scholarly journals Recent Developments in the Immobilization of Laccase on Carbonaceous Supports for Environmental Applications - A Critical Review

2021 ◽  
Vol 9 ◽  
Author(s):  
Younes Adamian ◽  
Linson Lonappan ◽  
Komla Alokpa ◽  
Spiros N. Agathos ◽  
Hubert Cabana
Keyword(s):  
Culture Media ◽  
High Surface ◽  
High Surface Area ◽  
Catalyst System ◽  
Ligninolytic Enzyme ◽  
Environmental Applications ◽  
Laccase Production ◽  
High Porosity ◽  
Laccase Immobilization ◽  
Carbon Based

Τhe ligninolytic enzyme laccase has proved its potential for environmental applications. However, there is no documented industrial application of free laccase due to low stability, poor reusability, and high costs. Immobilization has been considered as a powerful technique to enhance laccase’s industrial potential. In this technology, appropriate support selection for laccase immobilization is a crucial step since the support could broadly affect the properties of the resulting catalyst system. Through the last decades, a large variety of inorganic, organic, and composite materials have been used in laccase immobilization. Among them, carbon-based materials have been explored as a support candidate for immobilization, due to their properties such as high porosity, high surface area, the existence of functional groups, and their highly aromatic structure. Carbon-based materials have also been used in culture media as supports, sources of nutrients, and inducers, for laccase production. This study aims to review the recent trends in laccase production, immobilization techniques, and essential support properties for enzyme immobilization. More specifically, this review analyzes and presents the significant benefits of carbon-based materials for their key role in laccase production and immobilization.

Highly stable metal-organic framework UiO-66-NH2 for high-performance triboelectric nanogenerators

2021 ◽  
Author(s):  
Yong-Mei Wang ◽  
Xinxin Zhang ◽  
Dingyi Yang ◽  
Liting Wu ◽  
Jiaojiao Zhang ◽  
...  
Keyword(s):  
High Performance ◽  
Metal Organic Framework ◽  
High Surface ◽  
High Surface Area ◽  
Triboelectric Nanogenerator ◽  
High Porosity ◽  
Chemically Modified ◽  
Metal Organic ◽  
Triboelectric Nanogenerators ◽  
Organic Framework

Abstract The high porosity, controllable size, high surface area, and chemical versatility of a metal-organic framework (MOF) enable it a good material for a triboelectric nanogenerator (TENG), and some MOFs have been incorporated in the fabrication of TENGs. However, the understanding of effects of MOFs on the energy conversion of a TENG is still lacking, which inhibits the improvement of the performance of MOF-based TENGs. Here, UiO-66-NH2 MOFs were found to significantly increase the power of a TENG and the mechanism was carefully examined. The electron-withdrawing ability of Zr-based UiO-66-family MOFs was enhanced by designing the amino functionalized 1,4-terephthalic acid (1,4-BDC) as ligand. The chemically modified UiO-66-NH2 was found to increase the surface roughness and surface potential of a composite film with MOFs embedded in polydimethylsiloxane (PDMS) matrix. Thus the total charges due to the contact electrification increased significantly. The composite-based TENG was found to be very durable and its output voltage and current were 4 times and 60 times higher than that of a PDMS-based TENG. This work revealed an effective strategy to design MOFs with excellent electron-withdrawing abilities for high-performance TENGs.

Synthesis and Characterization of Supercapacitor Electrode from Fiber of Borassus flabelifer L by Activation Method

2019 ◽  
Vol 966 ◽  
pp. 444-450 ◽  
Author(s):  
Fandi Angga Prasetya ◽  
Ufafa Anggarini ◽  
Yudha Zakaria ◽  
Rosa Dwi Sasqia Putri
Keyword(s):  
High Surface ◽  
High Surface Area ◽  
Raw Material ◽  
High Porosity ◽  
Supercapacitor Electrode ◽  
Nitrogen Gas ◽  
Reduced Graphene ◽  
Higher Temperature ◽  
Constant Heating

Supercapacitor require electrode which has high surface area so that it able to store large amounts of charge. In this study, electrode was synthesized from carbon of Borassus Flabellifer L fiber which was carried out through activation and carbonization processes. Raw material was calcined at 400°C for 4 hours followed by activation with NaOH 1 M. The carbonization was then conducted in Nitrogen gas flowing by temperature variations; 650°C, 750°C, and 850°C with a constant heating rate of 20 °C/min. Based on XRD data, it was shown that the material has formed Reduced graphene Oxide (RGO) which has main peaks at (2θ) 240 and 440 with higher purity in higher temperature. SEM results clarified more pores formation at higher temperature which is mesoporous. Cyclic Voltammetry (CV) test was done to determine the capacitance value. By RGO forming with high porosity, it is suitable for supercapacitor electrode application and CV test has examined that heating of Borassus Flabelifer L fiber at 850°C with 5 mV/s scan rate has the highest specific capacitance by 8.25 F/gram with Energy density is 4.125 watt/gram.

scholarly journals Carbon-Based Catalysts for Biodiesel Production—A Review

2020 ◽  
Vol 10 (3) ◽  
pp. 918 ◽  
Author(s):  
Jack Clohessy ◽  
Witold Kwapinski
Keyword(s):  
Heterogeneous Catalysts ◽  
Catalyst Activity ◽  
High Surface ◽  
High Surface Area ◽  
Acid Catalyst ◽  
Biodiesel Production ◽  
Catalyst Characterization ◽  
Synthesis Methods ◽  
And Performance ◽  
Carbon Based

In recent years, a new class of superior heterogeneous acid catalyst for biodiesel production has emerged. These catalysts offer advantages over their predecessors such as high surface area, elevated acid site density, enhanced catalyst activity, good operation stability and relevant economic affordability in an environmentally friendly frame. This review was concerned with carbon-based solid acid (CBAS) catalysts derived from both carbohydrate and pyrolysis products. A series of CBASs with various origins such as D-glucose, sucrose, starch, cellulose and vegetable oil asphalt, converted to char and sulphonated, have been explored as potential heterogeneous catalysts. Catalyst preparation and synthesis methods were briefly summarized. Catalyst characterization and performance for biofuels related reactions were elucidated, identifying potential research applications. Three catalysts in particular were identified as having potential for industrial application and requiring further research.

scholarly journals Nanotheranostic Carbon Dots as an Emerging Platform for Cancer Therapy

2020 ◽  
Vol 1 (1) ◽  
pp. 58-77
Author(s):  
Sumiya Adrita ◽  
Khandaker Tasnim ◽  
Ji Ryu ◽  
Shazid Sharker
Keyword(s):  
Cancer Treatment ◽  
Carbon Dots ◽  
High Surface ◽  
High Surface Area ◽  
Volume Ratio ◽  
Biomedical Sciences ◽  
Diagnosis And Therapy ◽  
Low Dimensional ◽  
Carbon Based Nanomaterials ◽  
Carbon Based

Cancer remains one of the most deadly diseases globally, but carbon-based nanomaterials have the potential to revolutionize cancer diagnosis and therapy. Advances in nanotechnology and a better understanding of tumor microenvironments have contributed to novel nanotargeting routes that may bring new hope to cancer patients. Several low-dimensional carbon-based nanomaterials have shown promising preclinical results; as such, low-dimensional carbon dots (CDs) and their derivatives are considered up-and-coming candidates for cancer treatment. The unique properties of carbon-based nanomaterials are high surface area to volume ratio, chemical inertness, biocompatibility, and low cytotoxicity. It makes them well suited for delivering chemotherapeutics in cancer treatment and diagnosis. Recent studies have shown that the CDs are potential applicants in biomedical sciences, both as nanocarriers and nanotransducers. This review covers the most commonly used CD nanoparticles in nanomedicines intended for the early diagnosis and therapy of cancer.

scholarly journals Application of Nanostructured Carbon-Based Electrochemical (Bio)Sensors for Screening of Emerging Pharmaceutical Pollutants in Waters and Aquatic Species: A Review

Nanomaterials ◽  
2020 ◽  
Vol 10 (7) ◽  
pp. 1268 ◽  
Author(s):  
Álvaro Torrinha ◽  
Thiago M. B. F. Oliveira ◽  
Francisco W.P. Ribeiro ◽  
Adriana N. Correia ◽  
Pedro Lima-Neto ◽  
...  
Keyword(s):  
Carbon Nanomaterials ◽  
Low Cost ◽  
High Surface ◽  
High Surface Area ◽  
Aquatic Species ◽  
Transfer Rates ◽  
Production Methods ◽  
Pharmaceutical Pollutants ◽  
Carbon Based Nanomaterials ◽  
Carbon Based

Pharmaceuticals, as a contaminant of emergent concern, are being released uncontrollably into the environment potentially causing hazardous effects to aquatic ecosystems and consequently to human health. In the absence of well-established monitoring programs, one can only imagine the full extent of this problem and so there is an urgent need for the development of extremely sensitive, portable, and low-cost devices to perform analysis. Carbon-based nanomaterials are the most used nanostructures in (bio)sensors construction attributed to their facile and well-characterized production methods, commercial availability, reduced cost, high chemical stability, and low toxicity. However, most importantly, their relatively good conductivity enabling appropriate electron transfer rates—as well as their high surface area yielding attachment and extraordinary loading capacity for biomolecules—have been relevant and desirable features, justifying the key role that they have been playing, and will continue to play, in electrochemical (bio)sensor development. The present review outlines the contribution of carbon nanomaterials (carbon nanotubes, graphene, fullerene, carbon nanofibers, carbon black, carbon nanopowder, biochar nanoparticles, and graphite oxide), used alone or combined with other (nano)materials, to the field of environmental (bio)sensing, and more specifically, to pharmaceutical pollutants analysis in waters and aquatic species. The main trends of this field of research are also addressed.

Nanofibrous Scaffold Engineering Using Electrospinning

2007 ◽  
Vol 7 (12) ◽  
pp. 4595-4603 ◽  
Author(s):  
R. Murugan ◽  
Z. M. Huang ◽  
F. Yang ◽  
S. Ramakrishna
Keyword(s):  
Tissue Engineering ◽  
Cell Attachment ◽  
Dimensional Space ◽  
High Surface ◽  
Critical Role ◽  
High Surface Area ◽  
Structural Features ◽  
Tissue Growth ◽  
High Porosity ◽  
Fibrous Scaffold

Scaffold plays a critical role in tissue engineering where it provides necessary structural support for the cells to accommodate and to guide their growth in the three dimensional space into a specific tissue. Therefore, engineering scaffolds favorable for cell/tissue growth is of great importance and a pre-requisite for scaffold-based tissue engineering. Electrospinning is a versatile method that has been recently adapted in engineering nano-fibrous scaffolds that mimic the structural features of biological extracellular matrix (ECM). It offers many advantages over conventional scaffold methodologies, for example, capable of producing ultra-fine fibers with high porosity, high spatial orientation, high aspect ratio, and high surface area, which are highly required for the initial cell attachment, tissue formation, and continued function. Considering these astonishing merits, this article emphasis on nano-fibrous scaffold engineering by electrospinning.

Preparation and characterization of high surface area, high porosity carbon monoliths from pyrolyzed bovine bone and their performance as supercapacitor electrodes

Carbon ◽  
2013 ◽  
Vol 55 ◽  
pp. 291-298 ◽  
Author(s):  
Paul A. Goodman ◽  
H. Li ◽  
Y. Gao ◽  
Y.F. Lu ◽  
J.D. Stenger-Smith ◽  
...  
Keyword(s):  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Bovine Bone ◽  
High Porosity

Preparation and Application of High Surface Area Activated Carbon Based on Pine Nut Shell

2014 ◽  
Vol 4 (4) ◽  
pp. 336-340 ◽  
Author(s):  
Xuebin Chu ◽  
Likun Zhao ◽  
Yunze Sun ◽  
Hanbo Xie ◽  
Chunyu Xi
Keyword(s):  
Activated Carbon ◽  
Surface Area ◽  
High Surface ◽  
High Surface Area ◽  
Pine Nut ◽  
Carbon Based

scholarly journals Bifunctional Materials for CO₂ Adsorption: Short Review

2021 ◽  
Vol 7 (2) ◽  
pp. 15-19
Author(s):  
S. M. Yusof ◽  
L. P. Teh
Keyword(s):  
Surface Area ◽  
Active Sites ◽  
Co2 Adsorption ◽  
High Surface ◽  
Co Adsorption ◽  
High Surface Area ◽  
Short Review ◽  
High Dispersion ◽  
High Porosity ◽  
Adsorption Performance

In recent years, there has been growing interest in adsorbents with high surface area, high porosity, high stability and high selectivity for CO2 adsorption. By the incorporation of the additive on the supports such as zeolite, silica, and carbon, the physicochemical properties of the adsorbent and CO2 adsorption performance can be enhanced. In this review, we focus on the overview of bifunctional materials (BFMs) for CO2 adsorption. The findings of this study suggests that the high surface area and high porosity of the support provide a good medium for high dispersion and accessibility of additives (amine or metal oxide), enhancing the CO2 adsorption efficiency. The excessive additive however may lead to a decrease of CO2 adsorption performance due to pore blockage and the decrease of active sites for CO2 interactions. The synergistic relationship of the supporting material and additive is significant towards the enhancement of CO2 adsorption.

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