scholarly journals Live-Scale Testing of Granular Materials Stabilized with Alkali-Activated Waste Glass and Carbide Lime

2021 ◽  
Vol 11 (23) ◽  
pp. 11286
Author(s):  
Marina Paula Secco ◽  
Débora Thaís Mesavilla ◽  
Márcio Felipe Floss ◽  
Nilo Cesar Consoli ◽  
Tiago Miranda ◽  
...  
Keyword(s):  
Portland Cement ◽  
Mechanical Performance ◽  
Raw Materials ◽  
Sodium Hydroxide Solution ◽  
Fine Sand ◽  
Field Application ◽  
Natural Soil ◽  
In Situ Tests ◽  
Alkali Activated

The increasingly strong search for alternative materials to Portland cement has resulted in the development of alkali-activated cements (AAC) that are very effective at using industrial by-products as raw materials, which also contributes to the volume reduction in landfilled waste. Several studies targeting the development of AAC—based on wastes containing silicon and calcium—for chemical stabilization of soils have demonstrated their excellent performance in terms of durability and mechanical performance. However, most of these studies are confined to a laboratory characterization, ignoring the influence and viability of the in situ construction process and, also important, of the in situ curing conditions. The present work investigated the field application of an AAC based on carbide lime and glass wastes to stabilize fine sand acting as a superficial foundation. The assessment was supported on the unconfined compressive strength (UCS) and initial shear modulus (G0) of the developed material, and the field results were compared with those prepared in the laboratory, up to 120 days curing. In situ tests were also developed on the field layers (with diameters of 450 and 900 mm and thickness of 300 mm) after different curing times. To establish a reference, the mentioned precursors were either activated with a sodium hydroxide solution or hydrated with water (given the reactivity of the lime). The results showed that the AAC-based mixtures developed greater strength and stiffness at a faster rate than the water-based mixtures. Specimens cured under controlled laboratory conditions showed better results than the samples collected in the field. The inclusion of the stabilized layers clearly increased the load-bearing capacity of the natural soil, while the different diameters produced different failure mechanisms, similar to those found in Portland cement stabilization.

scholarly journals Low-Carbon Concrete Based on Binary Biomass Ash–Silica Fume Binder to Produce Eco-Friendly Paving Blocks

Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1534 ◽  
Author(s):  
André Henrique Campos Teixeira ◽  
Paulo Roberto Ribeiro Soares Junior ◽  
Thiago Henrique Silva ◽  
Richard Rodrigues Barreto ◽  
Augusto Cesar da Silva Bezerra
Keyword(s):  
Organic Matter ◽  
Portland Cement ◽  
Silica Fume ◽  
Raw Materials ◽  
Sodium Hydroxide Solution ◽  
Alkali Activation ◽  
Low Carbon ◽  
Biomass Ash ◽  
Microstructural Investigation ◽  
Alkali Activated

The civil construction industry consumes huge amounts of raw materials and energy, especially infrastructure. Thus, the use of eco-friendly materials is indispensable to promote sustainable development. In this context, the present work investigated low-carbon concrete to produce eco-friendly paving blocks. The binder was defined according to two approaches. In the first, a binary binder developed with eucalyptus biomass ash (EBA) and silica fume (SF) was used, in total replacement for Portland cement. In the second, the mixture of residues was used as a precursor in alkali-activation reactions, forming alkali-activated binder. The experimental approach was carried out using five different mixtures, obtained by varying the amount of water or sodium hydroxide solution. The characterization of this new material was carried out using compressive strength, expandability, water absorption, deep abrasion, microstructural investigation, and organic matter degradation potential. The results showed that the EBA-SF system has a performance compatible with Portland cement when used as an alternative binder, in addition to functioning as a precursor to alkali-activated concrete. The blocks produced degraded organic matter, and this degradation is more intense with the incidence of UV. In this way, the EBA-SF binder can be successfully used for the manufacture of ecological paving blocks with low carbon emissions.

scholarly journals Laboratory and In Situ Determination of Hydraulic Conductivity and Their Validity in Transient Seepage Analysis

Water ◽  
2021 ◽  
Vol 13 (8) ◽  
pp. 1131
Author(s):  
Soonkie Nam ◽  
Marte Gutierrez ◽  
Panayiotis Diplas ◽  
John Petrie
Keyword(s):  
Hydraulic Conductivity ◽  
Field Measurements ◽  
Natural Soil ◽  
In Situ Tests ◽  
Seepage Analysis ◽  
Soil Deposits ◽  
Seepage Modeling ◽  
Sample Disturbance

This paper critically compares the use of laboratory tests against in situ tests combined with numerical seepage modeling to determine the hydraulic conductivity of natural soil deposits. Laboratory determination of hydraulic conductivity used the constant head permeability and oedometer tests on undisturbed Shelby tube and block soil samples. The auger hole method and Guelph permeameter tests were performed in the field. Groundwater table elevations in natural soil deposits with different hydraulic conductivity values were predicted using finite element seepage modeling and compared with field measurements to assess the various test results. Hydraulic conductivity values obtained by the auger hole method provide predictions that best match the groundwater table’s observed location at the field site. This observation indicates that hydraulic conductivity determined by the in situ test represents the actual conditions in the field better than that determined in a laboratory setting. The differences between the laboratory and in situ hydraulic conductivity values can be attributed to factors such as sample disturbance, soil anisotropy, fissures and cracks, and soil structure in addition to the conceptual and procedural differences in testing methods and effects of sample size.

scholarly journals Volcanic Ash as a Sustainable Binder Material: An Extensive Review

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1302
Author(s):  
Andrés Játiva ◽  
Evelyn Ruales ◽  
Miren Etxeberria
Keyword(s):  
Chemical Composition ◽  
Portland Cement ◽  
Urban Areas ◽  
Volcanic Ash ◽  
Mechanical Performance ◽  
Cement Clinker ◽  
Alkali Activation ◽  
Cement Production ◽  
Sustainable Solutions ◽  
Alkali Activated

The construction industry is affected by the constant growth in the populations of urban areas. The demand for cement production has an increasing environmental impact, and there are urgent demands for alternative sustainable solutions. Volcanic ash (VA) is an abundant low-cost material that, because of its chemical composition and amorphous atomic structure, has been considered as a suitable material to replace Portland cement clinker for use as a binder in cement production. In the last decade, there has been interest in using alkali-activated VA material as an alternative material to replace ordinary Portland cement. In this way, a valuable product may be derived from a currently under-utilized material. Additionally, alkali-activated VA-based materials may be suitable for building applications because of their good densification behaviour, mechanical properties and low porosity. This article describes the most relevant findings from researchers around the world on the role of the chemical composition and mineral contents of VA on reactivity during the alkali-activation reaction; the effect of synthesis factors, which include the concentration of the alkaline activator, the solution-to-binder ratio and the curing conditions, on the properties of alkali-activated VA-based materials; and the mechanical performance and durability properties of these materials.

scholarly journals Research on Eco-friendly Alkali Activated Concrete Incorporating Industrial Wastes

2019 ◽  
Vol 8 (9S2) ◽  
pp. 477-482
Keyword(s):  
Raw Materials ◽  
Sodium Hydroxide Solution ◽  
Industrial Wastes ◽  
Liquid Sodium ◽  
Alkali Activation ◽  
Waste Glass Powder ◽  
Fine Aggregates ◽  
Alkaline Activator ◽  
Alkali Activated Concrete ◽  
Alkali Activated

In the present scenario, the production of green and sustainable concrete has become a must to substitute the ordinary Portland cement (OPC) concrete. It is an eminent fact that the manufacture of OPC requires burning of its raw materials which lead to a huge amount of carbon dioxide liberation; thus it requires a large amount of energy dissipation. The concrete produced using alkali activation has become renowned methods to replace the conventional OPC, which gives an answer to find a way to produce environmentally friendly concrete. In the current study, the alkaline activator used to activate the binder was sodium hydroxide solution dispersed in liquid sodium silicate. The utilization of industrial dissipate materials such as GGBS, fly ash, and waste glass powder was used as the binding ingredients, and stone crusher dust was used as fine aggregates. The experimental investigation showed that a quality concrete can be easily produced using alkali activation of industrial wastes satisfying its strength requirements. The statistical models developed shown that there is a significant relationship between various cube and cylinder strengths. Thus alkali-activated concrete(AAC) can effectively reduce the environmental hazards associated with OPC concrete, which also provides an effective way of utilizing major industrial byproducts

scholarly journals Alkali-Activated Hybrid Cements Based on Fly Ash and Construction and Demolition Wastes Using Sodium Sulfate and Sodium Carbonate

Molecules ◽  
2021 ◽  
Vol 26 (24) ◽  
pp. 7572
Author(s):  
William Valencia-Saavedra ◽  
Rafael Robayo-Salazar ◽  
Ruby Mejía de Gutiérrez
Keyword(s):  
Compressive Strength ◽  
Fly Ash ◽  
Portland Cement ◽  
Sodium Carbonate ◽  
Sodium Sulfate ◽  
Room Temperature ◽  
Ordinary Portland Cement ◽  
Mechanical Performance ◽  
Construction And Demolition Wastes ◽  
Alkali Activated

This article demonstrates the possibility of producing alkali-activated hybrid cements based on fly ash (FA), and construction and demolition wastes (concrete waste, COW; ceramic waste, CEW; and masonry waste, MAW) using sodium sulfate (Na2SO4) (2–6%) and sodium carbonate (Na2CO3) (5–10%) as activators. From a mixture of COW, CEW, and MAW in equal proportions (33.33%), a new precursor called CDW was generated. The precursors were mixed with ordinary Portland cement (OPC) (10–30%). Curing of the materials was performed at room temperature (25 °C). The hybrid cements activated with Na2SO4 reached compressive strengths of up to 31 MPa at 28 days of curing, and the hybrid cements activated with Na2CO3 yielded compressive strengths of up to 22 MPa. Based on their mechanical performance, the optimal mixtures were selected: FA/30OPC-4%Na2SO4, CDW/30OPC-4%Na2SO4, FA/30OPC-10%Na2CO3, and CDW/30OPC-10%Na2CO3. At prolonged ages (180 days), these mixtures reached compressive strength values similar to those reported for pastes based on 100% OPC. A notable advantage is the reduction of the heat of the reaction, which can be reduced by up to 10 times relative to that reported for the hydration of Portland cement. These results show the feasibility of manufacturing alkaline-activated hybrid cements using alternative activators with a lower environmental impact.

Alkali Activated Binders Based on Metakaolin

2015 ◽  
Vol 1 ◽  
pp. 200
Author(s):  
Laura Sele ◽  
Diana Bajare ◽  
Girts Bumanis ◽  
Laura Dembovska
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Water Absorption ◽  
Raw Materials ◽  
Sodium Silicate Solution ◽  
Total Porosity ◽  
Lead Silicate ◽  
Cement Production ◽  
Alkali Activated Binders ◽  
Alkali Activated

<p>According to research conducted in last 25 years, alkali activated binders have been considered as one of the most progressive alternative binders, which can effectively replace Portland cement. Production of alkali activated binders differs from the Portland cement production and is associated with lower CO2 emissions. The use of recycled industrial by-products and wastes is also possible, what corresponds to the future guidelines and principles of sustainable binder production in the world.<br />The aim of this study was to create innovative alkali activated binders by using secondary raw materials, which will be different from the ones described in the scientific literature – alkali activated binders with porous structure. Raw materials used for the binders were metakaolin containing waste, waste from aluminium scrap recycling factory and recycled lead-silicate glass; solid contents were activated with modified sodium silicate solution with an addition of sodium hydroxide.<br />The physical properties of alkali activated binders, such as density, water absorption, open and total porosity, were determined and flexural and compressive strength of hardened alkali-activated binders were tested at the age of 28 days. Durability was examined by sulphate resistance test, which was performed according to SIA 262/1, appendix D: applicability and relevance for use in practice. 40x40x160 mm prismatic specimens were used for expansion measurement and determination of compressive strength. <br />The open porosity of obtained materials was up to 45%, density from 380 to 1720 kg/m3, compressive strength up to 29,8 MPa, water absorption 6 – 114 wt.%. After analysing the results from the sulphate test it was concluded that glass additive reduced the alkali activated binder resistance to sulphate attack.</p>

NDT Monitoring of Alkali-Activated Material Carbonation

2020 ◽  
Vol 868 ◽  
pp. 45-50
Author(s):  
Iveta Plšková ◽  
Michal Matysík ◽  
Libor Topolář ◽  
Petr Hrubý
Keyword(s):  
Portland Cement ◽  
Raw Materials ◽  
Ultrasound Velocity ◽  
Degradation Process ◽  
Dominant Frequency ◽  
Impact Echo ◽  
The Impact ◽  
Non Destructive ◽  
Impact Echo Method ◽  
Alkali Activated

Production of Portland cement is relatively environmentally demanding (high CO2 emissions, extraction of raw materials for its production). Alkali-activated materials are an alternative to conventional Portland cement in the production of concrete. For alkali-activated binder concretes, their ability to withstand corrosive environments and their ability to protect steel reinforcement must be assessed. It is also necessary to know the suitability of non-destructive methods for monitoring the degradation process of these concretes. The paper deals with the carbonation monitoring of concrete with alkali-activated binder (slag) by the impact-echo method. Slag activated by sodium hydroxide (NaOH) was used as a binder. The specimens were tested by the non-destructive method (Impact-echo, ultrasound velocity). We focused on the shift of the dominant frequency obtained by the Impact-echo method.

Review of Geopolymer Materials for Thermal Insulating Applications

2015 ◽  
Vol 660 ◽  
pp. 17-22 ◽  
Author(s):  
Emy Aizat Azimi ◽  
Mohd Mustafa Al Bakri Abdullah ◽  
Liew Yun Ming ◽  
Cheng Yong Heah ◽  
Kamarudin Hussin ◽  
...  
Keyword(s):  
Chemical Resistance ◽  
Mechanical Performance ◽  
Raw Materials ◽  
Good Resistance ◽  
Thermal Insulating ◽  
Cementitious Binder ◽  
Alkali Activated Binders ◽  
Alkali Activated ◽  
Geopolymer Composites ◽  
Geopolymer Material

Geopolymer is an environmentally cementitious binder that does not require the existence of ordinary Portland cement (OPC). Geopolymer has many excellent advantages, including high early strength, low shrinkage, good thermal resistance and good chemical resistance. Based on previous research, geopolymer offered good resistance to corrosion, abrasion and heat. Fly ash, metakaolin, kaolin, and slag are regularly used raw materials for the preparation of geopolymer composites. Geopolymer composites also offer a potential environmental friendly product by reduce the carbon dioxide (CO2) emissions. This geopolymer material also offers an innovative and sustainable solution for maintaining infrastructure and also provides superior thermal, chemical and mechanical performance. This paper summarizes some research outcomes on alkali-activated binders along with the potential of geopolymer composites for thermal insulating applications.

Effect of Polymer Admixtures on Metakaolin-Based Geopolymer

2016 ◽  
Vol 865 ◽  
pp. 67-71 ◽  
Author(s):  
Olesia Mikhailova ◽  
Pavel Rovnaník
Keyword(s):  
Compressive Strength ◽  
Flexural Strength ◽  
Portland Cement ◽  
Pore Size Distribution ◽  
Water Demand ◽  
Ordinary Portland Cement ◽  
Raw Materials ◽  
Inorganic Materials ◽  
Maximum Compressive Strength ◽  
Alkali Activated

Geopolymers are presented in many studies as binders alternative to ordinary Portland cement. Several inorganic materials have been used as raw materials for the production of geopolymers. One of them is metakaolin which is produced by dehydroxylation of kaolin. Metakaolin has a much larger surface area than cement, resulting in an increase in water demand to maintain workability. Polymer admixtures may contribute to reduction of this demand. However, another problem should be considered: plasticizers which improve rheological properties in cement technology are not effective for geopolymers. The aim of this study was to analyze the effect of different polymer admixtures on the compressive and flexural strength, pore size distribution and microstructure of alkali-activated metakaolin material. The results revealed that a maximum compressive strength of 18.6 MPa was achieved by adding 1.5% of VINNAPAS 7016 F, and a maximum flexural strength of 2.2 MPa when adding 0.5 or 1% of the same polymer admixture.

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