scholarly journals Time Evolution of CO2 Diffusivity of Carbonated Concrete

2020 ◽  
Vol 10 (24) ◽  
pp. 8910
Author(s):  
In-Seok Yoon ◽  
Chun-Ho Chang
Keyword(s):  
Time Evolution ◽  
Cement Paste ◽  
Functional Model ◽  
Cementitious Materials ◽  
Gas Flows ◽  
Reinforcement Corrosion ◽  
Pore System ◽  
Microstructural Characteristics ◽  
Co2 Gas ◽  
Decisive Parameter

Carbonation of cementitious materials is one of main causes of reinforcement corrosion and CO2 diffusivity influenced by microstructural characteristics of the cementitious materials is a decisive parameter for the carbonation rate. This study focused on establishing a multifactor functional model to calculate the CO2 diffusivity of carbonated cementitious materials. Because CO2 gas flows through carbonated zone, it is necessary to estimate CO2 diffusivity of carbonated concrete. Many factors on the CO2 diffusivity, such as the diffusivity in vapor, tortuosity, microstructural characteristics of cement paste, contribution of aggregate, and reduction of porosity due to carbonation, were considered. Apparent and effective CO2 diffusivity were calculated according to the absence or presence of moisture in the pore system of concrete, and the results were compared with previous research.

Using of Untreated Carbon Nanotubes in Cement Compositions

2016 ◽  
Vol 865 ◽  
pp. 6-11 ◽  
Author(s):  
Kateryna Pushkarova ◽  
Maryna Sukhanevych ◽  
Artur Martsikh
Keyword(s):  
Carbon Nanotubes ◽  
Cement Paste ◽  
Cementitious Materials ◽  
Positive Influence ◽  
Mechanical Tests ◽  
Strength Characteristics ◽  
Concrete Durability ◽  
Cement Mortars ◽  
Optimum Decision ◽  
Cement System

One of the most important problem of concrete durability is increasing of waterproofing. Researches are devoted studying of cement mortars modified by carbon nanotubes, dispersed in plasticizers solutions. Were investigated physico-mechanical properties of cement paste, cement-sand mortar into which structure entered untreated carbon nanotubes (production of plant TM "Spetsmash" Kyiv, Ukraine) in various quantity. Were used as plasticizers in cement compositions additives substances of the various chemical nature – naphtaleneformaldehyde, melamineformaldehyde and polycarboxylate. Quantity of untreated nanotubes varied from 0,5%; 1,0% and to 1,5%. Concentration of additives was accepted taking into account recommendations of producers and made about 1% from the weight of cement. Were studied some technological processes of introduction untreated carbon nanotubes in cement system and is shown that the way of introduction of nanomodifiers has essential impact on strength characteristics of cementitious materials. Optimum decision introduction of untreated carbon nanotubes is using its in dispersion plasticizer of the working concentration prepared in an ultrasonic dispergator is established. Results of physico-mechanical tests of cement paste and cement-sand mortar showed positive influence at introduction of untreated carbon nanotubes as cement modifiers on strength characteristics of samples. Resalts is shown that the nanomodifier, used quantity about 1% in solution of lignosulfonate with polycarboxylate and melamineformaldehyde plasticizer has great impact on strength characteristics.

Use of Algerian Natural Mineral Deposit as Supplementary Cementitious Materials

2018 ◽  
Vol 34 ◽  
pp. 48-58 ◽  
Author(s):  
Karima Arroudj ◽  
Saida Dorbani ◽  
Mohamed Nadjib Oudjit ◽  
Arezki Tagnit-Hamou
Keyword(s):  
Mechanical Strength ◽  
Calcium Hydroxide ◽  
Cement Paste ◽  
Cementitious Materials ◽  
Pozzolanic Reaction ◽  
Heat Of Hydration ◽  
Cement Industry ◽  
Supplementary Cementitious Materials ◽  
Natural Mineral ◽  
Different Ages

Much of the current research on concrete engineering has been focused on including siliceous additions as supplementary cementitious materials (SCMs). Silica reacts with Calcium hydroxide release during cement hydration, and produces more C-S-H. The latter contributes to increase compactness, mechanical strengths and sustainability of concrete. This paper explores the hydration characteristics of cement paste based on various natural mineral additions, that are very abundant in Algeria and present a high silica content (ground natural pozzolana “PZ” and ground dune sand “DS”). For this purpose, several analyses were carried out on modified cement pastes and mortars. TheseSCMswere introduced by replacement levels of 15, 20 and 25 by weight of cement. We first, studied the effect of these SCMs on the heat of hydration and mechanical strength of mortars at different ages. The evolution of hydration of modified paste was studied, by using Thermal analysis (TG/TDA) at different ages, to analyze the Calcium Hydroxide (CH) content of the modified pastes. It is shown that the CH content of the mixes including SCMs is lower than that of the plain cement paste, indicating that silica reacts with the cement paste through a pozzolanic reaction. Increased pozzolanic activity results in higher amounts of Calcium Silicate Hydrate in the paste, which in turn results in higher compressive strength for modified cement mortars. Due to its crystalline morphology, the ground DS particles present a partial pozzolanic effect, compared to PZ which is semi-crystalline. Modified mortars by 20% DS can be the optimal composition. It presents satisfactory results: good mechanical strength and low heat of hydration. It can lead to an economic and sustainable concrete. Ground DS is very abounded in Africa and free of any impurities and can be a good alternativeSCMsin cement industry.

scholarly journals Effect of nano-SnO2 on early-age hydration of Portland cement paste

2019 ◽  
Vol 11 (6) ◽  
pp. 168781401985194 ◽  
Author(s):  
Jianping Zhu ◽  
Genshen Li ◽  
Ruijie Xia ◽  
Huanhuan Hou ◽  
Haibin Yin ◽  
...  
Keyword(s):  
Portland Cement ◽  
Cement Paste ◽  
Cement Hydration ◽  
Cementitious Materials ◽  
Hydration Process ◽  
Strength Development ◽  
Early Age ◽  
Test Machine ◽  
Portland Cement Paste ◽  
Scanning Electron

Nanomaterial, as a new emerging material in the field of civil engineering, has been widely utilized to enhance the mechanical properties of cementitious material. Nano-SnO2 has presented high hardness characteristics, but there is little study of the application of nano-SnO2 in the cementitious materials. This study mainly investigated the hydration characteristics and strength development of Portland cement paste incorporating nano-SnO2 powders with 0%, 0.08%, and 0.20% dosage. It was found that the early-age compressive strength of cement paste could be greatly improved when nano-SnO2 was incorporated with 0.08% dosage. The hydration process and microstructure were then measured by hydraulic test machine, calorimeter, nanoindentation, X-ray diffraction, scanning electron microscope, and mercury intrusion porosimetry. It was found that the cement hydration process was promoted by the addition of nano-SnO2, and the total amount of heat released from cement hydration is also increased. In addition, the addition of nano-SnO2 can promote the generations of high density C-S-H and reduce the generations of low density C-S-H indicating the nucleation effect of nano-SnO2 in the crystal growth process. The porosity and probable pore diameter of cement paste with 0.08% nano-SnO2 were decreased, and the scanning electron microscopic results also show that the cement paste with 0.08% nano-SnO2 promotes the densification of cement microstructure, which are consistent with the strength performance.

scholarly journals Minimum Water Requirement Method for High-Performance Sulphoaluminate Cement-Based Materials

2019 ◽  
Vol 2019 ◽  
pp. 1-11
Author(s):  
Hong-ping Zhang ◽  
Pei-kang Bai ◽  
Jian-hong Wang ◽  
Yan-li Dong ◽  
Yun-shan Han
Keyword(s):  
Cement Paste ◽  
High Performance ◽  
Steel Slag ◽  
Cementitious Materials ◽  
Water Requirement ◽  
Mineral Admixtures ◽  
Poor Correlation ◽  
Sulphoaluminate Cement ◽  
Cement Based Materials ◽  
Orthogonal Tests

In this work, we propose the use of steel slag instead of slag powder, in addition to fly ash and silica fume, to obtain high-performance sulphoaluminate cement-based materials. According to the closest-packing theory and on the basis of the minimum water requirement test, the influence of mineral admixtures on the minimum water requirement was evaluated for sulphoaluminate composite system paste. The optimal composition of the cementitious materials was thus determined. Orthogonal tests were used to assess the validity of this ratio. The correlation between minimum water requirement and the standard consistence was not only analyzed in the system of the minimum water requirement method decided but also in the complicate system of the orthogonal tests determined. Experimental results show that the influence of steel slag on the minimum water requirement is the largest in composite cement paste; minimum water requirement and standard consistency have a good correlation; the cement paste designed with the optimum composite had the highest strength of all the tested materials, but minimum water requirement and strength have a poor correlation in the orthogonal tests. We demonstrate that standard consistency evaluation can replace the minimum water requirement method to determine the optimum ratio of cement mineral admixtures. The proposed method not only simplifies the process but also makes the method more scientific.

scholarly journals Characterization of Titanium Nanotube Reinforced Cementitious Composites: Mechanical Properties, Microstructure, and Hydration

Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1617 ◽  
Author(s):  
Hyeonseok Jee ◽  
Jaeyeon Park ◽  
Erfan Zalnezhad ◽  
Keunhong Jeong ◽  
Seung Min Woo ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Cement Paste ◽  
Cementitious Materials ◽  
Cement Clinker ◽  
Early Age ◽  
Potential Candidate ◽  
Hydration Kinetics ◽  
Cement Pastes ◽  
Viable Solution ◽  
First Time

In recent years, nano-reinforcing technologies for cementitious materials have attracted considerable interest as a viable solution for compensating the poor cracking resistance of these materials. In this study, for the first time, titanium nanotubes (TNTs) were incorporated in cement pastes and their effect on the mechanical properties, microstructure, and early-age hydration kinetics was investigated. Experimental results showed that both compressive (~12%) and flexural strength (~23%) were enhanced with the addition of 0.5 wt.% of TNTs relative to plain cement paste at 28 days of curing. Moreover, it was found that, while TNTs accelerated the hydration kinetics of the pure cement clinker phase (C3S) in the early age of the reaction (within 24 h), there was no significant effect from adding TNTs on the hydration of ordinary Portland cement. TNTs appeared to compress the microstructure by filling the cement paste pore of sizes ranging from 10 to 100 nm. Furthermore, it could be clearly observed that the TNTs bridged the microcracks of cement paste. These results suggested that TNTs could be a great potential candidate since nano-reinforcing agents complement the shortcomings of cementitious materials.

scholarly journals Additive Manufacturing of Cementitious Materials by Selective Paste Intrusion: Numerical Modeling of the Flow Using a 2D Axisymmetric Phase Field Method

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 5024
Author(s):  
Alexandre Pierre ◽  
Daniel Weger ◽  
Arnaud Perrot ◽  
Dirk Lowke
Keyword(s):  
Numerical Modeling ◽  
3D Printing ◽  
Cement Paste ◽  
Phase Field ◽  
Numerical Approach ◽  
Cementitious Materials ◽  
Field Method ◽  
Phase Field Method ◽  
Shape Accuracy ◽  
Cement Pastes

The 3D printing of concrete has now entered a new era and a transformation of the construction sector is expected to reshape fabrication with concrete. This work focuses on the selective paste intrusion method, which consists of bonding dry particles of aggregate with a cement paste. This innovative technique could lead to the production of very precise component for specific applications. The main obstacle to tackle in order to reach a high shape accuracy of high mechanical performances of 3D printing elements by selectively activating the material is the control of the distribution of the cement paste through the particle bed. With the aim to better understand the path followed by the solution as it penetrates a cut-section of the granular packing, two-dimensional numerical modeling is carried out using Comsol software. A phase-field method combined with a continuous visco-plastic model has been used to study the influence of the average grain diameter, the contact angle, and the rheological properties of cement pastes on the penetration depth. We compare the numerical modeling results to existing experimental results from 3D experiments and a one-dimensional analytical model. We then highlight that the proposed numerical approach is reliable to predict the final penetration of the cement pastes.

scholarly journals CO2 Curing Efficiency for Cement Paste and Mortars Produced by a Low Water-to-Cement Ratio

Materials ◽  
2020 ◽  
Vol 13 (17) ◽  
pp. 3883
Author(s):  
Seong Ho Han ◽  
Yubin Jun ◽  
Tae Yong Shin ◽  
Jae Hong Kim
Keyword(s):  
Cement Paste ◽  
Pressure Vessel ◽  
Gas Pressure ◽  
Strength Development ◽  
Co2 Uptake ◽  
Cement Pastes ◽  
Co2 Gas ◽  
Cement Ratio ◽  
Mix Proportion ◽  
Water To Cement Ratio

Curing by CO2 is a way to utilize CO2 to reduce greenhouse gas emissions. Placing early-age cement paste in a CO2 chamber or pressure vessel accelerates its strength development. Cement carbonation is attributed to the quickened strength development, and CO2 uptake can be quantitatively evaluated by measuring CO2 gas pressure loss in the pressure vessel. A decrease in CO2 gas pressure is observed with all cement pastes and mortar samples regardless of the mix proportion and the casting method; one method involves compacting a low water-to-cement ratio mix, and the other method comprises a normal mix consolidated in a mold. The efficiency of the CO2 curing is superior when a 20% concentration of CO2 gas is supplied at a relative humidity of 75%. CO2 uptake in specimens with the same CO2 curing condition is different for each specimen size. As the specimen scale is larger, the depth of carbonation is smaller. Incorporating colloidal silica enhances the carbonation as well as the hydration of cement, which results in contributing to the increase in the 28-day strength.

The Effect of Sulfonated Graphene on the Rheological Properties of Cement Paste

2020 ◽  
Vol 20 (12) ◽  
pp. 7495-7505
Author(s):  
Jia-Ming Wu ◽  
Guo-Jian Jing ◽  
Xiao-Lei Lu ◽  
Tian-Yu Lei ◽  
Shu-Xian Wang ◽  
...  
Keyword(s):  
Rheological Properties ◽  
Cement Paste ◽  
Chemical Interaction ◽  
Cementitious Materials ◽  
Rheological Parameters ◽  
Physical Interaction ◽  
Mechanical And Thermal Properties ◽  
Practical Application ◽  
Sulfonated Graphene ◽  
Modified Graphene

With unique 2D nanostructures and excellent properties, graphene and its derivatives are a class of advanced nanosized reinforcements for cementitious materials. Sulfonated graphene (SG), one of the most important modified graphene materials, possesses sulfonate groups on the surface and significantly improves the mechanical and thermal properties of cement-based composites. It is important to investigate the influence of SG on cement-based materials as it is a prerequisite for practical applications. Herein, SG was prepared and introduced into cement paste to investigate its influence on the rheological properties of cement paste. With the increased addition of SG, a stable slurry was gradually obtained with low fluidity and high rheological parameters. The mechanism of the SG effect on the rheological properties of cement paste was also illustrated. Because of the high specific surface area and sulfonate groups of SG nanosheets, a large amount of flocculated structure was created by the complexing effect, chemical interaction, physical interaction and mechanical interlocking between SG and hydrated/unhydrated cement particles. Furthermore, polycarboxylate ether (PCE) superplasticizer was introduced to ensure fluidity and transportability in the practical application of SG. The results in this work lay a foundation for the practical application of modified graphene in cementitious materials.

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