and organic solvent extracts (pyridine and acetonitrile) of an ambient aerosol sample collected in a rural location that is impacted by natural and anthropogenic emission sources. A semiquantitative method was developed using proton nuclear magnetic resonance spectroscopy to determine that the amount of organic matter extracted by pyridine is comparable to that of water. Electrospray ionization Fourier transform ion cyclotron resonance mass spectra show that pyridine extracts a molecularly unique fraction of organic matter compared to water or acetonitrile, which extract chemically similar organic matter components. The molecular formulas unique to pyridine were less polar, more aliphatic, and reveal formulas containing sulfur to be an important component of insoluble aerosol organic matter.


2021 ◽  
Vol 42 (2) ◽  
pp. 891-906
Author(s):  
Maghsoud Besharati ◽  
◽  
Valiollah Palangi ◽  
Masomeh Niazifar ◽  
Zabihollah Nemati ◽  
...  

Purpose of the experiment was to evaluate the effect of lemon-seed essential oils on chemical composition and in vitro degradability of alfalfa silage. Treatments were alfalfa silage with no additive (control) or treated with 60 ml/kg DM of lemon-seed (C60), of lemon-seed (C120) essential oils and equal mixed of them (M60). Whole plant alfalfa silage was ensiled for 60 d in triplicate laboratory scale tubes. Dry matter, organic matter, crude protein, insoluble fiber in acidic and neutral detergent, water soluble carbohydrate, pH, were measured with 3 replicates by in vitro gas production method. Dry matter (DM) content was greater for leo60 than control. Compared with control, neutral detergent fiber (NDF) concentration was decreased in leo120. Addition of essential oils and their combination to the silage significantly decreased (p<.0001) silage pH compared with untreated silage interestingly increased for all the silages containing essential oil compared with untreated silage. Addition of lemon-seed essential to alfalfa silage decreased the rate of disappearance of organic matter and dry matter in all treatments compared to the control treatment. The degradability potential of alfalfa silage has increased in treatments containing lemon-seed essential oil (60 ml / kg DM) which is significantly different from the control. In general, the obtained data show the positive effect of lemon-seed essential oil on the quality of alfalfa silage and its fermentation properties.


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