scholarly journals An Influence of the Fuel Type on Element Behaviour in Domestic Boilers with Respect to the Circular Economy

2021 ◽  
Vol 11 (11) ◽  
pp. 4980
Author(s):  
Helena Raclavská ◽  
Pavel Kantor ◽  
Jana Růžičková ◽  
Marek Kucbel ◽  
Barbora Švédová ◽  
...  
Keyword(s):  
Trace Elements ◽  
Circular Economy ◽  
Total Content ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Waste Paper ◽  
Waste Wood ◽  
Residential Combustion ◽  
High Concentrations ◽  
Local Emissions

The use of waste from the regional production of waste wood, waste paper, and cardboard in the form of briquettes may be causing an increase in local emissions, both of major elements and trace elements. When burning paper and cardboard briquettes, more than 70% of Mn, Zn, As, and Pb is released into the air from the total content of trace elements in the fuel. The largest amounts of major and trace elements are released when burning paper briquettes (56 g/kg of fuel); half of these amounts are released from burning briquettes from waste wood and coal (23 g/kg of fuel). The pursuit of alternative uses for those cardboard components that are not suitable for recycling cannot be directed to the production of briquettes for residential combustion in the framework of the application of the principles of the circular economy. In particular, the high concentrations of undesirable elements in the emissions released in the gas phase into the atmosphere are an obstacle existing even when the parameters of the PM10 emissions of a boiler are met. This is related to the high ash content of the cardboard (13.5%). Waste paper or cardboard could be added to waste wood at a maximum of 10% to make the pollution produced comparable to the burning of coal briquettes.

Hydrochemistry and carbonate sediment characterisation of Bacalar Lagoon, Mexican Caribbean

2019 ◽  
Vol 70 (3) ◽  
pp. 382 ◽  
Author(s):  
Nidia I. Tobón Velázquez ◽  
Mario Rebolledo Vieyra ◽  
Adina Paytan ◽  
Kyle H. Broach ◽  
Laura M. Hernández Terrones
Keyword(s):  
Trace Elements ◽  
Water Column ◽  
Saturation Index ◽  
Major Elements ◽  
Anthropogenic Sources ◽  
Pollution Indices ◽  
Mexican Caribbean ◽  
High Concentrations ◽  
Geochemical Analyses ◽  
Changes Over Time

The aim of the study is to determine the distribution of trace and major elements in the water and in the sediments of the south part of the Bacalar Lagoon and to identify the sources of the trace elements and their changes over time. The western part of the lagoon water column is characterised by high concentrations of Ca2+, HCO3– and Sr2+, derived from groundwater input. In contrast, the eastern part of the lagoon is characterised by high concentrations of Mg2+, Na+ and Cl–. The lagoon is not affected by present-day seawater intrusion. Water column and sediment geochemical analyses performed in Bacalar Lagoon show clear spatial distribution of different parameters. The saturation index of the water column indicates three main groups: (1) a zone oversaturated with regard to aragonite, calcite and dolomite; (2) an undersaturated area where all three minerals are dissolving; and (3) an area with calcite equilibrium and undersaturation with regard to the other minerals. Herein we present the first measurements of trace element (Ba2+, Mn2+, K+, Ni2+, Zn2+) concentrations in carbonates obtained from sediments in Bacalar Lagoon. In order to evaluate whether the trace elements are derived from natural or anthropogenic sources, four pollution indices were calculated. The results confirmed that Bacalar Lagoon sediments are not contaminated with Ni2+, K+, Mn2+ and Ba2+, and that the Zn2+ seems to have a predominantly anthropogenic origin.

scholarly journals Evaluation of sediment contamination by trace elements and the zooplankton community analysis in area affected by gold exploration in Southeast (SE) of the Iron Quadrangle, Alto Rio Doce, (MG) Brazil

2013 ◽  
Vol 25 (2) ◽  
pp. 150-157
Author(s):  
Cláudia de Lima e Silva ◽  
Adivane Terezinha da Costa ◽  
Giovanni Guimarães Landa ◽  
Herton Fabrício Camargos Fonseca ◽  
Aléssio Silveira
Keyword(s):  
Trace Elements ◽  
Reference Values ◽  
Zooplankton Community ◽  
Reference Value ◽  
Community Analysis ◽  
Major And Trace Elements ◽  
Geochemical Composition ◽  
Gold Exploration ◽  
Local Reference ◽  
High Concentrations

AIM: The aim was to verify the geochemical composition of sediments samples (riverbed and bank) and the relationship of the following elements: Al, As, Cd. Cr, Cu, Fe, Mn, Ni and Zn with the zooplankton community. METHODS: Bank and riverbed sediments were collected in four sampling points along the studied area, in June/2010 (dry season) and March/2011 (rainy season). Three types of analysis were performed: granulometric, mineralogical (by X-Ray diffractometer) and geochemical (by ICPOES), where for the last two types, only a fraction of silt/clay (<0.062 mm) was used, and the results were compared with the following reference values: Local Reference Value (Costa et al., 2010), Quality Reference Values (São Paulo, 2005), PEC and TEC values (MacDonald et al., 2000). For identification of the zooplankton community, riverbed and bank samples were collected in polyethylene bottles, suspended with deionized water (bank sample only), stained with Rose Bengal and preserved in formalin at 4%. RESULTS: As concentrations at Col sampled point were 18 times greater than the Local Reference Value (3.84 mg.kg-1). Cd concentrations were greater than the values established by the QRV (<0.5 mg.kg-1) and PEC (4.98 mg.kg-1) in almost all the sampled points, regarding seasonality. The following zooplanktonic species were identified: Arcella costata (Ehrenberg, 1847), Arcella discoides (Ehrenberg, 1843), Arcella vulgaris (Ehrenberg, 1830), Centropyxis aculeata (Ehrenberg, 1838), Centropyxis ecornis (Ehrenberg, 1841), Difflugia sp., Difflugia acuminata (Ehrenberg, 1838), Euglypha laevis (Perty, 1849), Trynema enchelys (Ehrenberg, 1938), Asplanchna priodonta (Gosse, 1850), and Bedelloida, with, approximately 81% belonging to the Protozoa group. CONCLUSIONS: The studied area, with the exception of the Tripuí point, was found to be impacted by historical gold exploration in the region, as well as by the growing urbanization. Within the elements considered to be the most toxic to the biota, As and Cd violated all their reference values. In spite of high concentrations of major and trace elements encountered at downstream points, testacea species were identified, suggesting that this group has the capacity to adapt to adverse situations.

scholarly journals Total content of macroelements and trace elements in Holocene calcareous gyttja from the post-bog area of north-western Poland

2019 ◽  
Vol 14 (No. 1) ◽  
pp. 40-46
Author(s):  
Grzegorz Jarnuszewski ◽  
Edward Meller
Keyword(s):  
Trace Elements ◽  
Organic Carbon ◽  
Total Organic Carbon ◽  
Total Content ◽  
Major And Trace Elements ◽  
Carbonate Mineral ◽  
Minor Components ◽  
Ignition Loss ◽  
Calcareous Deposits ◽  
North Western

The study covered 6 sites located in the Vistula glaciation area in north-western Poland, where the Holocene calcareous (gyttja) deposits occur. Three types of such calcareous deposits were isolated: marly (groundwater calcretes) (CaCO<sub>3</sub> &gt; 80%, loss of ignition &lt; 20%, non-carbonate fractions &lt; 20%), calcareous gyttja (CaCO<sub>3</sub> 50–80%, loss of ignition &lt; 40%, non-carbonate fractions &lt; 40%), and clay calcareous gyttja (CaCO<sub>3</sub> 20–50%, loss of ignition &lt; 30%, non-carbonate fractions &lt; 60%). The content of major and trace elements was determined in different horizons. Several parameters of Holocene calcareous deposits were determined, namely carbonate status, total organic carbon, non-carbonate mineral fractions and several major and minor components. Close correlations between CaCO<sub>3</sub> and Ca, Mg contents, between non-carbonate fraction and K, Zn and Cu contents, as well as between ignition loss and Zn and Cu contents were observed in the sediments. The sediments exhibit vertical variability which relates to the genesis of sediments and soils. The highest content of macroelements was recorded in the uppermost layers for Ca, Mg, Na, and Mn and for microelements (trace elements) in bottom layers for S, P, K, Fe, Zn, Cu, Pb, and Ni.  

scholarly journals Geochemical features of the distribution of major and trace elements in sediments and soils of the Zarafshon River Valley

2021 ◽  
Author(s):  
Daler Abdusamadzoda ◽  
Djamshed Abdushukurov ◽  
Octavian Duliu ◽  
Inga Zinicovscaia ◽  
Pavel Nekhoroshkov
Keyword(s):  
Trace Elements ◽  
Terrestrial Ecosystems ◽  
Major And Trace Elements ◽  
Major Elements ◽  
River Valley ◽  
Careful Examination ◽  
Catchment Basin ◽  
Significant Similarity ◽  
Industrial Facilities ◽  
Soil Weathering

Abstract Purpose The aim of this research was to estimate impact of the geochemical features to distribution of major and trace elements in soil and sediments, assess of anthropogenic and natural factors in terrestrial ecosystems of Zarafshon. As well as to answer the common criticism of the water, soil and sediment pollution in Zarafshon. In this way this research will be reasonable substantial information about distribution of major and trace elements in mountains and piedmont regions. Materials and methods In view of a planned detailed investigation, and to get more data concerning the geochemistry of sediments and soils along the Zarafshon Valley of Western Tajikistan, as well as to assess of the local environmental situation, the mass fraction of eight major, rock-forming elements together with other 38 trace elements were determined by Instrumental Neutron Activation Analysis. To accomplish this task 116 samples of sediment and an equal number of soils were collected around the Tajik sector of the Zarafshon catchment basin and its main tributaries. Results and discussion Both major and trace elements proved a significant similarity between soil and sediments including potentially contaminating elements As, Sb and Hg, whose mass fractions showed in some places to be significantly higher. An analysis of the distribution of major elements oxides as well as of incompatible trace elements Sc, Zr, REE, Th, and U suggested that the analysed soil and sediments have rather a felsic origin. A more careful examination revealed a reduced degree of recycling and for some location, a certain degree of weathering. All these peculiarities could be ascribed to a vast investigated area spread onto a significant diversity of geological formations. Conclusion The process of soil weathering of the studied area takes place relatively quick, but mainly it's has a natural character rather. The high content of accumulation of major and trace element in the sediment also related to rock source but only in rare cases is it of an anthropogenic nature. Based on these results, it can be predicted that the seriously environmental threat was not observed in the Zarafshon river valley. The activities of industrial facilities cover only a small part of this region and their impacts on the ecological state of the Zarafshon river valley is very small.

scholarly journals Geochemistry of garnet megacrysts from the Mir kimberlite pipe (Yakutia) and the nature of prothokimberlite melt

2019 ◽  
Vol 486 (5) ◽  
pp. 583-587
Author(s):  
A. M. Agashev
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Rare Earth Elements ◽  
Negative Correlation ◽  
Kimberlite Pipe ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Incompatible Elements ◽  
Composition Study ◽  
Melt Composition

The paper presents the results of major and trace elements composition study of garnet megacrysts from Mir kimberlite pipe. On the major elements composition those garnets classified as low Cr and high Ti pyropes. Concentrations of TiO2 show a negative correlation with MgO и Cr2O3 contents in megacrysts composition. Fractional crystallization modeling indicates that the most appropriate melt to reproduce the garnet trace elements signatures is the melt of picritic composition. Composition of garnets crystallized from kimberlite melt do not correspond to observed natural garnets composition. Kimberlites contain less of Ti, Zr, Y and heavy REE (rare earth elements) but more of very incompatible elements such as light REE, Th, U, Nb, Ba then the model melt composition that necessary for garnet crystallization.

scholarly journals The distribution of the trace element contents in lignite and ash from Drama lignite deposit, using multivariate statistical analysis

2001 ◽  
Vol 34 (3) ◽  
pp. 1255
Author(s):  
S. PANILAS ◽  
G. HATZIYANNIS
Keyword(s):  
Trace Elements ◽  
Rare Earth ◽  
Statistical Analysis ◽  
Rare Earth Elements ◽  
Multivariate Statistical Analysis ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Geochemical Data ◽  
Multivariate Statistical ◽  
Inorganic Matter

Multivariate statistical analysis was used on existing geochemical data of the Drama lignite deposit, eastern Macedonia, Greece. Factor analysis with varimax rotation technique was applied to study the distribution of major, trace and rare earth elements in the lignite and 850°C lignitic ash, to find a small set of factors that could explain most of the geochemical variability. The study showed that major elements AI, Na, Κ, contained in the lignite samples, presented high correlation with most of the trace and rare earth elements. In 850°C lignitic ashes major and trace elements present different redistribution. Only Al remained correlated with the trace elements Co, Cr, Rb, Ta, Th, Ti, Sc and rare earths related with inorganic matter in the lignite beds. Trace elements Fe, Mo, U, V, W, and Lu were associated with organic matter of lignite and had also been affected by the depositional environment.

The Nutritional Value and Preliminary Risk Assessment of Major and Trace Elements Accumulated in 8 Edible Seaweeds

2013 ◽  
Vol 781-784 ◽  
pp. 1377-1384
Author(s):  
Ting Ting Feng ◽  
Hong Bo Chen ◽  
Ping Shao ◽  
Jin Zhe He
Keyword(s):  
Trace Elements ◽  
Nutritional Value ◽  
Toxic Elements ◽  
Porphyra Yezoensis ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Pollution Level ◽  
Nostoc Commune ◽  
Edible Seaweeds ◽  
Concentration Changes

16 major and trace elements content of 8 edible seaweeds were determined by ICP-AES after wet digestion to compare the nutritional value and pollution level between Cyanophyta (blue), Chlorophyta (green), Rhodophyta (red), Phaeophyta (brown) species. The concentration changes of trace elements in seaweeds had some differences from four species, but the concentration distribution tendency of trace elements was similar. Major elements ( K,Ca,Na,Mg,P) and functional elements (Fe,Mn,Zn,Cu,Se,Cr) were abundant in Cyanophyta (blue) and Phaeophyta (brown) species, these two species, however, accumulated Al selectively. The pollution levels of toxic elements like As, Pb and Hg in most seaweeds from this study demonstrated that the cultivation aquatic eco- environments were relatively safe. In this paper, Nostoc commune var. Flagelliforme (Cyanophyta) abounds in Fe, Zn and major elements, moreover the concentration of potentially toxic elements were relatively low. The second was Phaeophyta species, especially Laminaria japonica Aresch . Porphyra yezoensis Ueda (Rhodophyta) shows the lowest nutritional value.

scholarly journals Assessment of Major and Trace Elements in Drinking Groundwater in Bisha Area, Saudi Arabia

2020 ◽  
Vol 2020 ◽  
pp. 1-10
Author(s):  
Faleh Z. Alqahtani ◽  
Saifedin Y. DaifAllah ◽  
Yasir F. Alaryan ◽  
Abubakr M. Elkhaleefa ◽  
Eid I. Brima
Keyword(s):  
Trace Elements ◽  
Saudi Arabia ◽  
Inductively Coupled Plasma ◽  
Hard Water ◽  
Major And Trace Elements ◽  
Major Elements ◽  
World Health ◽  
Similar Distribution ◽  
Significant Difference ◽  
Health Organization

Drinking groundwater represents 30% of the world’s fresh water and 0.9% of the whole world’s water. Therefore, routine analysis and monitoring of the groundwater is a paramount issue, specifically the measurement of elemental concentrations due to aquifer characterization. Consequently, the purpose of this study was to determine major and trace elements in groundwater. In total, 25 samples of groundwater were collected from wells in the Bisha area, Asir province, Saudi Arabia. All samples were analyzed for major and trace elements by using Inductively Coupled Plasma Mass Spectrometry (ICP-MS). In total, 15 elements were measured including four major elements (Na, K, Mg, and Ca) and 11 trace elements (V, Cr, Mn, Co, Ni, Cu, Zn, As, Se, Cd, and Pb). Major elements (Na, Mg, and Ca) exceeded the guideline limits in some samples. In addition, only one trace element (Se) exceeded the World Health Organization (WHO) permissible limits in some samples. This could be due to rock characteristics in aquifers. Very hard water was shown in 92% of the samples. Moreover, a high percentage (32%) of the analyzed samples also exceeded the guideline levels for chloride. ANOVA analysis showed significant difference (p<0.05) between Bisha samples (North and South), Bisha samples (North), and the remaining samples, for V and pH, and Na, Cl−, EC, and TDS, respectively. No significant differences (p>0.05) were reported for Na, K, Mg, Ca, Cr, Mn, Co, Ni, Cu, Zn, As, Se, Cd, and Pb between all samples. In general, 25 significant (p>0.05) correlations were reported among the measured elements. For the positive correlations, similar distribution for the elements is anticipated. In conclusion, the groundwater in this study is not suitable for domestic use due to its hardness and only some are suitable for irrigation. More studies are needed to confirm our findings in the study area.

Major and trace elements in organically or conventionally produced milk

2005 ◽  
Vol 72 (3) ◽  
pp. 362-368 ◽  
Author(s):  
John E Hermansen ◽  
Jens H Badsberg ◽  
Troels Kristensen ◽  
Vagn Gundersen
Keyword(s):  
Trace Elements ◽  
Inductively Coupled Plasma ◽  
Production Systems ◽  
Atomic Emission ◽  
Major And Trace Elements ◽  
Major Elements ◽  
Emission Spectrometry ◽  
Plasma Atomic Emission Spectrometry ◽  
Inductively Coupled ◽  
Few Data

A total of 480 samples of milk from 10 organically and 10 conventionally producing dairy farms in Denmark and covering 8 sampling periods over 1 year (triplicate samplings) were analysed for 45 trace elements and 6 major elements by high-resolution inductively coupled plasma mass spectrometry and inductively coupled plasma atomic emission spectrometry. Sampling, sample preparation, and analysis of the samples were performed under carefully controlled contamination-free conditions. The dairy cattle breeds were Danish-Holstein or Jersey. Sources of variance were quantified, and differences between production systems and breeds were tested. The major source of variation for most elements was week of sampling. Concentrations of Al, Cu, Fe, Mo, Rb, Se, and Zn were within published ranges. Concentrations of As, Cd, Cr, Mn and Pb were lower, and concentrations of Co and Sr were higher than published ranges. Compared with Holsteins, Jerseys produced milk with higher concentrations of Ba, Ca, Cu, Fe, Mg, Mn, Mo, P, Rh, and Zn and with a lower concentration of Bi. The organically produced milk, compared with conventionally produced milk, contained a significantly higher concentration of Mo (48 v. 37 ng/g) and a lower concentration of Ba (43 v. 62 ng/g), Eu (4 v. 7 ng/g), Mn (16 v. 20 ng/g) and Zn (4400 v. 5150 ng/g respectively). The investigation yielded typical concentrations for the following trace elements in milk, for which no or very few data are available: Ba, Bi, Ce, Cs, Eu, Ga, Gd, In, La, Nb, Nd, Pd, Pr, Rh, Sb, Sm, Tb, Te, Th, Ti, Tl, U, V, Y, and Zr.

scholarly journals A Comparative Study of Heavy Metals and Trace Elements Concentration in Milk Samples Consumed in Iraq

2020 ◽  
Vol 17 (1(Suppl.)) ◽  
pp. 0310
Author(s):  
Nada M. Hasan
Keyword(s):  
Trace Elements ◽  
Nitrogen Concentration ◽  
Milk Powder ◽  
Major And Trace Elements ◽  
World Health ◽  
Silicon Iron ◽  
Food And Agriculture ◽  
Food And Agriculture Organization ◽  
High Concentrations ◽  
Health Organization

The measurements of major and trace elements in different brands of milk powder selected from the Iraqis market via the X-ray fluorescence (XRF) Technique have been studied in the present work. The result of the measurements reveals the high concentrations of sodium, phosphorus, sulfur, chlorine, potassium, calcium and magnesium. Furthermore, low concentrations of aluminum, silicon, iron, bromine, molybdenum, iodine, barium, titanium, manganese, cobalt, chrome, nickel, copper, zinc and lead were detected. Neutron activation analysis (NAA) and Kjeldahl technique were also employed to determine the concentrations of nitrogen. It was found that the nitrogen concentration was in the range of (1.96 - 3.23) % which is within the permissible limits. The concentrations of the trace elements (copper, manganese, zinc, lead) were verified via the atomic absorption spectrometer (AAS) technique. The results are compared with the authorized limit by the food and agriculture organization and the world health organization (FAO/WHO) standards.

Sign in / Sign up

Export Citation Format

Share Document