scholarly journals Characteristics of Shale Pores and Surfaces and Their Potential Effects on the Fluid Flow From Shale Formation to Fractures

2021 ◽  
Vol 9 ◽  
Author(s):  
Xu Li ◽  
Jingong Cai ◽  
Bo Gao ◽  
Shengxiang Long ◽  
Dongjun Feng ◽  
...  
Keyword(s):  
Fluid Flow ◽  
Surface Area ◽  
Clay Minerals ◽  
Fluid Composition ◽  
Organic Carbon Content ◽  
Carbonate Minerals ◽  
Shale Formations ◽  
Small Surface ◽  
Surface Areas ◽  
Large Pore

Fluid flow is critical for the efficient exploitation of shale resources and can be split into two stages: the flow in the artificial fractures and, more importantly, the flow from shale formations to the artificial fractures. In this study, X-ray diffraction, N2 adsorption, mercury intrusion, and ethylene glycol monoethyl ether adsorption were conducted on the shales collected from Es3middle, Es3lower, and Es4upper sub-members in the Dongying Sag to reveal the potential effects of the characteristics and properties of pores and surfaces on the fluid flow in shale formations. The results are indicated as follows: 1) The shales from Es3middle and Es3lower contain more I/S and detrital minerals but less illite and carbonate minerals than those of Es4upper. 2) The shales from Es3middle and Es3lower are mainly composed of smaller pores present in larger surface areas and lead to the steeper slope between the BrunauerEmmettTeller specific surface area (BET-SSA) and pore volumes. 3) Clay minerals mainly contribute to pore development, and carbonate minerals inhibit pore development. All kinds of surface areas (especially the inner surface area) are sourced by clay minerals, while I/S and illite present opposite effects. 4) Pore size and surface properties affect significantly the fluid flow in shale formations. The shales from Es4upper are the favorable interval for shale oil accumulation and flow, especially for the shales with depth ranges of 3360∼3410 m, which possess high carbonates, illite and total organic carbon content, low clay mineral content, large pore volume, high large pore content, and small surface areas. Additionally, fluid composition needs to be paid more concern in the future.

scholarly journals Impacts of Radiometric Uncertainty and Weather-Related Surface Conditions on Soil Moisture Retrievals with Sentinel-1

2019 ◽  
Vol 11 (17) ◽  
pp. 2025 ◽  
Author(s):  
Harm-Jan Benninga ◽  
Rogier van der Velde ◽  
Zhongbo Su
Keyword(s):  
Surface Roughness ◽  
Soil Moisture ◽  
Surface Area ◽  
Incidence Angle ◽  
Surface Condition ◽  
Integral Equation Method ◽  
Surface Scattering ◽  
Small Surface ◽  
Surface Conditions ◽  
Surface Areas

The radiometric uncertainty of Synthetic Aperture Radar (SAR) observations and weather-related surface conditions caused by frozen conditions, snow and intercepted rain affect the backscatter ( σ 0 ) observations and limit the accuracy of soil moisture retrievals. This study estimates Sentinel-1’s radiometric uncertainty, identifies the effects of weather-related surface conditions on σ 0 and investigates their impact on soil moisture retrievals for various conditions regarding soil moisture, surface roughness and incidence angle. Masking rules for the surface conditions that disturb σ 0 were developed based on meteorological measurements and timeseries of Sentinel-1 observations collected over five forests, five meadows and five cultivated fields in the eastern part of the Netherlands. The Sentinel-1 σ 0 observations appear to be affected by frozen conditions below an air temperature of 1 ∘ C , snow during Sentinel-1’s morning overpasses on meadows and cultivated fields and interception after more than 1.8 m m of rain in the 12 h preceding a Sentinel-1 overpass, whereas dew was not found to be of influence. After the application of these masking rules, the radiometric uncertainty was estimated by the standard deviation of the seasonal anomalies timeseries of the Sentinel-1 forest σ 0 observations. By spatially averaging the σ 0 observations, the Sentinel-1 radiometric uncertainty improves from 0.85 dB for a surface area of 0.25 h a to 0.30 dB for 10 h a for the VV polarization and from 0.89 dB to 0.36 dB for the VH polarization, following approximately an inverse square root dependency on the surface area over which the σ 0 observations are averaged. Deviations in σ 0 were combined with the σ 0 sensitivity to soil moisture as simulated with the Integral Equation Method (IEM) surface scattering model, which demonstrated that both the disturbing effects by the weather-related surface conditions (if not masked) and radiometric uncertainty have a significant impact on the soil moisture retrievals from Sentinel-1. The soil moisture retrieval uncertainty due to radiometric uncertainty ranges from 0.01 m 3 m − 3 up to 0.17 m 3 m − 3 for wet soils and small surface areas. The impacts on soil moisture retrievals are found to be weakly dependent on the surface roughness and the incidence angle, and strongly dependent on the surface area (or the σ 0 disturbance caused by a weather-related surface condition for a specific land cover type) and the soil moisture itself.

scholarly journals Filter properties of seam material from paved urban soils

2007 ◽  
Vol 4 (4) ◽  
pp. 2625-2657
Author(s):  
T. Nehls ◽  
G. Jozefaciuk ◽  
Z. Sokolowska ◽  
M. Hajnos ◽  
G. Wessolek
Keyword(s):  
Organic Matter ◽  
Cation Exchange ◽  
Urban Areas ◽  
Exchange Capacity ◽  
Organic Carbon Content ◽  
Natural Soils ◽  
Small Surface ◽  
Surface Areas ◽  
Heavy Metal Transport

Abstract. We studied pavement seam material. This is the soil substrate in joints of pervious pavements in urban areas. It is mostly 1 cm thick and develops from the original seam filling by depositions of all kinds of urban residues, including anthropogenic organic substances. It was investigated, how this unique form of organic matter influences the filter properties of seam material and how the seam material influences heavy metal transport through the pavement. The seam material is characterised by a darker munsell colour, higher organic carbon content, higher surface areas, higher cation exchange capacities, but a lower fraction of high adsorption energy sites compared to the original seam filling. The deposited anthropogenic organic matter itself could be characterised as particulate and non-polar. Compared to natural soils, it has a small surface area and a low surface charge density resulting in a small cation exchange capacity of only 75 cmol(+) kg−1C. The seam material shows stronger sorption of Pb and Cd compared to the original construction sand. The retardation capacity of seam material towards Pb is similar, towards Cd it is much smaller compared to natural soils. The simulated long term displacement scenarios for a street in Berlin do not indicate an acute contamination risk for Pb. For Cd the infiltration from ponds can lead to a displacement of Cd during only one decade.

Cell morphology, volume, and surface area determinations from multilevel contouring within HVEM micrographs of serial sections and whole-cell mounts

1987 ◽  
Vol 45 ◽  
pp. 588-589
Author(s):  
M. Marko ◽  
A. Leith ◽  
D. Parsons
Keyword(s):  
Surface Area ◽  
Electron Micrographs ◽  
Cell Morphology ◽  
Individual Variation ◽  
Serial Section ◽  
Stereo Pair ◽  
Complex Structures ◽  
Serial Sections ◽  
Surface Areas ◽  
Computer Based

The use of serial sections and computer-based 3-D reconstruction techniques affords an opportunity not only to visualize the shape and distribution of the structures being studied, but also to determine their volumes and surface areas. Up until now, this has been done using serial ultrathin sections.The serial-section approach differs from the stereo logical methods of Weibel in that it is based on the Information from a set of single, complete cells (or organelles) rather than on a random 2-dimensional sampling of a population of cells. Because of this, it can more easily provide absolute values of volume and surface area, especially for highly-complex structures. It also allows study of individual variation among the cells, and study of structures which occur only infrequently.We have developed a system for 3-D reconstruction of objects from stereo-pair electron micrographs of thick specimens.

scholarly journals Tuning the hierarchical pore structure of graphene oxide through dual thermal activation for high-performance supercapacitor

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Jeongpil Kim ◽  
Jeong-Hyun Eum ◽  
Junhyeok Kang ◽  
Ohchan Kwon ◽  
Hansung Kim ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Pore Structure ◽  
Specific Capacitance ◽  
Surface Area ◽  
Thermal Annealing ◽  
High Performance ◽  
Annealing Process ◽  
Supercapacitor Electrode ◽  
Simple Method ◽  
Surface Areas

AbstractHerein, we introduce a simple method to prepare hierarchical graphene with a tunable pore structure by activating graphene oxide (GO) with a two-step thermal annealing process. First, GO was treated at 600 °C by rapid thermal annealing in air, followed by subsequent thermal annealing in N2. The prepared graphene powder comprised abundant slit nanopores and micropores, showing a large specific surface area of 653.2 m2/g with a microporous surface area of 367.2 m2/g under optimized conditions. The pore structure was easily tunable by controlling the oxidation degree of GO and by the second annealing process. When the graphene powder was used as the supercapacitor electrode, a specific capacitance of 372.1 F/g was achieved at 0.5 A/g in 1 M H2SO4 electrolyte, which is a significantly enhanced value compared to that obtained using activated carbon and commercial reduced GO. The performance of the supercapacitor was highly stable, showing 103.8% retention of specific capacitance after 10,000 cycles at 10 A/g. The influence of pore structure on the supercapacitor performance was systematically investigated by varying the ratio of micro- and external surface areas of graphene.

scholarly journals Ultrafine porous boron nitride nanofibers synthesized via a freeze-drying and pyrolysis process and their adsorption properties

RSC Advances ◽  
2016 ◽  
Vol 6 (2) ◽  
pp. 1253-1259 ◽  
Author(s):  
Jing Lin ◽  
Lulu Xu ◽  
Yang Huang ◽  
Jie Li ◽  
Weijia Wang ◽  
...  
Keyword(s):  
Boron Nitride ◽  
Specific Surface ◽  
Freeze Drying ◽  
Adsorption Properties ◽  
Pyrolysis Process ◽  
Surface Areas ◽  
Aspect Ratios ◽  
Large Pore ◽  
Specific Surface Areas

Ultrafine porous boron nitride nanofibers with high aspect ratios, high specific surface areas and large pore volumes has been synthesized in large quantity via a freeze-drying and post pyrolysis process.

The new face of large dams in the 21st century

2021 ◽  
Author(s):  
Atal Ahmadzai
Keyword(s):  
Surface Area ◽  
Aquatic Ecosystems ◽  
Energy Demand ◽  
Environmental Aspects ◽  
Water Insecurity ◽  
Surface Areas ◽  
Large Dams ◽  
Physical Attributes ◽  
Under Construction ◽  
Ecological Disturbances

Alerted by increasing water insecurity and energy demand, countries, mainly in the Global South, are building dams of unprecedented magnitude. Hundreds of large dams (≥ 100 metres) have been constructed since 2000, with hundreds more under construction. Analyses of the physical attributes of these dams present a concerning image. While they create expansive reservoirs with large surface areas, they have inefficient surface area-to-volume ratios ('S2VR'). Their unprecedented size and the reservoirs’ expansive surface area, indicate severe environmental costs, mainly through ecological disturbances to the (riverine) aquatic ecosystems; and greenhouse gas emissions (GHG). Other ecological costs due to the larger S2VR include a high evaporation rate and compromised biodiversity of a wider area, both up- and downstream. The safety and environmental aspects of these large dams should be robustly scrutinised.

scholarly journals The Effects of Methane Storage Capacity Using Upgraded Activated Carbon by KOH

2018 ◽  
Vol 8 (9) ◽  
pp. 1596 ◽  
Author(s):  
Jung Park ◽  
Gi Lee ◽  
Sang Hwang ◽  
Ji Kim ◽  
Bum Hong ◽  
...  
Keyword(s):  
Surface Area ◽  
Storage Capacity ◽  
Activated Carbons ◽  
Chemical Activation ◽  
High Surface ◽  
Heat Of Adsorption ◽  
Low Grade ◽  
Surface Areas ◽  
Ch4 Adsorption ◽  
Ch4 Storage

In this study, a feasible experiment on adsorbed natural gas (ANG) was performed using activated carbons (ACs) with high surface areas. Upgraded ACs were prepared using chemical activation with potassium hydroxide, and were then applied as adsorbents for methane (CH4) storage. This study had three principal objectives: (i) upgrade ACs with high surface areas; (ii) evaluate the factors regulating CH4 adsorption capacity; and (iii) assess discharge conditions for the delivery of CH4. The results showed that upgraded ACs with surface areas of 3052 m2/g had the highest CH4 storage capacity (0.32 g-CH4/g-ACs at 3.5 MPa), which was over two times higher than the surface area and storage capacity of low-grade ACs (surface area = 1152 m2/g, 0.10 g-CH4/g-ACs). Among the factors such as surface area, packing density, and heat of adsorption in the ANG system, the heat of adsorption played an important role in controlling CH4 adsorption. The released heat also affected the CH4 storage and enhanced available applications. During the discharge of gas from the ANG system, the residual amount of CH4 increased as the temperature decreased. The amount of delivered gas was confirmed using different evacuation flow rates at 0.4 MPa, and the highest efficiency of delivery was 98% at 0.1 L/min. The results of this research strongly suggested that the heat of adsorption should be controlled by both recharging and discharging processes to prevent rapid temperature change in the adsorbent bed.

scholarly journals The Peroneus Brevis and Plantar Fascia Insertions Are Related to Proximal Fifth Metatarsal Fractures

2017 ◽  
Vol 2 (3) ◽  
pp. 2473011417S0001
Author(s):  
Ali Hosseini ◽  
Pim Van Dijk ◽  
Sofie Breuking ◽  
Bryan Vopat ◽  
Daniel Guss ◽  
...  
Keyword(s):  
Surface Area ◽  
Fracture Mechanism ◽  
Soft Tissues ◽  
Plantar Fascia ◽  
Dorsal Side ◽  
Fracture Zones ◽  
Surface Areas ◽  
Metatarsal Bones ◽  
Metatarsal Fractures ◽  
Peroneus Brevis

Category: Midfoot/Forefoot Introduction/Purpose: Proximal fifth metatarsal fractures (PFMF) are among the most common fractures in the foot and can be categorized into three fracture zones [1]. To investigate the fracture mechanism of PFMF in different zones, a better understanding of the anatomy of the bone and its surrounding soft tissues is required. Both the plantar fascia (PF) and the peroneus brevis (PB) tendon insertions are at the base of the fifth metatarsal, and may contribute to the pathophysiology of PFMF. However, the role of the PB and PF insertions in the pathogenesis of PFMF remains unclear. The purpose of this study was to accurately define the footprint of the PB and PF insertions of the base of the 5th metatarsal in relation to the different zones of PFMF. Methods: 21 cadaveric fifth metatarsal bones were harvested from cadaveric feet. All bones were freed of any remaining soft tissue adherence, except for the PB and the PF insertions. Three reference screws with a diameter of 1 mm were placed and secured on each bone with 2 screws distally and 1 screw proximally for registration. All bones were CT scanned to create a 3D bone reconstruction. Next, the insertions of the PB and PF and the reference screws of each bone were digitized and then mapped to its corresponding 3D bone model. In order to describe the three different fracture zones of the 5th metatarsal, an established coordinate system was made for each bone to simulate separate fracture zones (Figure a) based on Lawrence guideline [1]. The shape, location and surface areas of both insertions and their relation to the different fractures zones were determined (Figure b). Results: The insertion of the PB was oval shaped and located on the dorsal side of the base, with a mean surface area of 88.1 ± 46.4 mm2. The PF was oval shaped and situated around the tip of tuberosity, with a mean surface area of 150.7±53.5 mm2. The PB insertion was present in zone 1 fractures in 100% (21/21) of the 5th metatarsal models and 29% (6/21) of the models for zone 2 fractures. The PF insertion was involved in 100% (21/21) of the 5th metatarsal models for zone 1 fractures and 43% (9/21) of the models for zone 2 fractures. Conclusion: Results of this study demonstrate that the insertion of both the PB and PF are involved in all zone 1 PFMF and a significant percentage of zone 2 PFMF. The location of tendon insertions affect the forces exerted on the bone, which may indicate a relation of the insertions of both the PB and the PF with the fracture mechanism of many zone 1 and 2 PFMF. Moreover, in the treatment of these fractures, care should be taken to maintain or restore the anatomy of these insertions to maximize functional outcomes.

Periodically Converging-Diverging Tubes and Their Turbulent Heat Transfer, Pressure Drop, Fluid Flow, and Enhancement Characteristics

1984 ◽  
Vol 106 (1) ◽  
pp. 55-63 ◽  
Author(s):  
P. Souza Mendes ◽  
E. M. Sparrow
Keyword(s):  
Heat Transfer ◽  
Fluid Flow ◽  
Surface Area ◽  
Equal Mass ◽  
Turbulent Heat Transfer ◽  
Turbulent Heat ◽  
Transfer Coefficients ◽  
Pressure Drops ◽  
Heat Transfer Coefficients ◽  
Friction Factors

A comprehensive experimental study was performed to determine entrance region and fully developed heat transfer coefficients, pressure distributions and friction factors, and patterns of fluid flow in periodically converging and diverging tubes. The investigated tubes consisted of a succession of alternately converging and diverging conical sections (i.e., modules) placed end to end. Systematic variations were made in the Reynolds number, the taper angle of the converging and diverging modules, and the module aspect ratio. Flow visualizations were performed using the oil-lampblack technique. A performance analysis comparing periodic tubes and conventional straight tubes was made using the experimentally determined heat transfer coefficients and friction factors as input. For equal mass flow rate and equal transfer surface area, there are large enhancements of the heat transfer coefficient for periodic tubes, with accompanying large pressure drops. For equal pumping power and equal transfer surface area, enhancements in the 30–60 percent range were encountered. These findings indicate that periodic converging-diverging tubes possess favorable enhancement characteristics.

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