scholarly journals Three-Year Variations in Criteria Atmospheric Pollutants and Their Relationship with Rainwater Chemistry in Karst Urban Region, Southwest China

Atmosphere ◽  
2021 ◽  
Vol 12 (8) ◽  
pp. 1073
Author(s):  
Jie Zeng ◽  
Xin Ge ◽  
Qixin Wu ◽  
Shitong Zhang

Air pollutants have been investigated in many studies, but the variations of atmospheric pollutants and their relationship with rainwater chemistry are not well studied. In the present study, the criteria atmospheric pollutants in nine monitoring stations and rainwater chemistry were analyzed in karst Guiyang city, since the time when the Chinese Ambient Air Quality Standards (CAAQS, third revision) were published. Based on the three-year daily concentration dataset of SO2, NO2, CO, PM10 and PM2.5, although most of air pollutant concentrations were within the limit of CAAQS III-Grade II standard, the significant spatial variations and relatively heavy pollution were found in downtown Guiyang. Temporally, the average concentrations of almost all air pollutants (except for CO) decreased during three years at all stations. Ratios of PM2.5/PM10 in non- and episode days reflected the different contributions of fine and coarse particles on particulate matter in Guiyang, which was influenced by the potential meteorological factors and source variations. According to the individual air quality index (IAQI), the seasonal variations of air quality level were observed, that is, IAQI values of air pollutants were higher in winter (worst air quality) and lower in summer (best air quality) due to seasonal variations in emission sources. The unique IAQI variations were found during the Chinese Spring Festival. Air pollutant concentrations are also influenced by meteorological parameters, in particular, the rainfall amount. The air pollutants are well scoured by the rainfall process and can significantly affect rainwater chemistry, such as SO42−, NO3−, Mg2+, and Ca2+, which further alters the acidification/alkalization trend of rainwater. The equivalent ratios of rainwater SO42−/NO3− and Mg2+/Ca2+ indicated the significant contribution of fixed emission sources (e.g., coal combustion) and carbonate weathering-influenced particulate matter on rainwater chemistry. These findings provide scientific support for air pollution management and rainwater chemistry-related environmental issues.

2020 ◽  
Author(s):  
Zhiyuan Li ◽  
Steve Hung Lam Yim ◽  
Kin-Fai Ho

<p>Land use regression (LUR) models estimate air pollutant concentrations for areas without air quality measurements, which provides valuable information for exposure assessment and epidemiological studies. In the present study, we developed LUR models for ambient air pollutants in Hong Kong, China, a typical high-density and high-rise city. Air quality measurements at sixteen air quality monitoring stations, operated by the Hong Kong Environmental Protection Department, were collected. Moreover, five categories of predictor variables, including population distribution, traffic emissions, land use variables, urban/building morphology, and meteorological parameters, were employed to establish the LUR models of various air pollutants. Then the spatial distribution of air pollutant concentrations at 1 km × 1 km grid cells were plotted. Taking fine particle (PM2.5) as an example, the developed LUR model explained 89% of variability of PM2.5 concentrations, with a leave-one-out-cross-validation R2 of 0.64. LUR modelling results for other air pollutants will be presented. In addition, further improvements on the development of LUR models will be discussed. This study can help to assess long-term exposures to air pollutants for high-density and high-rise urban areas like Hong Kong.</p>


2021 ◽  
Vol 13 (21) ◽  
pp. 12217
Author(s):  
Mohd Shahrul Mohd Nadzir ◽  
Mohd Zaim Mohd Nor ◽  
Mohd Fadzil Firdzaus Mohd Nor ◽  
Muhamad Ikram A Wahab ◽  
Sawal Hamid Md Ali ◽  
...  

Globally, the COVID-19 pandemic has had both positive and negative impacts on humans and the environment. In general, a positive impact can be seen on the environment, especially in regard to air quality. This positive impact on air quality around the world is a result of movement control orders (MCO) or lockdowns, which were carried out to reduce the cases of COVID-19 around the world. Nevertheless, data on the effects on air quality both during and post lockdown at local scales are still sparse. Here, we investigate changes in air quality during normal days, the MCOs (MCO 1, 2 and 3) and post MCOs, namely the Conditional Movement Control Order (CMCO) and the Recovery Movement Control Order (RMCO) in the Klang Valley region. In this study, we used the air sensor network AiRBOXSense that measures carbon monoxide (CO), nitrogen dioxide (NO2), sulfur dioxide (SO2) and particulate matter (PM2.5 and PM10) at Petaling Jaya South (PJS), Kelana Jaya (KJ) and Kota Damansara (KD). The results showed that the daily average concentrations of CO and NO2 mostly decreased in the order of normal days > MCO (MCO 1, 2 and 3) > CMCO > RMCO. PM10, PM2.5, SO2 and O3 showed a decrease from the MCO to RMCO. PJS showed that air pollutant concentrations decreased from normal days to the lockdown phases. This clearly shows the effects of ‘work from home’ orders at all places in the PJS city. The greatest percentage reductions in air pollutants were observed during the change from normal days to MCO 1 (24% to 64%), while during MCO 1 to MCO 2, the concentrations were slightly increased during the changes of the lockdown phase, except for SO2 and NO2 over PJS. In KJ, most of the air pollutants decreased from MCO 1 to MCO 3 except for CO. However, the percentage reduction and increments of the gas pollutants were not consistent during the different phases of lockdown, and this effect was due to the sensor location—only 20 m from the main highway (vehicle emissions). The patterns of air pollutant concentrations over the KD site were similar to the PJS site; however, the percentage reduction and increases of PM2.5, O3, SO2 and CO were not consistent. We believe that local burning was the main contribution to these unstable patterns during the lockdown period. The cause of these different changes in concentrations may be due to the relaxation phases during the lockdown at each station, where most of the common activities, such as commuting and industrial activities changed in frequency from the MCO, CMCO and RMCO. Wind direction also affected the concentrations, for example, during the CMCO and RMCO, most of the pollutants were blowing in from the Southeast region, which mostly consists of a city center and industrial areas. There was a weak correlation between air pollutants and the temperature and relative humidity at all stations. Health risk assessment analysis showed that non-carcinogenic risk health quotient (HQ) values for the pollutants at all stations were less than 1, suggesting unlikely non-carcinogenic effects, except for SO2 (HQ > 1) in KJ. The air quality information showed that reductions in air pollutants can be achieved if traffic and industry emissions are strictly controlled.


Author(s):  
Laura Goulier ◽  
Bastian Paas ◽  
Laura Ehrnsperger ◽  
Otto Klemm

Since operating urban air quality stations is not only time consuming but also costly, and because air pollutants can cause serious health problems, this paper presents the hourly prediction of ten air pollutant concentrations (CO2, NH3, NO, NO2, NOx, O3, PM1, PM2.5, PM10 and PN10) in a street canyon in Münster using an artificial neural network (ANN) approach. Special attention was paid to comparing three predictor options representing the traffic volume: we included acoustic sound measurements (sound), the total number of vehicles (traffic), and the hour of the day and the day of the week (time) as input variables and then compared their prediction powers. The models were trained, validated and tested to evaluate their performance. Results showed that the predictions of the gaseous air pollutants NO, NO2, NOx, and O3 reveal very good agreement with observations, whereas predictions for particle concentrations and NH3 were less successful, indicating that these models can be improved. All three input variable options (sound, traffic and time) proved to be suitable and showed distinct strengths for modelling various air pollutant concentrations.


Author(s):  
B. Yorkor ◽  
T. G. Leton ◽  
J. N. Ugbebor

This study investigated the temporal variations of air pollutant concentrations in Ogoni area, Niger Delta, Nigeria. The study used hourly data measured over 8 hours for 12 months at selected locations within the area. The analyses were based on time series and time variations techniques in Openair packages of R programming software. The variations of air pollutant concentrations by time of day and days of week were simulated. Hours of the day, days of the week and monthly variations were graphically simulated. Variations in the mean concentrations of air pollutants by time were determined at 95 % confidence intervals. Sulphur dioxide (SO2), Nitrogen dioxide (NO2), ground level Ozone (O3) and fine particulate matter (PM2.5) concentrations exceeded permissible standards. Air pollutant concentrations showed increase in January, February, November and December compared to other months. Simulation showed that air pollutants varied significantly by hours-of-the-day and days-of-the-week and months-of-the-year. Analysis of temporal variability revealed that air pollutant concentrations increased during weekdays and decreased during weekends. The temporal variability of air pollutants in Ogoni area showed that anthropogenic activities were the main sources of air pollution in the area, therefore further studies are required to determine air pollutant dispersion pattern and evaluation the potential sources of air pollution in the area.


2021 ◽  
pp. 045
Author(s):  
Jimmy Leyes ◽  
Laure Roussel

La surveillance réglementaire de la qualité de l'air en France est confiée aux associations régionales agréées de surveillance de la qualité de l'air (Aasqa) telles qu'Atmo Hauts-de-France. Elles s'appuient sur une palette d'outils et leur expertise pour mesurer les polluants dans l'air de leur territoire, alerter les populations en cas d'épisode de pollution, répondre aux exigences réglementaires de surveillance définies au niveau européen, tout en prenant en compte les spécificités régionales. Cet article présente les différents outils utilisés par les Aasqa, et plus particulièrement Atmo Hauts-de-France, pour surveiller et estimer la qualité de l'air. L'association régionale opère ainsi un ensemble de stations de mesures fixes et mobiles pour suivre en continu les concentrations de polluants réglementés ou non sur son territoire, et dispose d'outils de modélisation pour évaluer et prévoir la qualité de l'air en tous points de la région. Cet article présente également certains des paramètres météorologiques qui influencent la qualité de l'air de la région Hauts-de-France, particulièrement concernée par les épisodes de pollution aux particules. Regulatory air quality monitoring in France is performed by government-approved non-profit organisations called AASQAs, one of which is Atmo Hauts-de-France. These organisations rely on decades of accumulated air quality expertise and use several techniques to measure air pollutant concentrations, inform the public when pollutant levels are unhealthy, and comply with E.U. air quality monitoring regulations. This paper gives an overview of the tools used by AASQAs, and more particularly by Atmo Hauts-de-France, to monitor and forecast air quality. The year-round continuous monitoring of air pollutant levels at fixed sites is supplemented by short-term measurements made with fully-equipped vehicles or trailers and by modelling tools that forecast air quality and estimate pollutant levels where there are no measurements. AASQAs study pollutants which ambient concentrations are regulated by European air quality standards as well as other pollutants which are not regulated in this way. This work also discusses some of the meteorological factors, that affect air quality in the region Hauts-de-France, which is heavily impacted by particulate matter pollution.


Author(s):  
Han Cao ◽  
Bingxiao Li ◽  
Tianlun Gu ◽  
Xiaohui Liu ◽  
Kai Meng ◽  
...  

Evidence regarding the effects of environmental factors on COVID-19 transmission is mixed. We aimed to explore the associations of air pollutants and meteorological factors with COVID-19 confirmed cases during the outbreak period throughout China. The number of COVID-19 confirmed cases, air pollutant concentrations, and meteorological factors in China from January 25 to February 29, 2020, (36 days) were extracted from authoritative electronic databases. The associations were estimated for a single-day lag as well as moving averages lag using generalized additive mixed models. Region-specific analyses and meta-analysis were conducted in 5 selected regions from the north to south of China with diverse air pollution levels and weather conditions and sufficient sample size. Nonlinear concentration–response analyses were performed. An increase of each interquartile range in PM2.5, PM10, SO2, NO2, O3, and CO at lag4 corresponded to 1.40 (1.37–1.43), 1.35 (1.32–1.37), 1.01 (1.00–1.02), 1.08 (1.07–1.10), 1.28 (1.27–1.29), and 1.26 (1.24–1.28) ORs of daily new cases, respectively. For 1°C, 1%, and 1 m/s increase in temperature, relative humidity, and wind velocity, the ORs were 0.97 (0.97–0.98), 0.96 (0.96–0.97), and 0.94 (0.92–0.95), respectively. The estimates of PM2.5, PM10, NO2, and all meteorological factors remained significantly after meta-analysis for the five selected regions. The concentration–response relationships showed that higher concentrations of air pollutants and lower meteorological factors were associated with daily new cases increasing. Higher air pollutant concentrations and lower temperature, relative humidity and wind velocity may favor COVID-19 transmission. Controlling ambient air pollution, especially for PM2.5, PM10, NO2, may be an important component of reducing risk of COVID-19 infection. In addition, as winter months are arriving in China, the meteorological factors may play a negative role in prevention. Therefore, it is significant to implement the public health control measures persistently in case another possible pandemic.


2021 ◽  
Vol 2139 (1) ◽  
pp. 012002
Author(s):  
L A Manco-Perdomo ◽  
L A Pérez-Padilla ◽  
C A Zafra-Mejía

Abstract The objective of this paper is to show an intervention analysis with autoregressive integrated moving average models for time series of air pollutants in a Latin American megacity. The interventions considered in this study correspond to public regulations for the control of urban air quality. The study period comprised 10 years. Information from 10 monitoring stations distributed throughout the megacity was used. Modelling showed that setting maximum emission limits for different pollution sources and improving fuel were the most appropriate regulatory interventions to reduce air pollutant concentrations. Modelling results also suggested that these interventions began to be effective between the first 4 days-15 days after their publication. The models developed on a monthly timescale had a short autoregressive memory. The air pollutant concentrations at a given time were influenced by the concentrations of up to three months immediately preceding. Moving average term of the models showed fluctuations in time of the air pollutant concentrations (3 months - 14 months). Within the framework of the applications of physics for the air pollution control, this study is relevant for the following findings: the usefulness of autoregressive integrated moving average models to temporal simulate air pollutants, and for its suitable performance to detect and quantify regulatory interventions.


2019 ◽  
Vol 19 (12) ◽  
pp. 8209-8228 ◽  
Author(s):  
Min Zhong ◽  
Eri Saikawa ◽  
Alexander Avramov ◽  
Chen Chen ◽  
Boya Sun ◽  
...  

Abstract. Air pollution is one of the most pressing environmental issues in the Kathmandu Valley, where the capital city of Nepal is located. We estimated emissions from two of the major source types in the valley (vehicles and brick kilns) and analyzed the corresponding impacts on regional air quality. First, we estimated the on-road vehicle emissions in the valley using the International Vehicle Emissions (IVE) model with local emissions factors and the latest available data for vehicle registration. We also identified the locations of the brick kilns in the Kathmandu Valley and developed an emissions inventory for these kilns using emissions factors measured during the Nepal Ambient Monitoring and Source Testing Experiment (NAMaSTE) field campaign in April 2015. Our results indicate that the commonly used global emissions inventory, the Hemispheric Transport of Air Pollution (HTAP_v2.2), underestimates particulate matter emissions from vehicles in the Kathmandu Valley by a factor greater than 100. HTAP_v2.2 does not include the brick sector and we found that our sulfur dioxide (SO2) emissions estimates from brick kilns are comparable to 70 % of the total SO2 emissions considered in HTAP_v2.2. Next, we simulated air quality using the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) for April 2015 based on three different emissions scenarios: HTAP only, HTAP with updated vehicle emissions, and HTAP with both updated vehicle and brick kilns emissions. Comparisons between simulated results and observations indicate that the model underestimates observed surface elemental carbon (EC) and SO2 concentrations under all emissions scenarios. However, our updated estimates of vehicle emissions significantly reduced model bias for EC, while updated emissions from brick kilns improved model performance in simulating SO2. These results highlight the importance of improving local emissions estimates for air quality modeling. We further find that model overestimation of surface wind leads to underestimated air pollutant concentrations in the Kathmandu Valley. Future work should focus on improving local emissions estimates for other major and underrepresented sources (e.g., crop residue burning and garbage burning) with a high spatial resolution, as well as the model's boundary-layer representation, to capture strong spatial gradients of air pollutant concentrations.


2021 ◽  
Author(s):  
Arnab Mondal ◽  
Asha Sunilkumar ◽  
Shishir Kumar Singh ◽  
Surajit Mondal ◽  
Amit Kumar Mondal

Abstract In the beginning of March 2020, cases of CoVID-19 infections began rising worldwide, reacting to which the Government of India called for nationwide lockdown initially for March 25th to April 14th, 2020 and later extended it in phases till May 31st, 2020. Due to the forced restrictions pan-India on every level, the move led to drastic drop in pollution levels. The results demonstrated that during lockdown air quality is significantly improved and the pollution levels of PM2.5, PM10, SO2 and NO2 reduced drastically during the lockdown period than the preceding year for the same time frame. A direct relationship has been established between the high level of air pollutants (PM2.5, PM10, NO2 and SO2) and CoVID-19 infections being reported in these Indian cities. The correlation indicates that the air pollutants like PM2.5, PM10, NO2 and SO2 are aggravating the number of casualties due to the CoVID-19 infections. The high-level exposure of PM2.5 over a long period is found to be significantly correlated with the mortality per unit confirmed CoVID-19 cases as compared to other air pollutant parameters like PM10, NO2 and SO2.


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