Evaluation of sediment contamination by trace elements and the zooplankton community analysis in area affected by gold exploration in Southeast (SE) of the Iron Quadrangle, Alto Rio Doce, (MG) Brazil

AIM: The aim was to verify the geochemical composition of sediments samples (riverbed and bank) and the relationship of the following elements: Al, As, Cd. Cr, Cu, Fe, Mn, Ni and Zn with the zooplankton community. METHODS: Bank and riverbed sediments were collected in four sampling points along the studied area, in June/2010 (dry season) and March/2011 (rainy season). Three types of analysis were performed: granulometric, mineralogical (by X-Ray diffractometer) and geochemical (by ICPOES), where for the last two types, only a fraction of silt/clay (<0.062 mm) was used, and the results were compared with the following reference values: Local Reference Value (Costa et al., 2010), Quality Reference Values (São Paulo, 2005), PEC and TEC values (MacDonald et al., 2000). For identification of the zooplankton community, riverbed and bank samples were collected in polyethylene bottles, suspended with deionized water (bank sample only), stained with Rose Bengal and preserved in formalin at 4%. RESULTS: As concentrations at Col sampled point were 18 times greater than the Local Reference Value (3.84 mg.kg-1). Cd concentrations were greater than the values established by the QRV (<0.5 mg.kg-1) and PEC (4.98 mg.kg-1) in almost all the sampled points, regarding seasonality. The following zooplanktonic species were identified: Arcella costata (Ehrenberg, 1847), Arcella discoides (Ehrenberg, 1843), Arcella vulgaris (Ehrenberg, 1830), Centropyxis aculeata (Ehrenberg, 1838), Centropyxis ecornis (Ehrenberg, 1841), Difflugia sp., Difflugia acuminata (Ehrenberg, 1838), Euglypha laevis (Perty, 1849), Trynema enchelys (Ehrenberg, 1938), Asplanchna priodonta (Gosse, 1850), and Bedelloida, with, approximately 81% belonging to the Protozoa group. CONCLUSIONS: The studied area, with the exception of the Tripuí point, was found to be impacted by historical gold exploration in the region, as well as by the growing urbanization. Within the elements considered to be the most toxic to the biota, As and Cd violated all their reference values. In spite of high concentrations of major and trace elements encountered at downstream points, testacea species were identified, suggesting that this group has the capacity to adapt to adverse situations.

Download Full-text

A Comparative Study of Heavy Metals and Trace Elements Concentration in Milk Samples Consumed in Iraq

Baghdad Science Journal ◽

10.21123/bsj.2020.17.1(suppl.).0310 ◽

2020 ◽

Vol 17 (1(Suppl.)) ◽

pp. 0310

Author(s):

Nada M. Hasan

Keyword(s):

Trace Elements ◽

Nitrogen Concentration ◽

Milk Powder ◽

Major And Trace Elements ◽

World Health ◽

Silicon Iron ◽

Food And Agriculture ◽

Food And Agriculture Organization ◽

High Concentrations ◽

Health Organization

The measurements of major and trace elements in different brands of milk powder selected from the Iraqis market via the X-ray fluorescence (XRF) Technique have been studied in the present work. The result of the measurements reveals the high concentrations of sodium, phosphorus, sulfur, chlorine, potassium, calcium and magnesium. Furthermore, low concentrations of aluminum, silicon, iron, bromine, molybdenum, iodine, barium, titanium, manganese, cobalt, chrome, nickel, copper, zinc and lead were detected. Neutron activation analysis (NAA) and Kjeldahl technique were also employed to determine the concentrations of nitrogen. It was found that the nitrogen concentration was in the range of (1.96 - 3.23) % which is within the permissible limits. The concentrations of the trace elements (copper, manganese, zinc, lead) were verified via the atomic absorption spectrometer (AAS) technique. The results are compared with the authorized limit by the food and agriculture organization and the world health organization (FAO/WHO) standards.

Download Full-text

Element Concentrations in NIES Candidate Marine Sediment Certified Reference Material. Reference Values for Major and Trace Elements

Analytical Sciences ◽

10.2116/analsci.12.993 ◽

1996 ◽

Vol 12 (6) ◽

pp. 993-998 ◽

Cited By ~ 8

Author(s):

Jun YOSHINAGA ◽

Atsushi TANAKA ◽

Takejiro TAKAMATSU ◽

Masatoshi MORITA ◽

Kensaku OKAMOTO

Keyword(s):

Trace Elements ◽

Reference Material ◽

Reference Values ◽

Certified Reference Material ◽

Marine Sediment ◽

Major And Trace Elements ◽

Element Concentrations

Download Full-text

Pedo-geochemical baseline content levels and soil quality reference values of trace elements in soils from the Mediterranean (Castilla La Mancha, Spain)

Open Geosciences ◽

10.2478/v10085-010-0028-1 ◽

2010 ◽

Vol 2 (4) ◽

Cited By ~ 17

Author(s):

Raimundo Ballesta ◽

Paz Bueno ◽

Juan Rubi ◽

Rosario Giménez

Keyword(s):

Trace Elements ◽

Trace Element ◽

Soil Quality ◽

Reference Values ◽

Reference Value ◽

Soil Profiles ◽

Geochemical Baseline ◽

Maximum Value ◽

La Mancha ◽

The Mediterranean

AbstractTo evaluate trace element soil contamination, geochemical baseline contents and reference values need to be established. Pedo-geochemical baseline levels of trace elements in 72 soil samples of 24 soil profiles from the Mediterranean, Castilla La Mancha, are assessed and soil quality reference values are calculated. Reference value contents (in mg kg−1) were: Sc 50.8; V 123.2; Cr 113.4; Co 20.8; Ni 42.6; Cu 27.0; Zn 86.5; Ga 26.7; Ge 1.3; As 16.7; Se 1.4; Br 20.1; Rb 234.7; Sr 1868.4; Y 38.3; Zr 413.1; Nb 18.7; Mo 2.0; Ag 7.8; Cd 4.4; Sn 8.7; Sb 5.7; I 25.4; Cs 14.2; Ba 1049.3; La 348.4; Ce 97.9; Nd 40.1; Sm 10.7; Yb 4.2; Hf 10.0; Ta 4.0; W 5.5; Tl 2.3; Pb 44.2; Bi 2.2; Th 21.6; U 10.3. The contents obtained for some elements are below or close to the detection limit: Co, Ge, Se, Mo, Ag, Cd, Sb, Yb, Hf, Ta, W, Tl and Bi. The element content ranges (the maximum value minus the minimum value) are: Sc 55.0, V 196.0, Cr 346.0, Co 64.4, Ni 188.7, Cu 49.5, Zn 102.3, Ga 28.7, Ge 1.5, As 26.4, Se 0.9, Br 33.0 Rb 432.7, Sr 3372.6, Y 39.8, Zr 523.2, Nb 59.7, Mo 3.9, Ag 10.1, Cd 1.8, Sn 75.2, Sb 9.9, I 68.0, Cs 17.6, Ba 1394.9, La 51.3, Ce 93.5, Nd 52.5, Sm 11.2, Yb 4.2, Hf 11.3, Ta 6.3, W 5.2, Tl 2.1, Pb 96.4, Bi 3.0, Th 24.4, U 16.4 (in mg kg−1). The spatial distribution of the elements was affected mainly by the nature of the bedrock and by pedological processes. The upper limit of expected background variation for each trace element in the soil is documented, as is its range as a criterion for evaluating which sites may require decontamination.

Download Full-text

Mineralogical and Geochemical Study of the Zeolitized Volcaniclastic Rocks of Petrota region, Evros Prefecture, Northeastern Greece

Bulletin of the Geological Society of Greece ◽

10.12681/bgsg.20946 ◽

2020 ◽

Vol 56 (1) ◽

pp. 17

Author(s):

Eleni Michailidou ◽

Michael Vavelidis ◽

Lambrini Papadopoulou ◽

Nikolaos Kantiranis

Keyword(s):

Major And Trace Elements ◽

Volcanic Area ◽

Southeastern Part ◽

Quartz Crystals ◽

Geochemical Composition ◽

X Ray ◽

Polarizing Microscope ◽

Geochemical Study ◽

Icp Ms ◽

High Concentrations

The present work studies the tuffs associated with the volcanic area of the Paleogene Sheinovets caldera, located on the southeastern part of the Rhodope massif, in Bulgaria. Its purpose is to describe the mineralogical and geochemical composition of the zeolitized volcaniclastic deposits in the broader area of Petrota village, in the northwesternmost part of the Greek regional unit of Evros, in northeast Greece. The samples studied in this work were collected from seven (7) different locations, covering an area of almost 4 km in length and 2 km in width. Macroscopically, the samples display a greyish-green hue and they are widespread in the area of study. They often contain fragments of the crystalline metamorphic basement (mica-schists, phyllites, amphibolites, quartzites) and/or rhyolitic clasts. A rhyolitic outcrop of greyish-pink hue is observed in the Mavri Petra region, probably related to the Rupelian acid volcanism that occurred in the Sheinovets caldera. The mineralogy of the tuffs was studied under light polarizing microscope and using Scanning Electron Microscopy (SEM), and it was further confirmed by X-ray powder diffraction (XRPD) method. The initial matrix of the tuffs consisted predominantly of glass shards that are now partly or fully altered into zeolites and clay minerals, such as celadonite, displaying characteristic pseudomorphic structures. The dominant zeolite is clinoptilolite, while in some areas the presence of mordenite is also noticed. Feldspar phenocrysts are abundant, and they are represented by plagioclase and sanidine. Although quartz crystals can be observed under light-polarizing microscope solely in metamorphic fragments, the presence of silica polymorphs was also confirmed through SEM and XRPD analysis, with quartz and cristobalite prevailing. The mineralogical assemblage includes phenocrysts of biotite and in some cases amphiboles, while pyroxene, epidote, garnet, titanite, apatite, zircon, ilmenite, magnetite and rutile are additional minerals which have been identified locally in accessory quantities. Chemical analysis was carried out for major and trace elements, using the X-ray fluorescence (XRF) method and 4 Acid digestion ICP-MS analysis, respectively. The samples of Mavri Petra region, exhibit high concentrations in Cu, Pb, Mn, V, P and W. The analyzed concentrations of U in the area of Palaeokklisi are relatively high in comparison to the rest due to its proximity to a fault. Towards the northwestern study area, close to the Greek-Bulgarian border, the concentrations of Sr appear to be particularly high, probably because the area is closer to the volcanic centre.

Download Full-text

Oxidative Stress Status in COVID-19 Patients Hospitalized in Intensive Care Unit for Severe Pneumonia. A Pilot Study

Antioxidants ◽

10.3390/antiox10020257 ◽

2021 ◽

Vol 10 (2) ◽

pp. 257

Author(s):

Joël Pincemail ◽

Etienne Cavalier ◽

Corinne Charlier ◽

Jean-Paul Cheramy–Bien ◽

Eric Brevers ◽

...

Keyword(s):

Oxidative Stress ◽

Intensive Care Unit ◽

Trace Elements ◽

Intensive Care ◽

Vitamin C ◽

Reference Values ◽

Reference Value ◽

Severe Pneumonia ◽

Oxidative Stress Status ◽

Thiol Proteins

Background: A key role of oxidative stress has been highlighted in the pathogenesis of COVID-19. However, little has been said about oxidative stress status (OSS) of COVID-19 patients hospitalized in intensive care unit (ICU). Material and Methods: Biomarkers of the systemic OSS included antioxidants (9 assays), trace elements (3 assays), inflammation markers (4 assays) and oxidative damage to lipids (3 assays). Results: Blood samples were drawn after 9 (7–11) and 41 (39–43) days of ICU stay, respectively in 3 and 6 patients. Vitamin C, thiol proteins, reduced glutathione, γ-tocopherol, β-carotene and PAOT® score were significantly decreased compared to laboratory reference values. Selenium concentration was at the limit of the lower reference value. By contrast, the copper/zinc ratio (as a source of oxidative stress) was higher than reference values in 55% of patients while copper was significantly correlated with lipid peroxides (r = 0.95, p < 0.001). Inflammatory biomarkers (C-reactive protein and myeloperoxidase) were significantly increased when compared to normals. Conclusions: The systemic OSS was strongly altered in critically ill COVID-19 patients as evidenced by increased lipid peroxidation but also by deficits in some antioxidants (vitamin C, glutathione, thiol proteins) and trace elements (selenium).

Download Full-text

An Influence of the Fuel Type on Element Behaviour in Domestic Boilers with Respect to the Circular Economy

Applied Sciences ◽

10.3390/app11114980 ◽

2021 ◽

Vol 11 (11) ◽

pp. 4980

Author(s):

Helena Raclavská ◽

Pavel Kantor ◽

Jana Růžičková ◽

Marek Kucbel ◽

Barbora Švédová ◽

...

Keyword(s):

Trace Elements ◽

Circular Economy ◽

Total Content ◽

Major And Trace Elements ◽

Major Elements ◽

Waste Paper ◽

Waste Wood ◽

Residential Combustion ◽

High Concentrations ◽

Local Emissions

The use of waste from the regional production of waste wood, waste paper, and cardboard in the form of briquettes may be causing an increase in local emissions, both of major elements and trace elements. When burning paper and cardboard briquettes, more than 70% of Mn, Zn, As, and Pb is released into the air from the total content of trace elements in the fuel. The largest amounts of major and trace elements are released when burning paper briquettes (56 g/kg of fuel); half of these amounts are released from burning briquettes from waste wood and coal (23 g/kg of fuel). The pursuit of alternative uses for those cardboard components that are not suitable for recycling cannot be directed to the production of briquettes for residential combustion in the framework of the application of the principles of the circular economy. In particular, the high concentrations of undesirable elements in the emissions released in the gas phase into the atmosphere are an obstacle existing even when the parameters of the PM10 emissions of a boiler are met. This is related to the high ash content of the cardboard (13.5%). Waste paper or cardboard could be added to waste wood at a maximum of 10% to make the pollution produced comparable to the burning of coal briquettes.

Download Full-text

Major and Trace Elements in the Humic Acid

10.26434/chemrxiv.7122413.v1 ◽

2018 ◽

Author(s):

Zoltán Kis ◽

Katalin Gméling ◽

Tímea Kocsis ◽

János Osán ◽

Mihály András Pocsai ◽

...

Keyword(s):

Trace Elements ◽

Humic Acid ◽

Activation Analysis ◽

Analytical Techniques ◽

Major And Trace Elements ◽

Prompt Gamma Activation Analysis ◽

Prompt Gamma ◽

Gamma Activation ◽

X Ray ◽

Precise Analysis

We present precise analysis of major and trace elements of the humic acid. We used three different element analytical techniques in our investigations as prompt-gamma activation analysis (PGAA), neutron activation analysis (NAA) and X-ray fluorescence (XRF) analysis was carried out. We identified 42 elements in our sample.

Download Full-text